NO890513L - Fremgangsmaate ved fremstilling av mikrokapsler. - Google Patents
Fremgangsmaate ved fremstilling av mikrokapsler.Info
- Publication number
- NO890513L NO890513L NO89890513A NO890513A NO890513L NO 890513 L NO890513 L NO 890513L NO 89890513 A NO89890513 A NO 89890513A NO 890513 A NO890513 A NO 890513A NO 890513 L NO890513 L NO 890513L
- Authority
- NO
- Norway
- Prior art keywords
- microcapsules
- emulsion
- capsule
- capsules
- emulsifier
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 29
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
- 239000003094 microcapsule Substances 0.000 claims abstract description 41
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 32
- 239000000203 mixture Substances 0.000 claims abstract description 20
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000007864 aqueous solution Substances 0.000 claims abstract description 7
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims abstract description 3
- 159000000000 sodium salts Chemical class 0.000 claims abstract description 3
- 239000011162 core material Substances 0.000 claims description 14
- 239000000839 emulsion Substances 0.000 claims description 13
- 239000002243 precursor Substances 0.000 claims description 13
- 230000001681 protective effect Effects 0.000 claims description 13
- 239000000084 colloidal system Substances 0.000 claims description 12
- 239000000243 solution Substances 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 239000003822 epoxy resin Substances 0.000 claims description 8
- 229920000647 polyepoxide Polymers 0.000 claims description 8
- 229920002396 Polyurea Polymers 0.000 claims description 7
- 229920001228 polyisocyanate Polymers 0.000 claims description 7
- 239000005056 polyisocyanate Substances 0.000 claims description 7
- 239000004593 Epoxy Substances 0.000 claims description 6
- 229920000768 polyamine Polymers 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 239000007764 o/w emulsion Substances 0.000 claims description 5
- 230000001804 emulsifying effect Effects 0.000 claims description 4
- 238000009835 boiling Methods 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract description 24
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract description 23
- 238000006116 polymerization reaction Methods 0.000 abstract description 8
- 230000008569 process Effects 0.000 abstract description 8
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract description 7
- 239000001257 hydrogen Substances 0.000 abstract description 6
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 6
- 238000012546 transfer Methods 0.000 abstract description 5
- 239000002775 capsule Substances 0.000 description 65
- 239000002002 slurry Substances 0.000 description 21
- 239000000463 material Substances 0.000 description 12
- 239000012948 isocyanate Substances 0.000 description 11
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 10
- 150000002513 isocyanates Chemical class 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 238000005054 agglomeration Methods 0.000 description 8
- 230000002776 aggregation Effects 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 8
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 7
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 7
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 7
- 238000001694 spray drying Methods 0.000 description 7
- QKOWXXDOHMJOMQ-UHFFFAOYSA-N 1,3,5-tris(6-isocyanatohexyl)biuret Chemical compound O=C=NCCCCCCNC(=O)N(CCCCCCN=C=O)C(=O)NCCCCCCN=C=O QKOWXXDOHMJOMQ-UHFFFAOYSA-N 0.000 description 6
- -1 aliphatic isocyanates Chemical class 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000005538 encapsulation Methods 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 238000002845 discoloration Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 4
- 238000012695 Interfacial polymerization Methods 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 229920001568 phenolic resin Polymers 0.000 description 4
- 239000005011 phenolic resin Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 239000000376 reactant Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- LIZLYZVAYZQVPG-UHFFFAOYSA-N (3-bromo-2-fluorophenyl)methanol Chemical compound OCC1=CC=CC(Br)=C1F LIZLYZVAYZQVPG-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- 230000002363 herbicidal effect Effects 0.000 description 2
- 239000004009 herbicide Substances 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 239000011268 mixed slurry Substances 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- IAUKWGFWINVWKS-UHFFFAOYSA-N 1,2-di(propan-2-yl)naphthalene Chemical compound C1=CC=CC2=C(C(C)C)C(C(C)C)=CC=C21 IAUKWGFWINVWKS-UHFFFAOYSA-N 0.000 description 1
- PWGJDPKCLMLPJW-UHFFFAOYSA-N 1,8-diaminooctane Chemical compound NCCCCCCCCN PWGJDPKCLMLPJW-UHFFFAOYSA-N 0.000 description 1
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 101150096185 PAAS gene Proteins 0.000 description 1
- 229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000005700 Putrescine Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- ZKURGBYDCVNWKH-UHFFFAOYSA-N [3,7-bis(dimethylamino)phenothiazin-10-yl]-phenylmethanone Chemical compound C12=CC=C(N(C)C)C=C2SC2=CC(N(C)C)=CC=C2N1C(=O)C1=CC=CC=C1 ZKURGBYDCVNWKH-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- MRNZSTMRDWRNNR-UHFFFAOYSA-N bis(hexamethylene)triamine Chemical compound NCCCCCCNCCCCCCN MRNZSTMRDWRNNR-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- YQLZOAVZWJBZSY-UHFFFAOYSA-N decane-1,10-diamine Chemical compound NCCCCCCCCCCN YQLZOAVZWJBZSY-UHFFFAOYSA-N 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- FDENMIUNZYEPDD-UHFFFAOYSA-L disodium [2-[4-(10-methylundecyl)-2-sulfonatooxyphenoxy]phenyl] sulfate Chemical compound [Na+].[Na+].CC(C)CCCCCCCCCc1ccc(Oc2ccccc2OS([O-])(=O)=O)c(OS([O-])(=O)=O)c1 FDENMIUNZYEPDD-UHFFFAOYSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- CBYZIWCZNMOEAV-UHFFFAOYSA-N formaldehyde;naphthalene Chemical class O=C.C1=CC=CC2=CC=CC=C21 CBYZIWCZNMOEAV-UHFFFAOYSA-N 0.000 description 1
- UPBDXRPQPOWRKR-UHFFFAOYSA-N furan-2,5-dione;methoxyethene Chemical compound COC=C.O=C1OC(=O)C=C1 UPBDXRPQPOWRKR-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- GKQPCPXONLDCMU-CCEZHUSRSA-N lacidipine Chemical compound CCOC(=O)C1=C(C)NC(C)=C(C(=O)OCC)C1C1=CC=CC=C1\C=C\C(=O)OC(C)(C)C GKQPCPXONLDCMU-CCEZHUSRSA-N 0.000 description 1
- 239000004850 liquid epoxy resins (LERs) Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- WMVXNHRAGUXWKG-UHFFFAOYSA-N phenoxysulfonyl phenyl sulfate Chemical compound C=1C=CC=CC=1OS(=O)(=O)OS(=O)(=O)OC1=CC=CC=C1 WMVXNHRAGUXWKG-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000005648 plant growth regulator Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
- B41M5/165—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components characterised by the use of microcapsules; Special solvents for incorporating the ingredients
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
- B01J13/16—Interfacial polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
- C08G18/0842—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
- C08G18/0861—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers
- C08G18/0866—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being an aqueous medium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3225—Polyamines
- C08G18/3228—Polyamines acyclic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249994—Composite having a component wherein a constituent is liquid or is contained within preformed walls [e.g., impregnant-filled, previously void containing component, etc.]
- Y10T428/249995—Constituent is in liquid form
- Y10T428/249997—Encapsulated liquid
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Manufacturing & Machinery (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Developing Agents For Electrophotography (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Color Printing (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Immobilizing And Processing Of Enzymes And Microorganisms (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Epoxy Resins (AREA)
- Polyurethanes Or Polyureas (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/153,449 US4785048A (en) | 1988-02-08 | 1988-02-08 | Polyurea and polyurea-epoxy microcapsules |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| NO890513D0 NO890513D0 (no) | 1989-02-07 |
| NO890513L true NO890513L (no) | 1989-08-09 |
Family
ID=22547271
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO89890513A NO890513L (no) | 1988-02-08 | 1989-02-07 | Fremgangsmaate ved fremstilling av mikrokapsler. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US4785048A (de) |
| EP (1) | EP0327748B1 (de) |
| JP (1) | JPH0620535B2 (de) |
| AT (1) | ATE68368T1 (de) |
| AU (1) | AU600140B2 (de) |
| BR (1) | BR8805686A (de) |
| CA (1) | CA1300987C (de) |
| DE (1) | DE3865663D1 (de) |
| DK (1) | DK330788A (de) |
| FI (1) | FI882920A (de) |
| MX (1) | MX163593B (de) |
| NO (1) | NO890513L (de) |
| NZ (1) | NZ225105A (de) |
| PT (1) | PT87795B (de) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5015527A (en) * | 1989-01-13 | 1991-05-14 | Moore Business Forms, Inc. | Interfacial epoxy microcapsulation system |
| US5037716A (en) * | 1989-10-02 | 1991-08-06 | Xerox Corporation | Encapsulated toners and processes thereof |
| US5225118A (en) * | 1990-08-15 | 1993-07-06 | Boise Cascade Corporation | Process for manufacturing polyurea microcapsules and product therefrom |
| US5714711A (en) * | 1990-12-31 | 1998-02-03 | Mei Corporation | Encapsulated propellant grain composition, method of preparation, article fabricated therefrom and method of fabrication |
| IT1276525B1 (it) * | 1994-04-13 | 1997-10-31 | Webcraft Technologies Inc | Dispositivo e procedimento per la esposizione selettiva di liquidi microincapsulati. |
| FR2723032B1 (fr) | 1994-07-26 | 1996-11-22 | Copigraph Sa | Nouveau solvant organique pour microcapsules utiles notamment pour la realisation de papier autocopiant sensible a la pression et papier sensible a lapression revetu de telles microcapsules |
| FR2727633A1 (fr) | 1994-12-02 | 1996-06-07 | Copigraph | Microcapsules contenant a titre de solvant un derive terpenique ou d'acide abietique et papiers sensibles a la pression revetus de ces microcapsules |
| US5705174A (en) * | 1995-06-07 | 1998-01-06 | American Cyanamid Company | Process for the preparation of microcapsule compositions |
| US5861360A (en) * | 1995-12-21 | 1999-01-19 | Basf Corporation | Encapsulated plant growth regulator formulations and applications |
| WO1997023133A1 (en) * | 1995-12-21 | 1997-07-03 | Basf Corporation | Low rate application of inhibitors of ethylene biosynthesis or action |
| EP1028627B1 (de) * | 1995-12-21 | 2002-05-22 | Basf Corporation | Aminoethoxyvinylglycine in kombination mit mepiquatchlorid |
| WO1997022249A1 (en) * | 1995-12-21 | 1997-06-26 | Basf Corporation | Enhancing the rate of seed germination with application of ethylene biosynthesis inhibitors |
| WO1998027811A1 (en) | 1996-12-20 | 1998-07-02 | Basf Corporation | Plant growth regulators in pyrrolidone solvents |
| US9816059B2 (en) | 2009-09-18 | 2017-11-14 | International Flavors & Fragrances | Stabilized capsule compositions |
| WO2015023961A1 (en) * | 2013-08-15 | 2015-02-19 | International Flavors & Fragrances Inc. | Polyurea or polyurethane capsules |
| US10085925B2 (en) | 2009-09-18 | 2018-10-02 | International Flavors & Fragrances Inc. | Polyurea capsule compositions |
| US11311467B2 (en) | 2009-09-18 | 2022-04-26 | International Flavors & Fragrances Inc. | Polyurea capsules prepared with a polyisocyanate and cross-linking agent |
| US10226405B2 (en) | 2009-09-18 | 2019-03-12 | International Flavors & Fragrances Inc. | Purified polyurea capsules, methods of preparation, and products containing the same |
| US9687424B2 (en) | 2009-09-18 | 2017-06-27 | International Flavors & Fragrances | Polyurea capsules prepared with aliphatic isocyanates and amines |
| US9126000B2 (en) | 2010-02-26 | 2015-09-08 | Nihon Kohden Corporation | Artificial ventilation apparatus |
| EP3265065A4 (de) * | 2015-03-06 | 2018-08-01 | International Flavors & Fragrances Inc. | Mikrokapselzusammensetzung en mit hoher leistung |
| WO2018032388A1 (en) * | 2016-08-17 | 2018-02-22 | Jiangsu Rotam Chemistry Co., Ltd. | Herbicide composition comprising clomazone and use thereof |
| GB2567099B (en) * | 2016-08-17 | 2022-04-06 | Jiangsu Rotam Chemistry Co Ltd | Herbicide composition comprising clomazone and use thereof |
| MX2019003078A (es) * | 2016-09-16 | 2019-07-08 | Int Flavors & Fragrances Inc | Composiciones de microcapsulas estabilizadas con agentes de control de la viscosidad. |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2712507A (en) * | 1953-06-30 | 1955-07-05 | Ncr Co | Pressure sensitive record material |
| US3666680A (en) * | 1970-03-05 | 1972-05-30 | Purex Corp Ltd | Method of combining optical brighteners with polymers for stability in bleach and encapsulated product |
| US4563212A (en) * | 1983-12-27 | 1986-01-07 | Monsanto Company | High concentration encapsulation by interfacial polycondensation |
| EP0214936B1 (de) * | 1985-09-13 | 1992-07-08 | Ciba-Geigy Ag | Verfahren zur Herstellung von Mikrokapseln |
| US4680056A (en) * | 1986-01-23 | 1987-07-14 | Koch Industries, Inc. | Carbonless paper solvent utilizing triisopropyltoluene |
-
1988
- 1988-02-08 US US07/153,449 patent/US4785048A/en not_active Expired - Fee Related
- 1988-06-16 DE DE8888305513T patent/DE3865663D1/de not_active Expired - Fee Related
- 1988-06-16 AT AT88305513T patent/ATE68368T1/de not_active IP Right Cessation
- 1988-06-16 EP EP88305513A patent/EP0327748B1/de not_active Expired - Lifetime
- 1988-06-16 DK DK330788A patent/DK330788A/da not_active Application Discontinuation
- 1988-06-17 AU AU17798/88A patent/AU600140B2/en not_active Ceased
- 1988-06-17 FI FI882920A patent/FI882920A/fi not_active Application Discontinuation
- 1988-06-20 NZ NZ225105A patent/NZ225105A/xx unknown
- 1988-06-22 CA CA000570056A patent/CA1300987C/en not_active Expired - Fee Related
- 1988-06-22 PT PT87795A patent/PT87795B/pt not_active IP Right Cessation
- 1988-07-04 MX MX12141A patent/MX163593B/es unknown
- 1988-09-07 JP JP63224354A patent/JPH0620535B2/ja not_active Expired - Lifetime
- 1988-11-03 BR BR888805686A patent/BR8805686A/pt not_active IP Right Cessation
-
1989
- 1989-02-07 NO NO89890513A patent/NO890513L/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FI882920A (fi) | 1989-08-09 |
| DK330788D0 (da) | 1988-06-16 |
| ATE68368T1 (de) | 1991-11-15 |
| EP0327748A1 (de) | 1989-08-16 |
| NZ225105A (en) | 1989-08-29 |
| JPH0620535B2 (ja) | 1994-03-23 |
| US4785048A (en) | 1988-11-15 |
| NO890513D0 (no) | 1989-02-07 |
| DK330788A (da) | 1989-08-09 |
| AU600140B2 (en) | 1990-08-02 |
| PT87795B (pt) | 1993-09-30 |
| EP0327748B1 (de) | 1991-10-16 |
| PT87795A (pt) | 1989-10-04 |
| FI882920A0 (fi) | 1988-06-17 |
| JPH01210030A (ja) | 1989-08-23 |
| CA1300987C (en) | 1992-05-19 |
| MX163593B (es) | 1992-06-04 |
| DE3865663D1 (de) | 1991-11-21 |
| BR8805686A (pt) | 1990-06-12 |
| AU1779888A (en) | 1989-08-10 |
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