NZ199855A - Detergent compositions containing a synergistic mixture of surfactants - Google Patents
Detergent compositions containing a synergistic mixture of surfactantsInfo
- Publication number
- NZ199855A NZ199855A NZ199855A NZ19985582A NZ199855A NZ 199855 A NZ199855 A NZ 199855A NZ 199855 A NZ199855 A NZ 199855A NZ 19985582 A NZ19985582 A NZ 19985582A NZ 199855 A NZ199855 A NZ 199855A
- Authority
- NZ
- New Zealand
- Prior art keywords
- composition
- alkyl
- fatty acid
- amphoteric
- carbon atoms
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 98
- 239000003599 detergent Substances 0.000 title claims description 24
- 230000002195 synergetic effect Effects 0.000 title claims description 7
- 239000004094 surface-active agent Substances 0.000 title description 11
- 239000000194 fatty acid Substances 0.000 claims description 28
- 239000003945 anionic surfactant Substances 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 15
- 229930195729 fatty acid Natural products 0.000 claims description 15
- 125000000217 alkyl group Chemical group 0.000 claims description 14
- -1 alkyl succinates Chemical class 0.000 claims description 13
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 150000004665 fatty acids Chemical class 0.000 claims description 11
- 125000000129 anionic group Chemical group 0.000 claims description 9
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 5
- 239000004615 ingredient Substances 0.000 claims description 5
- 125000005599 alkyl carboxylate group Chemical group 0.000 claims description 3
- 108090000623 proteins and genes Proteins 0.000 claims description 3
- 102000004169 proteins and genes Human genes 0.000 claims description 3
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 150000007942 carboxylates Chemical class 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 2
- 229940071089 sarcosinate Drugs 0.000 claims 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 239000006260 foam Substances 0.000 description 17
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 10
- 239000004166 Lanolin Substances 0.000 description 10
- 238000009472 formulation Methods 0.000 description 10
- 229940039717 lanolin Drugs 0.000 description 10
- 235000019388 lanolin Nutrition 0.000 description 10
- 239000008367 deionised water Substances 0.000 description 9
- 229910021641 deionized water Inorganic materials 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 7
- 230000007794 irritation Effects 0.000 description 7
- 239000002736 nonionic surfactant Substances 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 241000283973 Oryctolagus cuniculus Species 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000003755 preservative agent Substances 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 229940126062 Compound A Drugs 0.000 description 3
- 239000004375 Dextrin Substances 0.000 description 3
- 229920001353 Dextrin Polymers 0.000 description 3
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 3
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000002280 amphoteric surfactant Substances 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 235000019425 dextrin Nutrition 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 239000008233 hard water Substances 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- 239000002453 shampoo Substances 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- 239000003760 tallow Substances 0.000 description 3
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 description 2
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 1
- YLAXZGYLWOGCBF-UHFFFAOYSA-N 2-dodecylbutanedioic acid Chemical compound CCCCCCCCCCCCC(C(O)=O)CC(O)=O YLAXZGYLWOGCBF-UHFFFAOYSA-N 0.000 description 1
- LWYAUHJRUCQFCX-UHFFFAOYSA-N 4-dodecoxy-4-oxobutanoic acid Chemical compound CCCCCCCCCCCCOC(=O)CCC(O)=O LWYAUHJRUCQFCX-UHFFFAOYSA-N 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- 101100025412 Arabidopsis thaliana XI-A gene Proteins 0.000 description 1
- TXNJAVCZNMSELK-UHFFFAOYSA-N CCCCCCCCCCCCOC(=O)CNC Chemical compound CCCCCCCCCCCCOC(=O)CNC TXNJAVCZNMSELK-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 208000006069 Corneal Opacity Diseases 0.000 description 1
- 231100000635 Draize test Toxicity 0.000 description 1
- 206010015946 Eye irritation Diseases 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229910006127 SO3X Inorganic materials 0.000 description 1
- 108010077895 Sarcosine Proteins 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 238000006959 Williamson synthesis reaction Methods 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000006172 buffering agent Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- 229940106681 chloroacetic acid Drugs 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 210000000795 conjunctiva Anatomy 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 210000004087 cornea Anatomy 0.000 description 1
- 231100000269 corneal opacity Toxicity 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 229940079886 disodium lauryl sulfosuccinate Drugs 0.000 description 1
- KHIQYZGEUSTKSB-UHFFFAOYSA-L disodium;4-dodecoxy-4-oxo-3-sulfobutanoate Chemical compound [Na+].[Na+].CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O.CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O KHIQYZGEUSTKSB-UHFFFAOYSA-L 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 231100000013 eye irritation Toxicity 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 239000000413 hydrolysate Substances 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 210000000554 iris Anatomy 0.000 description 1
- 229940071204 lauryl sarcosinate Drugs 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 231100000344 non-irritating Toxicity 0.000 description 1
- 231100001254 ocular irritant Toxicity 0.000 description 1
- 208000013441 ocular lesion Diseases 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 229940057838 polyethylene glycol 4000 Drugs 0.000 description 1
- 229940093429 polyethylene glycol 6000 Drugs 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229940095696 soap product Drugs 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical class CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/886—Ampholytes containing P
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/92—Sulfobetaines ; Sulfitobetaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/74—Biological properties of particular ingredients
- A61K2800/75—Anti-irritant
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/08—Polycarboxylic acids containing no nitrogen or sulfur
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/32—Protein hydrolysates; Fatty acid condensates thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Veterinary Medicine (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
- Absorbent Articles And Supports Therefor (AREA)
Description
New Zealand Paient Spedficaiion for Paient Number 1 99855 1998 55 Priority Date{s}: Complcts Specjfscat'cn Falsdi:^' Class-.^l^'.^t ,..,.
Publication Date: ... JWV.Wf. P.O. Jourr.si, fto: .... .l?M, • s a 9 s mm Patents Form No. 5 Number PATENTS ACT 1953 Dated COMPLETE SPECIFICATION DETERGENT COMPOSITIONS pC\Ve JOHNSON & JOHNSON BABY PRODUCTS COMPANY , a corporation organized under the laws of the State of New Jersey, United States of America of 501 George Street, New Brunswick, New Jersey, United States of America. do hereby declare the invention for which X/we pray that a Patent may be granted to me^us, and the method by which it is to be performed, to be particularly described in and by the following statement: - 1 - (followed by page la) -la- 1998 5 5 jbp 184 Background of the Invention Detergent and cleansing compositions intended for use as personal cleansing products not only must exhibit good cleansing and foam characteristics but they must also be non-irritating or have low irritation potential to the skin and the eyes.
Synthetic detergents which are useful in such detergent and cleansing compositions are well known in the art and include anionic, cationic, amphoteric and nonionic detergents or surfactants, as they are usually referred 15 to. The surfactants generally exhibiting the more superior properties in terms of foaming, cleaning and end result attributes are the anionic detergents. Thus, most detergent and cleansing formulations, intended for personal use contain anionic surfactants as one of the active 20 ingredients. These surfactants, however, have a tendency to be very irritating to the skin and the eyes in the levels normally utilized, i.e., above 10% by weight of the total composition. For this reason, detergent compositions intended for personal use containing anionic 25 surfactants are modified by substituting a significant amount of nonionic surfactants which are generally mild although of less effective foaming and cleansing ability. Certain amphoteric surfactants have also been reported to have a low eye irritation potential. Although numerous 30 detergent and cleansing compositions are available commercially, there is still a need for compositions in which irritancy can be substantially eliminated without sacrificing other desired properties such as cleansing and foaming attributes.
Several U.S. patents describe compositions in which both amphoteric and nonionic surfactants are incorporated in detergent compositions containing anionic surfactants. Thus, in U.S. Patents Nos. 2,999,069 an 3,055,836 there 5 are described shampoo compositions comprising certain mixtures of ethoxylated anionic, amphoteric and polyethoxylated nonionic surfactants. Further, in U.S. Patent No. 3,928,251 there are described shampoo compositions comprising certain mixtures of anionic, 10 nonionic and zwitterionic surfactants. Similarly, in U.S. Patent No. 3,950,417 shampoo compositions are described for which low ocular irritancy is claimed. In these compositions, nonionic and amphoteric surfactants have been added to modify anionic surfactants. All of 15 these compositions include a nonionic surfactant as an essential component as well as an anionic surfactant and as mentioned above, these surfactants have various negatives.
It is, therefore, an object of this invention to provide improved detergent and cleansing compositions. 199855 Summary of the Invention The foregoing objects and other features and advantages of the present invention are achieved by detergent and cleansing compositions comprising a synergistic mixture of surfactants which exhibit low eye and skin irritancy and good foam properties. More specifically/ the present invention relates to detergent and cleansing compositions comprising a synergistic mixture of a specific amphoteric-fatty acid complex and specific anionic surfactants containing at least one carboxylic acid moiety.
Detailed Description of the Invention In general, this invention comprises a synergistic mixture of a specific amphoteric-fatty acid complex and a specific anionic surfactant in a ratio of from 1:4 to 4:1.
The term "synergistic mixture" as used herein refers to a mixture of two discrete compounds which display a degree 20 of initial foam height and quality which is greater than the sum of the initial foam heights of the compounds taken individually.
The specific amphoteric-fatty acid complexes which have 25 been found useful in the present invention are non-zwitterionic in nature and are of the formula 0 II R^C-0 © R2-N: I H -A1 *a2 ;© ;35 ;wherein R^ is alkyl or substituted alkyl containing from 6 to 18 carbon atoms and mixtures thereof. ;199255 ;-4- ;R2 is alkyl containing from 8 to 18 carbon atoms and mixtures thereof or alkyl amido of the formula ;0 Z ;R3-C-K-Y ;wherein R3 is alkyl containing from 8 to 18 carbon atoms, Z is H or lower alkyl containing from 1 to 4 carbon atoms; 10 and Y is lower alkylene containing from 1 to 4 carbon atoms; ;A-l and A2 are the same or different and are selected from the group of anionic salt moieties consisting of the 15 following: ;■fcH2CH2-COOx]n -fCH2-C00x]n ;-Ech2choh-ch2-so3x] n ;-fcH2-CHOH-CH2-OPC>3Xj,n when X is divalent 20 -fbt^-CHOH-CI^-OPC^xJ n when X is monovalent, ;wherein X is a water soluble cation such as Na+, K+, Ca++, Mg++ and the like and n is an integer of 1 or 2 with the proviso that if only one of A± and A2 is selected from the anionic salt moieties above the other can be hydrogen, 25 lower alkyl or lower hydroxyalkyl containing from 1 to 4 carbon atoms. ;The amphoteric-fatty acid complexes which are useful in the present invention are novel compounds described and 30 claimed in New Zealand Patent No. 199856 and can be prepared in accordance with the processes described therein; the teachings of said copending application are incorporated herein by reference. ;35 Representative amphoteric-fatty acid complexes useful in the present invention include the following: ;fiZ. PATENT 0?f?C@ ;- 9 MAY 1984 ;10 ;20 ;25 ;.1 "VP ;-i' z Z:'s'k. - J ;1 9 9 S 5 5 ;-5- ;(a) ;r ti ;[Ri-c-oJ ;■ } <. . u - t j ;0 b ;1 I ;CllB23-C-N(CH2)2-N ;c2h4oh ;|\:h2cook ;H ;© ;wherein is a ChH23 - CigH37 fixture. ;CH-CH-COONa y 2 2 ;0 ;II ;© ;(B) ;ll ;Ri-C-0 ;c14h29" ;15 ;h ;CH2 COCOON a wherein Rj, is an 80%/20% tallow coconut fatty acid mixture. ;-,0 ;(C) ;r 01 ;© ;rl-c-0 ;i ;O CH3 ;/ ;CH2CH0HCH2S03K ;R3-C-N-(CH2)2-NN ;h ;CH 2CHOHCH 2OP03Na 2 ;wherein Ri is tallow fatty acid and R3 is a c11h23"c17h25 mixture. ;30 ;35 ;40 ;(D) ;* O - II R^C-0 © CH-CHOHCH-SO.,. y 2 2 3 c18h37"nC I NCH-CHOHCH-SO ' H 2 23 © Mg wherein R} is a 70%/30% mixture of lauric and myristic acids.
(E) " 0 II RjC-0 © H c12h25 N-CH2CH2COONa H © wherein R^ is tallow fatty acid. [1998 55 (F) 0 II Ci2H25O0 © H CH2CH2COONa C14h29-N^ CH2CH2COONa 0 (G) " O " I RiC-0 0 c12h25-N\ CH2CH2COONa H CH2CH2COONa © wherein R^ is a C$Hi3 - Cl8H37 mixture.
The amphoteric-fatty acid complexes useful in the compositions of this invention are present in an amount of from about 1 to 50% by weight of the total composition, preferably about 5 to 15% by weight of the total composition.
The specific anionic surfactants which have been found useful in the present invention are those containing at least one carboxylic acid moiety and are selected from the group consisting of sulfosuccinates, alkyl carboxylates, a -sulfo fatty acid and ester carboxylates, alkyl succinates, alkyl sarcosinates and fatty acid protein condensates. All of these compounds are well known in the art and can be prepared according to well-recognized processes.
The sulfosuccinates are of the general formula 0 II R-0-C-CHCH2COOX 0S03Na 19 and can be prepared by reacting maleic acid with a suitable fatty alcohol followed by the addition of NaHS03 to the double bond.
The a-sulfo fatty acid and ester carboxylates are of the following general formuli respectively 0 II R-CH-C-OX' and I S03X 0 || R-CH-C-OR' I SO3X and can be prepared by sulfonation of the suitable fatty acids and esters.
The alkyl carboxylates are of the following general formula R-0 [ (CH2)20]a-CH2COOX wherein a is 1-4; and these compounds can be prepared by the Williamson ether synthesis which involves reacting an 30 alkoxide with chloroacetic acid.
The alkyl succinates are of the general formula 0 II R-O-C-CH2CH2COOX 19 and are the reaction product of a suitable fatty alcohol with succinic acid or succinic anhydride.
The alkyl sarcosinates are of the general formula 0 x II I r-c-n-ch2coox and are the reaction product of a suitable fatty acid with a lower substituted amine such as glycine or N-methyl glycine.
The fatty acid protein condensates are of the general 15 formula 0 r' o r" II I II I r-c-(nh-c-h-c—nh-ch)n coox and are the reaction products of a suitable fatty acid with an amino hydrolysate.
Specific examples of suitable anionic surfactants include 0 O II II (AA) CnH23-0-C-CHCH2-C-0-Na 3 0 OSC>3Na 0 II 3 5 (bb) ci2h25-ch-c-0-na SC>3Na 40 o II (cc) c10h2i-ch-c-och3 S03Na 199855 O O II II (DD) R-O-C-CH2-CH2-C-OK wherein R is 50/50 mixture of C12H25 and c14?29 (EE) Ci3H27-0-[(CH2)20]4 ~ CH2COONa 0 CH3O CH3 II I II I (FF) CnH23~C-(NH-CH-C-NH-CH)50COONa O CH3 II I (GG) CiiH23-C-N-CH2COONa The anionic surfactants useful in the compositions of this invention are present in an amount of from 2 to 50% by weight of the total composition, preferably 5 to 40% by weight of the total composition.
Further, to achieve the desired results of the present invention, the amphoteric-fatty acid complex and the specific anionic surfactant should be in a ratio of from about 4:1 to 1:4, preferably from about 2:1 to 1:2.
In preparing various formulations and compositions, if desired and if compatible, various other surfactants can be utilized such as other anionics, nonionics, amphoterics, cationics and the like. In addition to such 35 other surfactants, other ingredients conventionally added to detergent and cleansing compositions for personal use, such as dyes, preservatives, perfumes, thickeners, ~ ® KAY Kt-j ! - Bsc&vm ■ 199855 opacifiers, conditioners, emollients, buffering agents and the like, may be added in minor amounts. Ingredients such as dyes, preservatives and perfumes together usually constitute less than 2% by weight of the total composition 5 and thickeners may be added to the composition in an amount -_tsf fi-om to 3% £>y weight of the total composition.
The detergent and cleansing compositions of the present invention may be in the form of liquid detergent 10 compositions or detergent bar compositions, as desired.
Liquid detergent formulations utilizing the compositions of the present invention can be prepared by admixing the amphoteric-fatty acid complex and anionic surfactant at 15 room temperature or slightly elevated temperatures (about 50°C) and then sufficient deionized water is added to bring the composition to about three quarters of its intended weight. Other ingredients such as other surfactants, various detergency adjuncts, fillers, 20 carriers, perfumes, preservatives, gelling agents and the like are added as required followed by the balance of the water. The pH is then adjusted to within the desired range by the addition of strong acid, e.g., HC1, or strong base NaOH, as needed.
Detergent bar formulations utilizing the compositions of the present invention can be prepared by admixing the amphoteric-fatty acid complex and the anionic surfactant in a steam jacketed rotary mixer at temperatures within 30 the range of 60-80°C. Other surfactants, fillers, whitening agents and processing oils can be added, as needed, to the hot slurry. After adequate mixing to assure homogeneity and moisture balance the product is chill rolled or drum dried into flakes. Dyes and 35 fragrances are added to the flakes in a standard amalgamator together with additional water to provide 1998 5 -li- proper bar formation. After adequate mixing the flakes are milled and plodded into logs which are then cut into blanks prior to stamping into bar form.
The detergent compositions of the present invention can be tested for ocular irritation by the following modified Draize Test (J.H. et al., Toilet Goods Assn. No. 17, May 1952, No. 1, Proc. Sci. Sect.).
An 0.1 ml. sample of a neutral composition under test is dropped into one eye of an albino rabbit, the other eye serving as a control. Six rabbits are employed for each composition. Observations are made after 1, 24, 48, 72 and 96 hours and 7 days after initial instillation; second 15 and third instillations are made after the 24 and 48 hour readings. Results may vary from substantially no change or only a slight irritation in the appearance of the rabbit's eye after 7 days to severe irritation and/or complete corneal opacity. Ocular lesions are scored for 20 the cornea, iris and conjunctiva with a higher number indicating greater ocular irritation and the scores are added to give a total numerical value for each reading for six rabbits and averaged. The averaged score is an indication of the irritation potential of the composition 25 under test. Based on the averaged score, descriptive irritation evaluation may be given, e.g., none, slight, moderate, severe, as the case may be.
Detergent compositions of the invention provide high foam 30 volume and moreover outstanding foam stability as measured by an adaption of the well-known Ross-Miles foam test principle "Oil and Soap" 18.9-102 (1941): Lanolin, anhydrous, cosmetic grade is mixed with dioxane 35 (technical grade) in the proportion of 2.5 grams lanolin and 100 grams of dioxane. The lanolin is first mixed with cc. of dioxane. This mixture is heated over a steam bath to 45°C in order to dissolve the lanolin in the dioxane. The remainder of the dioxane is then added and mixed. This lanolin dioxane solution, which is stored in 5 an amber bottle, should be prepared fresh on the day that the tests are run.
The composition to be tested is diluted by adding 376 cc. of distilled water to 4 grams of the composition, and then 10 by adding 20 cc. of the lanolin dioxane solution described above while mixing. Heat is produced when the lanolin dioxane solution is added to the solution of the composition in water and care must be taken in adjusting the temperature of this solution to 24°-25°C. Both of 15 these intermediate solutions should therefore be adjusted to 23°C before mixing. The cooling of the lanolin dioxane solution should be gradual in order to avoid precipitation of the lanolin. This will produce a final solution with a temperature of 24°-25°C.
The final solution of the composition to be tested, water, dioxane and lanolin described above, is then run in a modified Ross-Miles foam column in the usual way. All tests are conducted in duplicate, and the average of the 25 two results is taken. Foam stability is determined by measuring the decay in foam height after two minutes, expressed as a percentage of the original height.
Specific embodiments of the present invention are 30 illustrated by the following representative examples. It will be understood, however, that the invention is not confined to the specific limitations set forth in the individual examples, but rather to the scope of the appended claims. 1998 55 Examples I-IX The following compositions are prepared by admixing the surfactant components, adjusting the pH to 7.2+. 2^ with dilute acid or base as required and adding deionized water 5 to 100%: % wt/wt.
EXAMPLES I II III IV V VI VII VIII I 10 Compound B 5.0 2.52.52.52. lauryl succinnic acid 5.0 2.5 disodium sulfococoate 5.0 2.5 lauryl ether (4) carboxylate 5.0 2.5 lauryl disodium sulfosuccinate 5.0 2. deionized water q.s. to 100% Example X The compositions prepared in Examples I-IX are tested for hard water foam properties using the modified Ross-Miles procedure set forth hereinbefore and the results are as follows: Initial Foam Height in mm -25 Example 200 ppm hard water I 358 II 330 III 348 IV 330 30 V 330 VI 365 VII 375 VIII 368 IX 378 199855 As can be readily seen from the results above, the compositions containing a mixture of the specific amphoteric - fatty acid complexes and the anionic surfactants of the present invention (Examples VI-IX) 5 exhibit a synergistic increase in initial foam height. It is also observed that the quality of the foam generated by the compositions of the present invention is superior to that of the other compositions in that it is denser and creamier. A generated foam of this nature is not only 10 perceived to be better by the consumer, but is also capable of supporting and suspending soils in a manner superior to the more open, lace-like foam of the compositions of Examples I-IV and thus these soils are more easily removed.
Example XI A detergent bar composition is prepared by charging to a steam-jacketed rotary mixer 23.7 parts by weight stearic acid, 13.3 parts by weight dextrin, 35.1 parts by weight 20 disodium -sulfococoate, 14,2 parts by weight compound A, 0.2 parts titanium dioxide and 10.0 parts water. The mixture is heated to 50-60°C and mixed until homogeneous and the pH is adjusted to 7.2+.2 with 50% NaOH solution. The resulting product is chilled, rolled in flakes, 25 milled, plodded and stamped into bars having the following composition: % wt/wt stearic acid 23.7 dextrin 13.3 disodium -sulfococoate 35.1 Compound A 14.2 Ti02 0.2 50% NaOH 5.2 deionized water 8.3 100.0 19 98 5 5 The resulting bar foams copiously in hard and soft water and free of lime soap deposits and is also found to be a slight ocular irritant when tested.
Example XII A low pH detergent bar composition is prepared in accordance with the procedure of Example XI and has the following formulation: % wt/wt Compound B 20.00 stearic acid 15.00 polyethylene glycol 4000 5.00 dextrin 10.00 talc 10.00 disodium lauryl sulfosuccinate 35.00 deionized water 5.00 100.00 Example XIII A liquid cream soap product is prepared as follows: 87.5 parts by weight of compound C and 20.0 parts by weight of lauryl succinic acid are charged to a vessel equipped with a stirrer and steam and are heated to 45°C. The pH is adjusted to 7.0+.2 with dilute NaOH followed by the 25 addition of 1 part of propylene glycol and 95 grams of deionized water. The mass is cooled to 30°C and 2 parts of a fragrance are added prior to filling into tubes. The resulting product has the following formulation; % wt/wt Compound C 42.57 lauryl succinate 9.73 propylene glycol 0.48 fragrance 0.97 deionized water q.s. to 100% The product is a smooth opaque mild cream gel easily dispensed from tubes. 199855 Example XIV An opaque liquid soap is prepared having the following formulation: % wt/wt Compound D 30.0 lauryl sarcosinate 20.0 polyethylene glycol 6000 distearate 3.0 deionized water q.s. to 100 The pH of the above formulation is adjusted to 6.0 with dilute HC1.
Example XV An opaque liquid soap is prepared having the following formulation: % wt/wt sulfosuccinate 3.00 Compound A 2.50 ammonium lauryl (3) ether sulfate 3.00 polyoxyethylene 80 sorbitan monolaurate 5.00 preservative .10 dye and fragrance .25 deionized water q.s. to 100 The pH of the above formulation is adjusted to 6.0 with dilute HC1.
In addition to the preferred embodiments described herein, other embodiments, arrangements, and variations within the spirit of the invention and the scope of the appended claims will occur to those skilled in the art. 1 ^ 9 fl S 5 JBP 184 1 ' y 0 JJ
Claims (10)
1. a detergent and cleansing composition comprising a synergistic mixture of- activfe ".ingredients consisting essentially of (a) from 1 to 50% by weight of an amphoteric-fatty acid complex of the formula 10 r "i [RlC-Oj © R2-N \ ■A1 a2 © 15 20 wherein R^ is alkyl or substituted alkyl containing from 6 to 18 carbon atoms and mixtures thereof; R2 is alkyl containing from 8 to .18 carbon atoms and mixtures thereof or alkyl amido of the formula 0 Z li I r.-j-C-K- 25 wherein R3 is alkyl containing from 8 to 18 carbon atoms/ Z is H or lower alkyl containing from j. to 4 carbon atoms; and Y is lower alkylene" containing . from 1 to 4 carbon atoms; 30 A^ and A2 are the same or different and are selected from the group of anionic salt moieties consisting of the following; -f-CH2CH2-COOX] n 4CH2-COOX]n 35 4CH2CH0H-CH2-S03X]n -tCH2-CH0H-CH2-0P03X] n when X is divalent -£CH2-CHOH-CH2-OPC>3X2^ n when X is monovalent 199855 18- wherein X is a water soluble cation and n is an integer of 1 or 2 with the proviso that if only one of A^ and a2 -is^ selected from the anionic salt moieties above the other can be hydrogen, lower alkyl or lower hydroxy-5 alkyl containing from 1 to 4 carbon atoms;' and (b) from 2 to 50% by weight of an anionic surfactant selected from the group consisting of sulfosuccinates, alkyl carboxylates, a -sulfo fatty acid and ester 10 carboxylates, alkyl succinates, alkyl sarcosinates and fatty acid protein condensates.
2. The composition of claim 1 wherein the amphoteric-fatty acid complex and the anionic surfactant are in the 15 ratio of from 1:4 to 4:1.
3. The composition of claim 1 wherein the amphoteric fatty acid complex is of the formula 2° r ° I© rc-oJ wherein R^ is a C11H23 - Cl8H37 25 mixture. OH C2H4OH II I / CllH-23-C"NtCH2)5-Nv 1± 2 I CH2COOK) H ©
4. The composition of claim 1 wherein the amphoteric-fatty acid complex is of the formula 30 ,CH2CH2COONa c12h25 If\CH2CH2COONa - H 0 35 wherein R^ is a CgHj^ - C18H37 mixture. -19- 199855
5. The composition of claim 1 wherein the amphoteric-fatty acid complex is of the formula ©
6. The composition of claim 1 wherein the amphoteric fatty acid complex is from 5 to 15% by weight of the 10 total composition.
7. The composition of claim 1 wherein the anionic surfactant is an alkyl sarcosinate. 15
8. The composition of claim 1 wherein the anionic surfactant is a sulfosuccinate.
9. The composition of claim 1 wherein the anionic surfactant is an alkyl succinate. 20
10. The composition of claim 1 wherein the anionic surfactant is from 5 to 40% by weight of -the total composition. O D C11H23C"° 0 H^CH2CH2COONa C14H29-N CH2CH2COONa WEST -WALKER, McCABE per: ATTORNEYS FOR THE APPLICANT
Applications Claiming Priority (1)
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| JPS614800A (en) * | 1984-06-18 | 1986-01-10 | ユニ・チヤ−ム株式会社 | Body detergent composition |
| JP2562937B2 (en) * | 1988-05-20 | 1996-12-11 | 株式会社資生堂 | Detergent composition |
| JPH0721154B2 (en) * | 1988-10-15 | 1995-03-08 | 三洋化成工業株式会社 | Cleaning composition |
| JP2559500B2 (en) * | 1989-10-06 | 1996-12-04 | 花王株式会社 | Detergent composition |
| DE4108603A1 (en) * | 1991-03-16 | 1992-09-17 | Trigon Chemie Gmbh | New anionically substd. N-acyl-polyethylene polyamine derivs. - amphoteric surfactants, useful in washing and cleaning compsns. giving products stable at low temp. |
| AU3598597A (en) * | 1996-07-09 | 1998-02-02 | Colgate-Palmolive Company, The | Liquid cleaning compositions |
| US5958861A (en) * | 1996-12-06 | 1999-09-28 | Colgate Palmolive Company | Liquid cleaning compositions containing a Lewis neutral base polymer |
| DE19714370A1 (en) † | 1997-04-08 | 1998-10-15 | Henkel Kgaa | Aqueous caring skin and hair treatment products |
| JP4792628B2 (en) * | 2000-10-16 | 2011-10-12 | 日油株式会社 | Cleaning composition |
| JP4729782B2 (en) * | 2000-10-16 | 2011-07-20 | 日油株式会社 | Cleaning composition |
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| DE5446C (en) * | L. SENF in Buckau-Magdeburg | Zither ring | ||
| US3055836A (en) * | 1957-12-24 | 1962-09-25 | Johnson & Johnson | Detergent composition |
| US2970160A (en) * | 1959-02-11 | 1961-01-31 | Johnson & Johnson | Process for making amphoteric surface active agents |
| US3950417A (en) * | 1975-02-28 | 1976-04-13 | Johnson & Johnson | High-lathering non-irritating detergent compositions |
| JPS5397009A (en) * | 1977-02-03 | 1978-08-24 | Kanebo Ltd | Toilet soap composition |
| JPS53102912A (en) * | 1977-02-22 | 1978-09-07 | Kanebo Ltd | Toilet soap composition |
| US4181634A (en) * | 1977-06-17 | 1980-01-01 | Johnson & Johnson | Mild cleansing compositions comprising an alkyleneoxylated bisquaternary ammonium compound and an anionic or amphoteric detergent such as a phosphobetaine |
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- 1982-03-09 JP JP57035969A patent/JPS57159897A/en active Granted
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| FI67723B (en) | 1985-01-31 |
| FI820797L (en) | 1982-09-10 |
| JPH0252680B2 (en) | 1990-11-14 |
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| BR8201230A (en) | 1983-01-18 |
| GR76364B (en) | 1984-08-06 |
| BE892427A (en) | 1982-09-09 |
| GB2094335A (en) | 1982-09-15 |
| MX156368A (en) | 1988-08-15 |
| SE448632B (en) | 1987-03-09 |
| JPS57159897A (en) | 1982-10-02 |
| IT8247923A0 (en) | 1982-03-05 |
| SE8201213L (en) | 1982-09-10 |
| ES8305822A1 (en) | 1983-04-16 |
| CH651584A5 (en) | 1985-09-30 |
| ZA821526B (en) | 1983-10-26 |
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