NO303761B1 - Virkestoffinneholdende formlegemer pÕ basis av termoplastbearbeidbare elastomere styrol-butylen-blokkopolymerer - Google Patents
Virkestoffinneholdende formlegemer pÕ basis av termoplastbearbeidbare elastomere styrol-butylen-blokkopolymerer Download PDFInfo
- Publication number
- NO303761B1 NO303761B1 NO924173A NO924173A NO303761B1 NO 303761 B1 NO303761 B1 NO 303761B1 NO 924173 A NO924173 A NO 924173A NO 924173 A NO924173 A NO 924173A NO 303761 B1 NO303761 B1 NO 303761B1
- Authority
- NO
- Norway
- Prior art keywords
- stands
- spp
- hydrogen
- tert
- halogen
- Prior art date
Links
- 239000004480 active ingredient Substances 0.000 title claims description 11
- 229920001400 block copolymer Polymers 0.000 title claims description 7
- 238000000465 moulding Methods 0.000 title description 4
- 229920001169 thermoplastic Polymers 0.000 title description 2
- 239000004416 thermosoftening plastic Substances 0.000 title description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 30
- 239000001257 hydrogen Substances 0.000 claims description 30
- 239000013543 active substance Substances 0.000 claims description 24
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 21
- 229910052736 halogen Inorganic materials 0.000 claims description 21
- 150000002367 halogens Chemical class 0.000 claims description 21
- 150000001875 compounds Chemical class 0.000 claims description 12
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 10
- 239000000460 chlorine Substances 0.000 claims description 10
- 229910052801 chlorine Inorganic materials 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 229910052731 fluorine Inorganic materials 0.000 claims description 9
- 239000011737 fluorine Substances 0.000 claims description 9
- 150000002431 hydrogen Chemical class 0.000 claims description 9
- 229920002725 thermoplastic elastomer Polymers 0.000 claims description 9
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 8
- VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 claims description 7
- 239000004793 Polystyrene Substances 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 6
- 229920002223 polystyrene Polymers 0.000 claims description 6
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 claims description 5
- 239000002949 juvenile hormone Substances 0.000 claims description 5
- 229930014550 juvenile hormone Natural products 0.000 claims description 5
- 150000003633 juvenile hormone derivatives Chemical class 0.000 claims description 5
- 229930191400 juvenile hormones Natural products 0.000 claims description 5
- 125000001997 phenyl group Chemical class [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
- ISRUGXGCCGIOQO-UHFFFAOYSA-N Rhoden Chemical compound CNC(=O)OC1=CC=CC=C1OC(C)C ISRUGXGCCGIOQO-UHFFFAOYSA-N 0.000 claims description 4
- YXWCBRDRVXHABN-JCMHNJIXSA-N [cyano-(4-fluoro-3-phenoxyphenyl)methyl] 3-[(z)-2-chloro-2-(4-chlorophenyl)ethenyl]-2,2-dimethylcyclopropane-1-carboxylate Chemical compound C=1C=C(F)C(OC=2C=CC=CC=2)=CC=1C(C#N)OC(=O)C1C(C)(C)C1\C=C(/Cl)C1=CC=C(Cl)C=C1 YXWCBRDRVXHABN-JCMHNJIXSA-N 0.000 claims description 4
- 150000001409 amidines Chemical class 0.000 claims description 4
- 229960002587 amitraz Drugs 0.000 claims description 4
- QXAITBQSYVNQDR-ZIOPAAQOSA-N amitraz Chemical compound C=1C=C(C)C=C(C)C=1/N=C/N(C)\C=N\C1=CC=C(C)C=C1C QXAITBQSYVNQDR-ZIOPAAQOSA-N 0.000 claims description 4
- 150000004657 carbamic acid derivatives Chemical class 0.000 claims description 4
- 229960001591 cyfluthrin Drugs 0.000 claims description 4
- QQODLKZGRKWIFG-QSFXBCCZSA-N cyfluthrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-QSFXBCCZSA-N 0.000 claims description 4
- 125000001188 haloalkyl group Chemical group 0.000 claims description 4
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 4
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 4
- LLMLSUSAKZVFOA-UHFFFAOYSA-N 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(O)=O LLMLSUSAKZVFOA-UHFFFAOYSA-N 0.000 claims description 3
- PNVJTZOFSHSLTO-UHFFFAOYSA-N Fenthion Chemical compound COP(=S)(OC)OC1=CC=C(SC)C(C)=C1 PNVJTZOFSHSLTO-UHFFFAOYSA-N 0.000 claims description 3
- 125000003545 alkoxy group Chemical group 0.000 claims description 3
- 125000004414 alkyl thio group Chemical group 0.000 claims description 3
- 150000001987 diarylethers Chemical class 0.000 claims description 3
- 239000002950 juvenile hormone derivative Substances 0.000 claims description 3
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 claims description 3
- 150000003008 phosphonic acid esters Chemical class 0.000 claims description 3
- LLMLSUSAKZVFOA-UJURSFKZSA-N (1S,3R)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@@H]1C(O)=O LLMLSUSAKZVFOA-UJURSFKZSA-N 0.000 claims description 2
- NFGXHKASABOEEW-UHFFFAOYSA-N 1-methylethyl 11-methoxy-3,7,11-trimethyl-2,4-dodecadienoate Chemical compound COC(C)(C)CCCC(C)CC=CC(C)=CC(=O)OC(C)C NFGXHKASABOEEW-UHFFFAOYSA-N 0.000 claims description 2
- HBAQYPYDRFILMT-UHFFFAOYSA-N 8-[3-(1-cyclopropylpyrazol-4-yl)-1H-pyrazolo[4,3-d]pyrimidin-5-yl]-3-methyl-3,8-diazabicyclo[3.2.1]octan-2-one Chemical class C1(CC1)N1N=CC(=C1)C1=NNC2=C1N=C(N=C2)N1C2C(N(CC1CC2)C)=O HBAQYPYDRFILMT-UHFFFAOYSA-N 0.000 claims description 2
- 239000005946 Cypermethrin Substances 0.000 claims description 2
- 239000005892 Deltamethrin Substances 0.000 claims description 2
- 239000005927 Pyriproxyfen Substances 0.000 claims description 2
- INISTDXBRIBGOC-CGAIIQECSA-N [cyano-(3-phenoxyphenyl)methyl] (2s)-2-[2-chloro-4-(trifluoromethyl)anilino]-3-methylbutanoate Chemical compound N([C@@H](C(C)C)C(=O)OC(C#N)C=1C=C(OC=2C=CC=CC=2)C=CC=1)C1=CC=C(C(F)(F)F)C=C1Cl INISTDXBRIBGOC-CGAIIQECSA-N 0.000 claims description 2
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 125000004183 alkoxy alkyl group Chemical group 0.000 claims description 2
- 125000005083 alkoxyalkoxy group Chemical group 0.000 claims description 2
- 125000000304 alkynyl group Chemical group 0.000 claims description 2
- 229960005424 cypermethrin Drugs 0.000 claims description 2
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 claims description 2
- 229960002483 decamethrin Drugs 0.000 claims description 2
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 claims description 2
- FHIVAFMUCKRCQO-UHFFFAOYSA-N diazinon Chemical compound CCOP(=S)(OCC)OC1=CC(C)=NC(C(C)C)=N1 FHIVAFMUCKRCQO-UHFFFAOYSA-N 0.000 claims description 2
- 125000004438 haloalkoxy group Chemical group 0.000 claims description 2
- 125000004995 haloalkylthio group Chemical group 0.000 claims description 2
- 125000001072 heteroaryl group Chemical group 0.000 claims description 2
- 125000005842 heteroatom Chemical group 0.000 claims description 2
- 125000005113 hydroxyalkoxy group Chemical group 0.000 claims description 2
- 229930002897 methoprene Natural products 0.000 claims description 2
- 229950003442 methoprene Drugs 0.000 claims description 2
- ZEPAEAMBLDGUPX-UHFFFAOYSA-N n-(4-chloro-2-methylphenyl)-3-methyl-1,3-thiazolidin-2-imine Chemical compound CN1CCSC1=NC1=CC=C(Cl)C=C1C ZEPAEAMBLDGUPX-UHFFFAOYSA-N 0.000 claims description 2
- 229960000490 permethrin Drugs 0.000 claims description 2
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 claims description 2
- NHDHVHZZCFYRSB-UHFFFAOYSA-N pyriproxyfen Chemical compound C=1C=CC=NC=1OC(C)COC(C=C1)=CC=C1OC1=CC=CC=C1 NHDHVHZZCFYRSB-UHFFFAOYSA-N 0.000 claims description 2
- -1 polyethylene Polymers 0.000 description 14
- 239000000203 mixture Substances 0.000 description 10
- 241001465754 Metazoa Species 0.000 description 9
- 239000004014 plasticizer Substances 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 241000282472 Canis lupus familiaris Species 0.000 description 4
- 239000000969 carrier Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 150000002815 nickel Chemical class 0.000 description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
- 229920002397 thermoplastic olefin Polymers 0.000 description 4
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 4
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 3
- 241000607479 Yersinia pestis Species 0.000 description 3
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 229920006132 styrene block copolymer Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 3
- PFTAWBLQPZVEMU-DZGCQCFKSA-N (+)-catechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-DZGCQCFKSA-N 0.000 description 2
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 2
- RMSGQZDGSZOJMU-UHFFFAOYSA-N 1-butyl-2-phenylbenzene Chemical group CCCCC1=CC=CC=C1C1=CC=CC=C1 RMSGQZDGSZOJMU-UHFFFAOYSA-N 0.000 description 2
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 2
- BVUXDWXKPROUDO-UHFFFAOYSA-N 2,6-di-tert-butyl-4-ethylphenol Chemical compound CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 BVUXDWXKPROUDO-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 241000282326 Felis catus Species 0.000 description 2
- HRYILSDLIGTCOP-UHFFFAOYSA-N N-benzoylurea Chemical class NC(=O)NC(=O)C1=CC=CC=C1 HRYILSDLIGTCOP-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 229920002614 Polyether block amide Polymers 0.000 description 2
- 241001481703 Rhipicephalus <genus> Species 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- FSAVDKDHPDSCTO-WQLSENKSSA-N [(z)-2-chloro-1-(2,4-dichlorophenyl)ethenyl] diethyl phosphate Chemical compound CCOP(=O)(OCC)O\C(=C/Cl)C1=CC=C(Cl)C=C1Cl FSAVDKDHPDSCTO-WQLSENKSSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 description 2
- 239000012876 carrier material Substances 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 125000006255 cyclopropyl carbonyl group Chemical group [H]C1([H])C([H])([H])C1([H])C(*)=O 0.000 description 2
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 239000001087 glyceryl triacetate Substances 0.000 description 2
- 235000013773 glyceryl triacetate Nutrition 0.000 description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 2
- 230000003054 hormonal effect Effects 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine Substances NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- 230000000366 juvenile effect Effects 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- 239000003077 lignite Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- IXHMTDIIQNIVBN-UHFFFAOYSA-N n'-(2,2-dihydroxyethyl)oxamide Chemical compound NC(=O)C(=O)NCC(O)O IXHMTDIIQNIVBN-UHFFFAOYSA-N 0.000 description 2
- FTWUXYZHDFCGSV-UHFFFAOYSA-N n,n'-diphenyloxamide Chemical class C=1C=CC=CC=1NC(=O)C(=O)NC1=CC=CC=C1 FTWUXYZHDFCGSV-UHFFFAOYSA-N 0.000 description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 2
- 244000045947 parasite Species 0.000 description 2
- 229940059574 pentaerithrityl Drugs 0.000 description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 2
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 description 2
- 229960000969 phenyl salicylate Drugs 0.000 description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 2
- YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 2
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 description 2
- 229960002622 triacetin Drugs 0.000 description 2
- 150000003918 triazines Chemical class 0.000 description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- HQEPZWYPQQKFLU-UHFFFAOYSA-N (2,6-dihydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC(O)=C1C(=O)C1=CC=CC=C1 HQEPZWYPQQKFLU-UHFFFAOYSA-N 0.000 description 1
- ATLWFAZCZPSXII-UHFFFAOYSA-N (2-octylphenyl) 2-hydroxybenzoate Chemical compound CCCCCCCCC1=CC=CC=C1OC(=O)C1=CC=CC=C1O ATLWFAZCZPSXII-UHFFFAOYSA-N 0.000 description 1
- WBSRIXCTCFFHEF-UHFFFAOYSA-N (3,5-ditert-butyl-4-hydroxyphenyl)methyl-ethoxyphosphinic acid Chemical compound CCOP(O)(=O)CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 WBSRIXCTCFFHEF-UHFFFAOYSA-N 0.000 description 1
- ZEBMSMUPGIOANU-UHFFFAOYSA-N (3,5-ditert-butyl-4-hydroxyphenyl)methylphosphonic acid Chemical class CC(C)(C)C1=CC(CP(O)(O)=O)=CC(C(C)(C)C)=C1O ZEBMSMUPGIOANU-UHFFFAOYSA-N 0.000 description 1
- GOZHNJTXLALKRL-UHFFFAOYSA-N (5-benzoyl-2,4-dihydroxyphenyl)-phenylmethanone Chemical compound OC1=CC(O)=C(C(=O)C=2C=CC=CC=2)C=C1C(=O)C1=CC=CC=C1 GOZHNJTXLALKRL-UHFFFAOYSA-N 0.000 description 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 description 1
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
- JDLQSLMTBGPZLW-UHFFFAOYSA-N 1-(1-hydroxyethyl)-2,2,6,6-tetramethylpiperidin-4-ol Chemical compound CC(O)N1C(C)(C)CC(O)CC1(C)C JDLQSLMTBGPZLW-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- UUAIOYWXCDLHKT-UHFFFAOYSA-N 2,4,6-tricyclohexylphenol Chemical compound OC1=C(C2CCCCC2)C=C(C2CCCCC2)C=C1C1CCCCC1 UUAIOYWXCDLHKT-UHFFFAOYSA-N 0.000 description 1
- OPLCSTZDXXUYDU-UHFFFAOYSA-N 2,4-dimethyl-6-tert-butylphenol Chemical compound CC1=CC(C)=C(O)C(C(C)(C)C)=C1 OPLCSTZDXXUYDU-UHFFFAOYSA-N 0.000 description 1
- CZNRFEXEPBITDS-UHFFFAOYSA-N 2,5-bis(2-methylbutan-2-yl)benzene-1,4-diol Chemical compound CCC(C)(C)C1=CC(O)=C(C(C)(C)CC)C=C1O CZNRFEXEPBITDS-UHFFFAOYSA-N 0.000 description 1
- JZODKRWQWUWGCD-UHFFFAOYSA-N 2,5-di-tert-butylbenzene-1,4-diol Chemical compound CC(C)(C)C1=CC(O)=C(C(C)(C)C)C=C1O JZODKRWQWUWGCD-UHFFFAOYSA-N 0.000 description 1
- FRAQIHUDFAFXHT-UHFFFAOYSA-N 2,6-dicyclopentyl-4-methylphenol Chemical compound OC=1C(C2CCCC2)=CC(C)=CC=1C1CCCC1 FRAQIHUDFAFXHT-UHFFFAOYSA-N 0.000 description 1
- SAJFQHPVIYPPEY-UHFFFAOYSA-N 2,6-ditert-butyl-4-(dioctadecoxyphosphorylmethyl)phenol Chemical compound CCCCCCCCCCCCCCCCCCOP(=O)(OCCCCCCCCCCCCCCCCCC)CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SAJFQHPVIYPPEY-UHFFFAOYSA-N 0.000 description 1
- SCXYLTWTWUGEAA-UHFFFAOYSA-N 2,6-ditert-butyl-4-(methoxymethyl)phenol Chemical compound COCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SCXYLTWTWUGEAA-UHFFFAOYSA-N 0.000 description 1
- LBOGPIWNHXHYHN-UHFFFAOYSA-N 2-(2-hydroxy-5-octylphenyl)sulfanyl-4-octylphenol Chemical compound CCCCCCCCC1=CC=C(O)C(SC=2C(=CC=C(CCCCCCCC)C=2)O)=C1 LBOGPIWNHXHYHN-UHFFFAOYSA-N 0.000 description 1
- FJGQBLRYBUAASW-UHFFFAOYSA-N 2-(benzotriazol-2-yl)phenol Chemical compound OC1=CC=CC=C1N1N=C2C=CC=CC2=N1 FJGQBLRYBUAASW-UHFFFAOYSA-N 0.000 description 1
- FEXBEKLLSUWSIM-UHFFFAOYSA-N 2-Butyl-4-methylphenol Chemical compound CCCCC1=CC(C)=CC=C1O FEXBEKLLSUWSIM-UHFFFAOYSA-N 0.000 description 1
- XQESJWNDTICJHW-UHFFFAOYSA-N 2-[(2-hydroxy-5-methyl-3-nonylphenyl)methyl]-4-methyl-6-nonylphenol Chemical compound CCCCCCCCCC1=CC(C)=CC(CC=2C(=C(CCCCCCCCC)C=C(C)C=2)O)=C1O XQESJWNDTICJHW-UHFFFAOYSA-N 0.000 description 1
- XBXUJQFRMLQPCG-UHFFFAOYSA-N 2-[12-hydroxyimino-23-(2-hydroxy-4-methylphenyl)tricosyl]-5-methylphenol Chemical compound OC1=CC(C)=CC=C1CCCCCCCCCCCC(=NO)CCCCCCCCCCCC1=CC=C(C)C=C1O XBXUJQFRMLQPCG-UHFFFAOYSA-N 0.000 description 1
- HHPDFYDITNAMAM-UHFFFAOYSA-N 2-[cyclohexyl(2-hydroxyethyl)amino]ethanol Chemical compound OCCN(CCO)C1CCCCC1 HHPDFYDITNAMAM-UHFFFAOYSA-N 0.000 description 1
- DOTYDHBOKPPXRB-UHFFFAOYSA-N 2-butyl-2-[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]propanedioic acid Chemical compound CCCCC(C(O)=O)(C(O)=O)CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 DOTYDHBOKPPXRB-UHFFFAOYSA-N 0.000 description 1
- ASLNDVUAZOHADR-UHFFFAOYSA-N 2-butyl-3-methylphenol Chemical compound CCCCC1=C(C)C=CC=C1O ASLNDVUAZOHADR-UHFFFAOYSA-N 0.000 description 1
- SMNNDVUKAKPGDD-UHFFFAOYSA-N 2-butylbenzoic acid Chemical compound CCCCC1=CC=CC=C1C(O)=O SMNNDVUKAKPGDD-UHFFFAOYSA-N 0.000 description 1
- AKNMPWVTPUHKCG-UHFFFAOYSA-N 2-cyclohexyl-6-[(3-cyclohexyl-2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound OC=1C(C2CCCCC2)=CC(C)=CC=1CC(C=1O)=CC(C)=CC=1C1CCCCC1 AKNMPWVTPUHKCG-UHFFFAOYSA-N 0.000 description 1
- OMCYEZUIYGPHDJ-UHFFFAOYSA-N 2-hydroxy-N-[(2-hydroxyphenyl)methylideneamino]benzamide Chemical compound OC1=CC=CC=C1C=NNC(=O)C1=CC=CC=C1O OMCYEZUIYGPHDJ-UHFFFAOYSA-N 0.000 description 1
- UORSDGBOJHYJLV-UHFFFAOYSA-N 2-hydroxy-n'-(2-hydroxybenzoyl)benzohydrazide Chemical compound OC1=CC=CC=C1C(=O)NNC(=O)C1=CC=CC=C1O UORSDGBOJHYJLV-UHFFFAOYSA-N 0.000 description 1
- MZZYGYNZAOVRTG-UHFFFAOYSA-N 2-hydroxy-n-(1h-1,2,4-triazol-5-yl)benzamide Chemical compound OC1=CC=CC=C1C(=O)NC1=NC=NN1 MZZYGYNZAOVRTG-UHFFFAOYSA-N 0.000 description 1
- WBJWXIQDBDZMAW-UHFFFAOYSA-N 2-hydroxynaphthalene-1-carbonyl chloride Chemical compound C1=CC=CC2=C(C(Cl)=O)C(O)=CC=C21 WBJWXIQDBDZMAW-UHFFFAOYSA-N 0.000 description 1
- GPNYZBKIGXGYNU-UHFFFAOYSA-N 2-tert-butyl-6-[(3-tert-butyl-5-ethyl-2-hydroxyphenyl)methyl]-4-ethylphenol Chemical compound CC(C)(C)C1=CC(CC)=CC(CC=2C(=C(C=C(CC)C=2)C(C)(C)C)O)=C1O GPNYZBKIGXGYNU-UHFFFAOYSA-N 0.000 description 1
- GUCMKIKYKIHUTM-UHFFFAOYSA-N 3,3,5,5-tetramethyl-1-[2-(3,3,5,5-tetramethyl-2-oxopiperazin-1-yl)ethyl]piperazin-2-one Chemical compound O=C1C(C)(C)NC(C)(C)CN1CCN1C(=O)C(C)(C)NC(C)(C)C1 GUCMKIKYKIHUTM-UHFFFAOYSA-N 0.000 description 1
- YLUZWKKWWSCRSR-UHFFFAOYSA-N 3,9-bis(8-methylnonoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound C1OP(OCCCCCCCC(C)C)OCC21COP(OCCCCCCCC(C)C)OC2 YLUZWKKWWSCRSR-UHFFFAOYSA-N 0.000 description 1
- PZRWFKGUFWPFID-UHFFFAOYSA-N 3,9-dioctadecoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound C1OP(OCCCCCCCCCCCCCCCCCC)OCC21COP(OCCCCCCCCCCCCCCCCCC)OC2 PZRWFKGUFWPFID-UHFFFAOYSA-N 0.000 description 1
- VSAWBBYYMBQKIK-UHFFFAOYSA-N 4-[[3,5-bis[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-2,4,6-trimethylphenyl]methyl]-2,6-ditert-butylphenol Chemical compound CC1=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C1CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 VSAWBBYYMBQKIK-UHFFFAOYSA-N 0.000 description 1
- WTWGHNZAQVTLSQ-UHFFFAOYSA-N 4-butyl-2,6-ditert-butylphenol Chemical compound CCCCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 WTWGHNZAQVTLSQ-UHFFFAOYSA-N 0.000 description 1
- OVARTXYXUGDZHU-UHFFFAOYSA-N 4-hydroxy-n-phenyldodecanamide Chemical compound CCCCCCCCC(O)CCC(=O)NC1=CC=CC=C1 OVARTXYXUGDZHU-UHFFFAOYSA-N 0.000 description 1
- RDZBAYGNTNYHAH-UHFFFAOYSA-N 4-hydroxy-n-phenyloctadecanamide Chemical compound CCCCCCCCCCCCCCC(O)CCC(=O)NC1=CC=CC=C1 RDZBAYGNTNYHAH-UHFFFAOYSA-N 0.000 description 1
- LZAIWKMQABZIDI-UHFFFAOYSA-N 4-methyl-2,6-dioctadecylphenol Chemical compound CCCCCCCCCCCCCCCCCCC1=CC(C)=CC(CCCCCCCCCCCCCCCCCC)=C1O LZAIWKMQABZIDI-UHFFFAOYSA-N 0.000 description 1
- 241000934067 Acarus Species 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000238679 Amblyomma Species 0.000 description 1
- 241001427556 Anoplura Species 0.000 description 1
- 241001480748 Argas Species 0.000 description 1
- 241000238708 Astigmata Species 0.000 description 1
- 241000304153 Auchmeromyia Species 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- 241000322475 Bovicola Species 0.000 description 1
- KWGUFOITWDSNQY-UHFFFAOYSA-N Bromophos-ethyl Chemical group CCOP(=S)(OCC)OC1=CC(Cl)=C(Br)C=C1Cl KWGUFOITWDSNQY-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- UHRASWZLCRHSJE-UHFFFAOYSA-N CC1(NC(CC(C1)C(C(C(C(C(=O)O)(C1CC(NC(C1)(C)C)(C)C)C1CC(NC(C1)(C)C)(C)C)C(=O)O)C(=O)O)(C(=O)O)C1CC(NC(C1)(C)C)(C)C)(C)C)C Chemical compound CC1(NC(CC(C1)C(C(C(C(C(=O)O)(C1CC(NC(C1)(C)C)(C)C)C1CC(NC(C1)(C)C)(C)C)C(=O)O)C(=O)O)(C(=O)O)C1CC(NC(C1)(C)C)(C)C)(C)C)C UHRASWZLCRHSJE-UHFFFAOYSA-N 0.000 description 1
- 241000257160 Calliphora Species 0.000 description 1
- 241000283707 Capra Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241001098608 Ceratophyllus Species 0.000 description 1
- GQKRUMZWUHSLJF-NTCAYCPXSA-N Chlorphoxim Chemical compound CCOP(=S)(OCC)O\N=C(/C#N)C1=CC=CC=C1Cl GQKRUMZWUHSLJF-NTCAYCPXSA-N 0.000 description 1
- 241000359266 Chorioptes Species 0.000 description 1
- 241001124179 Chrysops Species 0.000 description 1
- 241000933851 Cochliomyia Species 0.000 description 1
- 229920001634 Copolyester Polymers 0.000 description 1
- 241000304166 Cordylobia Species 0.000 description 1
- 241000258922 Ctenocephalides Species 0.000 description 1
- 241000256054 Culex <genus> Species 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 241001128004 Demodex Species 0.000 description 1
- 241001480824 Dermacentor Species 0.000 description 1
- 241001481694 Dermanyssus Species 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- 241001549210 Echidnophaga Species 0.000 description 1
- 241000283086 Equidae Species 0.000 description 1
- 241000371383 Fannia Species 0.000 description 1
- 241000322646 Felicola Species 0.000 description 1
- 241001660203 Gasterophilus Species 0.000 description 1
- 241000257324 Glossina <genus> Species 0.000 description 1
- 241001480796 Haemaphysalis Species 0.000 description 1
- 241000257224 Haematobia Species 0.000 description 1
- 241000562485 Haematobosca Species 0.000 description 1
- 241000790933 Haematopinus Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241000771999 Hippobosca Species 0.000 description 1
- 241001480803 Hyalomma Species 0.000 description 1
- 241000238729 Hydrotaea Species 0.000 description 1
- 241000257176 Hypoderma <fly> Species 0.000 description 1
- 241001495069 Ischnocera Species 0.000 description 1
- 241000238681 Ixodes Species 0.000 description 1
- 241001467800 Knemidokoptes Species 0.000 description 1
- 229920002633 Kraton (polymer) Polymers 0.000 description 1
- 241001113970 Linognathus Species 0.000 description 1
- 241000257162 Lucilia <blowfly> Species 0.000 description 1
- 241000124008 Mammalia Species 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 241000771995 Melophagus Species 0.000 description 1
- 241000322738 Menacanthus Species 0.000 description 1
- 241000035436 Menopon Species 0.000 description 1
- 241001481698 Mesostigmata Species 0.000 description 1
- 241000581988 Muscina Species 0.000 description 1
- 241001373727 Myobia Species 0.000 description 1
- 241001535851 Myocoptes Species 0.000 description 1
- 241001084186 Neotrombicula Species 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N Nitrogen dioxide Chemical compound O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 241000562097 Notoedres Species 0.000 description 1
- IWGBGUINMSOOKP-UHFFFAOYSA-N OC1=C(C(=O)CCCCCCCCCCC)C=NN1C1=CC=CC=C1 Chemical class OC1=C(C(=O)CCCCCCCCCCC)C=NN1C1=CC=CC=C1 IWGBGUINMSOOKP-UHFFFAOYSA-N 0.000 description 1
- XMXAJOSEGIUEOF-UHFFFAOYSA-N OS(S(O)(=O)=O)(=O)=O.OS(S(O)(=O)=O)(=O)=O.OS(S(O)(=O)=O)(=O)=O.P.P Chemical compound OS(S(O)(=O)=O)(=O)=O.OS(S(O)(=O)=O)(=O)=O.OS(S(O)(=O)=O)(=O)=O.P.P XMXAJOSEGIUEOF-UHFFFAOYSA-N 0.000 description 1
- 241000238887 Ornithodoros Species 0.000 description 1
- 241000273340 Ornithonyssus Species 0.000 description 1
- 241001480755 Otobius Species 0.000 description 1
- 241000790250 Otodectes Species 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 241000517325 Pediculus Species 0.000 description 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- 241000722350 Phlebotomus <genus> Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 241000238705 Prostigmata Species 0.000 description 1
- 241001016411 Psorergates Species 0.000 description 1
- 241001649229 Psoroptes Species 0.000 description 1
- 241000517309 Pthirus Species 0.000 description 1
- 241001194723 Rhinoestrus Species 0.000 description 1
- 241000257190 Sarcophaga <genus> Species 0.000 description 1
- 241000509416 Sarcoptes Species 0.000 description 1
- 241000256108 Simulium <genus> Species 0.000 description 1
- 241000258242 Siphonaptera Species 0.000 description 1
- 241000044136 Solenopotes Species 0.000 description 1
- 241001494139 Stomoxys Species 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 241000282887 Suidae Species 0.000 description 1
- 241000255626 Tabanus <genus> Species 0.000 description 1
- 239000003490 Thiodipropionic acid Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 241001259047 Trichodectes Species 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- PYHXGXCGESYPCW-UHFFFAOYSA-N alpha-phenylbenzeneacetic acid Natural products C=1C=CC=CC=1C(C(=O)O)C1=CC=CC=C1 PYHXGXCGESYPCW-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- QXAITBQSYVNQDR-UHFFFAOYSA-N amitraz Chemical compound C=1C=C(C)C=C(C)C=1N=CN(C)C=NC1=CC=C(C)C=C1C QXAITBQSYVNQDR-UHFFFAOYSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 125000005605 benzo group Chemical group 0.000 description 1
- 229940049706 benzodiazepine Drugs 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- SMISHRXKWQZCCQ-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-3-yl) decanedioate Chemical compound CC1(C)N(C)C(C)(C)CCC1OC(=O)CCCCCCCCC(=O)OC1C(C)(C)N(C)C(C)(C)CC1 SMISHRXKWQZCCQ-UHFFFAOYSA-N 0.000 description 1
- YWDBZVIHZORXHG-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-1-yl) decanedioate Chemical compound CC1(C)CCCC(C)(C)N1OC(=O)CCCCCCCCC(=O)ON1C(C)(C)CCCC1(C)C YWDBZVIHZORXHG-UHFFFAOYSA-N 0.000 description 1
- FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 1
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 244000309466 calf Species 0.000 description 1
- 229960005286 carbaryl Drugs 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000000068 chlorophenyl group Chemical group 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- BXNANOICGRISHX-UHFFFAOYSA-N coumaphos Chemical compound CC1=C(Cl)C(=O)OC2=CC(OP(=S)(OCC)OCC)=CC=C21 BXNANOICGRISHX-UHFFFAOYSA-N 0.000 description 1
- 229960000956 coumarin Drugs 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 125000001891 dimethoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- JMFYZMAVUHNCPW-UHFFFAOYSA-N dimethyl 2-[(4-methoxyphenyl)methylidene]propanedioate Chemical compound COC(=O)C(C(=O)OC)=CC1=CC=C(OC)C=C1 JMFYZMAVUHNCPW-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000012173 estrus Effects 0.000 description 1
- RIZMRRKBZQXFOY-UHFFFAOYSA-N ethion Chemical compound CCOP(=S)(OCC)SCSP(=S)(OCC)OCC RIZMRRKBZQXFOY-UHFFFAOYSA-N 0.000 description 1
- OYFLKNAULOKYRI-UHFFFAOYSA-N ethoxy-phenyl-quinolin-8-yloxy-sulfanylidene-$l^{5}-phosphane Chemical compound C=1C=CC2=CC=CN=C2C=1OP(=S)(OCC)C1=CC=CC=C1 OYFLKNAULOKYRI-UHFFFAOYSA-N 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- NZYMWGXNIUZYRC-UHFFFAOYSA-N hexadecyl 3,5-ditert-butyl-4-hydroxybenzoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NZYMWGXNIUZYRC-UHFFFAOYSA-N 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 230000007775 late Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- CPRRHERYRRXBRZ-SRVKXCTJSA-N methyl n-[(2s)-1-[[(2s)-1-hydroxy-3-[(3s)-2-oxopyrrolidin-3-yl]propan-2-yl]amino]-4-methyl-1-oxopentan-2-yl]carbamate Chemical group COC(=O)N[C@@H](CC(C)C)C(=O)N[C@H](CO)C[C@@H]1CCNC1=O CPRRHERYRRXBRZ-SRVKXCTJSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- YIMHRDBSVCPJOV-UHFFFAOYSA-N n'-(2-ethoxyphenyl)-n-(2-ethylphenyl)oxamide Chemical compound CCOC1=CC=CC=C1NC(=O)C(=O)NC1=CC=CC=C1CC YIMHRDBSVCPJOV-UHFFFAOYSA-N 0.000 description 1
- GTIBACHAUHDNPH-UHFFFAOYSA-N n,n'-bis(benzylideneamino)oxamide Chemical compound C=1C=CC=CC=1C=NNC(=O)C(=O)NN=CC1=CC=CC=C1 GTIBACHAUHDNPH-UHFFFAOYSA-N 0.000 description 1
- ZJFPXDGPJMHQMW-UHFFFAOYSA-N n,n'-bis[3-(dimethylamino)propyl]oxamide Chemical compound CN(C)CCCNC(=O)C(=O)NCCCN(C)C ZJFPXDGPJMHQMW-UHFFFAOYSA-N 0.000 description 1
- YUAUPYJCVKNAEC-UHFFFAOYSA-N n-(2,4-dimethylphenyl)-3-methyl-1,3-thiazol-2-imine Chemical compound CC1=CC(C)=CC=C1N=C1N(C)C=CS1 YUAUPYJCVKNAEC-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000002816 nickel compounds Chemical class 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- ATROHALUCMTWTB-OWBHPGMISA-N phoxim Chemical compound CCOP(=S)(OCC)O\N=C(\C#N)C1=CC=CC=C1 ATROHALUCMTWTB-OWBHPGMISA-N 0.000 description 1
- 229950001664 phoxim Drugs 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- 125000005554 pyridyloxy group Chemical group 0.000 description 1
- 229940066675 ricinoleate Drugs 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- IVIIAEVMQHEPAY-UHFFFAOYSA-N tridodecyl phosphite Chemical compound CCCCCCCCCCCCOP(OCCCCCCCCCCCC)OCCCCCCCCCCCC IVIIAEVMQHEPAY-UHFFFAOYSA-N 0.000 description 1
- RLMUBIZOFHUHBI-UHFFFAOYSA-N trifluoromethyl hypochlorite Chemical compound FC(F)(F)OCl RLMUBIZOFHUHBI-UHFFFAOYSA-N 0.000 description 1
- 125000004953 trihalomethyl group Chemical group 0.000 description 1
- CNUJLMSKURPSHE-UHFFFAOYSA-N trioctadecyl phosphite Chemical compound CCCCCCCCCCCCCCCCCCOP(OCCCCCCCCCCCCCCCCCC)OCCCCCCCCCCCCCCCCCC CNUJLMSKURPSHE-UHFFFAOYSA-N 0.000 description 1
- WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0058—Biocides
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Biodiversity & Conservation Biology (AREA)
- Agronomy & Crop Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
Foreliggende oppfinnelse angår nye virkestoffinneholdende formlegemer på basis av termoplastbearbeidbare elastomere styrol-butylen-blokkopolymerer. Formlegemene kan benyttes for kontroll av skadedyr, særlig for nytte- og husdyr.
Formlegemer som inneholder virkestoffer for kontroll av skadedyr er kjent. De baserer seg på langsom frisetting av virkestoffer fra en virkestoffholdig bærermatriks av kunststoffer (sammenlign f.eks. Aries et al TJS-P 3.814.061, Greenberg US-P 3.918.407, Miller et al US-P 3.944.662, Millionis et al US-P 4.041.151, Pasarela US-P 4.145.409, Greenberg og Cloud US-P 4.158.051, v. Bittera et al US-P 4.225.578, McDaniel et al EP-OS 0.052.411 Bl, Grubb et al US-P 3.852.416 og Pearce US-P 4.536.388).
PVC er praktisk talt den utelukkende anvendte bærer for formlegemer. Andre bærere er riktignok nevnt i litteraturen, men har til nå ikke funnet noe anvendelse i praksis. Således blir det i US-P 4.195.075 blant annet nevnt at det som bærerpolymerer for øremerker også er aktuelt med termoplastiske elastomerer. I dette sitatet blir imidlertid det utelukkende bare beskrevet eksempler med mykgjørerholdig PVC som bærerpolymer.
Dette er heller ikke overraskende. PVC er prisgunstig og lett tilgjengelig. Den er også blandbar innenfor vide områder med andre stoffer, særlig mykgjørere. Disse mykgjørerne har den funksjonen i virkestoffholdig PVC-legemer at de skal holde virkestoffet oppløst i bæreren og transportere det langsomt til legemenes overflate. Der fordamper virkestoffet eller blir sammen med mykgjøreren drevet av overflaten. Sammen-virkningen av de tre komponentene PVC-bærer, mykgjører og virkestoff bestemmer om og hvorvidt formlegemene er praktisk anvendbare.
Dersom en komponent i det samlede systemet blir endret, lar det seg ikke lenger forutse om systemet ennå virker i praksis. Dette inntreffer spesielt dersom mykgjøreren innehar en nøkkelfunksjon ved virkestofftransport som blir endret eller tatt bort.
Av forskjellige grunner er det ønskelig å erstatte PVC som bæremateriale. Det er også fordelaktig å helt eller delvis gi avkall på anvendelse av mykgjørere. Det gjelder derfor å finne et virkestoff-formlegeme-system der man gir avkall på PVC som bæremateriale så vel som mykgjører og som likevel er godt virksom i praksis.
Termoplastiske elastomerer er råstoffer som inneholder elastomere faser i termoplastisk bearbeidede polymerer som enten er fysikalsk innblandet eller kjemisk innbundet. Man adskiller polyblandinger ved at de elastomere fasene foreligger fysikalsk innblandet og blokk-kopolymerer der de elastomere fasene er bestanddeler i det polymere skjelettet. Gjennom oppbyggingen av de termoplastiske elastomerene foreligger harde og myke områder ved siden av hverandre. De harde områdene danner således en krystallinsk nettstruktur eller en kontinuerlig fase hvori mellomrommene er fylt av elastomere segmenter. På grunn av denne oppbyggingen har disse råstoffene kautsjuklignende egenskaper.
Man kan inndele termoplastiske eleastomerer i fem hoved-grupper :
1. Kopolyester
2. Polyeter-blokk-amider (PEBA)
3. Termoplastiske polyuretaner (TPU)
4. Termoplastiske polyolefiner (TPO)
5. Styrol-blokk-kopolymerer
Disse fem hovedgruppene med kjemisk fullstendig forskjellig oppbygning viser like makroskopiske fysikalske egenskaper. Til tross for disse makroskopiske likeartede egenskapene oppfører disse hovedgruppene ved innblanding og frisetting av råstoffer seg fullstendig forskjellig.
Anvendelse av termoplastiske elastomerer på basis av kopolymerer som bærere for virkestoffer er kjent. I EP-OS 338.821 blir det beskrevet anvendelse av styrol-butadien-blokkopolymerer som bærere. I EP-OS 338.732 blir det beskrevet anvendelse av polyuretan-polydisiloksan-kopolymerer som bærere.
Gjenstand for foreliggende oppfinnelse er virkestoffholdige formlegemer kjennetegnet ved at de som bærere inneholder termoplastiske elastomerer på basis av styrol-butylen-blokkopolymerer med mindre enn 30# polysterolandel eventuelt ved siden av vanlige tilsetninger og som virkestoff inneholder fosfor- eller fosfonsyreester, naturlige og syntetiske pyretroider, karbamater, amidiner, juvenilhormoner og juvenoide syntetiske virkestoffer med følgende formler
Oppfinnelsen angår videre formlegemer som er kjennetegnet ved at de som virkestoffer inneholder forbindelse med formel I
der
R<1>og R<2>står for halogen, eventuelt halogensubstituert
alkyl, eventuelt halogensubstituert fenyl,
R<3>står for hydrogen eller CN,
R^ står for hydrogen eller halogen,
R<5>står for hydrogen eller halogen.
Det var overraskende at virkestoffer uten tilsats av mykgjørere også av termoplastiske elastomerer på basis av styrol og butylen nådde fra polymermatriks til polymer-overflaten, da denne evnen bare er begrenset til noen ganske få polymerer. Endrer man bare en komponent av det samlede systemet, så er virkningen ikke forutsigbar. Termoplastiske elastomere på basis av termoplastiske olefiner (TPO) eller termoplastiske polyuretaner er f.eks. ikke i den situasjonen at de lar virkestoffene migrere til overflaten.
De anvendbare styrol-butylen-blokkopolymerene ifølge oppfinnelsen består av en polyetylenbutylen-kautsjuk- middelblokk med en til begge ender kjemisk koblet polystyrol-endeblokk. Polystyrolandelen utgjør mindre enn 30$. Poly-styrolendeblokken fordeler seg jevnt som sfæriske polystyrol-domener i etylenkautsjuk-matriksen.
Fremgangsmåte for syntese av egnede styrol-blokkopolymerer er kjent f.eks. fra US-P 3.485.787, 4.006.116 og 4.039.629.
Egnede styrol-butylen-blokkpolymerer er f.eks. tilgjengelig under varemerkene Kraton G og Elexar fra firma Shell Chemie GmbH og Thermolast-K-Compounds fra firma Kraiburg.
Som virkestoffer for formlegemene ifølge oppfinnelsen skal det blant foretrukkede insektsider spesielt nevnes parasiti-sider for anvendelse på dyr. Til insektisider hører fosfor-holdige forbindelser som fosfor- eller fosfonsyreestere, naturlige og syntetiske pyretroider, karbamater, amidiner, juvenilhormoner og juvenoide syntetiske virkestoffer.
Til fosfor- eller fosforsyreestere hører: 0-etyl-0-(8-kinolyl)fenyl-tiofosfat (Quintiofos),
0 , 0-dietyl-0-(3-klor -4-mety1-7 -coumar iny1)-tiofosfat (Coumaphos),
0,0-dietyl-0-fenylglyoksylonitril-oksim-tiofosfat (Phoxim),
0,O-dietyl-0-cyanoklorbenzaldoksim-tiofosfat (Chlorphoxim),
0,0-dietyl-0-(4-brom-2,5-diklorfenyl)-fosfortionat (Bromo-phos-etyl),
0,0,0',0'-tetraetyl-S,S'-metylen-di(fosforditionat) (Ethion),
2,3-p-dioksanditiol-S,S-bis(0,0-dietylfosforditionat,
2-klor-l-(2,4-diklorfenyl )-vinyldietylfosfat (Chlorfenvin-phos),
0 , 0-dimetyl-0-(3-metyl-4-nietyltiofenyl )-tionofosforsyreester
(Fenthion)
Til karbamatene hører:
2-isopropoksyfenylmetylkarbamat (Propoxur),
1-naftyl-N-metylkarbamat (Carbaryl).
Til de syntetiske pyretroidene teller forbindelser med formel
I
der
R<1>og R<2>står for halogen, eventuelt halogensubstituert
alkyl, eventuelt halogensubstituert fenyl,
R<3>står for hydrogen eller CN,
R<4>står for hydrogen eller halogen,
R<5>står for hydrogen eller halogen.
Det er foretrukket med syntetiske pyretroider med formel I der
R<*>står for halogen, særlig fluor, klor, brom,
R<2>står for halogen, særlig fluor, klor, brom,
trihalogenmetyl, fenyl, klorfenyl,
R<3>står for hydrogen eller CN
R<4>står for hydrogen eller fluor,
R<5>står for hydrogen.
Spesielt foretrukket er syntetiske pyretroider med formel I der
R<*>står for klor,
R<2>står for klor, trifluormetyl, p-klorfenyl,
R<3>står for CN,
R<4>står for hydrogen eller fluor,
R^ står for hydrogen.
Spesielt skal det nevnes forbindelser med formel I der
R<1>står for klor,
R<2>står for klor eller p-klorfenyl,
R<3>står for CN,
R<4>står for fluor i 4-stilling,
R<5>står for hydrogen.
Enkeltforbindelser kan nevnes: 3 - [2 - ( 4-kl or f enyl )-2-klorvlnyl] -2,2-dimetyl-cyklopropankar-boksylsyre [a-cyano-4-fluor-3-fenoksy)-benzyl]-ester (Flumethrin), 2 , 2-dlmetyl-3-( 2 , 2-diklorvinyl )-cyklopropankarboksylsyre-a-cyano(4-fluor-3-fenoksy)-benzyl-ester (Cyfluthrin) og dens enantlomere og stereoisomere,
cx-cyano-3-fenoksybenzyl(+ )-cis , trans-3-(2 ,2-dibromvlnyl )-2,2,-dlmetylcyklopropankarboksylat (Deltamethrin), 2 , 2-dimetyl-3- ( 2 , 2-diklorvinyl )-cyklopropankarboksylsyre-oc-cyano-3-fenoksybenzylester (Cypermethrin),
3-fenoksybenzyl(±)-cis, trans-3-(2,2-diklorvinyl)-2,2-dimetylcyklopropankarboksylat (Permethrin),
a-(p-Cl - f enyl)-isovaleriansyre-a-cyano-3-fenoksy-benzylester (Fenvalerate),
2- cyano-3-fenoksybenzyl-2-(2-klor-a,a,a-tri fluor-p-tolui-dino )-3-metylbutyrat (Fluvalinate).
Til amidinet hører: 3- metyl-2-[2,4-dimetyl-fenylimino]-tiazolin,
2-(4-klor-2-metylfenylimino)-3-metyltiazolidin,
2-(4-klor-2-metylfenylimino )-3-(isobutyl-l-enyl)-tiazolidin
l,5-bis-(2,4-dimetylfenyl)-3-metyl-l,3,5-triazapenta-l,4-dien (Amitraz).
Til juvenilhormonene eller Juvenilhormonlignende substanser hører substituerte diaryleter, benzoylurea og triazinderiva-ter. Til juvenilhormonene og juvenilhormonlignende substanser hører særlig forbindelser med følgende formler: Til de substituerte diaryletrene hører særlig substituerte alkoksydifenyleter eller -difenylmetan med generell formel I
der
R<1>står for hydrogen, halogen, alkyl, alkoksy, alkyltio,
halogenalkyl, halogenalkoksy, halogenalkyltio, dioksyalkylen, dioksyhalogenalkylen, CN, NO2, alkenyl, alkinyl, alkoksyalkyl, alkoksyalkoksy, hydroksyalkoksy,
R<2>står for de ved R<*>angitte rester,
R<3>står for de ved R<*>angitte rester,
R<4>står for hydrogen, alkyl, halogenalkyl eller halogen R<5>står for de ved R<4>angitte rester,
Het står for eventuell substituert heteroaryl som ikke er
bundet over heteroatomen til den øvrige resten,
X, Y står uavhengig av hverandre for -0-, -S-,
Z står for -0-, -S-, -CH2-, -CHCH3-, -C(CH3)2-,
m og n står uavhengig av hverandre for 0, 1, 2, 3, summen er
imidlertid like eller større enn 2.
Spesielt foretrukket er forbindelsen med formel I der
R<1>står for hydrogen, metyl, trifluormetyl, metoksy,
trlfluormetoksy, klor, fluor,
R<2>står for hydrogen,
R<3>står for hydrogen, fluor, klor, metyl,
R<4>står for hydrogen eller metyl,
R<5>står for metyl, etyl, trifluormetyl eller hydrogen,
Het står for pyridyl eller pyridzinyl som eventuelt er substituert med fluor, klor, metyl, N02, metoksy, metylmerkapto,
X står for 0,
Y står for 0,
Z står for 0, CH2eller -C(CH3)2-,
m står for 1,
n står for 1.
Enkeltvis skal følgende forbindelser nevnes:
Til benzoylurea hører forbindelsen med formel (V):
der
R<1>står for halogen,
R<2>står for hydrogen eller halogen,
R<3>står for hydrogen, halogen eller C1_4~alkyl,
R<4>står for halogen, l-5-halogen-Ci_4-alkyl, C1-4-alkoksy, l-5-halogen-C1_4-alkoksy, C1_4-alkyltio, 1-5-halogen-C1_4-alkyltio, fenoksy eller pyridyloksy som eventuelt kan være substituert med halogen, C^_4~alkyl, l-5-halogen-C1_4-alkyl, C1_4-alkoksy, 1-5-halogen-<C>1_4-alkoksy,<C>1_4-alkoksy,<C>1_4-alkyltio, 1-5-halogen-Ci_4~<a>lkyltio.
Spesielt skal nevnes:
Til triazinene hører forbindelsen med formel (VI)
der
R<*>står for cyklopropyl eller isopropyl;
R<2>betyr hydrogen, halogen, C j-C-^-alkylkarbonyl»
cyklopropylkarbonyl , Ci_<C>i2-alkylkarbonyl, ^1-^12" alkyltiokarbamoyl eller C2-C£,-alkenylkarbamoyl; og
R3står for hydrogen, C-^C-^-alkyl»cyklopropyl, C2_Cfc-alkenyl, C^C^-alkylkarbonyl» cyklopropylkarbonyl, Ci-C-j^-alkylkarbamoyl • Ci_Ci2-alkyltiokarbamoyl eller Cg-Cfc-alkenylkarbamoyl og deres syreaddisjonssalter som er utoksisk for varmblodige.
Spesielt kan nevnes:
Spesielt er virkestoffene med de vanlige navnene Propoxur, Cyfluthrin, Flumethrin, Pyriproxyfen, Methoprene, Diazinon, Amitraz, Fenthion.
Virkestoffene kan foreligge i formlegemer alene eller i blanding med hverandre.
Virkestoffene foreligger i formlegemene i konsentrasjoner fra 0,1 - 20 vekt-#, fortrinnsvis mellom 1-10 vekt-#.
Formlegemene ifølge oppfinnelsen kan videre inneholde de vanlige additivene for kunststoff. Vanlige additiver er f.eks. pigmenter, stabilisatorer, flytmiddel, glidemiddel, avformuleringsmiddel.
Eksempler på vanlige additiver er:
1. Antioksidanter
1.1 Alkylerte monofenoler. f.eks. 2,6—di—tert.butyl—4-metylfenol, 2—tert.butyl—4,6-dimetylfenol, 2,6—di—tert.-butyl-4-etylfenol, 2,6-di-tert.butyl-4-n-butylfenol, 2,6-di-tert.butyl-4-i-butylfenol, 2,6-di-cyklopentyl-4-metylfenol, 2—(a—metylcykloheksyl)—4,6-dimetylfenol, 2,6—di—oktadecyl—4-metylfenol, 2,4,6-tricykloheksylfenol, 2,6—di—tert.butyl—4-metoksymetylfenol.
1.2 Alkylerte hydrokinoner. f.eks. 1,6—di—tert.butyl—4-metoksyfenol, 2,5—di—tert.butyl—hydrokinon, 2,5—di—tert.-amyl—hydrokinon, 2,6—difenyl-4—oktadecyloksyfenyl.
1.3 Hydroksylerte tiodlfenyletere.f.eks. 2,2'—tio-bis-(6-tert.butyl-4-metylfenol), 2,2'-tio-bis-(4-oktylfenol), 4,4'-tio-bis-(6-tert.butyl-3-metylfenol), 4,4'-tio-bis-(6-tert.butyl—2—metylfenol).
1.4 Alkyliden— bisfenoler. f.eks. 2,2'—metylen—bis—(6-tert.butyl-4-metylfenol), 2 ,2'-metylen-bis-(6-tert.butyl-4-etylfenol), 2,2 '—metylen—bis-(4—metyl—6(cx—metylcykloheksyl )-fenol), 2,2'-metylen-bis-(4-metyl-6-cykloheksylfenol), 2,2'-metylen-bis-(6-nonyl-4-metylfenol), 2,2'-metylenbis-(4 ,6-di-tert .butylf enol ), 2,2 '-etyliden-bis-(4,6-ditert.butylfenol), 2,2'-etyliden-bis-(6-tert.butyl-4-isobutylfenol), 2,2'-mety-len—bis—[6—(a—metylbenzyl )-4-nonylfenol], 2,2'—metylen-bis—[6—[a,a—dimetylbenzyl)-4-nonylfenol], 4,4'—metylen-bis—(2,6—di—tert.butylfenol), 4,4'—metylen-bis—(6—tert.-butyl-2-metylfenol), 1,1 '-bis-(5-tert.butyl-4-hydroksy-2-metylfenyl)-butan, 2,6-di-(3-tert.butyl-5-metyl-2-hydroksy-benzyl)-4-metylfenol, 1,1,3-tris-(5-tert.butyl-4-hydroksy-2-metylfenyl)—butan, 1,1—bis-(5—tert.butyl—4-hydroksy—2-metylfenyl)—3—n—dodecylmerkaptobutan, etylenglykol—bis—[3,3-bis—( 3 '—tert .butyl—4 '—hydroksyf enyl )—butyrat] , di—(3—tert.-
butyl-4-hydroksy-5-metylfenyl)-dicyklopentadien, di-[2-(3'-tert.butyl-2'-hydroksy-5'-metylbenzyl)-6-tert.butyl-4-metylfenyl]—tereftalat.
1.5 Benzvlforbindelser. f.eks. 1,3,5—tri—(3,5-di-tert.-butyl-4-hydroksybenzyl)-2,4,6-trimetylbenzol, dl-(3,5-di - tert .butyl-4-hydroksybenzyl )-sulf id, 3 ,5-di-tert .buty.1-4-hydroksybenzyl—merkaptoeddiksyre—isooktylester, bis—(4-tert.butyl-3-hydroksy-2,6-dimetylbenzyl)-ditiol-tereftalat, 1,3,5-tris-(3,5-di-tert.butyl-4-hydroksybenzyl)-isocyanurat, 1,3,5-tris-(4-tert.butyl-3-hydroksy-2,6-dimetylbenzyl)-isocyanurat, 3,5—di-tert.butyl—4—hydroksybenzyl—fosfonsyre-dioktadecylester, 3,5—di—tert.butyl—4—hydroksybenzyl—fos-fonsyre—monoetylester, kalsiumsalt.
1.6 Ac<y>laminofenoler. f.eks. 4—hydroksy—laurinsyreanilid, 4—hydroksystearinsyreanilid, 2,4—bis—oktylmerkapto—6—(3,5-di—tert.butyl—4—hydroksyanilino)—s—triazin, N—(3,5—di—tert.-butyl—4—hydroksyfenyl)—karbaminsyreoktylester.
1.7 Ester av p—( 3. 5— di— tert. butyl— 4— hydroksyfenyl)— pro-pionsyre med en— eller flerverdige alkoholer, som f.eks. metanol, oktadekanol, 1,6—heksandiol, neopentylglykol, tiodietylenglykol, dietylenglykol, trietylenglykol, penta-erytrit, tris—hydroksyetylisocyanurat, di—hydroksyetyl—oksal-syrediamid.
1.8 Ester av p—( 5- tert. butyl— 4— hydroksy— 3— metylfenyl )-proplonsyre med en— eller flerverdige alkoholer, som f.eks. metanol, oktadekanol, 1,6—heksandiol, neopentylglykol, tiodietylenglykol, dietylenglykol, trietylenglykol, penta-erytrit, tris-hydroksyetyl-isocyanurat, di-hydroksyetyl-oksyalsyrediamid.
1.9 Amider av p—( 3. 5- di— tert. butyl— 4— hydroksyfenyl)— pro-plonsyre . som f.eks. N,N'-di-(3,5-di-tert.butyl-4-hydroksy-fenylpropionyl)—heksametylendiamin, N,N'—(3,5—di—tert.-
butyl-4-hydroksyfenylpropionyl)-tri-metylendiamin, N,N'-di-(3,5-di-tert.butyl-4-hydroksyfenylpropionyl)-hydrazin.
2. UV— absorberer og lysbeskyttelsesmlddel
2.1 2—( 2'— hydroksyfenyl)— benztriazol. som f.eks. 5'-metyl-, 3 *,5'-di-tert.butyl-, 5'-tert.butyl-, 5'-(1,1,3,3-tetrametylbutyl)—, 5—klor-3',5'-di—tert.butyl—, 5—klor—3'-tert.butyl-5'-metyl-, 3'-sec.butyl-5'-tert.butyl, 4'-okt-oksy—, 3',5'—di—tert.amyl—, 3',5'—bis—(a,a—dimetylbenzyl)-derivat.
2.2 2— hydroksybenzofenon. som f.eks. 4—hydroksy-, 4—metoksy—, 4—oktoksy—, 4—decyloksy—, 4—dodecyloksy—, 4—benzyloksy—, 4 ,2 ' ,4'—trihydoksy—, 2'—hydroksy—4,4'di-metoksy—derivat.
2.3 Ester av eventuelle substituerte benzos<y>rer, som f.eks. 4—tert.butyl-fenylsalicylat, fenylsalicylat, oktyl-fenylsalicylat, dibenzoylresorcin, bis—(4—tert.butylbenzoyl)-resorcin, benzoylresorcin, 3,5-di-tert.butyl-4-hydroksybenzo-syre-2,4-di-tert.butylfenylester, 3,5-di-tert.butyl-4-hydroksybenzosyre—heksadecylester.
2.4 Akr<y>later. som f.eks. a-cyan-p,p-difenylakrylsyre-etylester hhv. —isooktylester, a—karbometoksy—zimtsyremetyl-ester , a—cyano—p—metyl—p—metoksy—zimtsyremetylester hhv. butylester, a—karbometoksy—p—metoksy—zimtsyremetylester, N—(<p>—karbometoksy-p<->cyanovinyl)—2—metylindolin.
2.5 Nikkelforbindelser. som f.eks. nikkelkomplekser av 2,2'-tio-bis-[4-(l,l,3,3-tetrametylbutyl)-fenoler], som 1:1 eller 1:2-kompleks, eventuelt med ytterligere ligander som n—butylamin, trietanolamin eller N—cykloheksyl—dietanolamin, nikkeldibutyl—ditiokarbamat, nikkelsalter av 4—hydroksy—3,5-di—tert.butylbenzyl-fosfonsyremonoalkylester, som av metyl— eller etylester, nikkelkomplekser av ketoksimer som av
2-hydroksy-4-metyl-fenyl-undecylketonoksim, nikkelkomplekser av 1—fenyl—4—lauroyl—5—hydroksypyrazoler, eventuelt med ytterligere ligander.
2.6 Sterisk hindrede aminer, som f.eks. bis—(2,2,6,6-tetrametylpiperidyl)—sebakat, bis—(1,2,2,6,6—pentametylpi-peridyl)—sebakat, n—butyl—3,5—di—tert.butyl—4—hydroksy-benzyl—mal onsyr e—bis— ( 1 ,2,2,6,6—pentametylpiperidyl)—ester, kondensasjonsprodukt av 1—hydroksyetyl—2,2,6,6-tetramety1—4-hydroksypiperidin og bernsteinsyre, kondensasjonsprodukt av N,N'-(2,2,6 ,6-tetramety1-4-piperidyl)-heksametyldiamin og 4—tert.oktylamino—2,6—diklor—1,3,5—s—triazin, tris—(2,2,6,6-tetrametyl-4-piperidyl)-nitrotriacat, tetrakis-(2,2,6,6-tetrametyl—4—piperidyl)—1,2,3,4—butantetrakarboksylsyre, 1,1'—(1,2—etandiyl)—bis—(3,3,5,5—tetrametylpiperazinon).
2.7 Oksalsvrediamider. som f.eks. 4,4'—di—oktyloksy—oksa-nilid, 2,2'—di—oktyloksy—5,5'—di—tert.butyl—oksanilid, 2,2'—di—dodecyloksy—5,5'—di—tert.butyl—oksanilid, 2—etoksy-2'-etyl-oksanilid, N,N'—bis—(3—dimetylaminopropyl)-oksalamid, 2—etoksy—5—tert.butyl—2'—etyloksanilid og blandinger med 2—etoksy—2'—etyl—5,4'—di—tert.butyl—oksanilid blandinger av o— og p—metoksy— så vel som o— og p—etoksy—disubstituerte oksaniliden.
3. Metalldesaktivatorer. som f.eks. N,N'—difenyloksal-syrediamid, N—salicylal—N'—salicyloylhydrazin, N,N'—bis—sali-cyloylhydrazin, N,N'-bis-(3,5-di-tert.buty1-4-hydroksy-fenylpropionyl)—hydrazin, 3—salicyloylamino—1,2,4-triazol, bis—benzyl iden—oksalsyredihydrazid. 4. Fosfitter og fosfonitter. som f.eks. trifenylfosfitt, difenylalkylfosfitt, fenyldialkylfosfitt, tri—(nonylfenyl)-fosfitt, trilaurylfosfitt, trioktadecylfosfitt, distearyl-pentaerytritdifosfitt, tris-(2,4-di-tert.butylfenyl)-fosfitt, diisodecylpentaerytrit—difosfitt, di—(2,4—di-tert.butyl-fenyl)—pentaerytritdifosfitt, tristearyl—sorbitt—trifosfitt,
tetrakis-(2 ,4-di-tert.butylfenyl)-4,4'-bifenylen-dlfosfonitt, 3,9-bis-(2 ,4-di-tert.butylfenyl)-pentaerytritdifosfitt, tristearyl-sorbit-trifosfitt, tetrakls-(2,4-di-tert.butyl-fenyl )-4,4 '-bifenylen-difosfonitt, 3,9-bis-(2,4-di-tert.-butylfenoksy-2,4,8,10-tetraoksa-3,9-difosfaspiro[5,5]-unde-can. 5. Peroksidforstvrrende forbindelser . som f.eks. ester av<p>—tiodipropionsyre, f.eks. av lauryl—, stearyl—, myristyl— eller tridecylester, merkaptobenzimidazol, sinksaltet av 2—merkaptobenzimidazoler, sink—dibutyl—ditiokarbamat, diokta-decyldisulfid, pentaerytritt-tetrakis-(p-dodecylmerkapto )-propionat. 6. Pol<y>amidstabilisatorer. som f.eks. kobbersalter i kombinasjon med jodider og/eller fosforforbindelser og salter av toverdige manganer. 7. Basiske Co— stabilisatorer. som f.eks. melamin, polyvinylpyrrolidon, dicyandiamid, triallylcyanurat, harnstoff—derivat, amin, polyamid, polyuretan, alikali— og jordalkalisalter av høyere fettsyrer, f.eks. Ca—stearat, Zn—stearat, Mg—stearat, Na—ricinoleat, K—palmitat, antimon-brenzkatecinat eller tinnbrenzkatecinat. 8. Nukleierin<g>smidler. som f.eks. 4—tert.butylbenzosyre, adipinsyre, difenyleddiksyre. 9. Fyllstoffer og forsterkningsmidler . som f.eks. kalsiumkarbonat, silikater, glassfibre, asbest, talk, kaolin, glimmer, bariumsulfat, metalloksider og —hydroksider, russ, grafitt. 10. Ytterligere tilsetninger, som mykgjørere, glidemiddel, emulgatorer, pigmenter, optiske lysgjørere, flammebe-skyttelsesmidler, antistatika, drivmidler.
Formlegemene ifølge oppfinnelsen blir oppnådd ved blanding av enkelkomponenten. Blandingen kan foregå etter kjente teknikker på vanlig måte f.eks. med kna— eller snekke-maskiner. Viderebearbeidingen foregår ved kjent teknikk innenfor termoplastbearbeiding f.eks. ved ekstrudering eller sprøytestøping. Formlegemer ifølge foreliggende oppfinnelse er halsbånd, halsbåndanheng (medaljonger), øre—, hale—, fotbånd, øremerker, folier, avtrekkfolier, klebestrimler, strimler, plater, granulater. Fortrinnsvis skal det nevnes halsbånd og medaljonger for hunder og katter.
Formlegemene tjener til bekjemping av parasitter på vertsdyr, i vertsdyr og i omgivelsene til vertsdyr som hus—, hobby— og nyttedyr.
Til hus—, hobby— og nyttedyr hører pattedyr som f.eks. kalver, sauer, geiter, hester, svin, hunder, katter.
Til skadedyrene hører:
Fra orden Anoplura f.eks. Haematopinus spp., Linognathus spp., Solenopotes spp., Pediculus spp., Pthirus spp.;
fra orden Mallophaga z.B. Trimenopon spp., Menopon spp., Eomenacanthus spp., Menacanthus spp., Trichodectes spp., Felicola spp., Damalinea spp., Bovicola spp.;
fra orden Diptera f.eks. Åedes spp., Culex spp., Simulium spp., Phlebotomus spp., Chrysops spp., Tabanus spp., Musea spp., Hydrotaea spp., Muscina spp., Haematobosca spp. , Haematobia spp., Stomoxys spp., Fannia spp., Glossina spp., Lucilia spp., Calliphora spp., Auchmeromyia spp., Cordylobia spp. , Cochliomyia spp., Chrysomyia spp., Sarcophaga spp. , Wohlfartia spp., Gasterophilus spp., Oesteromyia spp., Oedemagena spp., Hypoderma spp., Oestrus spp., Rhinoestrus spp., Melophagus spp., Hippobosca spp..
Fra orden Siphonaptera f.eks. Ctenocephalides spp., Echid-nophaga spp., Ceratophyllus spp..
Fra orden Metastigmata f.eks. Hyalomma spp., Rhipicephalus spp. , Boophilus spp., Amblyomma spp., Haemaphysalis spp., Dermacentor spp., Ixodes spp., Argas spp., Ornithodorus spp., Otobius spp.;
fra orden Mesostigmata f.eks. Dermanyssus spp., Ornithonyssus spp., Pneumonyssus spp..
Fra orden Prostigmata f.eks. Cheyletiella spp., Psorergates spp., Myobia spp., Demodex spp., Neotrombicula spp.;
fra orden Astigmata f.eks. Acarus spp., Myocoptes spp., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp. , Notoedres spp., Knemidocoptes spp., Neoknemidocoptes spp., Cytodites spp., Laminosioptes spp..
De følgende eksemplene for insektiside formdeler på basis av styrol-butylen-blokkopolymerer skal illustrere oppfinnelsen nærmere:
Eksempel A
Fremstilling:
Blandingen blir ekstrudert på vanlig måte til hundehalsbånd.
Eksempel B
Fremstilling:
Virkestoffene og triacetin blir oppvarmet sammen så lenge inntil det ikke foreligger noen klar oppløsning. Termoplast K blir blandet i en blander med den varme oppløsningen av virkestoffet og triacetin. Man blander så lenge inntil blandingen er homogen. Det krever oppvarming av blandingen f.eks. som følge av en forhøyelse av omdreiningstallet til blanderen, innføring av oppløsningen i styrol-blokkopoly-meren. Blandingen blir ekstrudert på en ekstruder til plater, som blir stanset ut til medaljonger (= anheng for halsbånd) til 2 x 4 cm.
Eksempel C
Fremstilling:
Virkestoffet blir anbrakt i en en intensivblander på bæreren og blandingen blir formet i sprøyteforming til hundehalsbånd.
Claims (8)
1.
Virkestoffholdige formlegemer,karakterisertved at de som bærere inneholder termoplastiske elastomerer på basis av styrol-butylen-blokkopolymerer med mindre enn 30% polysterolandel eventuelt ved siden av vanlige tilsetninger og som virkestoff inneholder fosfor- eller fosfonsyreester, naturlige og syntetiske pyretroider, karbamater, amidiner, juvenilhormoner og juvenoide syntetiske virkestoffer med følgende formler
2.
Formlegemer ifølge krav 1,karakterisert, ved at de som virkestoffer inneholder forbindelse med formel I
der
R<1>og R<2>står for halogen, eventuelt halogensubstituert
alkyl, eventuelt halogensubstituert fenyl,
R<3>står for hydrogen eller CN,
R<4>står for hydrogen eller halogen,
r<5>står for hydrogen eller halogen.
3.
Formlegemer ifølge krav 2,karakterisertved at de inneholder syntetiske pyretroider med formel I ifølge krav 2 hvori
R<1>står for klor,
R<2>står for klor, trifluormetyl, p-klorfenyl,
R<3>står for CN,
R<4>står for hydrogen eller fluor,
R<5>står for hydrogen.
4.
Formlegemer ifølge krav 1,karakterisertved at de inneholder et av de følgende virkestoffene:
3- [2 - ( 4-kl or f enyl )-2-kl or vinyl] -2 ,2-dimetyl-cyklopropankar-boksylsyre [a-cyano-4-fluor-3-fenoksy)-benzyl]-ester (Flumethrin),
2,2-dimetyl-3-(2 ,2-diklorvinyl )-cyklopropankarboksylsyre-a-cyano(4-fluor-3-fenoksy)-benzyl-ester (Cyfluthrin) og deres enantiomerer og stereoisomerer,
a-cyano-3-fenoksybenzyl(±)-cis, trans-3-(2,2-dibromvinyl )-2,2,-dimetylcyklopropankarboksylat (Deltamethrin ),
2 , 2-dimetyl-3- ( 2 , 2-diklorvinyl )-cyklopropankarboksylsyre-oc-cyano-3-fenoksybenzylester (Cypermethrin),
3-fenoksybenzyl(±)-cis, trans-3-(2,2-diklorvinyl)-2 ,2-dimetylcyklopropankarboksylat (Permethrin),
a-(p-Cl - f enyl )-isovaleriansyre-a-cyano-3-f enoksy-benzylester (Fenvalerate), 2- c<y>ano-3-fenoks<y>benz<y>l-2-(2-klor-a,a, a-trifluor-p-tolui-dino)-3-metylbutyrat (Fluvalinate), 3- metyl-2-[2,4-dimetyl-fenylimino]-tlazolin,
2-(4-klor-2-metylfenylimlno)-3-metyltiazolldin, 2-(4-klor-2-metylfenylimino)-3-(isobutyl-l-enyl)-tlazolldin 1,5-bis-(2,4-dimetylfenyl)-3-metyl-l,3,5-trlazapenta-l,4-dien (Amitraz).
5.
Formlegemer Ifølge krav 1,karakterisertved at de som virkestoffer inneholder substituert diaryleter med generell formel
der
R<1>står for hydrogen, halogen, alkyl, alkoksy, alkyltio,
halogenalkyl, halogenalkoksy, halogenalkyltio, dioksyalkylen, dioksyhalogenalkylen, CN, N0£, alkenyl, alkinyl, alkoksyalkyl, alkoksyalkoksy, hydroksyalkoksy,
R<2>står for de ved R<*>angitte rester, R^ står for de ved R<*>angitte rester,
R<4>står for hydrogen, alkyl, halogenalkyl eller halogen r<5>står for de ved R<4>angitte rester,
Het står for eventuell substituert heteroaryl som ikke er
bundet over heteroatomet til den øvrige resten,
X, Y står uavhengig av hverandre for -0-, -S-,
Z står for -0-, -S-, -CH2-, -CHCH3-, -C(CH3)2-,
m og n står uavhengig av hverandre for 0, 1, 2, 3, summen er
imidlertid like eller større enn 2.
6.
Formlegemer ifølge krav 1,karakterisertved at de som virkestoffer inneholder en av de følgende forbindelser:
7.
Formlegemer ifølge krav 1,karakterisertved at de som virkestoff inneholder et av virkestoffene med de generelle navnene propoksur, cyflutrin, flumetrin, pyriproksyfen, metopren, diazinon, amitraz og fention.
8.
Formlegemer ifølge krav 1 - 7,karakterisertved at virkestoffene foreligger i konsentrasjon fra 0,1-20 vekt-*.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4137272A DE4137272A1 (de) | 1991-11-13 | 1991-11-13 | Wirkstoffhaltige formkoerper auf basis thermoplastisch verarbeitbarer elastomerer styrol-butylen-blockcopolymerer, verfahren zu ihrer herstellung und verwendung zur kontrolle von schaedlingen |
Publications (3)
Publication Number | Publication Date |
---|---|
NO924173D0 NO924173D0 (no) | 1992-10-29 |
NO924173L NO924173L (no) | 1993-05-14 |
NO303761B1 true NO303761B1 (no) | 1998-08-31 |
Family
ID=6444679
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO924173A NO303761B1 (no) | 1991-11-13 | 1992-10-29 | Virkestoffinneholdende formlegemer pÕ basis av termoplastbearbeidbare elastomere styrol-butylen-blokkopolymerer |
Country Status (16)
Country | Link |
---|---|
EP (1) | EP0542078A1 (no) |
JP (1) | JPH05222265A (no) |
CN (1) | CN1072692A (no) |
AU (1) | AU662180B2 (no) |
CA (1) | CA2082533A1 (no) |
CZ (1) | CZ337992A3 (no) |
DE (1) | DE4137272A1 (no) |
FI (1) | FI925127A (no) |
HU (2) | HU212796B (no) |
IL (1) | IL103700A (no) |
MX (1) | MX9206330A (no) |
NO (1) | NO303761B1 (no) |
NZ (1) | NZ245084A (no) |
PL (1) | PL171240B1 (no) |
TR (1) | TR26341A (no) |
ZA (1) | ZA928714B (no) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU715843B2 (en) * | 1994-11-28 | 2000-02-10 | Laboratoires Virbac | Residual control of parasites by long-acting shampoo formulations |
US6528556B1 (en) * | 1999-06-01 | 2003-03-04 | Ciba Speciality Chemicals Corporation | Process for the biocidal finishing of plastic materials |
DE102004031325A1 (de) | 2004-06-29 | 2006-01-19 | Bayer Healthcare Ag | Wirkstoffhaltige feste Formkörper zur äußerlichen Anwendung gegen Parasiten an Tieren |
DE102014117437A1 (de) * | 2014-11-27 | 2016-06-02 | Dr. Ing. H.C. F. Porsche Aktiengesellschaft | Anordnung mindestens eines Nebenaggregats an einem Gehäuse eines Motors |
CA3205997A1 (en) | 2020-12-21 | 2022-06-30 | University Of Georgia Research Foundation Inc. | Parasiticidal collar comprising isoxazoline compounds |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4400374A (en) * | 1979-06-22 | 1983-08-23 | Environmental Chemicals, Inc. | Controlled release of compounds utilizing a plastic matrix |
US4603152A (en) * | 1982-11-05 | 1986-07-29 | Baxter Travenol Laboratories, Inc. | Antimicrobial compositions |
GB8809262D0 (en) * | 1988-04-20 | 1988-05-25 | Secto Co Ltd | Devices for protecting animals from parasites |
AU617931B2 (en) * | 1989-03-09 | 1991-12-05 | Mitsubishi Gas Chemical Company, Inc. | Composite insecticide and package thereof |
-
1991
- 1991-11-13 DE DE4137272A patent/DE4137272A1/de not_active Withdrawn
-
1992
- 1992-10-29 NO NO924173A patent/NO303761B1/no unknown
- 1992-11-02 EP EP92118735A patent/EP0542078A1/de not_active Ceased
- 1992-11-04 MX MX9206330A patent/MX9206330A/es unknown
- 1992-11-06 JP JP4321379A patent/JPH05222265A/ja active Pending
- 1992-11-10 IL IL10370092A patent/IL103700A/xx not_active IP Right Cessation
- 1992-11-10 CA CA002082533A patent/CA2082533A1/en not_active Abandoned
- 1992-11-10 AU AU28257/92A patent/AU662180B2/en not_active Ceased
- 1992-11-11 FI FI925127A patent/FI925127A/fi unknown
- 1992-11-11 NZ NZ245084A patent/NZ245084A/en unknown
- 1992-11-12 TR TR92/1090A patent/TR26341A/xx unknown
- 1992-11-12 ZA ZA928714A patent/ZA928714B/xx unknown
- 1992-11-12 HU HU9203551A patent/HU212796B/hu not_active IP Right Cessation
- 1992-11-12 CZ CS923379A patent/CZ337992A3/cs unknown
- 1992-11-12 HU HU9203551A patent/HU9203551D0/hu unknown
- 1992-11-13 CN CN92112991A patent/CN1072692A/zh active Pending
- 1992-11-13 PL PL92296588A patent/PL171240B1/pl unknown
Also Published As
Publication number | Publication date |
---|---|
HU212796B (en) | 1996-11-28 |
NO924173D0 (no) | 1992-10-29 |
DE4137272A1 (de) | 1993-05-19 |
PL296588A1 (en) | 1993-07-26 |
JPH05222265A (ja) | 1993-08-31 |
CZ337992A3 (en) | 1993-06-16 |
EP0542078A1 (de) | 1993-05-19 |
PL171240B1 (en) | 1997-03-28 |
HU9203551D0 (en) | 1993-03-29 |
NO924173L (no) | 1993-05-14 |
AU662180B2 (en) | 1995-08-24 |
AU2825792A (en) | 1993-05-20 |
HUT64092A (en) | 1993-11-29 |
FI925127A (fi) | 1993-05-14 |
FI925127A0 (fi) | 1992-11-11 |
CN1072692A (zh) | 1993-06-02 |
IL103700A (en) | 1997-02-18 |
TR26341A (tr) | 1995-03-15 |
CA2082533A1 (en) | 1993-05-14 |
ZA928714B (en) | 1993-05-10 |
NZ245084A (en) | 1995-02-24 |
IL103700A0 (en) | 1993-04-04 |
MX9206330A (es) | 1993-05-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0682869B1 (de) | Nicht-systemische Bekämpfung von Parasiten | |
NO301863B1 (no) | Virkestoffinneholdende formlegemer på basis av termoplastbearbeidbare elastomere polyeter-blokkamider | |
EP1496744A1 (de) | Bekämpfung von parasiten bei tieren | |
DE4216535A1 (de) | Formkoerper zur bekaempfung von schaedlingen | |
AU662179B2 (en) | Shaped articles which contain active compounds and are based on elastomeric copolyesters which can be processed as thermoplastics, processes for their production and their use for control of pests | |
NO303761B1 (no) | Virkestoffinneholdende formlegemer pÕ basis av termoplastbearbeidbare elastomere styrol-butylen-blokkopolymerer | |
US4145409A (en) | Acaricidal resin composition containing spiro cyclopropane-1,-1'-indene!-2-carboxylic acid, 3,3-dimethyl-, α- | |
EP0936857A2 (de) | Wirkstoffhaltige formkörper auf basis biologisch abbaubarer, thermoplastisch verarbeitbarer polymere | |
WO2002078443A1 (de) | Wirkstoffhaltige formkörper auf basis thermoplastisch verarbeitbarer polyurethane zur bekämpfung von parasiten | |
AU657612B2 (en) | Shaped articles for combating ectoparasites on animals |