PL82249B1 - - Google Patents
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- Publication number
- PL82249B1 PL82249B1 PL1971149494A PL14949471A PL82249B1 PL 82249 B1 PL82249 B1 PL 82249B1 PL 1971149494 A PL1971149494 A PL 1971149494A PL 14949471 A PL14949471 A PL 14949471A PL 82249 B1 PL82249 B1 PL 82249B1
- Authority
- PL
- Poland
- Prior art keywords
- fleece
- bath
- surface layer
- smoothing
- dried
- Prior art date
Links
- 238000000034 method Methods 0.000 claims description 11
- 238000005507 spraying Methods 0.000 claims description 9
- 239000002649 leather substitute Substances 0.000 claims description 7
- 239000002344 surface layer Substances 0.000 claims description 7
- 230000015271 coagulation Effects 0.000 claims description 6
- 238000005345 coagulation Methods 0.000 claims description 6
- 238000009499 grossing Methods 0.000 claims description 6
- 229920002635 polyurethane Polymers 0.000 claims description 6
- 239000004814 polyurethane Substances 0.000 claims description 6
- 239000004816 latex Substances 0.000 claims description 5
- 229920000126 latex Polymers 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 3
- 239000003995 emulsifying agent Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 239000004848 polyfunctional curative Substances 0.000 claims description 2
- 239000011230 binding agent Substances 0.000 description 4
- 239000000835 fiber Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 230000000659 thermocoagulation Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
- D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
- D04H1/48—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres in combination with at least one other method of consolidation
- D04H1/482—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres in combination with at least one other method of consolidation in combination with shrinkage
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/04—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres having existing or potential cohesive properties, e.g. natural fibres, prestretched or fibrillated artificial fibres
- D04H1/06—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres having existing or potential cohesive properties, e.g. natural fibres, prestretched or fibrillated artificial fibres by treatment to produce shrinking, swelling, crimping or curling of fibres
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
- D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
- D04H1/48—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres in combination with at least one other method of consolidation
- D04H1/488—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres in combination with at least one other method of consolidation in combination with bonding agents
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
- D04H1/645—Impregnation followed by a solidification process
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
- D04H1/655—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions characterised by the apparatus for applying bonding agents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0025—Rubber threads; Elastomeric fibres; Stretchable, bulked or crimped fibres; Retractable, crimpable fibres; Shrinking or stretching of fibres during manufacture; Obliquely threaded fabrics
- D06N3/0031—Retractable fibres; Shrinking of fibres during manufacture
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
- D06N3/0077—Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Treatment Of Fiber Materials (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
Uprawniony z patentu: Artos Dr. Ing. Meier-Windhorst Kommandit- gesellschaft Hamburg (Republika Federalna Niemiec) Sposób wytwarzania sztucznej skóry Przedmiotem wynalazku jest sposób wytwarza¬ nia sztucznej skóry zwlaszcza na obuwie.Znane sa rózne sposoby wytwarzania sztucznej skóry. Wszystkie sztuczne skóry wytwarzane zna¬ nymi sposobami posiadaja jednak ze wzgledu na ich zastosowanie bezposrednio na material wierzch¬ ni do obuwia wiecej lub mniej niedogodnosci, po¬ niewaz zdarza sie czesto, ze ta sztuczna skóra nie posiada dostatecznej rozciagliwosci lub nie jest wy¬ starczajaco zdolna do przepuszczania pary, albo nie jest w stanie do przejecia wystarczajacej ilosci wilgotnosci, albo tez nie jest w dostatecznym stop¬ niu elastyczna.Zadaniem wynalazku jest przeto stworzenie sztucznej skóry, która posiadalaby w kazdych prak¬ tycznie warunkach dobre i uzyteczne wlasnosci skó¬ ry naturalnej, zwlaszcza w przypadku jej zasto¬ sowania na obuwie., Zadanie to zgodnie z wynalazkiem zostalo roz¬ wiazane w ten sposób, ze runo wlókien poddaje sie wykurczeniu do 30%, nastepnie impregnuje sie je calkowicie laktesem po czym poddaje sie koagulacji przy temperaturze 40 do 45°C oraz wymywaniu emulgatorów lub utwardzacza w kapieli kaskado¬ wej i wymywaniu soli. Po tym wszystkim runo pod¬ daje sie suszeniu oraz obróbce wygladzajacej i spilsniajacej w plaszczyznie runa a wreszcie na jedna strone runa natryskuje sie warstwe po¬ wierzchniowa po czym poddaje sie ostatecznemu suszeniu. 15 20 25 30 Inna postac wykonania wynalazku polega na tym, ze runo wlókien poddaje sie wykurczaniu do 30°/o, nastepnie impregnuje sie je calkowicie poliureta¬ nem, przeprowadza sie przez kapiel do koagulacji poliuretanu a na koniec przez kapiel do wymywa¬ nia rozpuszczalnika. Po tym wszystkim runo pod¬ daje sie suszeniu oraz obróbce wygladzajacej i spilsniajacej w plaszczyznie runa a wreszcie na jedna strone runa natryskuje sie wartwe powierzch¬ niowa po czym poddaje sie ostatecznemu susze¬ niu.Natryskiwanie wstegi materialu w celu wytwo¬ rzenia warstwy powierzchniowej dokonuje sie szczególnie w korzystny sposób w wielu nastepu¬ jacych po sobie operacjach natryskiwania przy czym do natryskiwanej substancji dodaje sie rózne ilosci powietrza. Przez to mozliwe jest uzyskanie w warstwie powierzchniowej zróznicowanej struk¬ tury, która po stronie zwróconej do runa jest luz¬ niejsza niz na powierzchni zewnetrznej.Wynalazek jest wyjasniony blizej na przykladach wykonania uwidocznionych na rysunku schematycz¬ nym, na którym fig. 1 przedstawia proces trakto¬ wania tasmy runa spoiwem w postaci lateksu i proces termokoagulacji po pelnej impregnacji, fig. 2 — proces traktowania tasmy runa lateksem i wprowadzenie tej tasmy do kapieli stracajacej a fig. 3 — proces obróbki, przy zastosowaniu poliure¬ tanu jako spoiwa. 82 24982 249 jednoczesnej obróbce cieplnej. Wreszcie zaopatruje sie tasme runa 10 jednostronnie w impergnacje koncowa, która nanosi sie przez natryskanie jej na te tasme. Natryskiwanie to odbywa sie za po- 5 moca kilku wlaczonych jedno za drugim urzadzen natryskowych 16 lub za pomoca urzadzenia na¬ tryskowego 17 lub 18, w którym znajduja sie umieszczone jedna za druga glowice rozpylajace.Po wyjsciu tasmy runa z tych urzadzen natrysko- 10 wych moze byc podjete celowo jeszcze suszenie koncowe.Na wszytkich figurach sa te same czesci za¬ opatrzone w te same oznaczenia liczbowe.Jak wynika z rysunku, uksztaltowana tasme ru¬ na 10 wprowadza sie najpierw do kapieli wykur- czajacej 11. Tu podejmuje sie wykurczanie wlókien, które sluzy do rozprezania tasmy runa i które nie powinno przekroczyc wartosci 30%. Wraz z wykur- czaniem tasme runa wprowadza sie do urzadzenia impregnujacego 12, w którym przeprowadza sie pelna impregnacje. Po wycisnieciu tasmy za pomo¬ ca urzadzenia wyciskajacego 13 moze nastapic przed wprowadzeniem tasmy do suszarki 14 stosowanie do zastosowanego spoiwa, rózna obróbka posrednia.Polega ona w przykladzie, przedstawionym na fig. 1 na tym, ze tasme run^ 10 przeprowadza sie naj¬ pierw przez suszarke wstepna 19, w której podej¬ muje sie koagulacje w temperaturze od 40 do 45°C.Z kolei po koagulacji tasme runa wprowadza sie do kapieli pluczacej 20, sluzacej do wymywania emulgatorów.W przykladzie wykonania przedstawionym na fig. 2, w którym stosuje sie równiez lateks jako spoiwo, obróbka posrednia polega na tym, ze po wycisnieciu tasmy na urzadzeniu wyciskajacym 13 tasme runa 10 wprowadza sie do kapieli wytraca¬ jacej w celu koagulacji lateksu, a nastepnie po wycisnieciu posrednim do nastepnej kapieli plu¬ czacej, w celu wyplukania soli.W przykladzie wykonania, przedstawionym na fig. 3, w którym stosuje sie poliuretan jako spoiwo, tasme runa 10 wprowadza sie po jej wycisnieciu za pomoca urzadzenia wyciskajacego 13 do kapieli koagulujacej, a nastepnie po wycisnieciu posrednim do kapieli w celu wyplukania rozpuszczalników.W suszarce 14, przez która przechodzi tasma runa 10, odbywa sie suszenie na okolo 15 lub 10% wil¬ gotnosci. W koncu tasme runa poddaje sie po¬ wierzchniowemu wygladzeniu i spilsnieniu w urza¬ dzeniu wygladzajacym i spilsniajacym 15, przy PL PL
Claims (3)
1. Zastrzezenia patentowe 1.-Sposób wytwarzania sztucznej skóry, znamien¬ ny tym, ze runo wlókien poddaje sie procesowi wykurczania do 30%, nastepnie impregnuje sie je calkowicie lateksem, po czym prowadzi sie koagu¬ lacje przy temperaturze 40—45°C oraz wymywanie emulgatorów lub utwardzaczy w kapieli kaskadowej i wymywanie soli, suszy sie a nastepnie poddaje sie obróbce wygladzajacej i spilsniajacej, po czym natryskuje sie na jedna strone runa warstwe po¬ wierzchniowa i poddaje sie ostatecznemu suszeniu.
2. Sposób wytwarzania sztucznej skóry, znamien¬ ny tym, ze runo wlókien poddaje sie procesowi wykurczania do 30%, nastepnie impregnuje sie cal¬ kowicie poliuretanem i przeprowadza sie przez kapiel do koagulacji poliuretanu a nastepnie przez kapiel do wymywania rozpuszczalnika, po czym runo suszy sie i poddaje obróbce wygladzajacej i spilsniajacej, nastepnie na jedna strone runa na¬ tryskuje sie warstwe powierzchniowa po czym pod¬ daje sie ostatecznemu suszeniu.
3. Sposób wedlug zastrz. 1 i 2, znamienny tym, ze natryskiwanie warstwy powierzchniowej pro¬ wadzi sie w wielu nastepujacych po sobie ope¬ racjach natryskiwania przy doprowadzaniu róznych ilosci powietrza. 20 25 30S2 249 10 11 13 "Q 20 S ~qj Lb d b 10 M Figi 11 20 '% I O" | ¦en -q p p (T-^-70 o p'oj- b dd ddo w ./. *^ 2* cf Ib i'III ii! :Ui lii fi'' ' J i i ¦ U J L dob ,000 vy/. # %<3 PL PL
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19702035502 DE2035502A1 (de) | 1970-07-17 | 1970-07-17 | Verfahren zur Herstellung von insbe sondere Schuhmaterial |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL82249B1 true PL82249B1 (pl) | 1975-10-31 |
Family
ID=5777062
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL1971149494A PL82249B1 (pl) | 1970-07-17 | 1971-07-16 |
Country Status (5)
| Country | Link |
|---|---|
| DE (1) | DE2035502A1 (pl) |
| ES (1) | ES393276A1 (pl) |
| FR (1) | FR2107024A5 (pl) |
| GB (1) | GB1349171A (pl) |
| PL (1) | PL82249B1 (pl) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3817820A (en) * | 1972-01-28 | 1974-06-18 | Fiberwoven Corp | Needled textile fabric |
-
1970
- 1970-07-17 DE DE19702035502 patent/DE2035502A1/de active Pending
-
1971
- 1971-07-07 FR FR7124849A patent/FR2107024A5/fr not_active Expired
- 1971-07-09 GB GB3226371A patent/GB1349171A/en not_active Expired
- 1971-07-15 ES ES393276A patent/ES393276A1/es not_active Expired
- 1971-07-16 PL PL1971149494A patent/PL82249B1/pl unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FR2107024A5 (pl) | 1972-05-05 |
| DE2035502A1 (de) | 1972-01-20 |
| GB1349171A (en) | 1974-03-27 |
| ES393276A1 (es) | 1973-08-16 |
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