PL445797A1 - Urethane-dimethacrylate resin, method of obtaining it and use - Google Patents

Urethane-dimethacrylate resin, method of obtaining it and use

Info

Publication number
PL445797A1
PL445797A1 PL445797A PL44579723A PL445797A1 PL 445797 A1 PL445797 A1 PL 445797A1 PL 445797 A PL445797 A PL 445797A PL 44579723 A PL44579723 A PL 44579723A PL 445797 A1 PL445797 A1 PL 445797A1
Authority
PL
Poland
Prior art keywords
group
urethane
bromide
general formula
dimethacrylate resin
Prior art date
Application number
PL445797A
Other languages
Polish (pl)
Inventor
Izabela Barszczewska-Rybarek
Patryk Drejka
Marta Chrószcz-Porębska
Original Assignee
Politechnika Śląska
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Politechnika Śląska filed Critical Politechnika Śląska
Priority to PL445797A priority Critical patent/PL445797A1/en
Publication of PL445797A1 publication Critical patent/PL445797A1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/34Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • C08F220/36Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate containing oxygen in addition to the carboxy oxygen, e.g. 2-N-morpholinoethyl (meth)acrylate or 2-isocyanatoethyl (meth)acrylate
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61CDENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
    • A61C5/00Filling or capping teeth
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00Preparations for dentistry
    • A61K6/80Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/884Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C08F2/40Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using retarding agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/16Catalysts
    • C08G18/161Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
    • C08G18/163Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 covered by C08G18/18 and C08G18/22
    • C08G18/165Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 covered by C08G18/18 and C08G18/22 covered by C08G18/18 and C08G18/24
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7614Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring

Landscapes

  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Plastic & Reconstructive Surgery (AREA)
  • Dentistry (AREA)
  • Dental Preparations (AREA)

Abstract

Przedmiotem zgłoszenia jest żywica uretanowo-dimetakrylanowa, o wzorze ogólnym 23, gdzie CH2=C(CH3)-(CO)O- - grupa metakrylanowa, >N+< - czwartorzędowa grupa amoniowa, Br- - anion bromkowy, CH3- - grupa metylowa, >C< - czwartorzędowy atom węgla, -1,3-C6H4- - pierścień benzenowy, który jest podstawiony w pozycjach 1 i 3, CH3(CH2)6CH2- - grupa n-oktylowa, -NH(CO)O - wiązanie uretanowe, które charakteryzuje się tym, że składa się z dwóch jednostek skrzydłowych, pochodzących od bromku [2-(metakryloiloksy)etylo]-2-hydroksyetylometylooktyloamoniovgego o wzorze ogólnym 18, gdzie CH2=C(CH3)-(CO)O- - grupa metakrylanowa, >N+< - czwartorzędowa grupa amoniowa, Br- - anion bromkowy, CH3- - grupa metylowa, CH3(CH2)6CH2- - grupa n-oktylowa, OH- - grupa hydroksylowa oraz rdzenia, pochodzącego od 1,3-bis(1-izocyjaniano-1-metyloetylo)benzenu o wzorze ogólnym 25, gdzie CH3- - grupa metylowa, >C< - czwartorzędowy atom węgla. -1,3-C6H4- - pierścień benzenowy, który jest podstawiony w pozycjach 1 i 3, NCO- - grupa izocyjanianowa. Zgłoszenie obejmuje także sposób otrzymywania żywicy uretanowo-dimetakrylanowej, o wzorze 23 oraz jej zastosowanie jako składnika spoiw stomatologicznych kompozytowych materiałów rekonstrukcyjnych o potencjalnych właściwościach antybakteryjnych.The subject of the application is a urethane dimethacrylate resin, of the general formula 23, where CH2=C(CH3)-(CO)O- - a methacrylate group, >N+< - a quaternary ammonium group, Br- - a bromide anion, CH3- - a methyl group, >C< - a quaternary carbon atom, -1,3-C6H4- - a benzene ring, which is substituted in positions 1 and 3, CH3(CH2)6CH2- - an n-octyl group, -NH(CO)O - a urethane bond, which is characterized in that it consists of two wing units derived from [2-(methacryloyloxy)ethyl]-2-hydroxyethylmethyloctylammonium bromide of the general formula 18, where CH2=C(CH3)-(CO)O- - a methacrylate group, >N+< - a quaternary ammonium bromide. ammonium group, Br- - bromide anion, CH3- - methyl group, CH3(CH2)6CH2- - n-octyl group, OH- - hydroxyl group and a core derived from 1,3-bis(1-isocyanato-1-methylethyl)benzene of general formula 25, where CH3- - methyl group, >C< - quaternary carbon atom. -1,3-C6H4- - benzene ring, which is substituted in positions 1 and 3, NCO- - isocyanate group. The application also covers a method of obtaining a urethane-dimethacrylate resin of formula 23 and its use as a component of dental binders of composite reconstructive materials with potential antibacterial properties.

PL445797A 2023-08-07 2023-08-07 Urethane-dimethacrylate resin, method of obtaining it and use PL445797A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL445797A PL445797A1 (en) 2023-08-07 2023-08-07 Urethane-dimethacrylate resin, method of obtaining it and use

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL445797A PL445797A1 (en) 2023-08-07 2023-08-07 Urethane-dimethacrylate resin, method of obtaining it and use

Publications (1)

Publication Number Publication Date
PL445797A1 true PL445797A1 (en) 2025-02-10

Family

ID=94479910

Family Applications (1)

Application Number Title Priority Date Filing Date
PL445797A PL445797A1 (en) 2023-08-07 2023-08-07 Urethane-dimethacrylate resin, method of obtaining it and use

Country Status (1)

Country Link
PL (1) PL445797A1 (en)

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