FI873012A - Process for treating a spherical catalyst used in the polymerization of olefins, use of the obtained catalyst in olefinic polymerization - Google Patents

Process for treating a spherical catalyst used in the polymerization of olefins, use of the obtained catalyst in olefinic polymerization Download PDF

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Publication number
FI873012A
FI873012A FI873012A FI873012A FI873012A FI 873012 A FI873012 A FI 873012A FI 873012 A FI873012 A FI 873012A FI 873012 A FI873012 A FI 873012A FI 873012 A FI873012 A FI 873012A
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FI
Finland
Prior art keywords
spherical
catalyst
polymerization
olefins
polymerisation
Prior art date
Application number
FI873012A
Other languages
Finnish (fi)
Swedish (sv)
Other versions
FI93367C (en
FI93367B (en
FI873012A0 (en
Inventor
Claude Brun
Auguste Cheux
Michel Avaro
Original Assignee
Atochem
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Application filed by Atochem filed Critical Atochem
Publication of FI873012A0 publication Critical patent/FI873012A0/en
Publication of FI873012A publication Critical patent/FI873012A/en
Application granted granted Critical
Publication of FI93367B publication Critical patent/FI93367B/en
Publication of FI93367C publication Critical patent/FI93367C/en

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D471/00Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
    • C07D471/02Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
    • C07D471/04Ortho-condensed systems
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Dental Preparations (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Polymerization Catalysts (AREA)

Abstract

Process for the treatment of a spherical catalyst for the polymerisation of olefins, containing at least one transition metal, a magnesium compound and a halogen, characterised in that ethylene is prepolymerised in the presence of the spherical catalyst, in the presence of a cocatalyst chosen from alkylaluminiums, at least partially in suspension, to a degree of prepolymerisation adapted to the polymerisation process in which the prepolymer will be subsequently used, a spheroprotector being used in combination with the various components not later than after the prepolymerisation, the accepted formula of the said spheroprotector being: AlR'mR''nClpHq in which 0.05 < p </= 1 0 < m < 2.95 0 < n < 2.95 0 </= q </= 1 it being known that m + n + p + q = 3 and R' and R'', which are identical or different, are linear, branched or cyclic hydrocarbon radicals containing from 1 to 14 carbon atoms. The catalyst thus treated conserves its spherical morphology in the subsequent polymerisation of ethylene. It is particularly suited for the manufacture of linear polyethylene powder with spherical morphology.
FI873012A 1986-07-08 1987-07-07 Process for treating a spherical catalyst used in the polymerization of olefins, use of the obtained catalyst in olefinic polymerization FI93367C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8609930 1986-07-08
FR8609930A FR2601372B1 (en) 1986-07-08 1986-07-08 PROCESS FOR THE TREATMENT OF SPHERICAL OLEFIN POLYMERIZATION CATALYSTS. APPLICATION OF THE CATALYST OBTAINED IN THE POLYMERIZATION OF OLEFINS

Publications (4)

Publication Number Publication Date
FI873012A0 FI873012A0 (en) 1987-07-07
FI873012A true FI873012A (en) 1988-01-09
FI93367B FI93367B (en) 1994-12-15
FI93367C FI93367C (en) 1995-03-27

Family

ID=9337202

Family Applications (1)

Application Number Title Priority Date Filing Date
FI873012A FI93367C (en) 1986-07-08 1987-07-07 Process for treating a spherical catalyst used in the polymerization of olefins, use of the obtained catalyst in olefinic polymerization

Country Status (11)

Country Link
EP (1) EP0252804B1 (en)
JP (1) JP2689381B2 (en)
CN (1) CN1010024B (en)
AT (1) ATE58147T1 (en)
AU (1) AU598828B2 (en)
CA (1) CA1294944C (en)
DE (1) DE3766022D1 (en)
ES (1) ES2019393B3 (en)
FI (1) FI93367C (en)
FR (1) FR2601372B1 (en)
NO (1) NO169776C (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2682305B2 (en) * 1991-10-29 1997-11-26 住友化学工業株式会社 Method for producing olefin polymer
BR9301438A (en) * 1993-04-05 1994-11-15 Petroleo Brasileiro Sa Process of preparation of spherical ziegler catalyst for polymerization of alpha-olefins, spherical catalyst, process of obtaining spherical polyethylene of very high molecular weight and spherical polyethylene of very high by molecular

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4312784A (en) * 1977-12-13 1982-01-26 Phillips Petroleum Co. Catalyst and process of polymerization of alpha monoolefins
JPS591723B2 (en) * 1980-01-17 1984-01-13 チッソ株式会社 Method for producing α-olefin polymer
JPS5928573B2 (en) * 1980-02-05 1984-07-13 チッソ株式会社 Method for producing α-olefin polymer
FR2586022B1 (en) * 1985-08-06 1987-11-13 Bp Chimie Sa POLYMERIZATION OF OLEFINS IN THE GASEOUS PHASE WITH A ZIEGLER-NATTA CATALYST AND TWO ORGANOMETALLIC COMPOUNDS
FR2591602B1 (en) * 1985-12-18 1988-02-26 Atochem PROCESS FOR THE TREATMENT OF SPHERICAL OLEFIN POLYMERIZATION CATALYSTS. APPLICATION OF THE CATALYST OBTAINED IN THE POLYMERIZATION OF OLEFINS.

Also Published As

Publication number Publication date
AU7532687A (en) 1989-01-12
ATE58147T1 (en) 1990-11-15
FI93367C (en) 1995-03-27
CA1294944C (en) 1992-01-28
EP0252804B1 (en) 1990-11-07
AU598828B2 (en) 1990-07-05
DE3766022D1 (en) 1990-12-13
JP2689381B2 (en) 1997-12-10
ES2019393B3 (en) 1991-06-16
NO872444L (en) 1988-01-11
FI93367B (en) 1994-12-15
FR2601372A1 (en) 1988-01-15
CN1010024B (en) 1990-10-17
FR2601372B1 (en) 1988-10-21
JPS6323905A (en) 1988-02-01
NO872444D0 (en) 1987-06-11
NO169776B (en) 1992-04-27
NO169776C (en) 1992-08-05
FI873012A0 (en) 1987-07-07
CN87104796A (en) 1988-01-20
EP0252804A1 (en) 1988-01-13

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Owner name: ATOCHEM

MA Patent expired