PL30726B1 - - Google Patents

Info

Publication number

PL30726B1

PL30726B1 PL30726A PL3072638A PL30726B1 PL 30726 B1 PL30726 B1 PL 30726B1 PL 30726 A PL30726 A PL 30726A PL 3072638 A PL3072638 A PL 3072638A PL 30726 B1 PL30726 B1 PL 30726B1

Authority

PL

Poland

Prior art keywords

bath

solution

acid

addition

magnesium

Prior art date

1938-09-29

Links

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• 238000000034 method Methods 0.000 claims description 17
• 239000000243 solution Substances 0.000 claims description 15
• 239000002253 acid Substances 0.000 claims description 12
• FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 10
• 239000011777 magnesium Substances 0.000 claims description 9
• 229910052749 magnesium Inorganic materials 0.000 claims description 9
• 229910045601 alloy Inorganic materials 0.000 claims description 8
• 239000000956 alloy Substances 0.000 claims description 8
• ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 claims description 8
• SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 claims description 8
• 239000000203 mixture Substances 0.000 claims description 7
• 239000011253 protective coating Substances 0.000 claims description 7
• -1 chromic acid ions Chemical class 0.000 claims description 6
• 239000007864 aqueous solution Substances 0.000 claims description 5
• CHKVPAROMQMJNQ-UHFFFAOYSA-M potassium bisulfate Chemical compound [K+].OS([O-])(=O)=O CHKVPAROMQMJNQ-UHFFFAOYSA-M 0.000 claims description 5
• 229910000831 Steel Inorganic materials 0.000 claims description 4
• 150000007513 acids Chemical class 0.000 claims description 4
• KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 claims description 4
• 238000004519 manufacturing process Methods 0.000 claims description 4
• 239000010959 steel Substances 0.000 claims description 4
• 150000002500 ions Chemical class 0.000 claims description 3
• ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
• 229910052700 potassium Inorganic materials 0.000 claims description 2
• 239000011591 potassium Substances 0.000 claims description 2
• QYHFIVBSNOWOCQ-UHFFFAOYSA-N selenic acid Chemical compound O[Se](O)(=O)=O QYHFIVBSNOWOCQ-UHFFFAOYSA-N 0.000 claims description 2
• QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 4
• PQMFVUNERGGBPG-UHFFFAOYSA-N (6-bromopyridin-2-yl)hydrazine Chemical compound NNC1=CC=CC(Br)=N1 PQMFVUNERGGBPG-UHFFFAOYSA-N 0.000 claims 1
• NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 1
• XLJMAIOERFSOGZ-UHFFFAOYSA-N cyanic acid Chemical compound OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 claims 1
• 150000002696 manganese Chemical class 0.000 claims 1
• 229910000510 noble metal Inorganic materials 0.000 claims 1
• XMXNVYPJWBTAHN-UHFFFAOYSA-N potassium chromate Chemical compound [K+].[K+].[O-][Cr]([O-])(=O)=O XMXNVYPJWBTAHN-UHFFFAOYSA-N 0.000 claims 1
• MCAHWIHFGHIESP-UHFFFAOYSA-N selenous acid Chemical compound O[Se](O)=O MCAHWIHFGHIESP-UHFFFAOYSA-N 0.000 claims 1
• 238000000576 coating method Methods 0.000 description 16
• 239000003792 electrolyte Substances 0.000 description 12
• 229910052751 metal Inorganic materials 0.000 description 9
• 239000002184 metal Substances 0.000 description 9
• 150000001875 compounds Chemical class 0.000 description 7
• 239000002966 varnish Substances 0.000 description 6
• 239000011248 coating agent Substances 0.000 description 5
• 238000007598 dipping method Methods 0.000 description 5
• 229910000861 Mg alloy Inorganic materials 0.000 description 4
• 239000013535 sea water Substances 0.000 description 4
• QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
• OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 3
• 229910052939 potassium sulfate Inorganic materials 0.000 description 3
• 239000001120 potassium sulphate Substances 0.000 description 3
• 235000011151 potassium sulphates Nutrition 0.000 description 3
• VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
• 229910019142 PO4 Inorganic materials 0.000 description 2
• 229920002678 cellulose Polymers 0.000 description 2
• 239000001913 cellulose Substances 0.000 description 2
• 239000004020 conductor Substances 0.000 description 2
• 238000001035 drying Methods 0.000 description 2
• 230000000694 effects Effects 0.000 description 2
• 235000021317 phosphate Nutrition 0.000 description 2
• KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 2
• 238000002360 preparation method Methods 0.000 description 2
• 150000003839 salts Chemical class 0.000 description 2
• 239000007921 spray Substances 0.000 description 2
• 238000005507 spraying Methods 0.000 description 2
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
• QLOKJRIVRGCVIM-UHFFFAOYSA-N 1-[(4-methylsulfanylphenyl)methyl]piperazine Chemical compound C1=CC(SC)=CC=C1CN1CCNCC1 QLOKJRIVRGCVIM-UHFFFAOYSA-N 0.000 description 1
• PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical class [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
• 230000002378 acidificating effect Effects 0.000 description 1
• 239000000654 additive Substances 0.000 description 1
• 230000000996 additive effect Effects 0.000 description 1
• 230000001464 adherent effect Effects 0.000 description 1
• 238000003287 bathing Methods 0.000 description 1
• 230000015572 biosynthetic process Effects 0.000 description 1
• 150000001642 boronic acid derivatives Chemical class 0.000 description 1
• 230000000052 comparative effect Effects 0.000 description 1
• 150000001913 cyanates Chemical class 0.000 description 1
• 230000002950 deficient Effects 0.000 description 1
• 238000005530 etching Methods 0.000 description 1
• 238000002474 experimental method Methods 0.000 description 1
• 230000002349 favourable effect Effects 0.000 description 1
• AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
• 229910001385 heavy metal Inorganic materials 0.000 description 1
• GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
• 238000007654 immersion Methods 0.000 description 1
• 239000004922 lacquer Substances 0.000 description 1
• 239000010410 layer Substances 0.000 description 1
• WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
• 230000003647 oxidation Effects 0.000 description 1
• 238000007254 oxidation reaction Methods 0.000 description 1
• 239000003973 paint Substances 0.000 description 1
• 238000009304 pastoral farming Methods 0.000 description 1
• 230000035515 penetration Effects 0.000 description 1
• NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
• 239000010452 phosphate Substances 0.000 description 1
• 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
• CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
• 229910001950 potassium oxide Inorganic materials 0.000 description 1
• 159000000001 potassium salts Chemical class 0.000 description 1
• 235000019353 potassium silicate Nutrition 0.000 description 1
• 230000001681 protective effect Effects 0.000 description 1
• 239000011241 protective layer Substances 0.000 description 1
• PXLIDIMHPNPGMH-UHFFFAOYSA-N sodium chromate Chemical compound [Na+].[Na+].[O-][Cr]([O-])(=O)=O PXLIDIMHPNPGMH-UHFFFAOYSA-N 0.000 description 1
• NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
• 239000000758 substrate Substances 0.000 description 1
• LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
• 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
• 229910021653 sulphate ion Inorganic materials 0.000 description 1
• LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical class [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
• 238000005406 washing Methods 0.000 description 1