PL122819B1 - Fungicide - Google Patents
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- PL122819B1 PL122819B1 PL1979230916A PL23091679A PL122819B1 PL 122819 B1 PL122819 B1 PL 122819B1 PL 1979230916 A PL1979230916 A PL 1979230916A PL 23091679 A PL23091679 A PL 23091679A PL 122819 B1 PL122819 B1 PL 122819B1
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- Poland
- Prior art keywords
- formula
- compound
- fungicide
- spraying
- plants
- Prior art date
Links
- 239000000417 fungicide Substances 0.000 title claims description 17
- 230000000855 fungicidal effect Effects 0.000 title claims description 12
- 150000001875 compounds Chemical group 0.000 claims description 20
- 239000013543 active substance Substances 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 5
- 229910052731 fluorine Chemical group 0.000 claims description 5
- 125000001153 fluoro group Chemical group F* 0.000 claims description 5
- 150000003230 pyrimidines Chemical class 0.000 claims description 5
- 239000000460 chlorine Substances 0.000 claims description 3
- 241000196324 Embryophyta Species 0.000 description 8
- 238000005507 spraying Methods 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 206010017533 Fungal infection Diseases 0.000 description 4
- 208000031888 Mycoses Diseases 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- NHOWDZOIZKMVAI-UHFFFAOYSA-N (2-chlorophenyl)(4-chlorophenyl)pyrimidin-5-ylmethanol Chemical compound C=1N=CN=CC=1C(C=1C(=CC=CC=1)Cl)(O)C1=CC=C(Cl)C=C1 NHOWDZOIZKMVAI-UHFFFAOYSA-N 0.000 description 3
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 235000008504 concentrate Nutrition 0.000 description 3
- 244000038559 crop plants Species 0.000 description 3
- 231100000252 nontoxic Toxicity 0.000 description 3
- 230000003000 nontoxic effect Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 229920001732 Lignosulfonate Polymers 0.000 description 2
- 239000005802 Mancozeb Substances 0.000 description 2
- -1 alkyl succinates Chemical class 0.000 description 2
- 239000011717 all-trans-retinol Substances 0.000 description 2
- 235000019169 all-trans-retinol Nutrition 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 239000007900 aqueous suspension Substances 0.000 description 2
- 229960000892 attapulgite Drugs 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 2
- 229910052625 palygorskite Inorganic materials 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000004563 wettable powder Substances 0.000 description 2
- SAPGTCDSBGMXCD-UHFFFAOYSA-N (2-chlorophenyl)-(4-fluorophenyl)-pyrimidin-5-ylmethanol Chemical compound C=1N=CN=CC=1C(C=1C(=CC=CC=1)Cl)(O)C1=CC=C(F)C=C1 SAPGTCDSBGMXCD-UHFFFAOYSA-N 0.000 description 1
- 240000004244 Cucurbita moschata Species 0.000 description 1
- 235000009854 Cucurbita moschata Nutrition 0.000 description 1
- 235000009852 Cucurbita pepo Nutrition 0.000 description 1
- 241000221785 Erysiphales Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 229910000503 Na-aluminosilicate Inorganic materials 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000004495 emulsifiable concentrate Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 235000019357 lignosulphonate Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- VSXGXPNADZQTGQ-UHFFFAOYSA-N oxirane;phenol Chemical class C1CO1.OC1=CC=CC=C1 VSXGXPNADZQTGQ-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229940083082 pyrimidine derivative acting on arteriolar smooth muscle Drugs 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000000429 sodium aluminium silicate Substances 0.000 description 1
- 235000012217 sodium aluminium silicate Nutrition 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 235000020354 squash Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
Description
Przedmiotem wynalazku jest srodek grzybobój¬ czy, stosowany do zwalczania infekcji grzybowych roslin uprawnych.Srodek grzybobójczy wedlug wynalazku zawiera jako substancje czynna pochodna pirymidyny o wzorze 1, w którym X oznacza atom chloru lub fluoru i zwiazek o wzorze 2, w polaczeniu z co najmniej jednym obojetnym, nietrujacym dla ros¬ lin nosnikiem.. Wyzej wymienione zwiazki sa znane, moga byc wytwarzane metodami opisanymi w literaturze.Pochodne pirymidyny o wzorze 1 przedstawiono w opisie patentowym Wielkiej Brytanii nr 1 218 623, a pochodna mocznika o wzorze 2 — w opisie pa¬ tentowym Wielkiej Brytanii nr 1 470 740.Nieoczekiwanie stwierdzono, ze nowy srodek grzybobójczy wedlug wynalazku zawierajacy mie¬ szanine podanych substancji czynnych jest sku¬ teczny w hamowaniu wzrostu lub zwalczaniu in¬ fekcji grzybowych roslin uprawnych. Jest on szcze¬ gólnie uzyteczny w zwalczaniu grzybów atakuja¬ cych szereg roslin uprawnych, takich jak zboza i fasola, a w szczególnosci roslin podatnych na atak maczniaka lub rdzy, tzn. roslin takich jak winorosl, dynia i tyton, podatnych na atak takich drobnoustrojów, jak Oomycastes i Erysiphales.Srodek grzybobójczy wedlug wynalazku stosuje sie do zwalczania infekcji grzybowych roslin, a zwlaszcza winorosli. Srodek stosuje sie do oprys- 10 ii 10 kiwania lisci lub gleby, w zaleznosci od rodzaju rosliny, w dowolnym etapie jej wzrostu, az do okresu zbiorów. Stopien i czestotliwosc opryski¬ wania zalezy od ostrosci lub spodziewanej ostro¬ sci zarazy grzybowej, a takze, co jest oczywiste dla fachowców, od wieku i stanu rosliny.Szczególna zaleta srodka grzybobójczego wedlug wynalazku polega jednak na tym, ze mozna go stosowac skutecznie ze zmniejszona czestotliwoscia, np. jedynie raz na 2 do 3 tygodni, przy zwalcza¬ niu maczniaka winnego, osiagajac w ten sposób znaczne obnizenie kosztów robocizny.Korzystna pochodna pirymidyny stosowana do opryskiwania lisci, np. winorosli, jest pochodna, w której X oznacza atom chloru. Okazalo sie jed¬ nak, ze w przypadku, gdy srodek grzybobójczy wedlug wynalazku stosuje sie do spryskiwania gleby, szczególnie uzyteczna jest ta pochodna pi¬ rymidyny o wzorze 1, gdzie X oznacza atom fluoru.Jak to zaznaczono powyzej i srodki grzybobójcze wedlug wynalazku stosowac mozna do opryskiwa¬ nia lisci lub gleby. Przy spryskiwaniu gleby zwia¬ zek o wzorze 1 korzystnie stosuje sie w ilosci od 50 do 500 g/ha.Przy spryskiwaniu lisci zwiazek o wzorze 1 ko¬ rzystnie stosuje sie w ilosci od 10 do 500 g/ha, a zwiazek o wzorze 2 korzystnie stosuje sie w ilo¬ sci od 50 do 500 g/ha. Zgodnie z tym stosunek wagowy zwiazku o wzorze 1 do zwiazku o wzo- 122 819122 819 rze 2 w srodkach grzybobójczych stosowanych do opryskiwania lisci wynosi korzystnie od 2:1 do 1:50.Zwiazek o wzorze 2 korzystnie stosuje sie w po¬ laczeniu z jeszcze innym srodkiem grzybobójczym, 5'" takim jak np. zineb lub mancozeb, tak jak to po¬ dano w opisie patentowym Wielkiej Brytanii nr 1470 740. Nalezy zaznaczyc, ze te dodatkowe srodki grzybobójcze stosuje sie w ilosci równej w przyblizeniu polowie ich normalnej dawki, io a takze, ze zwiazek o wzorze 2 nie da sie pogodzic ze zwiazkami zwiekszajacymi alkalicznosc.W celu uproszczenia wytwarzania, magazyno¬ wania i transportu, srodki grzybobójcze na pod¬ stawie zwiazków o-wzorze 1 i 2 zazwyczaj produ- 15 kuje sie w postaci koncentratu przeznaczonego do rozcienczania woda w stopniu niezbednym do uzyskania w prosty sposób wyzej wspomnianych dawek. Takie koncentraty srodka grzybobójczego zawieraja od 0,5 do 90^ a korzystnie od 5 do 90% 20 wagowych substancji czynnych w polaczeniu z co najmniej jednym obojetnym, nietrujacym dla roslin nosnikiem. Wytwarza sie je w postaci zwilzalnego proszku lub pylu, wodnej zawiesiny, koncentratu do emulgowania lub granulatu. 25 Koncentraty srodka grzybobójczego przeznaczone sa do odpowiedniego rozcienczania woda przed uzyciem.Wodna zawiesine mozna sporzadzac w zwyczaj¬ nych zbiornikach opryskiwaczy, nadajacych sie s0 do takiego celu. Oczywiste jest, ze tak Otrzymane rozcienczone preparaty równiez stanowia srodki grzybobójcze wedlug wynalazku, w którym jed¬ nym lub-wylacznym obojetnym nosnikiem nietru¬ jacym dla roslin jestwoda. & Zwilzalne proszki lub pyly zawieraja dokladnie wymieszane aktywne skladniki, jeden lub kilka obojetnych nosników oraz odpowiednie srodki po¬ wierzchniowo czynne. Obojetny nosnik moze sta¬ nowic glinka attapulgitowa, ziemia okrzemkowa, 40 kaolin, mika, talk oraz oczyszczone krzemiany.Skutecznymi srodkami powierzchniowo czynnymi sa sulfonowane ligniny, naftalenosulfoniany i skon¬ densowane naftalenosulfoniany, bursztyniany alki¬ lowe, alkilobenzenosulfoniany, siarczany alkilowe 45 oraz niejonowe srodki powierzchniowo czynne, ta¬ kie jak addukty tlenku etylenu z fenolem.Przykladem zwilzalnego proszku wchodzacego w zakres wynalazku jest preparat o nastepujacym skladzie: so % wagowe Zwiazek o wzorze1 — 1 do 10 Zwiazek o wzorze2 — 5 do 60 Srodek (srodki) powierzchniowo czynny — 0 do 10 Srodek dyspergujacy — 0 do 10 55 Srodek przeciwdzialajacy zbrylaniu — 0 do Wynalazek ilustruja nastepujace przyklady: zwiazek o wzorze 1, w którym X oznacza atom chloru, znany jest pod nazwa fenarimol, natomiast zwiazek pokrewny, w którym X oznacza atom fluoru, znany jest jako nuarimol. W ponizszych przykladach zwiazek o wzorze 2 oznaczony jest litera „C".Przyklady I —III. zwilzalne proszki: (I) Wytworzono nastepujace Zwiazek C Fenarimol Alkiloeterosiarczan sodowy Ligninosulfonian sodowy Krzemionka Attapulgit (II) Zwiazek C Fenarimol Zineb Sól sodowa skondensowanych kwa¬ sów naftaleno-sulfonowych Ligninosulfonian sodowy Uwodniony glinokrzemian sodowy Montmorylonit (III) Zwiazek C Fenarimol Mancozeb Proszek lugu siarczynowego Laurylosulfonian sodowy Krzemionka Kaolin % wagowe — 36,0 — 6,0 — 4,0 — 3,0 — 7,0 — do 100,0 % wagowe — 6,0 — 1,0 — 50,0 3,0 — 4,0 — 8,0 — do 100,0 % wagowe — 3,0 — 0,5 — 36,0 — 2,0 — 5,0 — 6,0 — do 100,0 Obojetny nosnik (nosniki) 15 — do 100 W kazdym z powyzszych przykladów substancje czynne dokladnie wymieszano z okreslonymi do¬ datkami w zwyklej mieszarce. Mieszanke rozdrob¬ niono dokladnie w mlynie fluidalnym na ziarno o srednicy od 1 do 10 firn, po czym ponownie wymieszano i odpowietrzono przed pakowaniem.Srodki opisane w przykladach I—III przeznaczone sa zwlaszcza do opryskiwania lisci.Zastrzezenia patentowe 1. Srodek grzybobójczy zawierajacy substancje czynna i obojetny nosnik, znamienny tym, ze jako substancje czynna zawiera pochodna pirymidyny o wzorze 1, w którym X oznacza atom chloru lub fluoru i zwiazek o wzorze 2. 2. Srodek wedlug zastrz. 1, znamienny tym, ze zawiera zwiazek o wzorze 1 i zwiazek o wzorze 2 w stosunku wagowym od 2:1 do 1:50.122819 j£—C —OH X Wzór 1 0 0 v C,H5NHCNHCCCN tacH3 IMzdr 2 PL PL PL The subject of the invention is a fungicide used to combat fungal infections of crop plants. The fungicide according to the invention contains as an active substance a pyrimidine derivative of formula 1, in which X is a chlorine or fluorine atom and a compound of formula 2, in combination with at least one an inert, non-toxic carrier for plants. The above-mentioned compounds are known and can be produced using methods described in the literature. Pyrimidine derivatives of the formula 1 are presented in the British patent description No. 1,218,623, and the urea derivative of the formula 2 - in the description pa. No. 1,470,740 of Great Britain. Surprisingly, it was found that the new fungicide according to the invention containing a mixture of the given active substances is effective in inhibiting the growth or combating fungal infections of crop plants. It is particularly useful in the control of fungi attacking a number of crop plants such as cereals and beans, and particularly plants susceptible to attack by mildew or rust, i.e. plants such as vines, squash and tobacco which are susceptible to attack by microorganisms such as Oomycastes and Erysiphales. The fungicide according to the invention is used to combat fungal infections of plants, especially vines. The agent is used for spraying leaves or soil, depending on the type of plant, at any stage of its growth until the harvest period. The degree and frequency of spraying depend on the severity or expected severity of the fungal infection and, as is obvious to those skilled in the art, on the age and condition of the plant. A particular advantage of the fungicide according to the invention, however, is that it can be used effectively with reduced frequency, e.g. only once every 2 to 3 weeks, in the control of vine mildew, thus achieving a significant reduction in labor costs. The preferred pyrimidine derivative used for spraying leaves, e.g. of vines, is the derivative in which X is a chlorine atom. It turned out, however, that when the fungicide according to the invention is used for spraying the soil, the pyrimidine derivative of formula 1, where X is a fluorine atom, is particularly useful. As noted above, the fungicides according to the invention can also be used for spraying leaves or soil. When spraying the soil, the compound of the formula 1 is preferably used in an amount of 50 to 500 g/ha. When spraying the leaves, the compound of the formula 1 is preferably used in an amount of 10 to 500 g/ha, and the compound of the formula 2 is preferably used are used in amounts from 50 to 500 g/ha. Accordingly, the weight ratio of the compound of formula 1 to the compound of formula 2 in foliar fungicides is preferably from 2:1 to 1:50. The compound of formula 2 is preferably used in combination with another another fungicide, 5" such as, for example, zineb or mancozeb, as described in British Patent No. 1,470,740. It should be noted that these additional fungicides are applied at approximately half their normal rate, and also that the compound of formula 2 cannot be reconciled with compounds increasing alkalinity. In order to simplify production, storage and transport, fungicides based on compounds of formula 1 and 2 are usually produced in the form concentrate intended for dilution with water to the extent necessary to obtain the above-mentioned doses in a simple manner. Such fungicide concentrates contain from 0.5 to 90°C and preferably from 5 to 90% by weight of active substances in combination with at least one inert, non-toxic plant carrier. They are produced in the form of a wettable powder or dust, an aqueous suspension, an emulsifiable concentrate or granules. 25 Fungicide concentrates are intended to be appropriately diluted with water before use. The aqueous suspension can be prepared in ordinary spray tanks suitable for this purpose. It is obvious that the diluted preparations obtained also constitute fungicides according to the invention, in which the one or only inert carrier non-toxic to plants is water. & Wettable powders or dusts contain thoroughly mixed active ingredients, one or more inert carriers and suitable surfactants. The inert carrier may be attapulgite clay, diatomaceous earth, kaolin, mica, talc and purified silicates. Effective surfactants include sulfonated lignins, naphthalenesulfonates and condensed naphthalenesulfonates, alkyl succinates, alkylbenzenesulfonates, alkyl sulfates and others. ionic agents surfactants, such as ethylene oxide-phenol adducts. An example of a wettable powder falling within the scope of the invention is a preparation having the following composition: 0 to 10 Dispersant - 0 to 10 55 Anti-caking agent - 0 to The invention is illustrated by the following examples: the compound of formula 1 in which X is a chlorine atom is known as fenarimol, and a related compound in which X is a fluorine atom, it is known as nuarimol. In the following examples, the compound of formula 2 is marked with the letter "C". Examples I-III. wettable powders: (I) The following were prepared Compound C Fenarimol Sodium alkyl ether sulfate Sodium lignin sulfonate Silica Attapulgite (II) Compound C Fenarimol Zineb Sodium salt of condensed naphthalene acids -sulfonic acids Sodium lignin sulfonate Hydrated sodium aluminosilicate Montmorillonite (III) Compound C Fenarimol Mancozeb Sulfite lique powder Sodium lauryl sulfonate Silica Kaolin % by weight - 36.0 - 6.0 - 4.0 - 3.0 - 7.0 - up to 100.0 % by weight - 6.0 - 1.0 - 50.0 3.0 - 4.0 - 8.0 - up to 100.0 % by weight - 3.0 - 0.5 - 36.0 - 2.0 - 5, 0 - 6.0 - up to 100.0 Inert carrier(s) 15 - up to 100 In each of the above examples, the active substances were thoroughly mixed with the specified additives in a conventional mixer. The mixture was finely ground in a fluidized bed mill into grains with a diameter of 1 to 10 firns, then mixed and deaerated again before packaging. The compositions described in Examples I-III are intended in particular for spraying leaves. Patent claims 1. A fungicide containing an active substance and an inert carrier, characterized in that the active substance contains a derivative pyrimidine of formula 1, wherein X is a chlorine or fluorine atom and a compound of formula 2. 2. The agent according to claim 1. 1, characterized in that it contains a compound of formula 1 and a compound of formula 2 in a weight ratio from 2:1 to 1:50.122819 j£—C —OH
Claims (2)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1282478 | 1978-04-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL122819B1 true PL122819B1 (en) | 1982-08-31 |
Family
ID=10011816
Family Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL1979214575A PL119526B1 (en) | 1978-04-01 | 1979-03-31 | Fungicide |
| PL1979230915A PL123456B1 (en) | 1978-04-01 | 1979-03-31 | Fungicide |
| PL1979230916A PL122819B1 (en) | 1978-04-01 | 1979-03-31 | Fungicide |
| PL1979230914A PL122824B1 (en) | 1978-04-01 | 1979-03-31 | Fungicide |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL1979214575A PL119526B1 (en) | 1978-04-01 | 1979-03-31 | Fungicide |
| PL1979230915A PL123456B1 (en) | 1978-04-01 | 1979-03-31 | Fungicide |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL1979230914A PL122824B1 (en) | 1978-04-01 | 1979-03-31 | Fungicide |
Country Status (34)
| Country | Link |
|---|---|
| JP (1) | JPS54132233A (en) |
| AR (4) | AR225414A1 (en) |
| AT (1) | AT364196B (en) |
| AU (1) | AU527924B2 (en) |
| BE (1) | BE875198A (en) |
| BG (4) | BG31364A3 (en) |
| BR (1) | BR7901929A (en) |
| CA (1) | CA1128854A (en) |
| CH (1) | CH638079A5 (en) |
| CS (4) | CS217977B2 (en) |
| DD (1) | DD143552A5 (en) |
| DE (1) | DE2912491A1 (en) |
| DK (4) | DK126779A (en) |
| EG (1) | EG13864A (en) |
| ES (1) | ES479135A1 (en) |
| FR (4) | FR2422332A1 (en) |
| GB (1) | GB2077591B (en) |
| GR (1) | GR67710B (en) |
| HU (2) | HU189633B (en) |
| IE (1) | IE47941B1 (en) |
| IL (1) | IL56963A (en) |
| IN (1) | IN149760B (en) |
| IT (1) | IT1120402B (en) |
| LU (1) | LU81096A1 (en) |
| NL (1) | NL7902435A (en) |
| NO (4) | NO147202C (en) |
| NZ (1) | NZ190062A (en) |
| PL (4) | PL119526B1 (en) |
| PT (1) | PT69407A (en) |
| RO (2) | RO75492A (en) |
| SE (4) | SE446811B (en) |
| SU (1) | SU1311600A3 (en) |
| TR (1) | TR20289A (en) |
| ZA (1) | ZA791494B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CS217977B2 (en) | 1978-04-01 | 1983-02-25 | Lilly Industries Ltd | Fungicide means |
| DE3326664A1 (en) * | 1982-07-29 | 1984-02-02 | Lilly Industries Ltd., London | Fungicidal agent and process for its preparation |
| ES2091078T3 (en) * | 1993-09-24 | 1996-10-16 | Basf Ag | FUNGICIDE MIXTURES. |
| PL224139B1 (en) | 2014-08-01 | 2016-11-30 | Ekobenz Spółka Z Ograniczoną Odpowiedzialnością | Fuel blend, particularly for engines with spark ignition |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3912752A (en) * | 1972-01-11 | 1975-10-14 | Bayer Ag | 1-Substituted-1,2,4-triazoles |
| OA04979A (en) * | 1974-04-09 | 1980-11-30 | Ciba Geigy | New aniline derivatives useful as microbicidal agents and their preparation process. |
| GB1561634A (en) * | 1975-10-29 | 1980-02-27 | Lilly Industries Ltd | Fungicidal compositions |
| DE2552967A1 (en) * | 1975-11-26 | 1977-06-08 | Bayer Ag | FUNGICIDALS |
| GB1559820A (en) * | 1975-12-09 | 1980-01-30 | Lilly Industries Ltd | Fungicidal compositions |
| GB1581527A (en) * | 1976-08-18 | 1980-12-17 | Lilly Industries Ltd | Fungicidal formulations |
| CS217977B2 (en) | 1978-04-01 | 1983-02-25 | Lilly Industries Ltd | Fungicide means |
-
1979
- 1979-03-23 CS CS802270A patent/CS217977B2/en unknown
- 1979-03-23 CS CS802269A patent/CS217976B2/en unknown
- 1979-03-23 CS CS802271A patent/CS217978B2/en unknown
- 1979-03-28 IL IL56963A patent/IL56963A/en unknown
- 1979-03-28 CA CA324,339A patent/CA1128854A/en not_active Expired
- 1979-03-28 EG EG190/79A patent/EG13864A/en active
- 1979-03-28 SE SE7902780A patent/SE446811B/en not_active IP Right Cessation
- 1979-03-28 AR AR275965A patent/AR225414A1/en active
- 1979-03-28 DK DK126779A patent/DK126779A/en not_active Application Discontinuation
- 1979-03-28 AU AU45485/79A patent/AU527924B2/en not_active Ceased
- 1979-03-28 FR FR7907805A patent/FR2422332A1/en active Granted
- 1979-03-28 GR GR58713A patent/GR67710B/el unknown
- 1979-03-29 BG BG043056A patent/BG31364A3/en unknown
- 1979-03-29 JP JP3768479A patent/JPS54132233A/en active Pending
- 1979-03-29 PT PT69407A patent/PT69407A/en unknown
- 1979-03-29 IN IN307/CAL/79A patent/IN149760B/en unknown
- 1979-03-29 BR BR7901929A patent/BR7901929A/en unknown
- 1979-03-29 BG BG045203A patent/BG31470A3/en unknown
- 1979-03-29 BE BE6/46792A patent/BE875198A/en not_active IP Right Cessation
- 1979-03-29 TR TR20289A patent/TR20289A/en unknown
- 1979-03-29 NL NL7902435A patent/NL7902435A/en not_active Application Discontinuation
- 1979-03-29 DE DE19792912491 patent/DE2912491A1/en not_active Ceased
- 1979-03-29 CH CH290179A patent/CH638079A5/en not_active IP Right Cessation
- 1979-03-29 ZA ZA791494A patent/ZA791494B/en unknown
- 1979-03-29 LU LU81096A patent/LU81096A1/en unknown
- 1979-03-29 BG BG045202A patent/BG31469A3/en unknown
- 1979-03-29 BG BG045204A patent/BG31471A3/en unknown
- 1979-03-29 CS CS792108A patent/CS221251B2/en unknown
- 1979-03-30 AT AT0239679A patent/AT364196B/en not_active IP Right Cessation
- 1979-03-30 HU HU83114A patent/HU189633B/en unknown
- 1979-03-30 IT IT48541/79A patent/IT1120402B/en active
- 1979-03-30 SU SU792748355A patent/SU1311600A3/en active
- 1979-03-30 HU HU79LI338A patent/HU182518B/en unknown
- 1979-03-30 ES ES479135A patent/ES479135A1/en not_active Expired
- 1979-03-30 RO RO7997081A patent/RO75492A/en unknown
- 1979-03-30 NZ NZ190062A patent/NZ190062A/en unknown
- 1979-03-30 GB GB8112001A patent/GB2077591B/en not_active Expired
- 1979-03-30 NO NO791074A patent/NO147202C/en unknown
- 1979-03-30 DD DD79211922A patent/DD143552A5/en unknown
- 1979-03-30 RO RO79102292A patent/RO80251A/en unknown
- 1979-03-31 PL PL1979214575A patent/PL119526B1/en unknown
- 1979-03-31 PL PL1979230915A patent/PL123456B1/en unknown
- 1979-03-31 PL PL1979230916A patent/PL122819B1/en unknown
- 1979-03-31 PL PL1979230914A patent/PL122824B1/en unknown
- 1979-06-29 FR FR7916985A patent/FR2424702A1/en active Granted
- 1979-06-29 FR FR7916982A patent/FR2424701A1/en active Granted
- 1979-06-29 FR FR7916986A patent/FR2424703A1/en active Granted
- 1979-08-08 IE IE665/79A patent/IE47941B1/en unknown
-
1981
- 1981-08-06 AR AR286354A patent/AR228962A1/en active
- 1981-08-06 AR AR286356A patent/AR227933A1/en active
- 1981-08-06 AR AR286355A patent/AR227932A1/en active
-
1982
- 1982-06-30 NO NO822278A patent/NO148768C/en unknown
- 1982-06-30 NO NO822279A patent/NO148767C/en unknown
- 1982-06-30 NO NO822277A patent/NO148766C/en unknown
-
1984
- 1984-02-22 SE SE8400978A patent/SE8400978L/en not_active Application Discontinuation
- 1984-02-22 SE SE8400977A patent/SE8400977D0/en not_active Application Discontinuation
- 1984-02-22 SE SE8400976A patent/SE454399B/en not_active IP Right Cessation
-
1988
- 1988-03-04 DK DK120588A patent/DK120588A/en not_active Application Discontinuation
- 1988-03-04 DK DK120688A patent/DK120688D0/en not_active Application Discontinuation
- 1988-03-04 DK DK120788A patent/DK120788D0/en unknown
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