PL111282B1 - Binder for moulding and core sands - Google Patents

Binder for moulding and core sands Download PDF

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Publication number
PL111282B1
PL111282B1 PL20300277A PL20300277A PL111282B1 PL 111282 B1 PL111282 B1 PL 111282B1 PL 20300277 A PL20300277 A PL 20300277A PL 20300277 A PL20300277 A PL 20300277A PL 111282 B1 PL111282 B1 PL 111282B1
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PL
Poland
Prior art keywords
binder
cores
moulding
weight
modifier
Prior art date
Application number
PL20300277A
Other languages
Polish (pl)
Other versions
PL203002A1 (en
Inventor
Dominik Wajszel
Original Assignee
Akad Gorniczo Hutnicza
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Akad Gorniczo Hutnicza filed Critical Akad Gorniczo Hutnicza
Priority to PL20300277A priority Critical patent/PL111282B1/en
Publication of PL203002A1 publication Critical patent/PL203002A1/en
Publication of PL111282B1 publication Critical patent/PL111282B1/en

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Description

Przedmiotem wynalazku jest spoiwo, znajdujace zastosowanie w odlewnictwie do wytwarzania mas rdzeniowych lub formierskich.Znane spoiwa to zywice moeznikowo-formalds^ hydowe, stosowane zwlaszcza do produkcji rdzeni metoda „goracej rdzennicy". Jak wykazaly prze¬ prowadzone badania, zywice te, zmieszane z kwas¬ nym utwardzaczem, na przyklad' z salmiakiem, daja spoiwo, które w zaleznosci od temperatury i czasu, nadaje rdzeniom wlasnosci wytrzymalo¬ sciowe, charakteryzujace sie wystepowaniem dwóch maksymalnych wartosci wytrzymalosci, po¬ miedzy którymi lokuje sie glebokie minimum. Ten niekorzystny przebieg zmian wytrzymalosciowych rdzeni, wytworzonych z opisanym spoiwem, pro¬ wadzi w praktyce przemyslowej do powstawania duzej ilosci braków, gdyz konieczne jest scisle przestrzeganie czasu i temperatury utwardzania.Wada opisanego wyzej spoiwa jest równiez i to, ze rdzenie z tym spoiwem przechodza po niezbyt dlugim czasie w stan termoplastyczny, uniemozli¬ wiajacy wyjecie ich z goracej rdzennicy bez zde¬ formowania.Wymienionych wad nie wykazuje spoiwo, o- , trzymywane z zywicy mocznikowo-formaldehydo- wej, modyfikowanej alkoholem furfurylowym. Jed¬ nakze wysoki koszt stosowanego modyfikatora po¬ draza produkcje spoiwa, a tym samym wytwarza¬ nie rdzeni. 10 19 20 25 30 Celem wynalazku jest opracowanie skladu spoi¬ wa, zapewniajacego wysoka jakosc rdzeni lub form sporzadzanych z udzialem tego spoiwa oraz eliminujacego inne wady znanych spoiw.Istota wynalazku polega na tym, ze spoiwo, skladajace sie z zywicy mocznikowo-formaldehy- dowej, i utwardzacza, zawiera jako modyfikator ekstrakt z tytoniu w ilosci 10—70% ciezarowych, korzystnie 20% ciezarowych, w przeliczeniu na su¬ che skladniki.Zaleta spoiwa, wedlug wynalazku, jest zapew¬ nienie wytworzonym rdzeniom lub formom wyso¬ kiej jakosci, zwlaszcza podwyzszenie ich wytrzy¬ malosci na zginanie w porównaniu do wytrzyma¬ losci rdzeni lub form z dodatkiem znanych spoiw.Dzieki wprowadzeniu ekstraktu tytoniowego do spoiwa uzyskuje sie wielokrotne wydluzenie cza¬ su pojawienia sie niepozadanego efektu termopla- stycznosci.Zastosowanie w spoiwie, jako modyfikatora eks¬ traktu tytoniowego obniza znacznie koszt produk¬ cji spoiwa.Przyklad. Spoiwo zawiera nastepujace sklad¬ niki, liczone jako substancje suche: zywica mocznikowo-formaldehydowa 80% cieza¬ rowych ekstrakt z tytoniu 20% ciezarowych Masa rdzeniowa zawiera 1,-83% ciezarowych su¬ chej substancji tego spoiwa oraz 10 cm8 utwar- 111282111282 dzacza kwasnego, otrzymanego z 30% wodnego roz¬ tworu azotanu glinu dziewieciowodnego i wody amoniakalnej o gestosci bezwzglednej 0,965, wzie¬ tych w równych objetosciach.Badania znormalizowanych ksztaltek plaskich wykazaly, ze rdzenie, wykonane metoda wstrzeli¬ wania do goracej rdzennicy, osiagaja maksimum wytrzymalosci na zginanie w temperaturze 270°C, po czasie 7—10 sekund, wynoszace 7,0 MN/m?.Efekt termoplastycznosci mierzony równiez na znormalizowanych plaskich ksztaltkach wystepuje u rdzeni po 40 sekundach utwardzania w wyzej wymienionej temperaturze. Dla porównania podaje sie, ze rdzenie wykonane z udzialem spoiwa mocz- 10 nikowo-formaldehydowego nie zawierajacego ek¬ straktu z tytoniu wykazuja w tych samych warun¬ kach badania maksymalna wytrzymalosc na zgi¬ nanie 6,0 MN/m2, zas czas pojawienia sie termo¬ plastycznosci wynosi 20 sekund.Zastrzezenie patentowe Spoiwo do mas formierskich i .rdzeniowych, skla¬ dajace sie z zywicy mocznikowo-formaldehydowej, modyfikatora i utwardzacza, znamienne tym, ze , jako modyfikator zawiera ekstrakt z tytoniu w ilosci 10—70% ciezarowych, korzystnie 20% cieza¬ rowych, w przeliczeniu na suche skladniki.DN-3, z. 147/81 Cena 45 zl PLThe subject of the invention is a binder that can be used in foundry for the production of cores or molding sands. Known binders are canes-formaldehyde resins, used in particular for the production of cores using the "hot core box" method. As the research carried out has shown, these resins mixed with acid With a hardener, for example with ammonium chloride, they give a binder which, depending on temperature and time, gives the cores strength properties, characterized by the presence of two maximum strength values, between which there is a deep minimum. This unfavorable course of strength changes the cores produced with the described binder lead in industrial practice to the formation of a large number of shortages, because it is necessary to strictly observe the hardening time and temperature. Another disadvantage of the binder described above is also that the cores with this binder undergo a state of shortage after a short time. thermoplastic, making it impossible to remove them from the hot core The binder, made of urea-formaldehyde resin, modified with furfuryl alcohol, does not show the above-mentioned disadvantages. However, the high cost of the modifier used exposes the production of the binder and thus the production of the cores. The object of the invention is to provide a binder composition that ensures high-quality cores or molds made with this binder and overcomes other drawbacks of known binders. The essence of the invention is that the binder, consisting of a urea-formaldehyde resin, and the hardener, it contains as a modifier tobacco extract in an amount of 10-70 wt.%, preferably 20 wt.%, based on the dry ingredients. The advantage of the binder, according to the invention, is to ensure the obtained cores or molds of a high quality, especially the increase in their bending strength compared to the strength of the cores or molds with the addition of known binders. By introducing tobacco extract into the binder, the time of the undesirable thermoplasticity effect is prolonged many times. Application in the binder as an exs modifier. The tobacco stock considerably reduces the production cost of the binder. Example. The binder contains the following components, calculated as dry substances: urea-formaldehyde resin 80% by weight tobacco extract 20% by weight The core weight contains 1.-83% by weight of dry substance of this binder and 10 cm8 of hardener 111282111282 , obtained from a 30% aqueous solution of aluminum nitrate nine-water and ammonia water with an absolute density of 0.965, taken in equal volumes. Tests of standardized flat shapes have shown that the cores, made by the hot core box method, achieve maximum bending strength at 270 ° C, after 7-10 seconds, amounting to 7.0 MN / m2. The thermoplasticity effect, also measured on standardized flat shapes, occurs in the cores after 40 seconds of curing at the above-mentioned temperature. For comparison, it is reported that cores made with a urea-formaldehyde binder containing no tobacco extract showed, under the same test conditions, a maximum bending strength of 6.0 MN / m2, and the time of appearance Plasticity is 20 seconds. Patent claim Binder for molding and core sands, consisting of urea-formaldehyde resin, modifier and hardener, characterized in that the modifier comprises tobacco extract in an amount of 10-70% by weight, preferably 20% by weight, calculated as dry ingredients DN-3, z. 147/81 Price PLN 45 PL

Claims (1)

1. Zastrzezenie patentowe Spoiwo do mas formierskich i .rdzeniowych, skla¬ dajace sie z zywicy mocznikowo-formaldehydowej, modyfikatora i utwardzacza, znamienne tym, ze , jako modyfikator zawiera ekstrakt z tytoniu w ilosci 10—70% ciezarowych, korzystnie 20% cieza¬ rowych, w przeliczeniu na suche skladniki. DN-3, z. 147/81 Cena 45 zl PL1. Patent claim Binder for molding and core sands, consisting of urea-formaldehyde resin, modifier and hardener, characterized in that the modifier contains tobacco extract in an amount of 10-70% by weight, preferably 20% by weight. in terms of dry ingredients. DN-3, z. 147/81 Price PLN 45 PL
PL20300277A 1977-12-14 1977-12-14 Binder for moulding and core sands PL111282B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL20300277A PL111282B1 (en) 1977-12-14 1977-12-14 Binder for moulding and core sands

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL20300277A PL111282B1 (en) 1977-12-14 1977-12-14 Binder for moulding and core sands

Publications (2)

Publication Number Publication Date
PL203002A1 PL203002A1 (en) 1979-07-16
PL111282B1 true PL111282B1 (en) 1980-08-30

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PL203002A1 (en) 1979-07-16

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