PL70713B2 - - Google Patents
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- Publication number
- PL70713B2 PL70713B2 PL14885471A PL14885471A PL70713B2 PL 70713 B2 PL70713 B2 PL 70713B2 PL 14885471 A PL14885471 A PL 14885471A PL 14885471 A PL14885471 A PL 14885471A PL 70713 B2 PL70713 B2 PL 70713B2
- Authority
- PL
- Poland
- Prior art keywords
- weight
- parts
- palladium
- gold
- resinate
- Prior art date
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- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 26
- 239000003973 paint Substances 0.000 claims description 14
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 13
- 239000010931 gold Substances 0.000 claims description 13
- 229910052737 gold Inorganic materials 0.000 claims description 13
- 229910052763 palladium Inorganic materials 0.000 claims description 13
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 10
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 10
- 239000011347 resin Substances 0.000 claims description 9
- 229920005989 resin Polymers 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 239000010938 white gold Substances 0.000 claims description 5
- 229910000832 white gold Inorganic materials 0.000 claims description 5
- 150000002739 metals Chemical class 0.000 claims description 4
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 238000003786 synthesis reaction Methods 0.000 claims description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 4
- 239000010426 asphalt Substances 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 4
- 239000011651 chromium Substances 0.000 description 4
- 238000005034 decoration Methods 0.000 description 4
- 238000010304 firing Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 229910052703 rhodium Inorganic materials 0.000 description 4
- 239000010948 rhodium Substances 0.000 description 4
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 4
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 4
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
- 229910052797 bismuth Inorganic materials 0.000 description 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000010665 pine oil Substances 0.000 description 3
- 229910052573 porcelain Inorganic materials 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 235000006679 Mentha X verticillata Nutrition 0.000 description 1
- 235000002899 Mentha suaveolens Nutrition 0.000 description 1
- 235000001636 Mentha x rotundifolia Nutrition 0.000 description 1
- 241001085205 Prenanthella exigua Species 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229940045985 antineoplastic platinum compound Drugs 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 150000003058 platinum compounds Chemical class 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Description
Pierwszenstwo: Zgloszenie ogloszono: 05.05.1973 Opis patentowy opublikowano: 03.06.1974 70713 KI. 80b, 23/03 MKP C03c 5/02 CZYTEL, A Urzedu Palent-¦ qo Pilskiej lier?,i.:,r-«rr •¦ j Twórcywynalazku: Stanislaw Rutkowski, Maria Karpiuk-Kokosinska, Pawel Polak Uprawniony z patentu tymczasowego: Mennica Panstwowa, Warszawa (Polska) blyszczacego zlota bialego Przedmiotem wynalazku jest farba blyszczacego zlota bialego stosowana szczególnie do dekoracji wyro¬ bów ceramicznych i szklanych.Znane farby zlota bialego stanowia mieszanine zywiczanów zlota i platyny oraz innych pigmentów w spoiwie. Jako pigmenty stosuje sie zwiazki organiczne najczesciej zywiczany: rodu, irydu, chromu, tytanu, niklu, srebra. Jako spoiwo stosuje sie zwiazki organiczne najczesciej zywiczany bizmutu, olowiu, boru, krzemu zmieszane z asfaltem syryjskim, kalafonia, terpentyna wenecka i balsamiczna.Stosowana w farbie blyszczacego zlota bialego platyna odbarwia zloto nadajac mu po wypaleniu na wyrobach z porcelany lub szkla barwe biala z silnym polyskiem. Farby takie ze wzgledu na wysoka cene platyny sa drogie.Znane sa próby odbarwiania zlota w farbach za pomoca innych metali. Do odbarwienia zlota potrzebne sa znaczne ilosci pigmentów. Praktycznemu zastosowaniu ich stoi na przeszkodzie zjawisko latwego utleniania sie tych metali w temperaturach wypalania wyrobów z porcelany lub szkla co prowadzi do zaniku efektu dekoracyj¬ nego otrzymanej powloki. Niedogodnosci tej nie ma farba blyszczacego zlota bialego wedlug wynalazku.Nieoczekiwanie stwierdzono, ze wprowadzenie do farby blyszczacego zlota bialego zywiezami palladu w okreslonym stosunku palladu metalicznego do zlota metalicznego umozliwia otrzymanie powloki bialej, blyszczacej, w która pallad w temperaturze wypalu nie ulega utlenieniu. Stosunek ten wynosi od 4 :1 do 19 :1 najkorzystniej 17 :3 zlota do palladu w przeliczeniu na metale, przy czym wlasciwosci te wykazuje farba, w której zastosowano zywiczan palladu wystepujacy jako produkt syntezy chlorku palladawego z sulfobalsamem w srodowisku chloroformu i acetonu. Stosunek wagowy chloroformu do acetonu wynosi 3 :2. Uzycie mieszaniny chloroformu i acetonu w ilosci nie mniejszej niz 1,5 g na 1 g palladu w chlorku palladowym zapewnia otrzymanie zywiczanu palladu, gwarantujacego uzyskanie nieoczekiwanych wlasnosci farby blyszczacego zlota bialego.Farba blyszczacego zlota bialego wedlug wynalazku pozwala na otrzymanie na porcelanie lub szkle powloki o. wysokich walorach dekoracyjnych po jednorazowym nalozeniu i wypaleniu.Farba blyszczacego zlota bialego do dekoracji porcelany: Przyklad I. 38,64 czesci wagowych zywiczanu zlota, 15,00 czesci wagowych zywiczanu palladu, 1,16 czesci wagowych zywiczanu rodu, 1,36 czesci wagowych zywiczanu chromu, 4,85 czesci wagowych zywiczanu70 713 bizmulu, 18,00 czesci wagowych asfaltu naturalnego, 9,00 czesci wagowych kalafonii, 3,50 czesci wagowych cykloheksanu, 8,49 czesci wagowych olejku sosnowego.Przyklad II. 36,36 czesci wagowych zywiczanu zlota, 20,00 czesc wagowych zywiczanu palladu, 1,16 czesci wagowych zywiczanu rodu, 1,36 czesci wagowych zywiczanu chromu, 4,85 czesci wagowych zywiczanu bizmutu, 18,00 czesci wagowych asfaltu naturalnego, 9,00 czesci wagowych kalafonii, 3,50 czesci wagowych cykloheksanu, 5,77 czesci wagowych olejku sosnowego.Farba blyszczacego zlota bialego do dekoracji szkla: Przyklad III. 38,64 czesci wagowych zywiczanu zlota, 15,00 czesci wagowych zywiczanu palladu, • 0,62 czesci wagowych zywiczanu rodu, 0,66 czesci wagowych zywiczanu chromu, 1,74 czesci wagowych zywi¬ czanu krzemu, 1,82 czesci wagowych zywiczanu wanadu, 3,50 czesci wagowych zywiczanu bizmutu, 18,00 czesci wagowych asfaltu naturalnego, 12,75 czesci wagowych kalafonii, 2,90 czesci wagowych cykloheksanu, 4,37 czesci wagowych olejku sosnowego.Farba blyszczacego zlota bialego wedlug wynalazku moze byc wypalona w szerokim zakresie temperatur od 520°C do 820°C, odznacza sie po wypaleniu pieknym polyskiem glebokim tonem, ladniejszym niz przy farbach z zastosowaniem zwiazków platyny i moze byc stosowana do róznych technik dekoracyjnych: recznie przy pomocy pedzla i stempla, sitodruku, dekoracji maszynowych. PL PLPriority: Application announced: May 5, 1973 Patent description was published: June 3, 1974 70713 KI. 80b, 23/03 MKP C03c 5/02 CZYTEL, A Urzedu Palent-¦ qo Pilska lier?, I.:, R- «rr • ¦ j Creators of the invention: Stanislaw Rutkowski, Maria Karpiuk-Kokosinska, Pawel Polak Authorized by a temporary patent: Mint Panstwowa, Warsaw (Poland) Shiny white gold The subject of the invention is a shining white paint used especially for decoration of ceramic and glass products. The well-known white gold paints are a mixture of gold and platinum resin and other pigments in a binder. The most commonly resinous organic compounds are used as pigments: rhodium, iridium, chromium, titanium, nickel, silver. Organic compounds are used as a binder, most often resinous bismuth, lead, boron, silicon mixed with Syrian asphalt, rosin, Venetian and balsamic turpentine. glossy. Due to the high price of platinum, such paints are expensive. There are known attempts to discolor gold in paints with other metals. Considerable amounts of pigments are needed to discolor gold. Their practical application is hindered by the phenomenon of easy oxidation of these metals at the firing temperatures of porcelain or glass products, which leads to the disappearance of the decorative effect of the coating obtained. This inconvenience is not experienced by the white shiny gold paint according to the invention. It has surprisingly been found that the incorporation of bright white palladium into the paint in a specific ratio of palladium metal to metal gold allows to obtain a glossy white coating in which the palladium is not oxidized at the firing temperature. The ratio is from 4: 1 to 19: 1, most preferably 17: 3 gold to palladium in terms of metals, these properties being shown by a paint using palladium resinate as a product of the synthesis of palladium chloride with sulfobalsam in the environment of chloroform and acetone. The weight ratio of chloroform to acetone is 3: 2. The use of a mixture of chloroform and acetone in an amount not lower than 1.5 g per 1 g of palladium in palladium chloride provides palladium resinate, which guarantees unexpected properties of shiny white gold paint. According to the invention, shiny gold paint allows to obtain a coating on porcelain or glass with high decorative value after a single application and firing. Shiny white gold paint for porcelain decoration: Example I. 38.64 parts by weight of gold resin, 15.00 parts by weight of palladium resin, 1.16 parts by weight of rhodium resin, 1.36 parts by weight Chromium resinate, 4.85 parts by weight resin 70 713 bismul, 18.00 parts by weight natural asphalt, 9.00 parts by weight rosin, 3.50 parts by weight cyclohexane, 8.49 parts by weight pine oil. Example II. 36.36 parts by weight of gold resin, 20.00 parts by weight of palladium resin, 1.16 parts by weight of rhodium resinate, 1.36 parts by weight of chromium resinate, 4.85 parts by weight of bismuth resin, 18.00 parts by weight of natural asphalt, 9, 00 parts by weight of rosin, 3.50 parts by weight of cyclohexane, 5.77 parts by weight of pine oil. Shiny gold paint for glass decoration: Example III. 38.64 parts by weight of gold resinate, 15.00 parts by weight of palladium resinate, 0.62 parts by weight of rhodium resinate, 0.66 parts by weight of chromium resinate, 1.74 parts by weight of silicon resinate, 1.82 parts by weight of vanadium resinate , 3.50 parts by weight of bismuth resinate, 18.00 parts by weight of natural asphalt, 12.75 parts by weight of rosin, 2.90 parts by weight of cyclohexane, 4.37 parts by weight of pine oil. Shiny gold paint according to the invention can be burned wide Temperature range from 520 ° C to 820 ° C, after firing it is distinguished by a beautiful deep gloss gloss, more beautiful than with paints using platinum compounds and can be used for various decorative techniques: manually with a brush and stamp, screen printing, machine decorations. PL PL
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL14885471A PL70713B2 (en) | 1971-06-16 | 1971-06-16 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL14885471A PL70713B2 (en) | 1971-06-16 | 1971-06-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL70713B2 true PL70713B2 (en) | 1974-04-30 |
Family
ID=19954724
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL14885471A PL70713B2 (en) | 1971-06-16 | 1971-06-16 |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL70713B2 (en) |
-
1971
- 1971-06-16 PL PL14885471A patent/PL70713B2/pl unknown
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