NO321115B1 - Fremgangsmate og apparat for produksjon av hydrokarboner ved hjelp av Fisher-Tropsch-prosessen i en reaktor som omfatter midler for begrensning av faststoff-abbrasjon i resirkuleringssloyfen - Google Patents
Fremgangsmate og apparat for produksjon av hydrokarboner ved hjelp av Fisher-Tropsch-prosessen i en reaktor som omfatter midler for begrensning av faststoff-abbrasjon i resirkuleringssloyfen Download PDFInfo
- Publication number
- NO321115B1 NO321115B1 NO20006516A NO20006516A NO321115B1 NO 321115 B1 NO321115 B1 NO 321115B1 NO 20006516 A NO20006516 A NO 20006516A NO 20006516 A NO20006516 A NO 20006516A NO 321115 B1 NO321115 B1 NO 321115B1
- Authority
- NO
- Norway
- Prior art keywords
- suspension
- solid particles
- liquid
- zone
- reaction
- Prior art date
Links
- 239000007787 solid Substances 0.000 title claims description 70
- 229930195733 hydrocarbon Natural products 0.000 title claims description 50
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 50
- 238000000034 method Methods 0.000 title claims description 19
- 238000005299 abrasion Methods 0.000 title description 6
- 238000004064 recycling Methods 0.000 title 1
- 239000002245 particle Substances 0.000 claims description 75
- 239000000725 suspension Substances 0.000 claims description 63
- 238000006243 chemical reaction Methods 0.000 claims description 52
- 239000007788 liquid Substances 0.000 claims description 49
- 239000003054 catalyst Substances 0.000 claims description 26
- 238000000926 separation method Methods 0.000 claims description 21
- 230000002194 synthesizing effect Effects 0.000 claims description 17
- 239000007789 gas Substances 0.000 claims description 16
- 239000004215 Carbon black (E152) Substances 0.000 claims description 13
- 230000015572 biosynthetic process Effects 0.000 claims description 11
- 238000003786 synthesis reaction Methods 0.000 claims description 11
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 10
- 239000011324 bead Substances 0.000 claims description 10
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 10
- 239000007809 chemical reaction catalyst Substances 0.000 claims description 10
- 238000007872 degassing Methods 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 10
- 239000000047 product Substances 0.000 claims description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 238000013467 fragmentation Methods 0.000 claims description 5
- 238000006062 fragmentation reaction Methods 0.000 claims description 5
- 230000001133 acceleration Effects 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- 239000011049 pearl Substances 0.000 claims 2
- 239000012263 liquid product Substances 0.000 claims 1
- 239000002002 slurry Substances 0.000 description 22
- 208000035874 Excoriation Diseases 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000010410 layer Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000011949 solid catalyst Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000011882 ultra-fine particle Substances 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- -1 naphtha-type Chemical class 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/34—Apparatus, reactors
- C10G2/342—Apparatus, reactors with moving solid catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/005—Separating solid material from the gas/liquid stream
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/005—Separating solid material from the gas/liquid stream
- B01J8/006—Separating solid material from the gas/liquid stream by filtration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
- B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
- B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
- B01J8/228—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement externally, i.e. the particles leaving the vessel and subsequently re-entering it
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/06—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons
- C07C1/063—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons the organic compound being the catalyst or a part of the catalyst system
- C07C1/066—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons the organic compound being the catalyst or a part of the catalyst system used for dissolving, suspending or transporting the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00654—Controlling the process by measures relating to the particulate material
- B01J2208/0069—Attrition
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9916316A FR2802832B1 (fr) | 1999-12-22 | 1999-12-22 | Installation et procede de production d'hydrocarbures par synthese fischer-tropsch dans un reacteur comportant sur la boucle de recirculation des moyens de limitation de l'attrition du solide |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO20006516D0 NO20006516D0 (no) | 2000-12-20 |
| NO20006516L NO20006516L (no) | 2001-06-25 |
| NO321115B1 true NO321115B1 (no) | 2006-03-20 |
Family
ID=9553690
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO20006516A NO321115B1 (no) | 1999-12-22 | 2000-12-20 | Fremgangsmate og apparat for produksjon av hydrokarboner ved hjelp av Fisher-Tropsch-prosessen i en reaktor som omfatter midler for begrensning av faststoff-abbrasjon i resirkuleringssloyfen |
Country Status (5)
| Country | Link |
|---|---|
| CA (1) | CA2328385C (fr) |
| FR (1) | FR2802832B1 (fr) |
| IT (1) | IT1320132B1 (fr) |
| NO (1) | NO321115B1 (fr) |
| ZA (1) | ZA200007692B (fr) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005068407A1 (fr) | 2004-01-07 | 2005-07-28 | Conocophillips Company | Systemes et procedes de separation catalyseur/produits hydrocarbones |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2161974A (en) * | 1937-01-21 | 1939-06-13 | Standard Oil Dev Co | Method of controlling exothermic reactions |
| US2440109A (en) * | 1945-02-06 | 1948-04-20 | Texas Co | Method of effecting catalytic reactions |
| DE3245318C3 (de) * | 1982-12-08 | 1996-06-20 | Bayer Ag | Verfahren zur Durchführung von Druckreaktionen mit suspendierten Katalysatoren |
| US5900159A (en) * | 1996-02-29 | 1999-05-04 | Shell Oil Company | Method for separating liquid from a slurry |
| ITMI980865A1 (it) * | 1998-04-23 | 1999-10-23 | Eniricerche S P A Ora Enitecno | Procedimento per la preparazione di idrocarburi da gas di sintesi |
-
1999
- 1999-12-22 FR FR9916316A patent/FR2802832B1/fr not_active Expired - Fee Related
-
2000
- 2000-12-19 CA CA002328385A patent/CA2328385C/fr not_active Expired - Fee Related
- 2000-12-20 ZA ZA200007692A patent/ZA200007692B/xx unknown
- 2000-12-20 NO NO20006516A patent/NO321115B1/no not_active IP Right Cessation
- 2000-12-21 IT IT2000MI002782A patent/IT1320132B1/it active
Also Published As
| Publication number | Publication date |
|---|---|
| IT1320132B1 (it) | 2003-11-18 |
| ITMI20002782A1 (it) | 2002-06-21 |
| FR2802832B1 (fr) | 2002-01-18 |
| CA2328385A1 (fr) | 2001-06-22 |
| CA2328385C (fr) | 2009-11-24 |
| FR2802832A1 (fr) | 2001-06-29 |
| ZA200007692B (en) | 2002-06-20 |
| NO20006516D0 (no) | 2000-12-20 |
| NO20006516L (no) | 2001-06-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM1K | Lapsed by not paying the annual fees |