PL10168B3 - Method for the preparation of disodium salts of 4-imino-methylene-sulfuric-2-metallocapto-benzole-i-sulfonic acids. - Google Patents
Method for the preparation of disodium salts of 4-imino-methylene-sulfuric-2-metallocapto-benzole-i-sulfonic acids. Download PDFInfo
- Publication number
- PL10168B3 PL10168B3 PL10168A PL1016826A PL10168B3 PL 10168 B3 PL10168 B3 PL 10168B3 PL 10168 A PL10168 A PL 10168A PL 1016826 A PL1016826 A PL 1016826A PL 10168 B3 PL10168 B3 PL 10168B3
- Authority
- PL
- Poland
- Prior art keywords
- imino
- sulfonic acids
- methylene
- metallocapto
- benzole
- Prior art date
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- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 title claims description 4
- XLNOKJLJDWVOQP-UHFFFAOYSA-L disodium;formaldehyde;sulfite Chemical compound [Na+].[Na+].O=C.[O-]S([O-])=O XLNOKJLJDWVOQP-UHFFFAOYSA-L 0.000 claims description 4
- 159000000000 sodium salts Chemical class 0.000 claims description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 1
- 150000003460 sulfonic acids Chemical class 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000009835 boiling Methods 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Substances SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 1
- 239000004552 water soluble powder Substances 0.000 description 1
Description
Najdluzszy czas trwania patentu do 24 stycznia 1944 r.The longest patent term is January 24, 1944.
Opisana w patencie Nr 9910 sól dwuso- dowa kwasu 4-imino-metyleno-siarkawo-2- zloto-merkapto-benzeno-7-sulfonowego (po¬ równaj przyklad III) moze byc tez otrzy¬ mana, jak to zostalo znalezione, na drodze dzialania siarczynem-formaldehydo-sodo- wym na sól sodowa kwasu 4-amino-2-zloto- merkapto-benzeno-7-sulfonowego (porów¬ naj przyklad II patentu glównego).The disodium salt of 4-imino-methylene-sulfurous-2-gold-mercapto-benzene-7-sulfonic acid described in Patent No. 9910 (e.g., Example III) can also be obtained, as has been found, by action of sodium sulfite-formaldehyde on the sodium salt of 4-amino-2-gold-mercapto-benzene-7-sulfonic acid (see Example 2 of the main patent).
W podobny sposób dochodzi sie do ana: logicznych zwiazków, podstawionych ciez- kiemi metalami.The ana is reached in a similar way: logical relations, substituted with heavy metals.
Przyklad I. Rozpuszcza sie 42,3 czesci i-amino-2-zloto-merkapto-benzeno-/-sulfo- nianu sodu w 200-stu czesciach wody, doda¬ je sie 13 czesci siarczynu-formaidehydo- sodowego i powstaly roztwór ogrzewa do wrzenia przy jednoczesnem sklócaniu. Po¬ tem z cieczy po ochlodzeniu jej wytraca sie alkoholem powstaly zwiazek kwasno- siarczyno-formaldehydowy. Zwiazek ten jest jasno-zólty, latwo rozpuszcza sie w wodzie i zawiera 36% zlota.EXAMPLE 1 42.3 parts of sodium i-amino-2-gold-mercapto-benzene-n-sulphonate are dissolved in 200 parts of water, 13 parts of sodium formidehydrate sulphite are added and the resulting solution is heated to boiling while confusing After cooling the liquid, the acid-sulfite-formaldehyde compound formed is precipitated with alcohol. This compound is light yellow, easily dissolves in water and contains 36% gold.
Przyklad II. 33,4 czesci 4-amino-2-sre- bro-merkapto-benzeno-/-sulfonianu sodu rozpuszcza sie w 150-ciu czesciach wody, dodaje 14 czesci siarczynu-formaldehydo- sodowego i roztwór ogrzewa do wrzenia przy jednoczesnem sklócaniu. Po ochlodze* niu, wytraca sie zapomoca alkoholu po-wstaly zwiazek kwasno-siarczyno-formal- dehydowy.Example II. 33.4 parts of sodium 4-amino-2-silver-mercapto-benzene sulphonate are dissolved in 150 parts of water, 14 parts of sodium formaldehyde sulphite are added and the solution is heated to the boil while quenching. After cooling, the resulting acid-sulfite-formaldehyde compound is destroyed with alcohol.
Spl dwusodowa- k^jasu 4-imino-metyle- no-siarkawo-2-srebro-merkapto-benzeno-7- sulfonowego jest proszkiem zlekka zabar¬ wionym na zólto, w wodzie latwo rozpu¬ szczalnym, o zawartosci srebra w wysoko¬ sci 24%, Przyklad III, Rozpuszcza sie 29,5 czesci 4-amino-2-bizmuto-merkapto - benzeno - 7- sulfonianu sodu w 150 czesciach wody, do¬ daje 14 czesci siarczynu-formaldehydo-so- dowego i ciecz ogrzewa do wrzenia. Z prze¬ zroczystego, czerwonawo-brunatnego roz¬ tworu wytraca sie alkoholem, po ochlodze¬ niu, produkt kondensacji, pod postacia la¬ two rozpuszczalnego w wodzie proszku, po¬ siadajacego zawartosc bizmutu w wysoko¬ sci 16,5% i zabarwionego na kolor poma- ranczowo-zólty.Spl disodium salt of 4-imino-methyl-sulfur-2-silver-mercapto-benzene-7-sulfonic acid is a slightly yellow colored powder, easily soluble in water, with a silver content of 24%, Example III, Dissolve 29.5 parts of sodium 4-amino-2-bismuth-mercapto-benzene-7- sulfonate in 150 parts of water, add 14 parts of sodium formaldehyde sulfite and heat the liquid to boiling . The clear, reddish-brown solution is triturated with alcohol after cooling, the condensation product in the form of a water-soluble powder with a bismuth content of 16.5% and a color tint. orange-yellow.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL10168B3 true PL10168B3 (en) | 1929-04-30 |
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