PL100819B1 - Sposob wytwarzania bromonitroalkoholi alifatycznych,zwlaszcza 2-bromo-2-nitropropandiolu-1,3 - Google Patents
Sposob wytwarzania bromonitroalkoholi alifatycznych,zwlaszcza 2-bromo-2-nitropropandiolu-1,3 Download PDFInfo
- Publication number
- PL100819B1 PL100819B1 PL17748175A PL17748175A PL100819B1 PL 100819 B1 PL100819 B1 PL 100819B1 PL 17748175 A PL17748175 A PL 17748175A PL 17748175 A PL17748175 A PL 17748175A PL 100819 B1 PL100819 B1 PL 100819B1
- Authority
- PL
- Poland
- Prior art keywords
- mole
- sie
- scheme
- sodium
- bromo
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 6
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 5
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 claims 6
- 229910052799 carbon Inorganic materials 0.000 claims 4
- 125000004432 carbon atom Chemical group C* 0.000 claims 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 3
- 125000001931 aliphatic group Chemical group 0.000 claims 2
- 230000031709 bromination Effects 0.000 claims 2
- 238000005893 bromination reaction Methods 0.000 claims 2
- 229910052794 bromium Inorganic materials 0.000 claims 2
- 239000000460 chlorine Substances 0.000 claims 2
- 229910052801 chlorine Inorganic materials 0.000 claims 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 2
- 159000000000 sodium salts Chemical class 0.000 claims 2
- 239000002904 solvent Substances 0.000 claims 2
- 239000000725 suspension Substances 0.000 claims 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 229910001513 alkali metal bromide Inorganic materials 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- -1 nitro alcohols Chemical class 0.000 claims 1
- 239000012451 post-reaction mixture Substances 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011780 sodium chloride Substances 0.000 claims 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Inorganic materials [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
- 241000357437 Mola Species 0.000 description 14
- 241000899771 Arenga undulatifolia Species 0.000 description 1
- RBWSWDPRDBEWCR-RKJRWTFHSA-N sodium;(2r)-2-[(2r)-3,4-dihydroxy-5-oxo-2h-furan-2-yl]-2-hydroxyethanolate Chemical compound [Na+].[O-]C[C@@H](O)[C@H]1OC(=O)C(O)=C1O RBWSWDPRDBEWCR-RKJRWTFHSA-N 0.000 description 1
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Claims (2)
1. Sposób wytwarzania bromonitroalkoholi ali- io fatycznych, posiadajacych atom bromu i grupe ni¬ trowa przy tym samym atomie wegla oraz grupe hydroksylowa przy sasiednim, atomie wegla, o ogólnym wzorze RCEr/N02/CH/OH/R', w którymi R oznacza atom wodoru lub grupe hydroksylowa, a w R' oznacza atom wodoru lub grupe metylowa, zwlaszcza 2-bromo-2-nitropropandiolu-l,3 na dro¬ dze bromowania soli sodowych odpowiednich ni- troalkohóli ^dyspergowanych w rozpuszczalniku, znamienny tym; ze zawiesine 2 moli sodi sodowej 20 nitroalkoholu w metanolu poddaje sie reakcji z 1 molem bromu, w temperaturze nie przekraczaja^ cej 20°C, po czym mieszanine poreakcyjna, zawie¬ rajaca produkt, substrat i powstaly ubocznie bro¬ mek sodowy traktuje sie 1 molem chloru, a na- 15 stepnie produkt wyodrebnia sie.
2. Sposób wytwarzania bromonitroalkoholi alifatycz¬ nych, posiadajacych atom bromu i grupe nitrowa przy tym samym atomie wegla oraz grupe hydro¬ ksylowa przy sasiednim atomie wegla o ogólnym 30 wzorze RCBr/N02/CH/OH/R', w którym R oznacza atom wodoru lub grupe hydroksylowa, a R' ozna¬ cza atom wodoru lub grupe metylowa, a zwlasz¬ cza 2-bromo-2-nitropropandiolu-l,3 na drodze bro¬ mowania soli sodowych odpowiednich nitroalko- 35 holi zdyspergowanych w rozpuszczalniku, znamien¬ ny tym, ze zawiesine 1 mola soli sodowej nitro¬ alkoholu w metanolu, poddaje sie reakcji z 1 mo¬ lem bromku metalu alkalicznego i 1 molem chlor- ru, po czym otrzymany produkt wyodrebnia sie.100810 »0A , W R-C-CH-R *8«k—*R-C-CH-R' *NoBr UaOH 6r ÓH «¦*"• Schemat I. aÓH ** JrÓH JSaOI 4a* 1»&N Schemat S. NaBr ? HCl4—NaCl ? %Br* Schemat J[. 2R-C-CH-R'—^R-c-CH-R^R-C-CH-R^-^R-C-CM-R' Ja OH ?•* Br OH NdOH *"* BriH ?R-C-CH-R'* Na Br *UaCl CIÓH Schemat IZ. xt ? Hao •— hx * hxo ho. , ^Oa t R-C-CH-R ? WX— R-C-CH-R'*NaX Schemat Y. R-C-CH-R *NaBr *Cli —* R-C-CH-R ?¦2Naa NaOH SrÓH SchemaiyL
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL17748175A PL100819B1 (pl) | 1975-01-22 | 1975-01-22 | Sposob wytwarzania bromonitroalkoholi alifatycznych,zwlaszcza 2-bromo-2-nitropropandiolu-1,3 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL17748175A PL100819B1 (pl) | 1975-01-22 | 1975-01-22 | Sposob wytwarzania bromonitroalkoholi alifatycznych,zwlaszcza 2-bromo-2-nitropropandiolu-1,3 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL100819B1 true PL100819B1 (pl) | 1978-11-30 |
Family
ID=19970655
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL17748175A PL100819B1 (pl) | 1975-01-22 | 1975-01-22 | Sposob wytwarzania bromonitroalkoholi alifatycznych,zwlaszcza 2-bromo-2-nitropropandiolu-1,3 |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL100819B1 (pl) |
-
1975
- 1975-01-22 PL PL17748175A patent/PL100819B1/pl unknown
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