NO329239B1 - Fremgangsmate for selektiv fremstilling av DIB fra en i-butenholdig C<N>4</N>-strom - Google Patents
Fremgangsmate for selektiv fremstilling av DIB fra en i-butenholdig C<N>4</N>-strom Download PDFInfo
- Publication number
- NO329239B1 NO329239B1 NO20014175A NO20014175A NO329239B1 NO 329239 B1 NO329239 B1 NO 329239B1 NO 20014175 A NO20014175 A NO 20014175A NO 20014175 A NO20014175 A NO 20014175A NO 329239 B1 NO329239 B1 NO 329239B1
- Authority
- NO
- Norway
- Prior art keywords
- column
- hydroisomerization
- butene
- carried out
- bar
- Prior art date
Links
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 238000000034 method Methods 0.000 title claims description 40
- IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical compound CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000003054 catalyst Substances 0.000 claims abstract description 30
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 claims abstract description 22
- FXNDIJDIPNCZQJ-UHFFFAOYSA-N 2,4,4-trimethylpent-1-ene Chemical group CC(=C)CC(C)(C)C FXNDIJDIPNCZQJ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000006243 chemical reaction Methods 0.000 claims abstract description 18
- 238000005194 fractionation Methods 0.000 claims abstract description 17
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims abstract description 13
- 230000002378 acidificating effect Effects 0.000 claims abstract description 8
- 238000004519 manufacturing process Methods 0.000 claims abstract description 4
- 238000004821 distillation Methods 0.000 claims description 19
- 229910052739 hydrogen Inorganic materials 0.000 claims description 18
- 239000001257 hydrogen Substances 0.000 claims description 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 17
- 238000006471 dimerization reaction Methods 0.000 claims description 12
- 150000002430 hydrocarbons Chemical class 0.000 claims description 11
- 229930195733 hydrocarbon Natural products 0.000 claims description 10
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims description 10
- 229910000510 noble metal Inorganic materials 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 238000005984 hydrogenation reaction Methods 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000012856 packing Methods 0.000 claims description 4
- 150000004760 silicates Chemical class 0.000 claims description 4
- 239000003377 acid catalyst Substances 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 239000012876 carrier material Substances 0.000 claims description 3
- 150000001768 cations Chemical class 0.000 claims description 3
- 238000004508 fractional distillation Methods 0.000 claims description 3
- 150000004675 formic acid derivatives Chemical class 0.000 claims description 2
- 239000000499 gel Substances 0.000 claims description 2
- 239000002638 heterogeneous catalyst Substances 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 2
- 125000001145 hydrido group Chemical class *[H] 0.000 claims 1
- 238000006317 isomerization reaction Methods 0.000 claims 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract description 29
- 235000013844 butane Nutrition 0.000 abstract description 6
- 239000000047 product Substances 0.000 description 27
- 239000000203 mixture Substances 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 5
- 238000010992 reflux Methods 0.000 description 4
- 238000000605 extraction Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000006384 oligomerization reaction Methods 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- -1 triisobutene (C12) Chemical compound 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- LAAVYEUJEMRIGF-UHFFFAOYSA-N 2,4,4-trimethylpent-2-ene Chemical compound CC(C)=CC(C)(C)C LAAVYEUJEMRIGF-UHFFFAOYSA-N 0.000 description 1
- QDTDKYHPHANITQ-UHFFFAOYSA-N 7-methyloctan-1-ol Chemical compound CC(C)CCCCCCO QDTDKYHPHANITQ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- 239000004439 Isononyl alcohol Substances 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 101150101537 Olah gene Proteins 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- QNRMTGGDHLBXQZ-UHFFFAOYSA-N buta-1,2-diene Chemical compound CC=C=C QNRMTGGDHLBXQZ-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- WFYPICNXBKQZGB-UHFFFAOYSA-N butenyne Chemical group C=CC#C WFYPICNXBKQZGB-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- DROMNWUQASBTFM-UHFFFAOYSA-N dinonyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCC DROMNWUQASBTFM-UHFFFAOYSA-N 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 150000002927 oxygen compounds Chemical class 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/04—Purification; Separation; Use of additives by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
- C07C7/163—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/2206—Catalytic processes not covered by C07C5/23 - C07C5/31
- C07C5/226—Catalytic processes not covered by C07C5/23 - C07C5/31 with metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
- C07C2531/08—Ion-exchange resins
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Cephalosporin Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10042280 | 2000-08-29 | ||
| DE10103834 | 2001-01-29 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO20014175D0 NO20014175D0 (no) | 2001-08-28 |
| NO20014175L NO20014175L (no) | 2002-03-01 |
| NO329239B1 true NO329239B1 (no) | 2010-09-20 |
Family
ID=26006839
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO20014175A NO329239B1 (no) | 2000-08-29 | 2001-08-28 | Fremgangsmate for selektiv fremstilling av DIB fra en i-butenholdig C<N>4</N>-strom |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6632972B2 (de) |
| EP (1) | EP1184361B1 (de) |
| JP (1) | JP5142433B2 (de) |
| KR (1) | KR100776553B1 (de) |
| AT (1) | ATE267153T1 (de) |
| AU (1) | AU782627B2 (de) |
| CA (1) | CA2355445C (de) |
| DE (1) | DE60103335T2 (de) |
| ES (1) | ES2219482T3 (de) |
| MX (1) | MXPA01008737A (de) |
| NO (1) | NO329239B1 (de) |
| PT (1) | PT1184361E (de) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FI20021806A0 (fi) | 2002-10-10 | 2002-10-10 | Fortum Oyj | Menetelmä bensiiniseoskomponentin valmistamiseksi |
| US7473811B2 (en) | 2003-11-13 | 2009-01-06 | Neste Oil Oyj | Process for the hydrogenation of olefins |
| US7329788B2 (en) * | 2003-12-22 | 2008-02-12 | Neste Oil Oyj | Process for producing gasoline components |
| US8975047B2 (en) * | 2006-06-16 | 2015-03-10 | E I Du Pont De Nemours And Company | Process for making isooctenes from dry 1-butanol |
| US20080015397A1 (en) * | 2006-06-16 | 2008-01-17 | D Amore Michael B | Process for making isooctenes from aqueous 1-butanol |
| US20090099401A1 (en) | 2006-06-16 | 2009-04-16 | D Amore Michael B | Process for making isooctenes from aqueous isobutanol |
| US20080131948A1 (en) * | 2006-12-01 | 2008-06-05 | Leo Ernest Manzer | Process for making isooctenes from dry 2-butanol |
| US9732018B2 (en) * | 2014-02-11 | 2017-08-15 | Saudi Arabian Oil Company | Process for production of mixed butanols and diisobutenes as fuel blending components |
| JP7090471B2 (ja) * | 2018-05-15 | 2022-06-24 | Ｅｎｅｏｓ株式会社 | ｐ－キシレンの製造方法 |
| CN114163286B (zh) * | 2021-11-29 | 2024-04-09 | 万华化学集团股份有限公司 | 一种异丁烯齐聚加氢生产异构十二烷及联产三异丁烯的方法及装置 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3256351A (en) | 1963-08-22 | 1966-06-14 | Monsanto Co | Conversion of o-nitrochlorobenzene to o-dichlorobenzene |
| US4242530A (en) * | 1978-07-27 | 1980-12-30 | Chemical Research & Licensing Company | Process for separating isobutene from C4 streams |
| DE2967531D1 (en) | 1978-07-27 | 1985-11-21 | Chemical Res & Licensin | Catalytic distillation process and catalyst |
| JPS61183231A (ja) * | 1985-02-12 | 1986-08-15 | Nippon Zeon Co Ltd | イソアミレンの製造法 |
| CA2043815C (en) * | 1990-09-04 | 1997-04-01 | Harvey D. Hensley | Methyl-tertiary ether production |
| DE19646405A1 (de) * | 1996-11-11 | 1998-05-14 | Erdoelchemie Gmbh | Verfahren zur Oligomerisierung von i-Buten |
| FR2757505B1 (fr) * | 1996-12-23 | 1999-02-19 | Inst Francais Du Petrole | Procede de production d'isobutene de haute purete combinant une distillation reactive d'hydroisomerisation, une distillation et une isomerisation squelettale |
| US5877372A (en) | 1997-11-21 | 1999-03-02 | Arco Chemical Technology, L.P. | Isobutylene oligomerization using isooctane diluent |
| DE29807007U1 (de) | 1998-04-18 | 1998-07-30 | Górak, Andrzej, Prof. Dr.-Ing., 58454 Witten | Packung für Stoffaustauschkolonnen |
| GB9930402D0 (en) * | 1999-12-23 | 2000-02-16 | Exxon Chemical Patents Inc | Selective removal of isobutene from C4 olefinic feedstocks |
| EP1167326B2 (de) * | 2000-06-26 | 2007-11-14 | Saudi Basic Industries Corporation | Dimerisierung von Isobuten |
-
2001
- 2001-08-09 EP EP01306804A patent/EP1184361B1/de not_active Expired - Lifetime
- 2001-08-09 ES ES01306804T patent/ES2219482T3/es not_active Expired - Lifetime
- 2001-08-09 AT AT01306804T patent/ATE267153T1/de active
- 2001-08-09 PT PT01306804T patent/PT1184361E/pt unknown
- 2001-08-09 DE DE60103335T patent/DE60103335T2/de not_active Expired - Lifetime
- 2001-08-16 US US09/930,267 patent/US6632972B2/en not_active Expired - Lifetime
- 2001-08-20 CA CA2355445A patent/CA2355445C/en not_active Expired - Lifetime
- 2001-08-27 AU AU65473/01A patent/AU782627B2/en not_active Ceased
- 2001-08-28 NO NO20014175A patent/NO329239B1/no not_active IP Right Cessation
- 2001-08-28 JP JP2001258720A patent/JP5142433B2/ja not_active Expired - Fee Related
- 2001-08-29 KR KR1020010052549A patent/KR100776553B1/ko not_active Expired - Fee Related
- 2001-08-29 MX MXPA01008737A patent/MXPA01008737A/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| DE60103335D1 (de) | 2004-06-24 |
| NO20014175L (no) | 2002-03-01 |
| MXPA01008737A (es) | 2004-08-11 |
| JP2002087996A (ja) | 2002-03-27 |
| ATE267153T1 (de) | 2004-06-15 |
| JP5142433B2 (ja) | 2013-02-13 |
| CA2355445C (en) | 2010-03-23 |
| EP1184361A1 (de) | 2002-03-06 |
| AU6547301A (en) | 2002-03-07 |
| US6632972B2 (en) | 2003-10-14 |
| AU782627B2 (en) | 2005-08-18 |
| NO20014175D0 (no) | 2001-08-28 |
| EP1184361B1 (de) | 2004-05-19 |
| PT1184361E (pt) | 2004-09-30 |
| KR20020018118A (ko) | 2002-03-07 |
| CA2355445A1 (en) | 2002-02-28 |
| DE60103335T2 (de) | 2006-03-30 |
| KR100776553B1 (ko) | 2007-11-16 |
| US20020045786A1 (en) | 2002-04-18 |
| ES2219482T3 (es) | 2004-12-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| CHAD | Change of the owner's name or address (par. 44 patent law, par. patentforskriften) |
Owner name: INEOS SALES (UK) LTD, GB |
|
| MM1K | Lapsed by not paying the annual fees |