NO169776C - PROCEDURE FOR PREPARING A MODIFIED SPAERIC POLYMERIZATION CATALYST AND USING THE CATALYST - Google Patents
PROCEDURE FOR PREPARING A MODIFIED SPAERIC POLYMERIZATION CATALYST AND USING THE CATALYSTInfo
- Publication number
- NO169776C NO169776C NO872444A NO872444A NO169776C NO 169776 C NO169776 C NO 169776C NO 872444 A NO872444 A NO 872444A NO 872444 A NO872444 A NO 872444A NO 169776 C NO169776 C NO 169776C
- Authority
- NO
- Norway
- Prior art keywords
- catalyst
- polymerisation
- spherical
- spaeric
- preparing
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
- C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
- C07D471/04—Ortho-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Dental Preparations (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Polymerization Catalysts (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Process for the treatment of a spherical catalyst for the polymerisation of olefins, containing at least one transition metal, a magnesium compound and a halogen, characterised in that ethylene is prepolymerised in the presence of the spherical catalyst, in the presence of a cocatalyst chosen from alkylaluminiums, at least partially in suspension, to a degree of prepolymerisation adapted to the polymerisation process in which the prepolymer will be subsequently used, a spheroprotector being used in combination with the various components not later than after the prepolymerisation, the accepted formula of the said spheroprotector being: AlR'mR''nClpHq in which 0.05 < p </= 1 0 < m < 2.95 0 < n < 2.95 0 </= q </= 1 it being known that m + n + p + q = 3 and R' and R'', which are identical or different, are linear, branched or cyclic hydrocarbon radicals containing from 1 to 14 carbon atoms. The catalyst thus treated conserves its spherical morphology in the subsequent polymerisation of ethylene. It is particularly suited for the manufacture of linear polyethylene powder with spherical morphology.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8609930A FR2601372B1 (en) | 1986-07-08 | 1986-07-08 | PROCESS FOR THE TREATMENT OF SPHERICAL OLEFIN POLYMERIZATION CATALYSTS. APPLICATION OF THE CATALYST OBTAINED IN THE POLYMERIZATION OF OLEFINS |
Publications (4)
Publication Number | Publication Date |
---|---|
NO872444D0 NO872444D0 (en) | 1987-06-11 |
NO872444L NO872444L (en) | 1988-01-11 |
NO169776B NO169776B (en) | 1992-04-27 |
NO169776C true NO169776C (en) | 1992-08-05 |
Family
ID=9337202
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO872444A NO169776C (en) | 1986-07-08 | 1987-06-11 | PROCEDURE FOR PREPARING A MODIFIED SPAERIC POLYMERIZATION CATALYST AND USING THE CATALYST |
Country Status (11)
Country | Link |
---|---|
EP (1) | EP0252804B1 (en) |
JP (1) | JP2689381B2 (en) |
CN (1) | CN1010024B (en) |
AT (1) | ATE58147T1 (en) |
AU (1) | AU598828B2 (en) |
CA (1) | CA1294944C (en) |
DE (1) | DE3766022D1 (en) |
ES (1) | ES2019393B3 (en) |
FI (1) | FI93367C (en) |
FR (1) | FR2601372B1 (en) |
NO (1) | NO169776C (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2682305B2 (en) * | 1991-10-29 | 1997-11-26 | 住友化学工業株式会社 | Method for producing olefin polymer |
BR9301438A (en) | 1993-04-05 | 1994-11-15 | Petroleo Brasileiro Sa | Process of preparation of spherical ziegler catalyst for polymerization of alpha-olefins, spherical catalyst, process of obtaining spherical polyethylene of very high molecular weight and spherical polyethylene of very high by molecular |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4312784A (en) * | 1977-12-13 | 1982-01-26 | Phillips Petroleum Co. | Catalyst and process of polymerization of alpha monoolefins |
JPS591723B2 (en) * | 1980-01-17 | 1984-01-13 | チッソ株式会社 | Method for producing α-olefin polymer |
JPS5928573B2 (en) * | 1980-02-05 | 1984-07-13 | チッソ株式会社 | Method for producing α-olefin polymer |
FR2586022B1 (en) * | 1985-08-06 | 1987-11-13 | Bp Chimie Sa | POLYMERIZATION OF OLEFINS IN THE GASEOUS PHASE WITH A ZIEGLER-NATTA CATALYST AND TWO ORGANOMETALLIC COMPOUNDS |
FR2591602B1 (en) * | 1985-12-18 | 1988-02-26 | Atochem | PROCESS FOR THE TREATMENT OF SPHERICAL OLEFIN POLYMERIZATION CATALYSTS. APPLICATION OF THE CATALYST OBTAINED IN THE POLYMERIZATION OF OLEFINS. |
-
1986
- 1986-07-08 FR FR8609930A patent/FR2601372B1/en not_active Expired
-
1987
- 1987-06-11 NO NO872444A patent/NO169776C/en not_active IP Right Cessation
- 1987-06-30 ES ES87401508T patent/ES2019393B3/en not_active Expired - Lifetime
- 1987-06-30 AT AT87401508T patent/ATE58147T1/en not_active IP Right Cessation
- 1987-06-30 DE DE8787401508T patent/DE3766022D1/en not_active Expired - Fee Related
- 1987-06-30 EP EP19870401508 patent/EP0252804B1/en not_active Expired - Lifetime
- 1987-07-07 FI FI873012A patent/FI93367C/en not_active IP Right Cessation
- 1987-07-07 CA CA000541455A patent/CA1294944C/en not_active Expired - Lifetime
- 1987-07-08 JP JP62170850A patent/JP2689381B2/en not_active Expired - Fee Related
- 1987-07-08 CN CN87104796A patent/CN1010024B/en not_active Expired
- 1987-07-08 AU AU75326/87A patent/AU598828B2/en not_active Ceased
Also Published As
Publication number | Publication date |
---|---|
FI93367B (en) | 1994-12-15 |
FR2601372A1 (en) | 1988-01-15 |
FI93367C (en) | 1995-03-27 |
NO169776B (en) | 1992-04-27 |
ES2019393B3 (en) | 1991-06-16 |
EP0252804B1 (en) | 1990-11-07 |
JP2689381B2 (en) | 1997-12-10 |
CA1294944C (en) | 1992-01-28 |
ATE58147T1 (en) | 1990-11-15 |
CN87104796A (en) | 1988-01-20 |
NO872444D0 (en) | 1987-06-11 |
EP0252804A1 (en) | 1988-01-13 |
CN1010024B (en) | 1990-10-17 |
DE3766022D1 (en) | 1990-12-13 |
FI873012A (en) | 1988-01-09 |
NO872444L (en) | 1988-01-11 |
FI873012A0 (en) | 1987-07-07 |
JPS6323905A (en) | 1988-02-01 |
AU598828B2 (en) | 1990-07-05 |
AU7532687A (en) | 1989-01-12 |
FR2601372B1 (en) | 1988-10-21 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MM1K | Lapsed by not paying the annual fees |