PL14599B1 - A way to prevent the formation of harmful calcium and magnesium soaps in baths. - Google Patents
A way to prevent the formation of harmful calcium and magnesium soaps in baths. Download PDFInfo
- Publication number
- PL14599B1 PL14599B1 PL14599A PL1459930A PL14599B1 PL 14599 B1 PL14599 B1 PL 14599B1 PL 14599 A PL14599 A PL 14599A PL 1459930 A PL1459930 A PL 1459930A PL 14599 B1 PL14599 B1 PL 14599B1
- Authority
- PL
- Poland
- Prior art keywords
- baths
- formation
- alcohols
- calcium
- prevent
- Prior art date
Links
- 239000000344 soap Substances 0.000 title claims description 12
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title claims description 7
- 229910052791 calcium Inorganic materials 0.000 title claims description 7
- 239000011575 calcium Substances 0.000 title claims description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims description 5
- 229910052749 magnesium Inorganic materials 0.000 title claims description 5
- 239000011777 magnesium Substances 0.000 title claims description 5
- 230000015572 biosynthetic process Effects 0.000 title claims description 4
- 150000001298 alcohols Chemical class 0.000 claims description 6
- -1 aliphatic alcohols Chemical class 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- 238000006277 sulfonation reaction Methods 0.000 claims description 3
- 150000001447 alkali salts Chemical class 0.000 claims description 2
- 150000003863 ammonium salts Chemical class 0.000 claims description 2
- 239000008233 hard water Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 5
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- 230000019635 sulfation Effects 0.000 claims 1
- 238000005670 sulfation reaction Methods 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 239000003568 Sodium, potassium and calcium salts of fatty acids Substances 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 229910000318 alkali metal phosphate Inorganic materials 0.000 description 1
- 235000013969 calcium salts of fatty acid Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 235000010933 magnesium salts of fatty acid Nutrition 0.000 description 1
- 239000001778 magnesium salts of fatty acids Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Description
Jak wiadomo, tworzenie sie mydel wapniowych i magnezowych, zwlaszcza przy traktowaniu materjalów wlókienni¬ czych, jest bardzo szkodliwe.Dotychczas proponowano, by w celu zwalczenia tej niedogodnosci do odjpowied- nich kapieli do traktowania dodawac sul¬ fonowane produkty olejowe, jak np, mydlo monopolowe.Wykryto, ze tworzeniu sie mydel wap¬ niowych i magnezowych w plynach, za¬ wierajacych obok soli wapniowych lub magnezowych mydlo albo wrazliwy na wapn olej turecki, mozna zapobiec, a na¬ wet wydzielone juz wapniowe i magnezo¬ we sole kwasów tluszczowych mozna prze¬ prowadzic w drobna zawiesine lub w roz¬ twór przez dodanie do owych plynów pro¬ duktów sulfonowania wyzszych alkoholi alifatycznych. Ilosci niezbedne do tego ce¬ lu sa znacznie mniejsze od ilosci mydla monopolowego, jakie nalezy uzyc do o- siagniecia tego samego wyniku. Najko¬ rzystniej jest dodawac sulfonowane alkoho¬ le, wzglednie ich sole alkaliczne lub amo¬ nowe, do twardej wody przed dodaniem mydla lub oleju tureckiego. W tym przy¬ padku przy wlasciwem dozowaniu wogóle nie wystepuje wydzielenie mydla wapnio*- wego i magnezowego, a roztwór pozostaje calkowicie przezroczysty. Natomiast sko.ro sulfonowane alkohole dodaje sie dopiero pododaniu mydla lub oleju tureckiego, wów¬ czas nastepuje WMd^vw»ystki'em rozjasnie¬ nie barazoi mefiief Kaplfeli, a po dodaniu wiekszych ilosci sulfonowanego alkoholu plyn staje sie prawie calkowicie przezro¬ czysty. Jednakze w tym przypadku zuzycie dodatkowego srodka jest wieksze, niz gdy mydlo lufo olej turecki dodaje sie do wody dopiero po uprzedniem jej skorygowaniu.Okazalo sie, ze do powyzszego celu na¬ daja sie zwlaszcza sulfonowane pochodne alkoholi, odpowiadajacych wyzszym kwa¬ som tluszczowym, jak np. sulfonowany al¬ kohol olktadecylowy lufo alkohol lauryno- wy. Zamiast tego ostatniego zwiazku moz¬ na z korzyscia uzywac mieszanine sulfono¬ wanych alkoholi tluszczowych, jaka sie o- trzymuje, przeprowadzajac kwasy tluszczu kokosowego w odpowiednia mieszanine al¬ koholi, która sie nastepnie sulfonuje.Jak sie okazalo, dzialanie sulfonowa¬ nych alkoholi tluszczowych mozna po¬ lepszyc przez uzycie ich w mieszaninie z drugorzedowemi fosforanami metali alka¬ licznych. Korzystna jest np. mieszanina, zawierajaca 30 czesci drugorzedowegó fosforanu sodowego na 70 czesci soli sodo¬ wej sulfonowanego alkoholu laurynowego.W wielu wypadkach okazalo sie, ze dodawanie wspomnianych zwiazków do Wody, uzywanej do plókania, jest takze bardzo korzystne. PLAs is well known, the formation of calcium and magnesium soaps, especially in the treatment of textile materials, is very detrimental. Hitherto it has been proposed to add sulfonated oil products, such as, for example, monopoly soap, to appropriate treatment baths to overcome this disadvantage. It has been found that the formation of calcium and magnesium soaps in liquids containing soap or lime-sensitive Turkish oil in addition to calcium or magnesium salts can be prevented, and that even the calcium and magnesium salts of fatty acids which have already been released can be prevented. To be finely suspended or in solution by adding sulfonation products of higher aliphatic alcohols to these fluids. The amounts required for this purpose are significantly less than the amounts of liquor soap that must be used to achieve the same result. It is most preferred to add the sulfonated alcohols or their alkali or ammonium salts to the hard water before adding the soap or Turkish oil. In this case, with proper dosing, no release of calcium and magnesium soap occurs and the solution remains completely transparent. On the other hand, the low-sulfonated alcohols are added only after the addition of soap or Turkish oil, then the WMd of the film brightens up Kaplfeli's barase and mephiief, and after adding larger amounts of sulfonated alcohol, the liquid becomes almost completely transparent. However, in this case, the consumption of the additional agent is greater than when soap or Turkish oil is added to the water only after it has been adjusted. It has turned out that especially sulfonated derivatives of alcohols corresponding to higher fatty acids, such as for example, sulfonated olctadecyl alcohol or lauric alcohol. Instead of the latter compound, one can advantageously use a mixture of sulfonated fatty alcohols, which is obtained, converting the coconut fatty acids into the appropriate alcohol mixture, which then sulfonates. As it turned out, the effect of sulfonated fatty alcohols can be obtained. improve by using them in a mixture with secondary alkali metal phosphates. For example, a mixture of 30 parts of secondary sodium phosphate to 70 parts of the sodium salt of sulphonated lauric alcohol is preferred. In many cases, the addition of these compounds to the water used for rinsing has proven to be very advantageous as well. PL
Claims (4)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL14599B1 true PL14599B1 (en) | 1931-10-31 |
Family
ID=
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| PH11493A (en) | Laundry detergent compositions in emulsion/suspension for | |
| US2383738A (en) | Detergent composition | |
| GB1329086A (en) | Bleaching composition | |
| KR930700631A (en) | Liquid detergent composition | |
| DE59102082D1 (en) | LIQUID, FLOWABLE AND PUMPABLE SURFACTANT CONCENTRATE. | |
| GB608923A (en) | Stable solid compositions for use in preparing cleansing and disinfecting solutions | |
| PL14599B1 (en) | A way to prevent the formation of harmful calcium and magnesium soaps in baths. | |
| US3728266A (en) | Liquid detergent composition | |
| US2757143A (en) | Detergent composition | |
| FR2171199B1 (en) | ||
| US3617207A (en) | Alkaline solutions containing certain alkylbenzene sulfonate wetting agents | |
| GB1014058A (en) | Washing composition | |
| US3342739A (en) | Detergent composition | |
| GB656248A (en) | A process for washing with soap or soap-containing washing agents and hard water or sea water and washing agents for this purpose | |
| GB523479A (en) | Improvements in and relating to detergent compositions | |
| US2296767A (en) | Detergent composition | |
| US2335466A (en) | Washing and cleaning composition | |
| GB551616A (en) | Improvements in washing agents and in the manufacture thereof | |
| GB1001966A (en) | Improvements in or relating to detergent compositions in bar form | |
| GB833201A (en) | Detergent compositions | |
| US1958860A (en) | Wetmng-out agent | |
| US1580952A (en) | Water-soluble essential oils and perfumes | |
| GB1046252A (en) | Improvements in and relating to surface active agents | |
| PL19679B1 (en) | Laundry detergents. | |
| GB424596A (en) | Improvements in or relating to soap substitutes |