NO995494L - Reduksjon av aromatiske halogenider - Google Patents
Reduksjon av aromatiske halogeniderInfo
- Publication number
- NO995494L NO995494L NO995494A NO995494A NO995494L NO 995494 L NO995494 L NO 995494L NO 995494 A NO995494 A NO 995494A NO 995494 A NO995494 A NO 995494A NO 995494 L NO995494 L NO 995494L
- Authority
- NO
- Norway
- Prior art keywords
- reduction
- oxygen
- aromatic halides
- technical
- lialh4
- Prior art date
Links
- -1 aromatic halides Chemical class 0.000 title abstract 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 3
- 239000012280 lithium aluminium hydride Substances 0.000 abstract 3
- 239000001301 oxygen Substances 0.000 abstract 3
- 229910052760 oxygen Inorganic materials 0.000 abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- QENVUHCAYXAROT-UHFFFAOYSA-N Galanthaminon Natural products O1C(=C23)C(OC)=CC=C2CN(C)CCC23C1CC(=O)C=C2 QENVUHCAYXAROT-UHFFFAOYSA-N 0.000 abstract 1
- QENVUHCAYXAROT-YOEHRIQHSA-N Narwedine Chemical compound O1C(=C23)C(OC)=CC=C2CN(C)CC[C@]23[C@@H]1CC(=O)C=C2 QENVUHCAYXAROT-YOEHRIQHSA-N 0.000 abstract 1
- WCRYNEMFWLZAAZ-WMLDXEAASA-N Narwedine Natural products COc1ccc2CCCC[C@@]34C=CC(=O)C[C@@H]3Oc1c24 WCRYNEMFWLZAAZ-WMLDXEAASA-N 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- 150000004678 hydrides Chemical class 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 210000005036 nerve Anatomy 0.000 abstract 1
- 230000035484 reaction time Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B31/00—Reduction in general
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
- C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
- C07D333/06—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
- C07D333/08—Hydrogen atoms or radicals containing only hydrogen and carbon atoms
- C07D333/10—Thiophene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/26—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Abstract
For reduksjon av (hetero)aromatiske halogenider med generell formel (I) Ar-Xn til forbindelser med generell formel (II) Ar-Hn anvendes et reduksjonsmiddel, spesielt en hydridreagens, som litiumaluminiumhydrid (LiAlH4) i nærvær av oksygen, spesielt i form av en oksygen-inertgass-blanding. Reduksjonen i nærvær av oksygen gir gode utbytter ved korte reaksjonstider, også når det arbeides i halvtekniske eller tekniske blandinger. Reduksjonen med LiAlH4 i nærvær av oksygen er også egnet for reduksjonen av kompliserte heieroaromatiske halogenider, eksempelvis for reduksjonen av bromnarwedinketal til narwedinketal i teknisk målestokk.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT0086597A AT405051B (de) | 1997-05-21 | 1997-05-21 | Reduktion aromatischer halogenide |
PCT/AT1998/000112 WO1998052885A1 (de) | 1997-05-21 | 1998-04-30 | Reduktion aromatischer halogenide |
Publications (2)
Publication Number | Publication Date |
---|---|
NO995494D0 NO995494D0 (no) | 1999-11-10 |
NO995494L true NO995494L (no) | 1999-11-10 |
Family
ID=3501602
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO995494A NO995494L (no) | 1997-05-21 | 1999-11-10 | Reduksjon av aromatiske halogenider |
Country Status (15)
Country | Link |
---|---|
EP (1) | EP0983215A1 (no) |
JP (1) | JP2001525828A (no) |
KR (1) | KR20010012795A (no) |
CN (1) | CN1257467A (no) |
AT (1) | AT405051B (no) |
AU (1) | AU7012798A (no) |
BG (1) | BG103880A (no) |
BR (1) | BR9809661A (no) |
CA (1) | CA2289992A1 (no) |
HU (1) | HUP0004681A2 (no) |
NO (1) | NO995494L (no) |
NZ (1) | NZ500733A (no) |
PL (1) | PL336906A1 (no) |
SK (1) | SK158399A3 (no) |
WO (1) | WO1998052885A1 (no) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006018703A2 (en) * | 2004-08-16 | 2006-02-23 | Ranbaxy Laboratories Limited | Processes for preparation of narwedine and its use in the synthesis of galantamine |
US9738122B2 (en) * | 2010-12-02 | 2017-08-22 | The Yokohama Rubber Co., Ltd. | Tire provided with information acquisition device |
CN107602318B (zh) * | 2017-09-08 | 2020-06-05 | 郑州大学 | 一种温和条件下卤代芳烃液相还原脱卤的方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3839329A1 (de) * | 1988-11-22 | 1990-05-31 | Basf Ag | Verfahren zur reduktiven enthalogenierung von aromaten |
-
1997
- 1997-05-21 AT AT0086597A patent/AT405051B/de not_active IP Right Cessation
-
1998
- 1998-04-30 CA CA002289992A patent/CA2289992A1/en not_active Abandoned
- 1998-04-30 AU AU70127/98A patent/AU7012798A/en not_active Abandoned
- 1998-04-30 SK SK1583-99A patent/SK158399A3/sk unknown
- 1998-04-30 CN CN98805275.XA patent/CN1257467A/zh active Pending
- 1998-04-30 NZ NZ500733A patent/NZ500733A/xx unknown
- 1998-04-30 KR KR1019997010758A patent/KR20010012795A/ko not_active Application Discontinuation
- 1998-04-30 PL PL98336906A patent/PL336906A1/xx unknown
- 1998-04-30 EP EP98916623A patent/EP0983215A1/de not_active Withdrawn
- 1998-04-30 JP JP54968898A patent/JP2001525828A/ja active Pending
- 1998-04-30 HU HU0004681A patent/HUP0004681A2/hu unknown
- 1998-04-30 BR BR9809661-3A patent/BR9809661A/pt not_active Application Discontinuation
- 1998-04-30 WO PCT/AT1998/000112 patent/WO1998052885A1/de not_active Application Discontinuation
-
1999
- 1999-11-10 NO NO995494A patent/NO995494L/no not_active Application Discontinuation
- 1999-11-15 BG BG103880A patent/BG103880A/xx unknown
Also Published As
Publication number | Publication date |
---|---|
PL336906A1 (en) | 2000-07-17 |
KR20010012795A (ko) | 2001-02-26 |
ATA86597A (de) | 1998-09-15 |
HUP0004681A2 (hu) | 2001-04-28 |
NO995494D0 (no) | 1999-11-10 |
CA2289992A1 (en) | 1998-11-26 |
BG103880A (en) | 2000-06-30 |
AU7012798A (en) | 1998-12-11 |
JP2001525828A (ja) | 2001-12-11 |
AT405051B (de) | 1999-05-25 |
CN1257467A (zh) | 2000-06-21 |
SK158399A3 (en) | 2000-07-11 |
WO1998052885A1 (de) | 1998-11-26 |
EP0983215A1 (de) | 2000-03-08 |
NZ500733A (en) | 2001-03-30 |
BR9809661A (pt) | 2000-07-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Herranz et al. | Osmium-catalyzed vicinal oxyamination of olefins by N-chloro-N-argentocarbamates | |
Mico et al. | Reductive oxygenation of carbon tetrachloride: trichloromethylperoxyl radical as a possible intermediate in the conversion of carbon tetrachloride to electrophilic chlorine | |
Yamada et al. | Synthesis and Reaction of New type I–N ylide, n-Tosyliminoiodinane | |
ATE202565T1 (de) | Dampfphase oxydierung von propylen zu propylenoxid | |
EA199900141A1 (ru) | Цветообразующая композиция, содержащая реагент, включающий пирогаллольные структурные фрагменты, соль железа (ii) и органическую кислоту | |
ES2005745A6 (es) | Un procedimiento para preparar arilpiperindionas. | |
Ishida et al. | Selective formation of HCOO–in the electrochemical CO 2 reduction catalysed by [Ru (bpy) 2 (CO) 2] 2+(bpy= 2, 2′-bipyridine) | |
TR199801982T2 (xx) | Kataliz�r ve vinilasetat �retimi i�in i�lem. | |
Mansuy et al. | Mono-oxigenase-like dioxygen activation leading to alkane hydroxylation and olefin epoxidation by an Mn III (porphyrin)–ascorbate biphasic system | |
Arase et al. | Dialkylborane-catalyzed hydroboration of alkynes with 1, 3, 2-benzodioxaborole in tetrahydrofuran | |
ES2057755T3 (es) | Derivados del 1-fenilimidazol, procedimiento para su preparacion y su uso. | |
Fowler | Relative stabilities of the N-methyldihydropyridines | |
Davis et al. | Coupling and hydroxylation of lithium and Grignard reagents by oxaziridines | |
BR8205877A (pt) | Processo para hidroxilar pelo menos um composto olefinico que tem pelo menos uma insaturacao etilenica | |
BR9808730A (pt) | Processo de preparação de 1,1,1,3,3 - pentaclorobutano | |
NO995494L (no) | Reduksjon av aromatiske halogenider | |
Santa et al. | Oxidation of tertiary amines and sulfides by an iron (III) porphyrin-O2-Na2S2O4 system as a model of cytochrome P-450 | |
De Ley et al. | Intramolecular electron transport in human ferroxidase (caeruloplasmin). | |
IL133099A0 (en) | Preparation of tri-iodo benzene compounds | |
Hiskey et al. | Colorimetric determination of phenylephrine using 4-aminoantipyrine | |
Koda et al. | Reaction kinetics of nitrogen dioxide with methanol in the gas phase | |
Miyake et al. | Flavin‐Catalyzed Aerobic Oxidative C− C Bond Formation by Metal/Light‐Free Cross‐Dehydrogenative Coupling | |
KR830004293A (ko) | 헤테로사이클 화합물의 제조방법 | |
Moss et al. | Mechanistic origins of acyloxydiazirines | |
NO996282L (no) | Homogen oksidasjonskatalyse ved anvendelse av metallkomplekser |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FC2A | Withdrawal, rejection or dismissal of laid open patent application |