NO760076L - - Google Patents
Info
- Publication number
- NO760076L NO760076L NO760076A NO760076A NO760076L NO 760076 L NO760076 L NO 760076L NO 760076 A NO760076 A NO 760076A NO 760076 A NO760076 A NO 760076A NO 760076 L NO760076 L NO 760076L
- Authority
- NO
- Norway
- Prior art keywords
- polyethylene
- molding compound
- compound according
- weight
- polyethylene molding
- Prior art date
Links
- -1 Polyethylene Polymers 0.000 claims description 30
- 239000004698 Polyethylene Substances 0.000 claims description 29
- 229920000573 polyethylene Polymers 0.000 claims description 29
- 150000001875 compounds Chemical class 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 17
- 238000000465 moulding Methods 0.000 claims description 17
- 239000006229 carbon black Substances 0.000 claims description 15
- 239000004071 soot Substances 0.000 claims description 12
- 238000010521 absorption reaction Methods 0.000 claims description 6
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 5
- 239000000155 melt Substances 0.000 claims description 4
- 239000003381 stabilizer Substances 0.000 claims description 4
- 239000000314 lubricant Substances 0.000 claims description 3
- 150000004982 aromatic amines Chemical class 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 150000002314 glycerols Chemical class 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 150000004989 p-phenylenediamines Chemical class 0.000 claims description 2
- 239000012778 molding material Substances 0.000 claims 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims 1
- CKQVRZJOMJRTOY-UHFFFAOYSA-N octadecanoic acid;propane-1,2,3-triol Chemical compound OCC(O)CO.CCCCCCCCCCCCCCCCCC(O)=O CKQVRZJOMJRTOY-UHFFFAOYSA-N 0.000 claims 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000007792 addition Methods 0.000 description 3
- VETPHHXZEJAYOB-UHFFFAOYSA-N 1-n,4-n-dinaphthalen-2-ylbenzene-1,4-diamine Chemical compound C1=CC=CC2=CC(NC=3C=CC(NC=4C=C5C=CC=CC5=CC=4)=CC=3)=CC=C21 VETPHHXZEJAYOB-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- VRKQEIXDEZVPSY-UHFFFAOYSA-N 4-n-phenyl-4-n-propan-2-ylbenzene-1,4-diamine Chemical compound C=1C=C(N)C=CC=1N(C(C)C)C1=CC=CC=C1 VRKQEIXDEZVPSY-UHFFFAOYSA-N 0.000 description 1
- 101100387923 Caenorhabditis elegans dos-1 gene Proteins 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 description 1
- 239000011231 conductive filler Substances 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J7/00—Apparatus for generating gases
- B01J7/02—Apparatus for generating gases by wet methods
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63C—LAUNCHING, HAULING-OUT, OR DRY-DOCKING OF VESSELS; LIFE-SAVING IN WATER; EQUIPMENT FOR DWELLING OR WORKING UNDER WATER; MEANS FOR SALVAGING OR SEARCHING FOR UNDERWATER OBJECTS
- B63C9/00—Life-saving in water
- B63C9/08—Life-buoys, e.g. rings; Life-belts, jackets, suits, or the like
- B63C9/18—Inflatable equipment characterised by the gas-generating or inflation device
Landscapes
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Ocean & Marine Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
- Toys (AREA)
- Catching Or Destruction (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
- Saccharide Compounds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Telephone Function (AREA)
- Primary Cells (AREA)
- Hybrid Cells (AREA)
Description
Polyetylen-formmasse til ekstrudering avPolyethylene molding compound for extrusion of
rør og plater med liten overflatemotstand.pipes and plates with low surface resistance.
Det er kjent at i eksplosjonstruede rom bør bare anvendes bygmngsst of f. er med en overf latemotstand under 10 Q• ohm It is known that in potentially explosive atmospheres only building materials with a surface resistance of less than 10 Q• ohms should be used
for med sikkerhet å unngå en statisk oppladning og gnissdannelse. Av denne grunn kan kunststoffer ofte ikke anvendes her, enskjønt de på grunn av deres øvrige egenskaper ville være utmerket egnet. in order to safely avoid a static charge and the formation of friction. For this reason, plastics often cannot be used here, although they would be excellently suited due to their other properties.
Det er riktignok kjent tallrike fremgangsmåter til antistatisk appretering av kunststoffer en senkning av overflatemotstanden under 10 9 ohm, lar seg imidlertid over lengere tid ikke oppnå med sikkerhet. Således kan det på overflaten påføres eller inkorporeres overflateaktive forbindelser eller overflaten kan endres, kjemisk, f.eks. sulfoneres (sammenlign DOS 1'.953.371). Alle disse fremgangsmåter har den ulempe at virkningen avhengig av luftfuktighet og slitasje helt eller forbigående går tapt. It is true that numerous methods are known for antistatic finishing of plastics, a lowering of the surface resistance below 10 9 ohms, however, cannot be achieved with certainty over a longer period of time. Thus, surface-active compounds can be applied or incorporated on the surface or the surface can be changed, chemically, e.g. sulfonated (compare DOS 1',953,371). All these methods have the disadvantage that, depending on humidity and wear, the effect is completely or temporarily lost.
Det er også kjent å nedsette overflatemotstandenIt is also known to reduce the surface resistance
av kunststoffer ved tilsetning av sot. For å nå en verdi under 10 9 ■ ohm er det i• mi•dlertid ved handelsvanlig ledende sot, som f.eks. "Corax L", fra Degussa AG nødvendig med mengder på ca. of plastics by adding soot. In order to reach a value below 10 9 ■ ohms, in the meantime, with commercially available conductive soot, such as e.g. "Corax L", from Degussa AG required quantities of approx.
20 vekt%.20% by weight.
Så høye sotmengder nedsetter imidlertid kunststoff-enes seighet, fremfor alt slagfastheten så betraktelig at de mekaniske egenskaper ikke mer er tilstrekkelig for de fleste an-vendelser. Such high amounts, however, reduce the plastic's toughness, above all the impact resistance, so considerably that the mechanical properties are no longer sufficient for most applications.
Det er nå funnet at man ved anvendelse av en spesi-ell sot allerede med meget mindre sottilsetning oppnår den ønskede nedsettelse av overflatemotstanden under 10 q ohm, således at man får formmasser som samtidig har en lav overflatemotstand og gode mekaniske egenskaper og egner seg fremragende til ekstrudering av rør og plater, som man også kan anvende der hvor det består'eksplosjonsfare, f.eks. i bergverk. It has now been found that by using a special carbon black already with very little carbon black addition, the desired reduction of the surface resistance below 10 q ohms is achieved, so that molding compounds are obtained which at the same time have a low surface resistance and good mechanical properties and are excellently suited for extrusion of pipes and plates, which can also be used where there is a risk of explosion, e.g. in mining.
Oppfinnelsens gjenstand er derfor en polyetylen-formmasse til ekstrudering av rør og plater med liten overflate motstand og bestående av 92,5 - 85, fortrinnsvis 92 - 88 vekt% polyetylen og 7,5 - 15, fortrinnsvis 8-12 vekt% sot, hver gang referert til polyetylen-sot-blandingen, idet massen erkarakterisert vedat soten har en BET-overflate på 300-150.0, fortrinnsvis 600-1100 m /g, en oljeabsorpsjon på 2,5 - 5,5»fortrinnsvis 3,0 - 4,0 .ml/g, , et innhold av flyktige bestanddeler på 0,1 - 6,0, fortrinnsvis 0,5~4 vekt%, en pH-verdi på 7 - 10, . fortrinnsvis 8 - 9,5Pg et askeinnhold på 0,5 - 5,0, fortrinnsvis 0,5 - 1,0 vekt$ samt vanlige tilsetninger som f.eks..stabilisatorer, forarbeidelseshjelpemidler og glidemidler. En slik sot oppstår som biprodukt ved kjente for-gassingsfremgangsmåter til fremstilling av karbonoksyd og hydrogenholdige gassblandinger av hydrokarboner, som det f.eks. er omtalt i "Advances in Petroleum Chemistry and Refining", volum 10, kapittel 4, side 123 - 189 (Interscience Publishers, New York, 1965). Denne sot ble riktignok allerede anvendt sam- men med ikke ledende fyllstoffer til fremstilling av elektrisk ledende vulkanisater, (DOS 2.047.333), derved henvises imidlertid uttrykkelig til at ved anvendelse av denne sot alene opptrer mange ulemper da forarbeidbarheten er vanskelig og de mekaniske egenskaper dårlige. Av disse angivelser kunne det ikke sluttes at polyetylenblandinger med denne sot uten ytterligere fyllstoffer er helt spesielt egnet til ekstrudering av rør og plater med lav overflatemotstand og gode mekaniske egenskaper. Som polyetylen for blandingen ifølge oppfinnelsen egner det seg spesielt et lineært polyetylen med en tetthet på 0,94 - 0,96 g/cm-5 og en smelteindeks MF I 190/5 ifølge DIN 53 735 på 0,2 - 2,0, fortrinnsvis 0,3 - 1,6 g/10 minutter. Egnet er også blandingspolymerisater av etylen med inntil 8 vekt% propylen og/eller buten-(l). The object of the invention is therefore a polyethylene molding compound for extruding pipes and plates with low surface resistance and consisting of 92.5 - 85, preferably 92 - 88% by weight polyethylene and 7.5 - 15, preferably 8-12% by weight carbon black, each once referred to the polyethylene-carbon black mixture, the mass being characterized in that the carbon black has a BET surface area of 300-150.0, preferably 600-1100 m /g, an oil absorption of 2.5 - 5.5", preferably 3.0 - 4, 0.ml/g, , a content of volatile components of 0.1 - 6.0, preferably 0.5~4% by weight, a pH value of 7 - 10, . preferably 8 - 9.5 Pg an ash content of 0.5 - 5.0, preferably 0.5 - 1.0 by weight as well as usual additives such as e.g. stabilizers, processing aids and lubricants. Such soot occurs as a by-product in known gasification processes for the production of carbon monoxide and hydrogen-containing gas mixtures of hydrocarbons, such as e.g. is discussed in "Advances in Petroleum Chemistry and Refining", Volume 10, Chapter 4, Pages 123-189 (Interscience Publishers, New York, 1965). This soot was, of course, already used together but with non-conductive fillers for the production of electrically conductive vulcanizates, (DOS 2,047,333), thereby explicitly referring to the fact that when this carbon black is used alone, many disadvantages arise as the workability is difficult and the mechanical properties are poor. From these statements, it could not be concluded that polyethylene mixtures with this carbon black without additional fillers are particularly suitable for extruding pipes and sheets with low surface resistance and good mechanical properties. As polyethylene for the mixture according to the invention, a linear polyethylene with a density of 0.94 - 0.96 g/cm-5 and a melt index MF I 190/5 according to DIN 53 735 of 0.2 - 2.0 is particularly suitable. preferably 0.3 - 1.6 g/10 minutes. Mixed polymers of ethylene with up to 8% by weight of propylene and/or butene-(1) are also suitable.
Som stabilisatorer egner.det seg fremfor alt aromatiske aminer, f.eks. oktylert difenylamin eller derivater av p-fenylendiamin, som N-fenyl-N',-isopropyl-p-f enylendiamin eller N,N'-di-2-naftyl-p-fenylendiamin i mengder på 0,05 - 2,0, fortrinnsvis 0,1 - 1,0 vekt/S, referert til blandingen. Suitable stabilizers are above all aromatic amines, e.g. octylated diphenylamine or derivatives of p-phenylenediamine, such as N-phenyl-N',-isopropyl-p-phenylenediamine or N,N'-di-2-naphthyl-p-phenylenediamine in amounts of 0.05 - 2.0, preferably 0 .1 - 1.0 wt/S, referred to the mixture.
Som glidemiddel resp. forarbeidelseshjelpemiddel anvendes fortrinnsvis metallstearater, f.eks. kalsiumstearat eller sinkstearat eller glycerolestere av fettsyrer med 12 til 24 C-atomer,- f.eks. glycerolstearat i mengder på 0,1 - 1,0 vekt%, referert til blandingen. As a lubricant or processing aids are preferably used metal stearates, e.g. calcium stearate or zinc stearate or glycerol esters of fatty acids with 12 to 24 C atoms, - e.g. glycerol stearate in amounts of 0.1 - 1.0% by weight, referred to the mixture.
Ved tilsetning av 7,5 8 vekt$ av denne sot til polyetylen senkes overflatemotstanden i formmassen under 10<9>ohm. Høyere tilsetninger nedsetter overflatemotstanden stérk-ere og påvirker imidlertid også de mekaniske egenskaper sterk-ere, således at tilsetningsmengder over 15 vekt$ ikke medfører fordeler. De beste resultater fåes med 8-10 vekt% sot, referert til blandingen. Ved disse blandinger er overflatemotstanden senket til den ønskede verdi, mens de mekaniske egenskaper omtrent.ikke påvirkes. By adding 7.5 8% by weight of this carbon black to polyethylene, the surface resistance in the molding compound is lowered below 10<9>ohm. Higher additions reduce the surface resistance more strongly and, however, also affect the mechanical properties more strongly, so that addition quantities above 15% by weight do not bring benefits. The best results are obtained with 8-10% by weight of soot, referred to the mixture. With these mixtures, the surface resistance is lowered to the desired value, while the mechanical properties are approximately not affected.
Pormmassene kan fremstilles etter vanlige fremgangsmåter, f.eks. ved forblanding av pulvere i langsomt gående bland-ere med etterfølgende homogenisering og granulering på dobbelt-snekkeekstrudere. Det har vist seg .fordelaktig i første rekke å forblande polyetylenet med stabilisatorene i en hurtiggående blander og deretter å tilsette soten i en langsomtgående blander. The porm masses can be produced according to usual methods, e.g. by premixing powders in slow-moving mixers with subsequent homogenization and granulation on twin-screw extruders. It has proven advantageous to firstly pre-mix the polyethylene with the stabilizers in a high-speed mixer and then to add the soot in a slow-speed mixer.
Da sot under innvirkning av oksygen og varme virker nettdannende på polyetylenet, lar de^ mekaniske egenskaper av den ferdige blanding seg forbedre ved innblanding og granulering under nitrogen. As soot under the influence of oxygen and heat has a network-forming effect on the polyethylene, the mechanical properties of the finished mixture can be improved by mixing and granulating under nitrogen.
Rør fremstillet av formmassene ifølge oppfinnelsen egner seg fremfor alt som transportrør for brennbare væsker eller pulvere, som på grunn av friksjon kan frembringe statisk oppladning. -Av platene kan det f.eks. fremstilles sjakter, transportkar eller luftsjakter for bergverk. Pipes made from the molding compounds according to the invention are above all suitable as transport pipes for flammable liquids or powders, which can cause static charging due to friction. -Of the plates, it can e.g. shafts, transport vessels or air shafts for quarries are produced.
Eksempel 1.Example 1.
Polyetylen av en tetthet på 0,946 g/cm^og en smelteindeks MFI 190/5, målt ifølge DIN 53 735 på 0,3 g/10 minutter i pulverform ble forblandet i en hurtiggående blander med 0,4 vekt$ N-fenyl-N'-isopropyl-p-fenylendiamin og 0,2 vekt$ glycerolstearat (blanding av 45$ mono-, 40$ di- og 15$ tri-stearat). Deretter ble det i en langsomtgående blander■tilsatt de i tabell 1 angitte mengder av en sot, som hadde en BET-overflate bestémt .ifølge Brunauer, Emmet og Teller, J. Amer. chem. Soc. 60, (1938), side 309, på 950 m<2>/g, en oljeabsorbsjon på Polyethylene of a density of 0.946 g/cm^ and a melt index MFI 190/5, measured according to DIN 53 735 of 0.3 g/10 minutes in powder form was premixed in a high-speed mixer with 0.4 wt% of N-phenyl-N -isopropyl-p-phenylenediamine and 0.2% by weight of glycerol stearate (mixture of 45% mono-, 40% di- and 15% tri-stearate). Then, in a slow-moving mixer, the quantities of a carbon black indicated in Table 1 were added, which had a BET surface area determined according to Brunauer, Emmet and Teller, J. Amer. chem. Soc. 60, (1938), page 309, of 950 m<2>/g, an oil absorption of
3,2 ml/g, et innhold av flyktige bestanddeler på 1,0 vekt$, en pH-verdi på 8 og et askeinnhold på 0,7 vekt$. Deretter ble blandingen homogenisert på en. dobbeltsnekkeekstruder ved en temperatur på 180 til 250°C og granulert.' Av granulatet ble det presset 1 resp. 4 mm tykke plater og derav fremstilt prøvelegeme. Til 3.2 ml/g, a volatile matter content of 1.0 wt%, a pH value of 8 and an ash content of 0.7 wt%. The mixture was then homogenized on a twin screw extruder at a temperature of 180 to 250°C and granulated.' From the granulate, 1 resp. 4 mm thick plates and the specimen produced from them. To
sammenligning ble det fremstillet tilsvarende blandinger med en handelsvanligjhøyledende sot "Corax" L, Degussa.AG med en BET-overflate på 133 m /g, en oljeabsorpsjon på 5,1 ml/g, et innhold av flyktige bestanddeler på 1 vekt% 3 et askeinnhold på 0,07 vekt% og en pH-verdi på 8. De oppnådde prøveresultater fremgår av tabell 1. for comparison, similar mixtures were prepared with a commercially available highly conductive carbon black "Corax" L, Degussa.AG with a BET surface area of 133 m /g, an oil absorption of 5.1 ml/g, a content of volatile components of 1% by weight 3 et ash content of 0.07% by weight and a pH value of 8. The test results obtained appear in table 1.
Av blandingen ifølge oppfinnelsen med 8, 10 resp. 14 vekt% av den spesielle sot lot det seg utmerket ekstrudere rør og plater med tilsvarende gode mekaniske egenskaper og den ønskede.lave overflatemotstand. Of the mixture according to the invention with 8, 10 resp. 14% by weight of the special soot, it was possible to extrude tubes and plates with correspondingly good mechanical properties and the desired low surface resistance.
Overflatemotstanden ble målt ifølge DIN 53 482 med elektrodeanordning A ved en målespenning på 1000 resp. 5 volt. Ved en motstand under 10 7 ohm maotte spenningen ned-settes for å hindre gjennomslag. The surface resistance was measured according to DIN 53 482 with electrode device A at a measuring voltage of 1000 resp. 5 volts. With a resistance below 10 7 ohms, the voltage must be reduced to prevent breakdown.
E ksempel 2.Example 2.
92 deler av et polyetylen med en tetthet på92 parts of a polyethylene with a density of
0,947 g/cm<5>og en smelteindeks MFI 190/5 på 0,5 g/10 min. i pulverform ble en langsomtgående blander blandet med hver gang 8 deler av en sot, som hadde en BET-overflate på 800 m /g, en oljeabsorbsjon på 3,2 ml/g, et innhold av flyktige bestanddeler på 3,5 vekt$, en pH-verdi på 8 og et askeinnhold på 0,7 vekt% samt 0,4 vekt% N,N'-di-2-naftyl-p-fenylendiamin og de i tabell 2 angitte mengder glycerolstearat og granulert som angitt i eksempel 1 og forarbeidet til prøvelegemer. Før den vanlige granulering ble hver gang halvparten av blandingen adskilt, granulert under nitrogen og likeledes forarbeidet, til prøve-legemet. De oppnådde resultater fremgår av tabell 2. 0.947 g/cm<5>and a melt index MFI 190/5 of 0.5 g/10 min. in powder form, a slow-moving mixer was mixed with each time 8 parts of a carbon black, which had a BET surface area of 800 m /g, an oil absorption of 3.2 ml/g, a volatile matter content of 3.5 wt$, a pH value of 8 and an ash content of 0.7% by weight as well as 0.4% by weight of N,N'-di-2-naphthyl-p-phenylenediamine and the amounts of glycerol stearate indicated in Table 2 and granulated as indicated in Example 1 and prepared for test specimens. Before the usual granulation, each time half of the mixture was separated, granulated under nitrogen and similarly processed, into the test body. The results obtained appear in table 2.
Claims (13)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1279/75A GB1505842A (en) | 1975-01-13 | 1975-01-13 | Gas generating systems |
GB128075 | 1975-01-13 | ||
GB128475 | 1975-01-13 | ||
GB128575 | 1975-01-13 |
Publications (3)
Publication Number | Publication Date |
---|---|
NO760076L true NO760076L (en) | 1976-07-14 |
NO143205B NO143205B (en) | 1980-09-22 |
NO143205C NO143205C (en) | 1981-01-02 |
Family
ID=27447147
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO760076A NO143205C (en) | 1975-01-13 | 1976-01-12 | WATER ACTIVATED BALLOON, LIFTING EQUIPMENT ETC. |
Country Status (11)
Country | Link |
---|---|
JP (1) | JPS5195385A (en) |
AU (1) | AU499141B2 (en) |
CA (1) | CA1085141A (en) |
DE (1) | DE2601029A1 (en) |
DK (1) | DK11076A (en) |
ES (1) | ES444246A1 (en) |
FR (1) | FR2297077A1 (en) |
GB (1) | GB1505842A (en) |
NL (1) | NL7600322A (en) |
NO (1) | NO143205C (en) |
SE (1) | SE7600181L (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58174086A (en) * | 1982-04-02 | 1983-10-13 | Yoshifumi Sakamoto | Gas self-generating type floating device |
JP2538001B2 (en) * | 1987-10-15 | 1996-09-25 | ザ・コカコーラ・カンパニー | Gas supply device |
US5398850A (en) * | 1993-08-06 | 1995-03-21 | River Medical, Inc. | Gas delivery apparatus for infusion |
DE19803552C2 (en) * | 1998-01-30 | 2000-05-25 | Eberhard Wistuba | Means for generating gas pressure |
FR2969934B1 (en) | 2010-12-30 | 2013-01-25 | Snpe Materiaux Energetiques | AUTORAGGED PRODUCTION, IN IMMERED CONDITION, OF A GAS GENERATED BY CHEMICAL REACTION BETWEEN A LIQUID AND A SOLID; ASSOCIATED DEVICE |
JP6219171B2 (en) * | 2011-02-25 | 2017-10-25 | アルキメデス プロプライエタリー リミテッドArchimedes Pty Ltd. | Buoyancy system |
CN115337868A (en) * | 2021-05-14 | 2022-11-15 | 广东小天才科技有限公司 | Gas generating device |
WO2023131942A1 (en) * | 2022-01-05 | 2023-07-13 | Neomare Ltd. | Wearable inflatable flotation device |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH199914A (en) * | 1937-11-06 | 1938-09-15 | Ind Patentwerte Kontroll A G | Rescue apparatus. |
US3355751A (en) * | 1965-12-27 | 1967-12-05 | Bryan M Mcgroarty | Automatically inflatable objects |
US3461835A (en) * | 1966-11-22 | 1969-08-19 | Lionel Hellier Ltd | Water-activated balloon inflating device |
US3733180A (en) * | 1971-01-08 | 1973-05-15 | Boeing Co | Solid state cool gas generator |
-
1975
- 1975-01-13 GB GB1279/75A patent/GB1505842A/en not_active Expired
-
1976
- 1976-01-06 CA CA243,035A patent/CA1085141A/en not_active Expired
- 1976-01-09 SE SE7600181A patent/SE7600181L/en not_active Application Discontinuation
- 1976-01-09 AU AU10168/76A patent/AU499141B2/en not_active Expired
- 1976-01-12 JP JP51003129A patent/JPS5195385A/ja active Pending
- 1976-01-12 FR FR7600646A patent/FR2297077A1/en active Granted
- 1976-01-12 NO NO760076A patent/NO143205C/en unknown
- 1976-01-13 ES ES444246A patent/ES444246A1/en not_active Expired
- 1976-01-13 NL NL7600322A patent/NL7600322A/en not_active Application Discontinuation
- 1976-01-13 DK DK11076*#A patent/DK11076A/en not_active Application Discontinuation
- 1976-01-13 DE DE19762601029 patent/DE2601029A1/en not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
AU1016876A (en) | 1977-07-14 |
SE7600181L (en) | 1976-07-14 |
NO143205C (en) | 1981-01-02 |
ES444246A1 (en) | 1977-10-01 |
JPS5195385A (en) | 1976-08-20 |
NO143205B (en) | 1980-09-22 |
DK11076A (en) | 1976-07-14 |
NL7600322A (en) | 1976-07-15 |
AU499141B2 (en) | 1979-04-05 |
FR2297077B1 (en) | 1981-03-27 |
FR2297077A1 (en) | 1976-08-06 |
DE2601029A1 (en) | 1976-07-15 |
CA1085141A (en) | 1980-09-09 |
GB1505842A (en) | 1978-03-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105038026B (en) | A kind of fire-resistant smoke-inhibiting PVC wiring duct and preparation method thereof | |
US5214091A (en) | Thermoplastic resin composition | |
George et al. | Studies on NBR/PVC blends | |
US4097656A (en) | Process for imparting antistatic properties to plastics | |
US3062778A (en) | High impact strength vinyl chloride resin compositions blended with ethylene-alkyl acrylate copolymers | |
CN105086283B (en) | A kind of high flowing flame-proof PVC/ABS alloy material and preparation method thereof | |
NO760076L (en) | ||
US3962164A (en) | Self-extinguishing acrylonitrile-butadiene-styrene moulding composition | |
CA2264003A1 (en) | Heat stabilized, flame retardant thermoplastic polymer compositions | |
CA1102989A (en) | Method for preparing fire retardant molding compositions | |
CN110982213A (en) | High-oxygen-index low-smoke flame-retardant ABS material and preparation method thereof | |
CA1056534A (en) | Flexible polyvinyl chloride plastics having improved flame retardancy and reduced smoke generating properties | |
US2480296A (en) | Ethylene polymer compositions | |
RU2072377C1 (en) | Polymeric material | |
CN112662037B (en) | Special high-performance high-flame-retardant polyethylene material for rotational molding and preparation method and application thereof | |
CN108276689A (en) | A kind of flame retardant plastics and preparation method thereof that performance is good | |
EP0761755B1 (en) | Moldable intumescent thermoplastic compositions | |
US3720734A (en) | Pvc compositions containing carboxylic acid anhydride copolymers | |
US3801526A (en) | Plasticized vinyl chloride polymer blends having improved fire retardancy | |
US3822234A (en) | Vinyl chloride polymers containing alkali metal zinc ferrocyanides | |
Trung et al. | Preparation and study on the properties of acrylonitrile butadiene styrene/polyphenylene oxide polymer blend | |
WO2019030756A1 (en) | Stabilization of flame-retarded polymers | |
US3089860A (en) | Stabilized polyolefin compositions | |
US2571928A (en) | Resinous compositions comprising a styrene isoolefin copolymer and a vinyl polymer | |
CN109161091B (en) | High-flame-retardancy EVA (ethylene-vinyl acetate) foam material and preparation method thereof |