PL110472B2 - Binder for emulsion,fluorescing paints,especially for colouring roof coatings and building elements - Google Patents

Binder for emulsion,fluorescing paints,especially for colouring roof coatings and building elements Download PDF

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Publication number
PL110472B2
PL110472B2 PL19455676A PL19455676A PL110472B2 PL 110472 B2 PL110472 B2 PL 110472B2 PL 19455676 A PL19455676 A PL 19455676A PL 19455676 A PL19455676 A PL 19455676A PL 110472 B2 PL110472 B2 PL 110472B2
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weight
emulsion
parts
binder
paints
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PL19455676A
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Polish (pl)
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Description

Przedmiotem wynalazku jest emulsyjne spoiwo do farb fluoryzujacych, zwlaszcza do koloryzowania pokryc dachowych i elementów budowlanych, takich jak: papa, eternit, dachówki, beton, drewno, tynk itp.Znane sa farby fluoryzujace oparte na pojedynczych dyspersjach akrylowych oraz emulsji polioctanu winylu.Farby te posiadaja powazna wade, a mianowicie reaguja z pigmentami rozpuszczajac je lub speczniajaca farby ze spoiwa na bazie polioctanu winylu cechuje oprócz tego slaba wodoodpornosc i duza scieralnosc.Okazalo sie, ze laczne zastosowanie tych dwu wyzej wymienionych rodzajów spoiw, a mianowicie w proporcji 5—60 czesci wagowych'emulsji winyloakrylowej i 5—34 czesci wagowych polioctanu winylu z dodatkiem 0,5—2 czesci wagowych emulgatora skladajacego sie z 1 czesci wagowej polioksyetylenowanego nonylofenolu, korzystnie z 8 molami tlenku etylenu i 2 czesci wagowych polioksyetylenowanej aminy tluszczowej, korzystnie z 8 molami tlenku etylenu, daje spoiwo do emulsyjnych farb fluoryzujacych o zupelnie nieoczekiwanych wlasnosciach, a mianowicie nie reagujace z organicznymi pigmentami o zwiekszonej przyczep¬ nosci, wodoodpornosci i elastycznosci powloki farby. Wskazuje to na synergizm skladników spoiwa wedlug wynalazku, a zwlaszcza emulgatora, który w tym zestawie wplywa w istotnym stopniu na uzyskanie wyzej wymienionych nowych i nieoczekiwanych wlasnosci spoiwa.Emulsyjne farby fluoryzujace na spoiwie wedlug wynalazku dzieki zapobieganiu migracji smoly i innych substancji organicznych przez powloki naniesionych farb sa szczególnie przydatne do koloryzowania papy i innych pokryc dachowych. Emulsyjne farby fluoryzujace oparte na spoiwie wedlug wynalazku moga równiez znalezc zastosowanie do koloryzowania domków campingowych i letniskowych, pawilonów handlowych itp.. Przyklad I.5 czesci wagowych emulsji winyloakrylowej, 34 czesci wagowe emulsji polioctanu winylu i 0,5 czesci wagowych emulgatora skladajacego sie z 1/6 czesci wagowej pol ioksyetylenowanego nonylofenolu z 8 molami tlenku etylenu i 1/3 czesci wagowej polioksyetylenowanej aminy tluszczowej z 8 molami tlenku2 110 472 etylenu, miesza sie ze soba i otrzymuje spoiwo do emulsyjnych farb fluoryzujacych nie reagujace z organicznymi pigmentami oraz dajace dostateczna wodoodpornosc, elastycznosc i duza przyczepnosc powloki farby.Przyklad II. 24 czesci wagowe emulsji winyloakrylowej, 15 czesci wagowych emulsji polioctanu winylu i 0,75 czesci wagowych emulgatora skladajacego sie z 0,25 czesci wagowych polioksyetylowanego nonylofenolu z 8 molami tlenku etylenu i 0,5 czesci polioksyetylenowanej aminy tluszczowej z 8 molami tlenku etylenu, miesza sie ze soba i otrzymuje spoiwo do emulsyjnych farb fluoryzujacych nie reagujace z organicznymi pigmentami oraz dajace wodoodpornosc, elastycznosc i duza przyczepnosc powloki farby.Przyklad III. 60 czesci wagowych emulsji winyloakrylowej, 5 czesci wagowych emulsji polioctanu winylu i 2 czesci wagowe emulgatora skladajacego sie z 2/3 czesci wagowych polioksyetylenowanego nonylofenolu z 8 molami tlenku etylenu i 4/3 czesci wagowych polioksyetylenowanej aminy tluszczowej z 8 molami tlenku etylenu, miesza sie ze soba i otrzymuje spoiwo do emulsyjnych farb fluoryzujacych nie reagujace z organicznymi pigmentami oraz dajace duza wodoodpornosc, elastycznosc i dostateczna przyczepnosc powloki farby.Spoiwo do emulsyjnych farb fluoryzujacych oparte na pojedynczej dyspersji winyloakrylowej reaguje z organicznymi pigmentami rozpuszczajac je lub speczniajac oraz daje niedostateczna wodoodpornosc i przyczep¬ nosc powloki farby.Równiez spoiwo do emulsyjnych farb fluoryzujacych oparte na pojedynczej emulsji polioctanu winylu reaguje z organicznymi pigmentami rozpuszczajac je lub speczniajac oraz daje slaba wodoodpornosc, duza scieralnosc i niedostateczna przyczepnosc powloki farby.Zastrzezenie patentowe Spoiwo do emulsyjnych farb fluoryzujacych, zwlaszcza do koloryzowania pokryc dachowych i elementów budowlanych, na bazie dyspersji tworzyw polimeryzacyjnych, znamienne t y m, ze zawiera 5—60 czesci wagowych emulsji winyloakrylowej, 5—34 czesci wagowych emulsji polioctanu winylu i 0,5—2 czesci wagowych emulgatora skladajacego sie z 1 czesci wagowej polioksyetylenowanego nonylofenolu, korzystnie z 8 molami tlenku etylenu i 2 czesci wagowych polioksyetylenowanej aminy tluszczowej, korzystnie z 8 molami tlenku etylenu.Prac. Poligraf. UP P RL naklad 120+18 Cena 45 zl PLThe subject of the invention is an emulsion binder for fluorescent paints, especially for coloring roofing and building elements such as: tar paper, eternit, roof tiles, concrete, wood, plaster, etc. Fluorescent paints based on single acrylic dispersions and polyvinyl acetate emulsions are known. they have a serious disadvantage, namely they react with pigments by dissolving them or foaming paints made of polyvinyl acetate binders, they are also characterized by poor water resistance and high abrasion. It turned out that the combined use of these two types of binders, namely in a proportion of 5 to 60 parts by weight of vinylacrylic emulsion and 5-34 parts by weight of polyvinyl acetate with the addition of 0.5-2 parts by weight of an emulsifier consisting of 1 part by weight of polyoxyethylene nonylphenol, preferably 8 moles of ethylene oxide and 2 parts by weight of polyoxyethylene fatty amine, preferably with 8 moles of oxide ethylene, gives a binder for fluorescent emulsion paints fully unexpected properties, namely non-reactive with organic pigments with increased adhesion, water resistance and elasticity of the paint coating. This indicates the synergism of the components of the binder according to the invention, and especially the emulsifier, which in this set significantly influences the achievement of the above-mentioned new and unexpected properties of the binder. Fluorescent emulsion paints on the binder according to the invention by preventing the migration of tar and other organic substances through the coatings applied they are especially useful for coloring felt and other roofing materials. The binder-based emulsion fluorescent paints according to the invention may also find use in the coloring of bungalows and summerhouses, commercial pavilions, etc. Example I.5 parts by weight of vinyl acrylic emulsion, 34 parts by weight of polyvinyl acetate emulsion and 0.5 parts by weight of an emulsifier consisting of 1 / 6 parts by weight of polyoxyethylene nonylphenol with 8 moles of ethylene oxide and 1/3 part by weight of polyoxyethylene fatty amine with 8 moles of ethylene oxide2 110 472, mixed with each other and obtained a binder for fluorescent emulsion paints that do not react with organic pigments and provide sufficient water resistance, flexibility and high adhesion of the paint film Example II. 24 parts by weight of vinyl acrylic emulsion, 15 parts by weight of polyvinyl acetate emulsion and 0.75 parts by weight of an emulsifier consisting of 0.25 parts by weight of polyoxyethylated nonylphenol with 8 moles of ethylene oxide and 0.5 parts of polyoxyethylene fatty amine with 8 moles of ethylene oxide, mixed with with himself and receives a binder for fluorescent emulsion paints that do not react with organic pigments and provide water resistance, flexibility and high adhesion of the paint coating. Example III. 60 parts by weight of vinyl acrylic emulsion, 5 parts by weight of polyvinyl acetate emulsion and 2 parts by weight of an emulsifier consisting of 2/3 parts by weight of polyoxyethylene nonylphenol with 8 moles of ethylene oxide and 4/3 parts by weight of polyoxyethylene fatty amine with 8 moles of ethylene oxide, mixed with Binder for fluorescent emulsion paints that does not react with organic pigments and provides high water resistance, flexibility and sufficient adhesion of the paint coating. Coating resistance of the paint. Also the binder for fluorescent emulsion paints based on a single emulsion of polyvinyl acetate reacts with the organic pigments, dissolving or foaming them and gives poor water resistance, high abrasion and insufficient adhesion of the paint coating. Patent binder for fluorescent emulsion paints, especially for coloring roofing and building elements, based on dispersion of polymerization materials, characterized in that it contains 5-60 parts by weight of vinylacrylic emulsion, 5-34 parts by weight of polyvinyl acetate emulsion and 0.5-2 parts by weight by weight of an emulsifier consisting of 1 part by weight of polyoxyethylene nonylphenol, preferably with 8 moles of ethylene oxide and 2 parts by weight of polyoxyethylene fatty amine, preferably with 8 moles of ethylene oxide. Typographer. UP P RL quantity 120 + 18 Price PLN 45 PL

Claims (1)

1. Zastrzezenie patentowe Spoiwo do emulsyjnych farb fluoryzujacych, zwlaszcza do koloryzowania pokryc dachowych i elementów budowlanych, na bazie dyspersji tworzyw polimeryzacyjnych, znamienne t y m, ze zawiera 5—60 czesci wagowych emulsji winyloakrylowej, 5—34 czesci wagowych emulsji polioctanu winylu i 0,5—2 czesci wagowych emulgatora skladajacego sie z 1 czesci wagowej polioksyetylenowanego nonylofenolu, korzystnie z 8 molami tlenku etylenu i 2 czesci wagowych polioksyetylenowanej aminy tluszczowej, korzystnie z 8 molami tlenku etylenu. Prac. Poligraf. UP P RL naklad 120+18 Cena 45 zl PL1. Patent claim Binder for fluorescent emulsion paints, especially for coloring roofing and building elements, based on polymerization material dispersions, characterized in that it contains 5-60 parts by weight of vinylacrylic emulsion, 5-34 parts by weight of polyvinyl acetate emulsion and 0.5 - 2 parts by weight of an emulsifier consisting of 1 part by weight of polyoxyethylene nonylphenol, preferably with 8 moles of ethylene oxide and 2 parts by weight of polyoxyethylene fatty amine, preferably with 8 moles of ethylene oxide. Wash. Typographer. UP P RL quantity 120 + 18 Price PLN 45 PL
PL19455676A 1976-12-18 1976-12-18 Binder for emulsion,fluorescing paints,especially for colouring roof coatings and building elements PL110472B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL19455676A PL110472B2 (en) 1976-12-18 1976-12-18 Binder for emulsion,fluorescing paints,especially for colouring roof coatings and building elements

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL19455676A PL110472B2 (en) 1976-12-18 1976-12-18 Binder for emulsion,fluorescing paints,especially for colouring roof coatings and building elements

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PL110472B2 true PL110472B2 (en) 1980-07-31

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