PL447020A1 - Wysokoporowate glino-naftalenodikarboksylowe sieci organiczne oraz ich kompozyty z nanostrukturalnym złotem, sposoby ich wytwarzania i zastosowanie w katalitycznej konwersji CO2 do cyklicznych estrów - Google Patents

Wysokoporowate glino-naftalenodikarboksylowe sieci organiczne oraz ich kompozyty z nanostrukturalnym złotem, sposoby ich wytwarzania i zastosowanie w katalitycznej konwersji CO2 do cyklicznych estrów

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Publication number
PL447020A1
PL447020A1 PL447020A PL44702023A PL447020A1 PL 447020 A1 PL447020 A1 PL 447020A1 PL 447020 A PL447020 A PL 447020A PL 44702023 A PL44702023 A PL 44702023A PL 447020 A1 PL447020 A1 PL 447020A1
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Poland
Prior art keywords
naphthalenedicarboxylic
highly porous
methods
gold
catalytic conversion
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PL447020A
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English (en)
Inventor
Elżbieta MEGIEL
Gabriela KOPACKA
Kinga WASILUK
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Uniwersytet Warszawski
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Publication date
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Priority to PL447020A priority Critical patent/PL447020A1/pl
Priority to PCT/IB2024/062398 priority patent/WO2025120614A1/en
Publication of PL447020A1 publication Critical patent/PL447020A1/pl

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
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    • B01J31/1691—Coordination polymers, e.g. metal-organic frameworks [MOF]
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    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
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    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
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    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
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    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
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    • B01J2531/0213—Complexes without C-metal linkages
    • B01J2531/0216—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
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    • C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/32—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D317/34—Oxygen atoms
    • C07D317/36—Alkylene carbonates; Substituted alkylene carbonates

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Przedmiotem niniejszego wynalazku jest wysokoporowatą glino-naftalenodikarboksylowa sieć organiczna o wzorze sumarycznym Al(C12H6O4) • X (CH3)2NHC(O)H • 3 H2O, gdzie X oznacza 0,22 albo 0,25 oraz kompozyt wysokoporowatej glino-naftalenodikarboksylowej sieci organicznej zdefiniowanej powyżej z nanostrukturalnym złotem o wzorze sumarycznym Al(C12H6O4) • Y (CH3)2NCH(O)H • ZS • 0.01 Au • 3 H2O, gdzie Y oznacza 0,13 albo 0,14, natomiast Z oznacza 0,05 albo 0,1, a także sposoby ich wytwarzania i zastosowanie w katalitycznej konwersji CO2 do cyklicznych estrów.
PL447020A 2023-12-07 2023-12-07 Wysokoporowate glino-naftalenodikarboksylowe sieci organiczne oraz ich kompozyty z nanostrukturalnym złotem, sposoby ich wytwarzania i zastosowanie w katalitycznej konwersji CO2 do cyklicznych estrów PL447020A1 (pl)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PL447020A PL447020A1 (pl) 2023-12-07 2023-12-07 Wysokoporowate glino-naftalenodikarboksylowe sieci organiczne oraz ich kompozyty z nanostrukturalnym złotem, sposoby ich wytwarzania i zastosowanie w katalitycznej konwersji CO2 do cyklicznych estrów
PCT/IB2024/062398 WO2025120614A1 (en) 2023-12-07 2024-12-09 Highly porous alumino-naphthalene dicarboxylic organic frameworks and their composites with nanostructured gold, methods of their production and use in the catalytic conversion of co2 to cyclic esters

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL447020A PL447020A1 (pl) 2023-12-07 2023-12-07 Wysokoporowate glino-naftalenodikarboksylowe sieci organiczne oraz ich kompozyty z nanostrukturalnym złotem, sposoby ich wytwarzania i zastosowanie w katalitycznej konwersji CO2 do cyklicznych estrów

Publications (1)

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PL447020A1 true PL447020A1 (pl) 2025-06-09

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080281116A1 (en) * 2005-12-16 2008-11-13 Basf Se Acid-Functionalized Organometallic Framework Materials
US20100166644A1 (en) * 2005-08-22 2010-07-01 Basf Se Method for producing organometallic framework materials containing main group metal ions
CN102766153A (zh) * 2012-07-30 2012-11-07 东南大学 铝基微孔配位聚合物合成方法
CN106749348A (zh) * 2016-11-22 2017-05-31 南开大学 一种金属有机框架材料及其制备方法及应用
US11406971B2 (en) * 2018-03-26 2022-08-09 Research Triangle Institute Method of making confined nanocatalysts within mesoporous materials and uses thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100166644A1 (en) * 2005-08-22 2010-07-01 Basf Se Method for producing organometallic framework materials containing main group metal ions
US20080281116A1 (en) * 2005-12-16 2008-11-13 Basf Se Acid-Functionalized Organometallic Framework Materials
CN102766153A (zh) * 2012-07-30 2012-11-07 东南大学 铝基微孔配位聚合物合成方法
CN106749348A (zh) * 2016-11-22 2017-05-31 南开大学 一种金属有机框架材料及其制备方法及应用
US11406971B2 (en) * 2018-03-26 2022-08-09 Research Triangle Institute Method of making confined nanocatalysts within mesoporous materials and uses thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
LIU, L., TAI, X., ZHOU, X. ET AL.: "Chem. Res. Chin. Univ. 33, 231–238 (2017), https://doi.org/10.1007/s40242-017-6420-7", SYNTHESIS, POST-MODIFICATION AND CATALYTIC PROPERTIES OF METAL-ORGANIC FRAMEWORK NH2-MIL-53(AL) *

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