PL422186A1 - Method for oxidation of limonene to 1,2-epoxylimonene - Google Patents

Method for oxidation of limonene to 1,2-epoxylimonene

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Publication number
PL422186A1
PL422186A1 PL422186A PL42218617A PL422186A1 PL 422186 A1 PL422186 A1 PL 422186A1 PL 422186 A PL422186 A PL 422186A PL 42218617 A PL42218617 A PL 42218617A PL 422186 A1 PL422186 A1 PL 422186A1
Authority
PL
Poland
Prior art keywords
limonene
epoxylimonene
oxidation
oxidant
mww
Prior art date
Application number
PL422186A
Other languages
Polish (pl)
Other versions
PL236166B1 (en
Inventor
Agnieszka Wróblewska
Alicja Gawarecka
Original Assignee
Zachodniopomorski Uniwersytet Technologiczny W Szczecinie
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zachodniopomorski Uniwersytet Technologiczny W Szczecinie filed Critical Zachodniopomorski Uniwersytet Technologiczny W Szczecinie
Priority to PL422186A priority Critical patent/PL236166B1/en
Publication of PL422186A1 publication Critical patent/PL422186A1/en
Publication of PL236166B1 publication Critical patent/PL236166B1/en

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  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Przedmiotem zgłoszenia jest sposób utleniania limonenu do 1,2-epoksylimonenu, gdzie za pomocą 5M roztworu wodoronadtlenku t-butylu w dekanie w obecności katalizatorów tytanowo-silikalitowych Ti-SBA-15, Ti-MWW, Ti-MCM-41 i TS-1 w ilości 3% wagowych w mieszaninie reakcyjnej, przy stosunku molowym limonen/utleniacz 1:1, charakteryzuje się tym, że proces bez dodatku rozpuszczalnika prowadzi się pod ciśnieniem atmosferycznym w temperaturze 80°C, w czasie 6 godzin, stosując intensywność mieszania 500 obr/min. Korzystnie surowce wprowadza się do reaktora w następującej kolejności: limonen, katalizator i na końcu utleniacz.The subject of the application is a method of oxidation of limonene to 1,2-epoxylimonene, where using a 5M solution of t-butyl hydroperoxide in decane in the presence of Ti-SBA-15, Ti-MWW, Ti-MCM-41 and TS-1 titanium-silicon catalysts 3% by weight in the reaction mixture, at a molar ratio of limonene / oxidant 1: 1, is characterized in that the solvent-free process is carried out at atmospheric pressure at 80 ° C for 6 hours using a stirring speed of 500 rpm . Preferably, the raw materials are introduced into the reactor in the following order: limonene, catalyst and finally the oxidant.

PL422186A 2017-07-11 2017-07-11 Method for oxidation of limonene to 1,2-epoxylimonene PL236166B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL422186A PL236166B1 (en) 2017-07-11 2017-07-11 Method for oxidation of limonene to 1,2-epoxylimonene

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL422186A PL236166B1 (en) 2017-07-11 2017-07-11 Method for oxidation of limonene to 1,2-epoxylimonene

Publications (2)

Publication Number Publication Date
PL422186A1 true PL422186A1 (en) 2019-01-14
PL236166B1 PL236166B1 (en) 2020-12-14

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ID=64958896

Family Applications (1)

Application Number Title Priority Date Filing Date
PL422186A PL236166B1 (en) 2017-07-11 2017-07-11 Method for oxidation of limonene to 1,2-epoxylimonene

Country Status (1)

Country Link
PL (1) PL236166B1 (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL409652A1 (en) * 2014-09-30 2016-04-11 Zachodniopomorski Uniwersytet Technologiczny W Szczecinie Method for epoxidation of limonene
PL413146A1 (en) * 2015-07-17 2017-01-30 Zachodniopomorski Uniwersytet Technologiczny W Szczecinie Method for epoxidation of limonene

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL409652A1 (en) * 2014-09-30 2016-04-11 Zachodniopomorski Uniwersytet Technologiczny W Szczecinie Method for epoxidation of limonene
PL413146A1 (en) * 2015-07-17 2017-01-30 Zachodniopomorski Uniwersytet Technologiczny W Szczecinie Method for epoxidation of limonene

Also Published As

Publication number Publication date
PL236166B1 (en) 2020-12-14

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