PL2633003T3 - Produkcja gazu syntezowego przez ogrzewanie utlenionej biomasy gorącym gazem uzyskiwanym z utleniania produktów resztkowych - Google Patents

Produkcja gazu syntezowego przez ogrzewanie utlenionej biomasy gorącym gazem uzyskiwanym z utleniania produktów resztkowych

Info

Publication number
PL2633003T3
PL2633003T3 PL11835379T PL11835379T PL2633003T3 PL 2633003 T3 PL2633003 T3 PL 2633003T3 PL 11835379 T PL11835379 T PL 11835379T PL 11835379 T PL11835379 T PL 11835379T PL 2633003 T3 PL2633003 T3 PL 2633003T3
Authority
PL
Poland
Prior art keywords
oxidation
production
residual products
synthesis gas
hot gas
Prior art date
Application number
PL11835379T
Other languages
English (en)
Inventor
Antonin Paquet
Martin Gagnon
Esteban Chornet
Original Assignee
Enerkem, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Enerkem, Inc. filed Critical Enerkem, Inc.
Publication of PL2633003T3 publication Critical patent/PL2633003T3/pl

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/04—Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
    • C10K1/046—Reducing the tar content
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/36—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using oxygen; using mixtures containing oxygen as gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/482—Gasifiers with stationary fluidised bed
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/485—Entrained flow gasifiers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/82—Gas withdrawal means
    • C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C10J2300/092—Wood, cellulose
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C10J2300/0976—Water as steam
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0993—Inert particles, e.g. as heat exchange medium in a fluidized or moving bed, heat carriers, sand
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0996—Calcium-containing inorganic materials, e.g. lime
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/12—Heating the gasifier
    • C10J2300/1253—Heating the gasifier by injecting hot gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656—Conversion of synthesis gas to chemicals
    • C10J2300/1659—Conversion of synthesis gas to chemicals to liquid hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1838—Autothermal gasification by injection of oxygen or steam
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1853—Steam reforming, i.e. injection of steam only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/02—Dust removal
    • C10K1/026—Dust removal by centrifugal forces
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Processing Of Solid Wastes (AREA)
  • Treatment Of Sludge (AREA)
  • Hydrogen, Water And Hydrids (AREA)
PL11835379T 2010-10-29 2011-10-18 Produkcja gazu syntezowego przez ogrzewanie utlenionej biomasy gorącym gazem uzyskiwanym z utleniania produktów resztkowych PL2633003T3 (pl)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US45599210P 2010-10-29 2010-10-29

Publications (1)

Publication Number Publication Date
PL2633003T3 true PL2633003T3 (pl) 2017-09-29

Family

ID=45992997

Family Applications (1)

Application Number Title Priority Date Filing Date
PL11835379T PL2633003T3 (pl) 2010-10-29 2011-10-18 Produkcja gazu syntezowego przez ogrzewanie utlenionej biomasy gorącym gazem uzyskiwanym z utleniania produktów resztkowych

Country Status (13)

Country Link
US (1) US8636923B2 (pl)
EP (1) EP2633003B1 (pl)
JP (1) JP6226423B2 (pl)
CN (1) CN103391988B (pl)
AU (1) AU2011320055A1 (pl)
BR (1) BR112013010087A2 (pl)
CA (1) CA2755612C (pl)
DK (1) DK2633003T3 (pl)
ES (1) ES2618420T3 (pl)
HU (1) HUE031990T2 (pl)
PL (1) PL2633003T3 (pl)
WO (1) WO2012055012A1 (pl)
ZA (1) ZA201302673B (pl)

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JPH0713597B2 (ja) 1989-01-19 1995-02-15 テルモ株式会社 酸素濃度測定用具
US10738249B2 (en) 2012-01-30 2020-08-11 Aries Gasification, Llc Universal feeder for gasification reactors
US9242219B2 (en) * 2012-01-30 2016-01-26 PHG Energy, LLC Fluidized bed biogasifier and method for gasifying biosolids
KR102092080B1 (ko) * 2012-07-09 2020-03-23 서던 컴퍼니 고 애쉬, 고 애쉬 용융 온도의 역청탄의 가스화
PL224212B1 (pl) * 2012-10-12 2016-11-30 Sarre Piotr Sposób zgazowania surowców węglonośnych, karbonizatów i węgli oraz układ urządzeń do prowadzenia tego procesu
JP2014205806A (ja) * 2013-04-15 2014-10-30 株式会社Ihi ガス化ガス生成システム
KR101455752B1 (ko) * 2013-04-22 2014-11-03 한국건설기술연구원 음식물 폐기물의 연료화 시스템 및 그 방법
CN105524665B (zh) * 2016-01-26 2018-10-26 成都易态科技有限公司 高温煤气过滤方法、系统
PL233286B1 (pl) * 2016-05-20 2019-09-30 Artur Welman Sposób i instalacja do strumieniowego zgazowania energetycznego paliwa stałego zwłaszcza węgla kamiennego, brunatnego oraz biomasy
CN106047413A (zh) * 2016-06-14 2016-10-26 山东大学 一种高一氧化碳浓度气化气的制备系统及制备方法
CN106904806B (zh) * 2017-04-27 2023-04-25 东方电气集团东方锅炉股份有限公司 一种污泥湿式氧化的一体化处理反应器及处理方法
RU2675864C1 (ru) * 2017-10-03 2018-12-25 Федеральное государственное бюджетное учреждение науки Объединенный институт высоких температур Российской академии наук (ОИВТ РАН) Способ получения синтез-газа с заданным соотношением между объемным содержанием водорода и монооксида углерода путем многостадийной пиролитической конверсии биомассы
CN113785035A (zh) * 2019-04-12 2021-12-10 埃讷肯公司 由使含碳材料气化和重整生产合成气
US12510295B2 (en) 2019-06-18 2025-12-30 Aries Clean Technologies Llc Inline particle size control for rotary drum drier recycle material
CN110903854A (zh) * 2019-11-18 2020-03-24 宁夏神耀科技有限责任公司 一种分体式气化装置
RU2756160C1 (ru) * 2020-12-11 2021-09-28 Федеральное государственное бюджетное учреждение высшего образования «Тамбовский государственный технический университет» (ФГБОУ ВО «ТГТУ») Способ получения синтез-газа из биоотходов
EP4086328B1 (en) * 2021-05-06 2024-08-28 GIDARA Energy B.V. Method and apparatus for industrial production of renewable synthetic fuels
CN113587104B (zh) * 2021-08-16 2024-04-05 昆明理工大学 一种垃圾热解废气净化系统及工艺
US11339337B1 (en) * 2021-08-19 2022-05-24 Aries Clean Technologies Llc Elimination of poly- and perfluoro alkyl substances (PFAS) in a wastewater biosolids gasification process using a thermal oxidizer and hydrated lime injection
JP2024540251A (ja) * 2021-10-29 2024-10-31 サイモンピエトリ エンタープライジーズ エルエルシー 建設および解体材料の処理およびガス化
US12565423B2 (en) 2023-01-26 2026-03-03 Valero Services, Inc. Process for producing hydrogen from natural gas

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US5900224A (en) * 1996-04-23 1999-05-04 Ebara Corporation Method for treating wastes by gasification
JP3964043B2 (ja) 1998-04-13 2007-08-22 新日本製鐵株式会社 廃棄物処理方法
JP3914474B2 (ja) 2002-07-09 2007-05-16 新日本製鐵株式会社 炭素質資源のガス化方法及びその装置
JP4731988B2 (ja) 2005-05-12 2011-07-27 新日本製鐵株式会社 炭素質資源のガス化方法及びその装置
US8888875B2 (en) * 2006-12-28 2014-11-18 Kellogg Brown & Root Llc Methods for feedstock pretreatment and transport to gasification
US20090093555A1 (en) * 2007-07-09 2009-04-09 Range Fuels, Inc. Methods and apparatus for producing syngas
US8137655B2 (en) 2008-04-29 2012-03-20 Enerkem Inc. Production and conditioning of synthesis gas obtained from biomass
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CN101412929B (zh) * 2008-11-28 2012-02-01 武汉凯迪工程技术研究总院有限公司 利用生物质制造合成气的高温气化工艺方法及系统
US8192647B2 (en) 2008-12-19 2012-06-05 Enerkem Inc. Production of synthesis gas through controlled oxidation of biomass
JP5153711B2 (ja) * 2009-03-31 2013-02-27 三井造船株式会社 ガス化装置、ガス化方法、および液体燃料製造設備

Also Published As

Publication number Publication date
DK2633003T3 (en) 2017-03-06
CA2755612C (en) 2015-06-16
ZA201302673B (en) 2014-10-29
JP6226423B2 (ja) 2017-11-08
EP2633003B1 (en) 2016-12-07
US20130026417A1 (en) 2013-01-31
CN103391988A (zh) 2013-11-13
CN103391988B (zh) 2017-04-26
BR112013010087A2 (pt) 2018-07-24
JP2013542291A (ja) 2013-11-21
WO2012055012A1 (en) 2012-05-03
US8636923B2 (en) 2014-01-28
HUE031990T2 (en) 2017-08-28
EP2633003A1 (en) 2013-09-04
CA2755612A1 (en) 2012-04-29
ES2618420T3 (es) 2017-06-21
EP2633003A4 (en) 2014-07-16
AU2011320055A1 (en) 2013-05-09

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