NZ541393A - Cerium oxide nanoparticles as fuel additives - Google Patents
Cerium oxide nanoparticles as fuel additivesInfo
- Publication number
- NZ541393A NZ541393A NZ541393A NZ54139304A NZ541393A NZ 541393 A NZ541393 A NZ 541393A NZ 541393 A NZ541393 A NZ 541393A NZ 54139304 A NZ54139304 A NZ 54139304A NZ 541393 A NZ541393 A NZ 541393A
- Authority
- NZ
- New Zealand
- Prior art keywords
- cerium oxide
- fuel
- detergent
- doped
- agent
- Prior art date
Links
- 229910000420 cerium oxide Inorganic materials 0.000 title claims abstract description 88
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 title claims abstract description 88
- 239000002816 fuel additive Substances 0.000 title claims abstract description 17
- 239000002105 nanoparticle Substances 0.000 title description 5
- 239000000446 fuel Substances 0.000 claims abstract description 43
- 238000000034 method Methods 0.000 claims abstract description 36
- 239000003599 detergent Substances 0.000 claims abstract description 30
- 238000002485 combustion reaction Methods 0.000 claims abstract description 8
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 claims description 25
- 125000001931 aliphatic group Chemical group 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- -1 praeseodymium Chemical compound 0.000 claims description 14
- 150000002148 esters Chemical class 0.000 claims description 13
- 239000002904 solvent Substances 0.000 claims description 12
- 229960002317 succinimide Drugs 0.000 claims description 12
- 239000002283 diesel fuel Substances 0.000 claims description 11
- 239000002518 antifoaming agent Substances 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 150000008064 anhydrides Chemical class 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 239000013556 antirust agent Substances 0.000 claims description 6
- 229910052723 transition metal Inorganic materials 0.000 claims description 6
- 150000003624 transition metals Chemical class 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 150000001408 amides Chemical group 0.000 claims description 5
- 125000003342 alkenyl group Chemical group 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 239000003963 antioxidant agent Substances 0.000 claims description 4
- 235000006708 antioxidants Nutrition 0.000 claims description 4
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 4
- 150000007524 organic acids Chemical class 0.000 claims description 4
- 229920000768 polyamine Polymers 0.000 claims description 4
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 4
- 150000002910 rare earth metals Chemical class 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 229940014800 succinic anhydride Drugs 0.000 claims description 4
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 3
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 239000005977 Ethylene Substances 0.000 claims description 3
- 239000002879 Lewis base Substances 0.000 claims description 3
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 3
- 238000011049 filling Methods 0.000 claims description 3
- 150000007527 lewis bases Chemical class 0.000 claims description 3
- 239000006078 metal deactivator Substances 0.000 claims description 3
- 229910052752 metalloid Inorganic materials 0.000 claims description 3
- 150000002738 metalloids Chemical class 0.000 claims description 3
- PDEDQSAFHNADLV-UHFFFAOYSA-M potassium;disodium;dinitrate;nitrite Chemical compound [Na+].[Na+].[K+].[O-]N=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PDEDQSAFHNADLV-UHFFFAOYSA-M 0.000 claims description 3
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 2
- WVRNUXJQQFPNMN-VAWYXSNFSA-N 3-[(e)-dodec-1-enyl]oxolane-2,5-dione Chemical group CCCCCCCCCC\C=C\C1CC(=O)OC1=O WVRNUXJQQFPNMN-VAWYXSNFSA-N 0.000 claims description 2
- KAYAKFYASWYOEB-UHFFFAOYSA-N 3-octadec-1-enyloxolane-2,5-dione Chemical compound CCCCCCCCCCCCCCCCC=CC1CC(=O)OC1=O KAYAKFYASWYOEB-UHFFFAOYSA-N 0.000 claims description 2
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- 229920002367 Polyisobutene Polymers 0.000 claims description 2
- 229910052772 Samarium Inorganic materials 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 229910052787 antimony Inorganic materials 0.000 claims description 2
- 229910052790 beryllium Inorganic materials 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 229910052733 gallium Inorganic materials 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- LSHROXHEILXKHM-UHFFFAOYSA-N n'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine Chemical compound NCCNCCNCCNCCNCCN LSHROXHEILXKHM-UHFFFAOYSA-N 0.000 claims description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- 229910052697 platinum Inorganic materials 0.000 claims description 2
- 229910052703 rhodium Inorganic materials 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 229960001124 trientine Drugs 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 2
- 230000003078 antioxidant effect Effects 0.000 claims 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 1
- 229910052771 Terbium Inorganic materials 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims 1
- 239000002585 base Substances 0.000 claims 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 239000011651 chromium Substances 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 claims 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 1
- 239000010948 rhodium Substances 0.000 claims 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims 1
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 claims 1
- 229910052711 selenium Inorganic materials 0.000 claims 1
- 239000011669 selenium Substances 0.000 claims 1
- 239000004332 silver Substances 0.000 claims 1
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- PSUYMGPLEJLSPA-UHFFFAOYSA-N vanadium zirconium Chemical compound [V].[V].[Zr] PSUYMGPLEJLSPA-UHFFFAOYSA-N 0.000 claims 1
- 239000002245 particle Substances 0.000 description 21
- 239000000654 additive Substances 0.000 description 17
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 12
- 229910052760 oxygen Inorganic materials 0.000 description 12
- 239000001301 oxygen Substances 0.000 description 12
- 239000011248 coating agent Substances 0.000 description 8
- 230000000996 additive effect Effects 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000006280 diesel fuel additive Substances 0.000 description 3
- 239000002019 doping agent Substances 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000003495 polar organic solvent Substances 0.000 description 2
- 150000007519 polyprotic acids Polymers 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- XUJLWPFSUCHPQL-UHFFFAOYSA-N 11-methyldodecan-1-ol Chemical compound CC(C)CCCCCCCCCCO XUJLWPFSUCHPQL-UHFFFAOYSA-N 0.000 description 1
- 239000000263 2,3-dihydroxypropyl (Z)-octadec-9-enoate Substances 0.000 description 1
- DKCPKDPYUFEZCP-UHFFFAOYSA-N 2,6-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=CC(C(C)(C)C)=C1O DKCPKDPYUFEZCP-UHFFFAOYSA-N 0.000 description 1
- NKRVGWFEFKCZAP-UHFFFAOYSA-N 2-ethylhexyl nitrate Chemical compound CCCCC(CC)CO[N+]([O-])=O NKRVGWFEFKCZAP-UHFFFAOYSA-N 0.000 description 1
- YAXXOCZAXKLLCV-UHFFFAOYSA-N 3-dodecyloxolane-2,5-dione Chemical class CCCCCCCCCCCCC1CC(=O)OC1=O YAXXOCZAXKLLCV-UHFFFAOYSA-N 0.000 description 1
- RZRNAYUHWVFMIP-GDCKJWNLSA-N 3-oleoyl-sn-glycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-GDCKJWNLSA-N 0.000 description 1
- RREANTFLPGEWEN-MBLPBCRHSA-N 7-[4-[[(3z)-3-[4-amino-5-[(3,4,5-trimethoxyphenyl)methyl]pyrimidin-2-yl]imino-5-fluoro-2-oxoindol-1-yl]methyl]piperazin-1-yl]-1-cyclopropyl-6-fluoro-4-oxoquinoline-3-carboxylic acid Chemical compound COC1=C(OC)C(OC)=CC(CC=2C(=NC(\N=C/3C4=CC(F)=CC=C4N(CN4CCN(CC4)C=4C(=CC=5C(=O)C(C(O)=O)=CN(C=5C=4)C4CC4)F)C\3=O)=NC=2)N)=C1 RREANTFLPGEWEN-MBLPBCRHSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- QQVGEJLUEOSDBB-KTKRTIGZSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(CO)(CO)CO QQVGEJLUEOSDBB-KTKRTIGZSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 125000002015 acyclic group Chemical group 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- HLYOOCIMLHNMOG-UHFFFAOYSA-N cyclohexyl nitrate Chemical compound [O-][N+](=O)OC1CCCCC1 HLYOOCIMLHNMOG-UHFFFAOYSA-N 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000007726 management method Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- RZRNAYUHWVFMIP-UHFFFAOYSA-N monoelaidin Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-UHFFFAOYSA-N 0.000 description 1
- 239000002707 nanocrystalline material Substances 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000002888 oleic acid derivatives Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 150000004986 phenylenediamines Chemical class 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 229940058287 salicylic acid derivative anticestodals Drugs 0.000 description 1
- 150000003872 salicylic acid derivatives Chemical class 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 150000003443 succinic acid derivatives Chemical class 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/12—Inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/02—Use of additives to fuels or fires for particular purposes for reducing smoke development
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/12—Inorganic compounds
- C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0301599.7A GB0301599D0 (en) | 2003-01-23 | 2003-01-23 | Cerium oxide nanoparticles as fuel additives |
| PCT/GB2004/000294 WO2004065529A1 (en) | 2003-01-23 | 2004-01-23 | Cerium oxide nanoparticles as fuel additives |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NZ541393A true NZ541393A (en) | 2008-12-24 |
Family
ID=9951695
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NZ541393A NZ541393A (en) | 2003-01-23 | 2004-01-23 | Cerium oxide nanoparticles as fuel additives |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US20060254130A1 (ko) |
| EP (1) | EP1587898A1 (ko) |
| JP (1) | JP2006516996A (ko) |
| KR (1) | KR101169804B1 (ko) |
| CN (1) | CN1764711B (ko) |
| AU (1) | AU2004205788B2 (ko) |
| BR (1) | BRPI0406921A (ko) |
| CA (1) | CA2514146A1 (ko) |
| GB (1) | GB0301599D0 (ko) |
| MX (1) | MXPA05007820A (ko) |
| NZ (1) | NZ541393A (ko) |
| RU (1) | RU2352618C2 (ko) |
| WO (1) | WO2004065529A1 (ko) |
| ZA (1) | ZA200505933B (ko) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050188605A1 (en) * | 2000-08-01 | 2005-09-01 | Valentine James M. | Reduced-emissions combustion utilizing multiple-component metallic combustion catalyst |
| FR2853261B1 (fr) * | 2003-04-04 | 2006-06-30 | Rhodia Elect & Catalysis | Dispersion colloidale d'un compose d'une terre rare comprenant un agent anti-oxydant et son utilisation comme adjuvant de gazole pour moteurs a combustion interne |
| GB0317852D0 (en) * | 2003-07-30 | 2003-09-03 | Oxonica Ltd | Cerium oxide nanoparticles as fuel supplements |
| EP1512736B1 (en) | 2003-09-05 | 2018-05-02 | Infineum International Limited | Stabilised diesel fuel additive compositions |
| GB0606986D0 (en) * | 2006-04-06 | 2006-05-17 | Oxonica Energy Ltd | Biofuels |
| AU2007236562B2 (en) | 2006-04-12 | 2011-04-14 | Very Small Particle Company Pty Ltd | Sulfur resistant emissions catalyst |
| US7967876B2 (en) | 2006-08-17 | 2011-06-28 | Afton Chemical Corporation | Nanoalloy fuel additives |
| EP2066767B1 (en) * | 2006-09-05 | 2015-10-21 | Cerion LLC | Cerium dioxide nanoparticle-containing fuel additive |
| US8883865B2 (en) | 2006-09-05 | 2014-11-11 | Cerion Technology, Inc. | Cerium-containing nanoparticles |
| US10435639B2 (en) | 2006-09-05 | 2019-10-08 | Cerion, Llc | Fuel additive containing lattice engineered cerium dioxide nanoparticles |
| US20080066375A1 (en) | 2006-09-19 | 2008-03-20 | Roos Joseph W | Diesel fuel additives containing cerium or manganese and detergents |
| US20080098644A1 (en) | 2006-09-19 | 2008-05-01 | Afton Chemical Corporation | Conductivity improving combination of cerium oxide and detergents for diesel fuels |
| US8741821B2 (en) * | 2007-01-03 | 2014-06-03 | Afton Chemical Corporation | Nanoparticle additives and lubricant formulations containing the nanoparticle additives |
| US7775166B2 (en) | 2007-03-16 | 2010-08-17 | Afton Chemical Corporation | Method of using nanoalloy additives to reduce plume opacity, slagging, fouling, corrosion and emissions |
| GB0705920D0 (en) * | 2007-03-28 | 2007-05-09 | Infineum Int Ltd | Method of supplying iron to the particulate trap of a diesel engine exhaust |
| KR100768536B1 (ko) * | 2007-05-30 | 2007-10-18 | 백 웨인 | 화석연료 연소장치의 고농도 나노 입자 크기의 마그네슘연료 첨가제 |
| KR100872703B1 (ko) * | 2007-06-07 | 2008-12-05 | 최태원 | 나노기술을 활용한 휘발유 절감을 위한 조성물 |
| US20090000186A1 (en) * | 2007-06-28 | 2009-01-01 | James Kenneth Sanders | Nano-sized metal and metal oxide particles for more complete fuel combustion |
| EP2247699A1 (en) * | 2008-01-16 | 2010-11-10 | Very Small Particle Company Limited | Fuel additive |
| CA2725035A1 (en) * | 2008-05-20 | 2009-11-26 | John C. Mills | Fuel additive and method for use for combustion enhancement and emission reduction |
| US8679344B2 (en) | 2008-12-17 | 2014-03-25 | Cerion Technology, Inc. | Process for solvent shifting a nanoparticle dispersion |
| GB0900994D0 (en) | 2009-01-21 | 2009-03-04 | Oxonica Materials Ltd | Solid fuel combustion process |
| US8377290B2 (en) * | 2009-03-31 | 2013-02-19 | James K. and Mary A. Sanders Family L.L.C. | Low sulfur fuels |
| US8182555B2 (en) | 2009-03-31 | 2012-05-22 | James Kenneth Sanders | Nano-sized zinc oxide particles for fuel |
| US8182554B2 (en) | 2009-03-31 | 2012-05-22 | James Kenneth Sanders | Fuels for cold start conditions |
| US8545577B2 (en) * | 2009-03-31 | 2013-10-01 | James K. And Mary A. Sanders Family Llc | Catalyst component for aviation and jet fuels |
| PL399654A1 (pl) * | 2012-06-25 | 2014-01-07 | Green Power Spólka Z Ograniczona Odpowiedzialnoscia Spólka W Organizacji | Sposób wytwarzania uszlachetnionego biokomponentu do biopaliw oraz uszlachetniony biokomponent do biopaliw |
| CN103074124A (zh) * | 2013-01-05 | 2013-05-01 | 大连理工大学 | 一种纳米复合氧化物重油添加剂的制备方法 |
| US10143661B2 (en) | 2013-10-17 | 2018-12-04 | Cerion, Llc | Malic acid stabilized nanoceria particles |
| CN105435770A (zh) * | 2014-09-29 | 2016-03-30 | 杨晓波 | 用于压燃式内燃机的前置助燃催化剂 |
| US9920724B2 (en) * | 2015-10-19 | 2018-03-20 | United Technologies Corporation | Chemical scavenging component for a fuel system |
| US10451211B2 (en) * | 2015-10-19 | 2019-10-22 | United Technologies Corporation | Radical-neutralizing coating for a lubricant system |
| CN105505490B (zh) * | 2015-12-08 | 2017-03-15 | 谢传林 | 氧化还原增压剂 |
| CN107189829A (zh) * | 2017-04-25 | 2017-09-22 | 南宁市钱隆汽车租赁有限公司 | 汽油添加剂 |
| EP3553155A1 (en) * | 2018-03-12 | 2019-10-16 | INDIAN OIL CORPORATION Ltd. | Nano perovskite materials as combustion improver for liquid and gaseous fuels |
| CN108822900A (zh) * | 2018-06-15 | 2018-11-16 | 广西隆昌德民生态农业发展有限公司 | 一种能够燃烧充分和减轻尾气污染排放的复合醇燃料 |
| KR102602410B1 (ko) * | 2018-07-10 | 2023-11-15 | 한국과학기술연구원 | 연료전지의 전해질막용 산화방지제 및 이의 제조방법 |
| DE112020000522T5 (de) | 2019-01-25 | 2021-10-07 | Kyung Hoon Jun | Wässriger Metallkolloidverbrennungszusatz |
| CN110373235B (zh) * | 2019-06-13 | 2021-06-18 | 交城县万里通加油站 | 一种环保汽油添加剂及其制备方法 |
| CN110373236B (zh) * | 2019-06-13 | 2021-09-17 | 徐武警 | 一种稀土改性汽油添加剂及其制备方法 |
| KR102219424B1 (ko) | 2019-08-27 | 2021-02-23 | 포항공과대학교 산학협력단 | 희토류금속 및 전이금속 공도핑에 의한 co 산화를 위한 고성능 세리아 촉매 및 그의 제조방법 |
| US11603503B2 (en) | 2021-05-20 | 2023-03-14 | Indian Oil Corporation Limited | Additive composition as a combustion improver for liquid and gaseous fuels |
| CN113800552A (zh) * | 2021-08-12 | 2021-12-17 | 淮阴师范学院 | 一种新型二氧化铈、制备方法及应用 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4522631A (en) * | 1983-11-18 | 1985-06-11 | Texaco Inc. | Diesel fuel containing rare earth metal and oxygenated compounds |
| EP0311836A3 (de) * | 1987-09-28 | 1989-06-14 | Franz Puschauer | Benzin und Ölverbrauchs-Umweltentlastungsanwendungsadditiv als Katalysatorersatz |
| GB9207383D0 (en) * | 1992-04-03 | 1992-05-13 | Ass Octel | Multi-functional gasoline detergent compositions |
| CN1079498A (zh) * | 1992-05-30 | 1993-12-15 | 初新东 | 机动车尾气净化剂的制备方法与产品 |
| FR2741281B1 (fr) * | 1995-11-22 | 1998-02-13 | Rhone Poulenc Chimie | Sol organique comportant au moins un compose oxygene de terre(s) rare(s), procede de synthese du dit sol et utilisation du dit sol pour la catalyse |
| GB9610563D0 (en) * | 1996-05-20 | 1996-07-31 | Bp Chemicals Additives | Marine diesel process and fuel therefor |
| FR2789601B1 (fr) * | 1999-02-17 | 2001-05-11 | Rhodia Chimie Sa | Sol organique et compose solide a base d'oxyde de cerium et d'un compose amphiphile et procedes de preparation |
| FR2797199B1 (fr) * | 1999-08-04 | 2001-10-05 | Rhodia Terres Rares | Dispersion colloidale organique de particules essentiellement monocristallines d'au moins un compose a base d'au moins une terre rare, son procede de preparation et son utilisation |
| MXPA02012584A (es) * | 2000-06-29 | 2004-05-17 | Neuftec Ltd | Aditivo de combustible. |
| CN1341700A (zh) * | 2000-09-05 | 2002-03-27 | 包头市龙腾稀土科贸有限责任公司 | 稀土燃油添加剂及其生产工艺 |
| GB0126663D0 (en) * | 2001-11-06 | 2002-01-02 | Oxonica Ltd | Cerium oxide nanoparticles |
| EP1344812A1 (en) * | 2002-03-13 | 2003-09-17 | Infineum International Limited | Overbased metallic salt diesel fuel additive compositions for improvement of particulate traps |
-
2003
- 2003-01-23 GB GBGB0301599.7A patent/GB0301599D0/en not_active Ceased
-
2004
- 2004-01-23 EP EP04704663A patent/EP1587898A1/en not_active Ceased
- 2004-01-23 BR BR0406921-8A patent/BRPI0406921A/pt not_active Application Discontinuation
- 2004-01-23 MX MXPA05007820A patent/MXPA05007820A/es active IP Right Grant
- 2004-01-23 CA CA002514146A patent/CA2514146A1/en not_active Abandoned
- 2004-01-23 NZ NZ541393A patent/NZ541393A/en not_active IP Right Cessation
- 2004-01-23 CN CN2004800078439A patent/CN1764711B/zh not_active Expired - Lifetime
- 2004-01-23 WO PCT/GB2004/000294 patent/WO2004065529A1/en active Application Filing
- 2004-01-23 RU RU2005123391/04A patent/RU2352618C2/ru active
- 2004-01-23 JP JP2006500244A patent/JP2006516996A/ja active Pending
- 2004-01-23 AU AU2004205788A patent/AU2004205788B2/en not_active Expired
- 2004-01-23 KR KR1020057013595A patent/KR101169804B1/ko active IP Right Grant
- 2004-01-23 US US10/542,770 patent/US20060254130A1/en not_active Abandoned
-
2005
- 2005-07-22 ZA ZA200505933A patent/ZA200505933B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US20060254130A1 (en) | 2006-11-16 |
| CA2514146A1 (en) | 2004-08-05 |
| AU2004205788B2 (en) | 2010-09-02 |
| EP1587898A1 (en) | 2005-10-26 |
| CN1764711B (zh) | 2010-11-24 |
| ZA200505933B (en) | 2006-04-26 |
| WO2004065529A1 (en) | 2004-08-05 |
| AU2004205788A1 (en) | 2004-08-05 |
| JP2006516996A (ja) | 2006-07-13 |
| KR20060006890A (ko) | 2006-01-20 |
| BRPI0406921A (pt) | 2006-01-03 |
| RU2352618C2 (ru) | 2009-04-20 |
| CN1764711A (zh) | 2006-04-26 |
| RU2005123391A (ru) | 2006-01-27 |
| GB0301599D0 (en) | 2003-02-26 |
| MXPA05007820A (es) | 2005-10-18 |
| KR101169804B1 (ko) | 2012-07-30 |
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