NO851339L - CORROSION PROTECTION PRIMER FOR PHOSPHATED OR CHROMATED, ELECTROLYTIC THICKLY Galvanized, formable steel sheet - Google Patents
CORROSION PROTECTION PRIMER FOR PHOSPHATED OR CHROMATED, ELECTROLYTIC THICKLY Galvanized, formable steel sheetInfo
- Publication number
- NO851339L NO851339L NO851339A NO851339A NO851339L NO 851339 L NO851339 L NO 851339L NO 851339 A NO851339 A NO 851339A NO 851339 A NO851339 A NO 851339A NO 851339 L NO851339 L NO 851339L
- Authority
- NO
- Norway
- Prior art keywords
- corrosion protection
- protection primer
- steel sheet
- dry film
- phosphated
- Prior art date
Links
- 238000005260 corrosion Methods 0.000 title claims description 33
- 230000007797 corrosion Effects 0.000 title claims description 33
- 229910000831 Steel Inorganic materials 0.000 title claims description 10
- 239000010959 steel Substances 0.000 title claims description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 15
- 229910052725 zinc Inorganic materials 0.000 claims description 13
- 239000011701 zinc Substances 0.000 claims description 13
- 239000011230 binding agent Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 229910001335 Galvanized steel Inorganic materials 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- 239000008397 galvanized steel Substances 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 claims description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 229920001225 polyester resin Polymers 0.000 claims description 2
- 239000004645 polyester resin Substances 0.000 claims description 2
- PTISTKLWEJDJID-UHFFFAOYSA-N sulfanylidenemolybdenum Chemical compound [Mo]=S PTISTKLWEJDJID-UHFFFAOYSA-N 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
- 239000000314 lubricant Substances 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 230000003111 delayed effect Effects 0.000 description 4
- 238000005246 galvanizing Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000004210 cathodic protection Methods 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000012216 bentonite Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- GQKCRUJOPUHISR-UHFFFAOYSA-M potassium;dizinc;dioxido(dioxo)chromium;hydroxide Chemical compound [OH-].[K+].[Zn+2].[Zn+2].[O-][Cr]([O-])(=O)=O.[O-][Cr]([O-])(=O)=O GQKCRUJOPUHISR-UHFFFAOYSA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/82—After-treatment
- C23C22/83—Chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Laminated Bodies (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Chemical Treatment Of Metals (AREA)
Description
Denne oppfinnelse angår en glidedyktig og sveisbar korrosjonsbeskyttelses-primer for fosfatert eller kromatert, elektrolytisk tynnforsinket, formbart stålblikk. This invention relates to a sliding and weldable corrosion protection primer for phosphated or chromated, electrolytically thin galvanized, malleable sheet steel.
Sinkstøv - primersystemer for formbart, fosfatert eller kromatert stålblikk ved hvilke korrosjonsbeskyttelsen bibeholdes etter formningen av blikket (f.eks. ved sponløs formning under pressing), er kjent fra DE-PS 32 32 755. Den korrosjonsbeskyttelse som disse sinkstøv-primersystemer gir, tilfredsstiller imidlertid ikke fordringene i våre dager, da det på grunn av manglende katodisk beskyttelse relativt tid-lig opptrer rødrustdannelse ved korrosjonsforsøk. På grunn av den bedre katodiske beskyttelse ved samtidig høyere over-flatekvalitet anvendes det idag i stor utstrekning elektrolytisk forsinket blikk med et forholdsvis tykt belegg på Zinc dust - primer systems for malleable, phosphated or chromated steel sheets in which the corrosion protection is maintained after the forming of the sheet (e.g. by chipless forming during pressing), is known from DE-PS 32 32 755. The corrosion protection that these zinc dust primer systems provide satisfies however, not the requirements these days, as due to a lack of cathodic protection, red rust formation occurs relatively early during corrosion tests. Due to the better cathodic protection at the same time higher surface quality, electrolytically delayed tin with a relatively thick coating on
7,5 - 10 jum. Voksende beleggtykkelse av sinksjiktet bringer imidlertid med seg problemer med hensyn til formbarheten. Riktignok lar sådant elektrolytisk forsinket blikk seg forme, men smøremiddelbehovet er da forholdsvis stort. Til tross for disse forholdsregler vil det med tiden avlagres sink på press-verktøyet, hvorved brukslevetiden forkortes vesentlig. Dessuten er energiforbruket ved påføringen av de for korrosjonsbeskyttelsen nødvendige sinktykkelser på 7,5 - 10 /um meget høyt. Allerede av denne grunn vil anvendelse av tynnforsinket blikk med en sinksjikttykkelse på ca. 2,5 jum være ønskelig. For opp-nåelse av den for korrosjonsbeskyttelsen nødvendige sjikt-tykkelse i området 7,5 - 10 yum i et elektrolytisk forsinkingsanlegg må belegningshastigheten sammenlignet med en tynnfor-sinking nedsettes ganske meget, nemlig til ca. 36 m/min. Hvis det kunne anvendes tynnforsinket blikk med et sinkbelegg på bare 2,5 um, så ville produksjonshastigheten kunne økes til 120 m/min. 7.5 - 10 days Increasing coating thickness of the zinc layer, however, brings with it problems with regard to formability. Admittedly, such electrolytically delayed tin can be formed, but the need for lubricant is relatively large. Despite these precautions, zinc will eventually be deposited on the press tool, thereby significantly shortening its service life. Furthermore, the energy consumption when applying the zinc thicknesses of 7.5 - 10 µm required for corrosion protection is very high. Already for this reason, the use of thin galvanized tin with a zinc layer thickness of approx. 2.5 jum be desirable. In order to achieve the layer thickness required for corrosion protection in the range of 7.5 - 10 µm in an electrolytic galvanizing plant, the coating speed must be reduced quite a lot compared to a thin galvanizing, namely to approx. 36 m/min. If thin galvanized sheet metal with a zinc coating of only 2.5 µm could be used, then the production speed could be increased to 120 m/min.
Oppfinnelsen tar derfor sikte på å skaffe en korrosjonsbeskyttelses-primer som tillater anvendelse av tynnforsinket stålblikk med en sinksjikttykkelse i området 2-4 jum, hvorved denne korrosjonsbeskyttelses-primer gir det tynnforsinkete blikk i det minste like god korrosjonsbeskyttelse som en sinksjikttykkelse på 7,5 - 10 jum, hvorved denne korrosjonsbeskyttelses-primer også letter eller forbedrer formbarheten sammenlignet med et tykkforsinket blikk. The invention therefore aims to provide a corrosion protection primer which allows the use of thin galvanized sheet steel with a zinc layer thickness in the range of 2-4 µm, whereby this corrosion protection primer gives the thin galvanized sheet at least as good corrosion protection as a zinc layer thickness of 7.5 - 10 jum, whereby this corrosion protection primer also facilitates or improves formability compared to a thick tinned tin.
Oppgaven løses i henhold til oppfinnelsen ved de trekk som er angitt i den karakteriserende del av krav 1. The task is solved according to the invention by the features specified in the characterizing part of claim 1.
Overraskende bevirker korrosjonsbeskyttelses-primeren ifølge oppfinnelsen, når den påføres med tørrfilmtykkelser på minst 4 /im på et tynnforsinket stålblikk med en sinksjikttykkelse på ca. 2,5 pm, en korrosjonsbeskyttelse som er ikke bare jevnbyrdig, men bedre enn den som ytes av et tykkforsinket blikk med en sinks j ikttykkelse på 7,5 jum. Surprisingly, the corrosion protection primer according to the invention, when applied with dry film thicknesses of at least 4 µm on a thin galvanized steel sheet with a zinc layer thickness of approx. 2.5 pm, a corrosion protection that is not only equal, but better than that provided by a thick galvanized sheet with a zinc thickness of 7.5 jum.
Dessuten kan et i henhold til oppfinnelsen belagt tynnforsinket blikk lettere formes (eksempelvis ved dyptrekking) enn et tykkforsinket blikk. En forurensning av formningsverk-tøyet og en herved betinget kortere brukslevetid unngås. In addition, a thin galvanized sheet coated according to the invention can be shaped more easily (for example by deep drawing) than a thick galvanized sheet. Contamination of the forming tool and a consequent shorter service life are avoided.
Korrosjonsbeskyttelses-primeren ifølge oppfinnelsen er formbar, eksempelvis ved sponløs formning, og sveisbar, slik at det med denne belagte stålblikk i tillegg til den tilstrek-kelige katodiske korrosjonsbeskyttelse er punktsveisbart og påny kan fosfateres og belegges elektroforetisk. Korrosjonsbeskyttelses-primeren ifølge oppfinnelsen tillater de i automobilindustrien vanlige tilknyttede arbeidsoperasjoner, så The corrosion protection primer according to the invention is formable, for example by chipless forming, and weldable, so that with this coated steel sheet, in addition to the sufficient cathodic corrosion protection, it is spot weldable and can be phosphated and electrophoretically coated again. The corrosion protection primer according to the invention allows the associated work operations common in the automotive industry, so
som avfetting, fosfatering, grunning med sprøyte- eller elektrodyppegrunninger på tilfredsstillende måte. Da oppfinnelsen ikke bare muliggjør bearbeidelse av meget store flater, men også i betydelig grad øker kapasiteten av de elektrolytiske forsinkingsanlegg, utgjør den et stort fremskritt, spesielt for stål- og automobilindustrien. Oppfinnelsen er imidlertid like meget anvendbar i skipsbygnings-, stålmøbel- og i emballasje-såvel som automobilindustrien. such as degreasing, phosphating, priming with spray or electrode dip primers in a satisfactory manner. As the invention not only enables the processing of very large surfaces, but also significantly increases the capacity of the electrolytic galvanizing plants, it constitutes a major advance, especially for the steel and automobile industries. However, the invention is just as applicable in the shipbuilding, steel furniture and packaging industries as well as the automobile industry.
De produkter som anvendes som bindemiddel i korrosjonsbeskyttelses-primeren ifølge oppfinnelsen, er kjent. Det dreier seg her om mettede polyesterharpikser og/eller epoksydharpikser og deres derivater, som f.eks. forkondensater og estere. The products used as binders in the corrosion protection primer according to the invention are known. These are saturated polyester resins and/or epoxy resins and their derivatives, such as e.g. precondensates and esters.
Foruten sink, aluminium "og/eller et glidemiddel så som grafitt eller molybdensulfid kan det eventuelt medanvendes andre korrosjonsbeskyttelsespigmenter, fortrinnsvis på kromat-, fosfat- eller boratbasis, som f.eks. sinkkaliumkromat og/eller sinkfosfat. Videre kan det i preparatet av korrosjonsbeskyttelses-primeren , som anvendes i'de vanlige organiske løs-ningsmidler, medanvendes kjente additiver som skal hindre sedimentering. Det dreier seg om i og for seg kjente anti-sedimenteringsmidler, f.eks. på basis av pyrogen kiselsyre, bentonitter og hydrert Ricinusolje. In addition to zinc, aluminium, and/or a lubricant such as graphite or molybdenum sulphide, other corrosion protection pigments can optionally be used, preferably on a chromate, phosphate or borate basis, such as zinc potassium chromate and/or zinc phosphate. Furthermore, in the preparation of corrosion protection -the primer, which is used in the usual organic solvents, is also used with known additives to prevent sedimentation. These are known anti-sedimentation agents in and of themselves, for example on the basis of fumed silicic acid, bentonites and hydrated castor oil.
Mengden av glidemiddel i korrosjonsbeskyttelses-primeren ifølge oppfinnelsen er avhengig av arten av det anvendte glidemiddel og utgjør ca. 1-5% beregnet på den tørre film. For meget glidemiddel forringer vedheftningen av de etterfølgende sjikt, og for lite medfører dårligere formbarhet. The amount of lubricant in the corrosion protection primer according to the invention depends on the nature of the lubricant used and amounts to approx. 1-5% calculated on the dry film. Too much lubricant impairs the adhesion of the subsequent layers, and too little leads to poorer formability.
Tørrfilm-sjikttykkelsen bør fortrinnsvis være minstThe dry film layer thickness should preferably be at least
4 Aim. Oppad er tykkelsen begrenset av sveisbarheten; i regelen er den øvre grense 10 yum. 4 Aim. Upwards, the thickness is limited by the weldability; as a rule, the upper limit is 10 yum.
Vektangivelsene er ved den glidedyktige og elektrisk ledende korrosjonsbeskyttelses-primer angitt på basis av det etter tørkingen gjenværende faste stoff. The weight specifications for the slippery and electrically conductive corrosion protection primer are given on the basis of the solid substance remaining after drying.
Oppfinnelsen belyses nærmere ved hjelp av de følgende eksempler, hvor det anvendes elektrolytisk med 2,5 / am forsinket stålblikk, som på kjent måte ble renset, avfettet og fosfatert eller kromatert, hvoretter det ble belagt med primeren ifølge oppfinnelsen under anvendelse av sprøyte-, dyppe-, påstryknings-, oversvømnings- eller Coil-Coiting-metoden, og herdet ved objekttemperaturer på 210 - 250°C. The invention is elucidated in more detail with the help of the following examples, where it is used electrolytically with 2.5 / am delayed steel tin, which was cleaned, degreased and phosphated or chromated in a known manner, after which it was coated with the primer according to the invention using spray, the dipping, brushing, flooding or Coil-Coiting method, and cured at object temperatures of 210 - 250°C.
I eksemplene er den vektbaserte sammensetning av den løsningsmiddelholdige korrosjonsbeskyttelses-primer angitt, d.v.s. den oppløste form som er påkrevet for anvendelsen. In the examples, the weight-based composition of the solvent-based corrosion protection primer is indicated, i.e. the dissolved form required for the application.
EKSEMPEL 1EXAMPLE 1
Det anvendte forsinkete stålblikk har en tykkelse påThe delayed steel sheet used has a thickness of
0,75 mm og en bredde på 1,85 m og er på konvensjonell måte avfettet, fosfatert eller kromatert. 0.75 mm and a width of 1.85 m and is conventionally degreased, phosphated or chromated.
For den videre behandling av overflaten anvendes de nedenfor nærmere beskrevne oppløsninger. De angitte deler er overalt vektdeler. For the further treatment of the surface, the solutions described in more detail below are used. The specified parts are everywhere parts by weight.
Det ifølge eksempel 1 belagte blikk sammenlignes med et elektrolytisk tykkforsinket blikk med en sinksjikttykkelse på 7,5 - 8fim i en korrosjonstest (SS DIN 50021), hvorved korro-sjonsbelastningen etter 360 timer ble målt. The sheet metal coated according to example 1 is compared with an electrolytically thick galvanized sheet metal with a zinc layer thickness of 7.5 - 8 fim in a corrosion test (SS DIN 50021), whereby the corrosion load after 360 hours was measured.
Mengden og størrelsen av blærene ble bestemt i henhold til DIN 53209 og rustgraden Ri i henhold til DIN 53 219. The amount and size of the blisters was determined according to DIN 53209 and the rust degree Ri according to DIN 53 219.
Claims (7)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19843412234 DE3412234A1 (en) | 1984-04-02 | 1984-04-02 | SLIDABLE AND WELDABLE CORROSION PROTECTION PRIMER FOR ELECTROLYTICALLY THIN GALVANIZED, DEFORMABLE, PHOSPHATED OR CHROMATIZED STEEL SHEET |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO851339L true NO851339L (en) | 1985-10-03 |
Family
ID=6232364
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO851339A NO851339L (en) | 1984-04-02 | 1985-04-01 | CORROSION PROTECTION PRIMER FOR PHOSPHATED OR CHROMATED, ELECTROLYTIC THICKLY Galvanized, formable steel sheet |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0157392A3 (en) |
| DE (1) | DE3412234A1 (en) |
| DK (1) | DK148085A (en) |
| FI (1) | FI851320L (en) |
| NO (1) | NO851339L (en) |
| PT (1) | PT80206B (en) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3828888A1 (en) * | 1988-08-25 | 1990-03-08 | Ford Werke Ag | MULTIPLE COATED STEEL SHEET FOR THE EXTERIOR OF MOTOR VEHICLE BODY PARTS |
| FR2648822B1 (en) * | 1989-06-27 | 1994-09-30 | Norsolor Sa | METHOD FOR GRAFTING AMORPHOUS SILICA ON A FERROUS SUBSTRATE |
| DK0560785T3 (en) * | 1990-11-27 | 1996-08-12 | Sika Chemie Gmbh | Two-component epoxy resin-zinc dust primer for steel surfaces |
| CN1159851A (en) * | 1994-10-04 | 1997-09-17 | 新日本制铁株式会社 | Steel pipe joint having high galling resistance and surface treatment method thereof |
| US5677367A (en) * | 1995-08-15 | 1997-10-14 | Savin; Ronald R. | Graphite-containing compositions |
| DE19748764A1 (en) | 1997-11-05 | 1999-05-06 | Henkel Kgaa | Conductive, organic coatings |
| WO2000011238A2 (en) * | 1998-08-18 | 2000-03-02 | Walter Hillebrand Gmbh & Co. | Coating system |
| DE19853772C1 (en) * | 1998-11-21 | 2000-07-06 | Daimler Chrysler Ag | Process for welding steel components provided with corrosion protection layers |
| US6312812B1 (en) | 1998-12-01 | 2001-11-06 | Ppg Industries Ohio, Inc. | Coated metal substrates and methods for preparing and inhibiting corrosion of the same |
| US6440580B1 (en) | 1998-12-01 | 2002-08-27 | Ppg Industries Ohio, Inc. | Weldable, coated metal substrates and methods for preparing and inhibiting corrosion of the same |
| DE10022075A1 (en) | 2000-05-06 | 2001-11-08 | Henkel Kgaa | Conductive and weldable corrosion protection composition for metal surfaces in coil coating comprises a conductive pigment of zinc, aluminum, graphite, molybdenum sulfide, carbon or iron phosphide. |
| ES2254652T3 (en) | 2001-03-05 | 2006-06-16 | Georg Gros | WATER BASED COATING MIX, PROCEDURE FOR APPLYING A PROTECTION LAYER AGAINST CORROSION WITH THIS MIXTURE, COATED BASE OF THIS MODE AND ITS USE. |
| DE10114232C2 (en) * | 2001-03-22 | 2003-03-20 | Dilo Trading Ag Zug | Process for producing and applying an electrically conductive protective coating |
| CA2484314A1 (en) | 2002-04-20 | 2003-10-30 | Chemetall Gmbh | Mixture for applying a non-corrosive, polymer coating which can be shaped in a low-abrasive manner, and method for producing the same |
| US20040086718A1 (en) | 2002-11-06 | 2004-05-06 | Pawlik Michael J | Corrosion and alkali-resistant compositions and methods for using the same |
| US7147897B2 (en) | 2002-11-06 | 2006-12-12 | Ppg Industries Ohio, Inc. | Weldable compositions comprising a conductive pigment and silicon and methods for using the same |
| US7345101B2 (en) | 2002-11-06 | 2008-03-18 | Ppg Industries Ohio, Inc. | Aqueous composition of reaction product of epoxy and phosphorus materials with curing agent |
| US7399397B2 (en) | 2004-05-10 | 2008-07-15 | E.I. Du Pont De Nemours And Company | Process for the production of coated substrates |
| DE102004028764A1 (en) * | 2004-06-16 | 2006-01-12 | Henkel Kgaa | Radiation curable electrically conductive coating mixture |
| DE102004035142A1 (en) | 2004-07-13 | 2006-02-02 | Varta Microbattery Gmbh | Galvanic element |
| DE102006035660B4 (en) * | 2006-07-31 | 2009-08-20 | Voestalpine Stahl Gmbh | Corrosion protection layer with improved properties and process for its preparation |
| DE102006062500A1 (en) | 2006-12-28 | 2008-07-03 | Henkel Kgaa | Anticorrosion composition for coating metal surfaces comprises a crosslinkable polyester resin binder and aluminum flakes |
| DE102007001654A1 (en) | 2007-01-04 | 2008-07-10 | Henkel Kgaa | Conductive, organic coatings with optimized polymer system |
| DE102007001653A1 (en) | 2007-01-04 | 2008-07-10 | Henkel Kgaa | Conductive, organic coatings with low layer thickness and good formability |
| FR3053352A1 (en) | 2016-07-04 | 2018-01-05 | Airbus Safran Launchers Sas | ANTI-CORROSION PROTECTIVE COMPOSITION |
| WO2019126527A1 (en) * | 2017-12-20 | 2019-06-27 | Ppg Industries Ohio, Inc. | Coating compositions having improved corrosion resistance |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL290287A (en) * | 1962-03-15 | |||
| US3446770A (en) * | 1966-07-13 | 1969-05-27 | Hercules Inc | Zinc-rich coatings containing conductive carbon black |
| US4079163A (en) * | 1974-11-29 | 1978-03-14 | Nippon Steel Corporation | Weldable coated steel sheet |
| JPS5530987A (en) * | 1978-08-29 | 1980-03-05 | Sumitomo Metal Ind | Corrosion preventive painted steel |
| DE3232755C2 (en) * | 1982-09-03 | 1984-06-28 | Inmont GmbH, 5300 Bonn | Zinc dust primer system for deformable phosphated or chromated sheet steel |
| US4701382A (en) * | 1984-03-22 | 1987-10-20 | Akzo N.V. | Liquid coating composition containing lubricants |
-
1984
- 1984-04-02 DE DE19843412234 patent/DE3412234A1/en active Granted
-
1985
- 1985-03-29 EP EP85103838A patent/EP0157392A3/en not_active Withdrawn
- 1985-04-01 PT PT8020685A patent/PT80206B/en not_active IP Right Cessation
- 1985-04-01 NO NO851339A patent/NO851339L/en unknown
- 1985-04-01 DK DK148085A patent/DK148085A/en not_active IP Right Cessation
- 1985-04-02 FI FI851320A patent/FI851320L/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| DK148085D0 (en) | 1985-04-01 |
| EP0157392A3 (en) | 1987-06-24 |
| FI851320L (en) | 1985-10-03 |
| DE3412234C2 (en) | 1988-10-20 |
| DE3412234A1 (en) | 1985-10-10 |
| EP0157392A2 (en) | 1985-10-09 |
| PT80206B (en) | 1987-02-16 |
| PT80206A (en) | 1985-05-01 |
| DK148085A (en) | 1985-10-03 |
| FI851320A0 (en) | 1985-04-02 |
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