PL5940B1 - Method of obtaining hydrogen and carbon dioxide from spirit and water. - Google Patents
Method of obtaining hydrogen and carbon dioxide from spirit and water. Download PDFInfo
- Publication number
- PL5940B1 PL5940B1 PL5940A PL594026A PL5940B1 PL 5940 B1 PL5940 B1 PL 5940B1 PL 5940 A PL5940 A PL 5940A PL 594026 A PL594026 A PL 594026A PL 5940 B1 PL5940 B1 PL 5940B1
- Authority
- PL
- Poland
- Prior art keywords
- water
- spirit
- carbon dioxide
- obtaining hydrogen
- hydrogen
- Prior art date
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 title claims description 7
- 239000001257 hydrogen Substances 0.000 title claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 6
- 238000000034 method Methods 0.000 title claims description 5
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims description 4
- 239000001569 carbon dioxide Substances 0.000 title claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 235000019441 ethanol Nutrition 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229910052797 bismuth Inorganic materials 0.000 claims description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 2
- 235000013980 iron oxide Nutrition 0.000 claims description 2
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims 1
- 229910000420 cerium oxide Inorganic materials 0.000 claims 1
- DRVWBEJJZZTIGJ-UHFFFAOYSA-N cerium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Ce+3].[Ce+3] DRVWBEJJZZTIGJ-UHFFFAOYSA-N 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 235000002595 Solanum tuberosum Nutrition 0.000 description 2
- 244000061456 Solanum tuberosum Species 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 235000012015 potatoes Nutrition 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
Description
Kwest ja otrzymywania taniego wodoru jest kwest ja, od której zalezy rozwój syn¬ tezy amonjaku. Otrzymywanie wodoru z produktów rolniczych umozliwiloby rozpo¬ wszechnienie syntezy amonjaku we wszyst¬ kich krajach rolniczych, poniewaz do prze¬ prowadzenia gotowego wodoru na amon jak potrzeba tylko niewiele energji.Niniejszy wynalazek pozwala otrzymac bardzo latwio wodór i dwutlenek wegla ze spirytusu. Okazalo sie, ze jezeli pary spi¬ rytusu przepuszczac w temperaturze okolo 400—600°C w obecnosci pary wodnej po¬ nad zelazem lub tlenkami zelaza, to za¬ chodzi reakcja: C2H6OH + 3 H20 = 2C02 + 6 H2.Reakcja zachodzi szybciej, jezeli zelazo, wzglednie tlenki zawieraja niektóre do¬ mieszki, jak tlenki manganu, bizmutu, ceru i tym (podobnych.Reakcja idzie tern szybciej im przy wyz¬ szej temperaturze sie pracuje, wtedy jednak powstaja wieksze ilosci tlenku wegla.Spirytus moze byc nierafinowany, po¬ niewaz fuzel rozklada sie w tych warun¬ kach podobnie.Znaczenie tej metody polega na tern, ze na 1 kg zwiazanego azotu potrzeba zuzyc 1 kg alkoholu etylowego, zas 1 kg zwiaza¬ nego azotu uzyty jako nawóz pod ziemnia¬ ki spowoduje podwyzke plonu ziemniaków wystarczajaca na wyprodukowanie 10 kg alkoholu. PLThe question of how to obtain cheap hydrogen is one on which the development of ammonia synthesis depends. Obtaining hydrogen from agricultural products would make it possible to spread the synthesis of ammonia in all agricultural countries, since only a little energy is needed to convert the finished hydrogen into ammonium. The present invention makes it very easy to obtain hydrogen and carbon dioxide from spirit. It turned out that if the alcohol vapors are passed at a temperature of about 400-600 ° C in the presence of water vapor over iron or iron oxides, the reaction occurs: C2H6OH + 3 H2O = 2CO2 + 6H2. The reaction is faster, if iron or oxides contain some admixtures, like oxides of manganese, bismuth, cerium and the like (the like. The reaction goes faster the faster you work at higher temperatures, but then more carbon monoxide is produced. Spirit can be unrefined when The importance of this method is that for 1 kg of nitrogen bound, 1 kg of ethyl alcohol is needed, and 1 kg of nitrogen used as fertilizer for potatoes will increase the yield of potatoes. enough to produce 10 kg of alcohol PL
Claims (2)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL5940B1 true PL5940B1 (en) | 1926-10-30 |
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