NO164522B - LIGHTING DEVICE FOR ELECTRIC WELDING DEVICE. - Google Patents

LIGHTING DEVICE FOR ELECTRIC WELDING DEVICE. Download PDF

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Publication number
NO164522B
NO164522B NO853761A NO853761A NO164522B NO 164522 B NO164522 B NO 164522B NO 853761 A NO853761 A NO 853761A NO 853761 A NO853761 A NO 853761A NO 164522 B NO164522 B NO 164522B
Authority
NO
Norway
Prior art keywords
welding
cyanate
electric welding
aryl
solution
Prior art date
Application number
NO853761A
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Norwegian (no)
Other versions
NO853761L (en
NO164522C (en
Inventor
Torben Laustsen
Christian Chemnitz
Torsten Chemnitz
Original Assignee
Torben Laustsen
Christian Chemnitz
Torsten Chemnitz
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Torben Laustsen, Christian Chemnitz, Torsten Chemnitz filed Critical Torben Laustsen
Publication of NO853761L publication Critical patent/NO853761L/en
Publication of NO164522B publication Critical patent/NO164522B/en
Publication of NO164522C publication Critical patent/NO164522C/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K9/00Arc welding or cutting
    • B23K9/095Monitoring or automatic control of welding parameters
    • B23K9/0956Monitoring or automatic control of welding parameters using sensing means, e.g. optical

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Mechanical Engineering (AREA)
  • Arc Welding Control (AREA)
  • Non-Portable Lighting Devices Or Systems Thereof (AREA)
  • Laser Beam Processing (AREA)

Abstract

En belysningsanordning for et elektrisk sveiseapparat består av en anordning (5) hvorfra lyskilden ledes frem til sveisehåndtaket (1) gjennom en lyslederkabel (8) som ved sin ene ende (9) munner ut et sted på undersiden av sveisehåndtaket (1) og belyser det sted som sveisepistolen. (1) fares hen imot.Ved bruk av en slik belysningsanordning. er det gjort mulig for sveisere å sveise på ellers utilgjengelige steder uten å fjerne sveisehjelmen fra øynene, hvorved fenomenet "sveiseøyne" blir. unngått.An illumination device for an electric welding apparatus consists of a device (5) from which the light source is led to the welding handle (1) through a light guide cable (8) which at one end (9) opens out somewhere on the underside of the welding handle (1) and illuminates it. place as the welding gun. (1) hazard. When using such a lighting device. it is made possible for welders to weld in otherwise inaccessible places without removing the welding helmet from the eyes, whereby the phenomenon of "welding eyes" becomes. avoided.

Description

Anvendelse av stabiliserende middel overfor innvirkning av varme og fuktighet i estergruppeholdige polyuretankunststoffer. Use of stabilizing agents against the effects of heat and humidity in polyurethane plastics containing ester groups.

Estergruppeholdige polyuretankunststoffer viser den ulempe at de har tendens Polyurethane plastics containing ester groups have the disadvantage that they tend to

til en hydrolytisk spaltning ved innvirkning av varme og fuktighet. Disse estergruppeholdige polyuretankunstoffer anvendes meget til fremstilling av porøse eller to a hydrolytic cleavage under the influence of heat and moisture. These polyurethane resins containing ester groups are widely used for the production of porous or

homogene kunststoffer i form av kunst-stoffelastiske produkter, lakker, filmer, homogeneous plastics in the form of plastic-fabric elastic products, lacquers, films,

støpeharpikser og skumstoffer. molding resins and foams.

Det er allerede kjent å anvende kar-bodiimider som stabiliserende middel overfor innvirkning av varme og fuktighet, dvs. It is already known to use carbodiimides as stabilizing agents against the effects of heat and moisture, i.e.

altså for å hindre aldring ved hydrolytisk thus to prevent aging by hydrolytic

innvirkning i estergruppeholdige kunststoffer. Slike stabiliseringsmidler har imidler-tid for mange anvendelsesformål et for impact in plastics containing ester groups. Such stabilizers, however, have too many applications for one purpose

høyt damptrykk og har tendens til van-dringsforeteelser. Deres anvendelse er un-dertiden vanskelig ved forskjellige anven-delsesområder, eksempelvis der hvor nett-dannelse av polyesterene må gjennomføres high vapor pressure and tends to migration phenomena. Their application is sometimes difficult in different areas of application, for example where net formation of the polyesters must be carried out

ved polyfunksjonelle isocyanater da karbodiimidene kan forsinke nettdannelsesfor-løpet, spesielt når det for reaksjonsforløpet with polyfunctional isocyanates as the carbodiimides can delay the course of network formation, especially when the course of the reaction

er nødvendig med nærvær av mindre mengder vann. is required with the presence of smaller amounts of water.

Oppfinnelsens gjenstand er anvendel-sen av arylcyanater som stabiliserende middel overfor innvirkning av varme og fuktighet i estergruppeholdige polyuretankunststoffer. Arylcyanatene utmerker seg The object of the invention is the use of aryl cyanates as stabilizing agents against the effects of heat and humidity in polyurethane plastics containing ester groups. The aryl cyanates excel

sammenlignet med karbodiimidene av sam-menlignbar molekylvekt ved at et større compared to the carbodiimides of comparable molecular weight in that a larger

antall virksomme cyanatgrupper kan være number of active cyanate groups can be

inneholdt i stabilisatoren, hvorved det kan contained in the stabilizer, whereby it can

oppnåes en øket beskyttelsesvirkning med mengdemessig samme anvendelse. De for-blir også ved høyere reaksjon- eller for-arbeidelsestemperaturer i det estergruppeholdige polyuretankunststoff. En vandring av cyansyreestere til det utreagerte kunst-stoffs overflate iakttas heller ikke ved arylcyanater med liten molekylvekt. an increased protective effect is achieved with the same amount of application. They also remain at higher reaction or processing temperatures in the ester group-containing polyurethane plastic. A migration of cyanic acid esters to the surface of the unreacted plastic is also not observed with low molecular weight aryl cyanates.

Arylcyanater er tilgjengelig ifølge DAS 1.195.764 eller ifølge Chemische Berichte 97 Aryl cyanates are available according to DAS 1,195,764 or according to Chemische Berichte 97

(1964) 3012—3017. Ifølge oppfinnelsen egnede en- eller flerverdige arylcyanater er f. eks. fenylcyanat, o-, m- eller p-fenylen-biscyanat, o-, m- eller p-metylfenylcyanat, o-, m- eller p-acetyl-fenylcyanat, o-, m-eller p-nitrofenylcyanat, n-nonylcyanat, iso-dodecyl-fenylcyanat, 2,2-bis-(p-cyana-tofenyl)-propan, 1,3,5-tricyanato-benzol, 1,5-naftalindicyanat, o-, m- eller p-di-me-tylaminofenylcyanat. (1964) 3012—3017. According to the invention, suitable mono- or polyvalent aryl cyanates are e.g. phenyl cyanate, o-, m- or p-phenylene biscyanate, o-, m- or p-methylphenyl cyanate, o-, m- or p-acetyl phenyl cyanate, o-, m- or p-nitrophenyl cyanate, n-nonyl cyanate, iso-dodecyl-phenylcyanate, 2,2-bis-(p-cyanatophenyl)-propane, 1,3,5-tricyanato-benzene, 1,5-naphthalenedicyanate, o-, m- or p-di-me- tylaminophenyl cyanate.

Ved cyanatenes substitusjon har man det for hånden å variere reaksjonsevnen til OCN-gruppen således at de tilpasses de eventuelle krav. When substituting the cyanates, it is possible to vary the reactivity of the OCN group so that they are adapted to the possible requirements.

Videre lar det seg ved langkjedede ali-fatiske hydrokarboner anvende substituer-te cyansyreestere, hvorved sluttproduktet får vannavvisende egenskaper. Furthermore, with long-chain aliphatic hydrocarbons, it is possible to use substituted cyanic acid esters, whereby the end product acquires water-repellent properties.

Fortrinnsvis anvendes til stabilisering polyfunksjonelle cyansyreestere, som ved det større antall av cyanatgrupper ved anvendelse i tilsvarende mengder sikrer en høyere stabiliseringsvirkning. Preferably, polyfunctional cyanic acid esters are used for stabilization, which with the greater number of cyanate groups when used in corresponding amounts ensure a higher stabilization effect.

Arylcyanatet kan anvendes enkelt eller i blanding som ufortynnet stoff eller som oppløsning i organiske oppløsnings-midler. Egnede oppløsningsmidler er f. eks. aceton, eddikestere, benzen, kloroform, alkohol, dimetylformamid, tetraklorkarbon, acetonitril, dimetylsulfoksyd. The aryl cyanate can be used singly or in a mixture as an undiluted substance or as a solution in organic solvents. Suitable solvents are e.g. acetone, acetic esters, benzene, chloroform, alcohol, dimethylformamide, carbon tetrachloride, acetonitrile, dimethyl sulfoxide.

Oppløsningskonsentrasjonen er da uten avgjørelse og retter seg hver gang etter de praktiske krav. Tilsetningen foregår even-tuelt til en av utgangskomponentene for kunststoffremstillingen. Den kan imidler-tid også foregå under kunststoffremstillingen og hvis det er teknisk mulig kan arylcyanatene inforleves også til det ferdige kunststoff. Det lønner seg å anvende mel-lom 0,0005 og 0,05 mol arylcyanat pr. 100 g av det estergruppeholdige polyuretankunststoff som skal stabiliseres. The solution concentration is then without a decision and is always based on the practical requirements. The addition takes place possibly to one of the starting components for the production of plastics. However, it can also take place during the manufacture of the plastic and if it is technically possible, the aryl cyanates can also be incorporated into the finished plastic. It pays to use between 0.0005 and 0.05 mol of aryl cyanate per 100 g of the ester group-containing polyurethane plastic to be stabilized.

Arylcyanatenes stabiliserende virkning strekker seg til alle estergruppeholdige po-lyuretankunststof f er. Slike kunststoffer kan eksempelvis foreligge som lakker, folier, overtrekk, fibre, skumstoffer, elastomere, støpeharpikser eller presslegemer. Kjemisk sett kan de eksempelvis være polyaddisjons-produkter av polyestere og polyisocyanater. The stabilizing effect of the aryl cyanates extends to all polyurethane plastics containing ester groups. Such plastics can, for example, be present as lacquers, foils, coverings, fibres, foams, elastomers, casting resins or pressed bodies. Chemically speaking, they can for example be polyaddition products of polyesters and polyisocyanates.

Eksempel 1: Example 1:

100 g av en polyester av 14 mol adipin-syre og 15 mol dietylenglykol (hydroksyl-tall 40; syre tall 1,0) omsettes i blanding med 100 g av en polyester av 100 mol adi-pinsyre og 11 mol etylenglykol (hydroksyl-tall 55; syretall 1,0) med 16 g toluylendi-isocyanat til et i etylacetat til 30 vektprosent med 22.000 cP/20° C oppløselig pro-dukt. Til 100 g av denne oppløsning settes 5 g av en 75 %-ig oppløsning i etylacetat 100 g of a polyester of 14 mol adipic acid and 15 mol diethylene glycol (hydroxyl number 40; acid number 1.0) is reacted in a mixture with 100 g of a polyester of 100 mol adipic acid and 11 mol ethylene glycol (hydroxyl number 55; acid number 1.0) with 16 g of toluylene diisocyanate to a product soluble in ethyl acetate to 30% by weight with 22,000 cP/20° C. To 100 g of this solution, add 5 g of a 75% solution in ethyl acetate

av polyfunksjonelt isocyanat med 12,5 % NCO, dannet ved omsetning av 1 mol tri-metylolpropan og 3 mol toluylen diisocya-nat, såvel som 2,5 g av en 10 %-ig oppløs-ning i aceton av et arylcyanat ifølge tabellen. of polyfunctional isocyanate with 12.5% NCO, formed by reacting 1 mol of trimethylolpropane and 3 mol of toluylene diisocyanate, as well as 2.5 g of a 10% solution in acetone of an aryl cyanate according to the table.

De av blandingen ved fordampning av oppløsningsmidlet dannede 0,5 mm tykke folier har etter en oppholdstid på 48 timer ved 20° C og 60% relativ fuktighet sammenlignet med den uten stabiliseringsmid-del fremstilte folie de i tabellen oppførte prøveverdier (ikke aldret) og etter 12 da-gers aldring ved 95 % relativ fuktighet og 70° C de likeledes angitte prøveverdier (aldret). After a residence time of 48 hours at 20° C and 60% relative humidity, the 0.5 mm thick foils formed from the mixture by evaporation of the solvent have the sample values listed in the table (not aged) compared to the foil produced without stabilizers and after 12-day aging at 95% relative humidity and 70° C the test values indicated (aged).

Eksempel 2: Example 2:

Av 100 g av en polyester av 10 mol adi-pinsyre og 11 mol etylenglykol (hydroksyl-tall 55; syretall 1,0) og 8 g toluylen-diiso-cyanat fremstilles et i etylacetat til 30 vektprosent oppløselig addukt. Oppløsnin-gens viskositet utgjør 15,000 cP/20° C. 100 g av denne oppløsning tilsettes 5 g av en 75 %-ig oppløsning i etylacetat av det polyfunksjonelle isocyanat fra eksempel 1. From 100 g of a polyester of 10 mol of adipic acid and 11 mol of ethylene glycol (hydroxyl number 55; acid number 1.0) and 8 g of toluylene diisocyanate, an adduct soluble in ethyl acetate to 30% by weight is prepared. The viscosity of the solution is 15,000 cP/20° C. 100 g of this solution, 5 g of a 75% solution in ethyl acetate of the polyfunctional isocyanate from example 1 is added.

Til oppløsningen settes de i tabellen angitte arylcyanater. Folier fremstillet fra oppløsningen undersøkes, under betingel-sene angitt i eksempel 1. The aryl cyanates specified in the table are added to the solution. Foils produced from the solution are examined under the conditions stated in example 1.

Claims (1)

Anvendelse av arylcyanater som stabiliserende middel mot innvirkning av varme og fuktighet i estergruppeholdige polyuretankunststoffer.Use of aryl cyanates as stabilizing agents against the effects of heat and humidity in polyurethane plastics containing ester groups.
NO853761A 1984-11-14 1985-09-25 LIGHTING DEVICE FOR ELECTRIC WELDING DEVICE. NO164522C (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DK540884A DK154481C (en) 1984-11-14 1984-11-14 LIGHTING FOR AN ELECTRIC WELDING APPLIANCE

Publications (3)

Publication Number Publication Date
NO853761L NO853761L (en) 1986-05-15
NO164522B true NO164522B (en) 1990-07-09
NO164522C NO164522C (en) 1990-10-17

Family

ID=8142187

Family Applications (1)

Application Number Title Priority Date Filing Date
NO853761A NO164522C (en) 1984-11-14 1985-09-25 LIGHTING DEVICE FOR ELECTRIC WELDING DEVICE.

Country Status (6)

Country Link
DE (1) DE3527487A1 (en)
DK (1) DK154481C (en)
FR (1) FR2572975A1 (en)
GB (2) GB8527760D0 (en)
NO (1) NO164522C (en)
SE (1) SE8503838L (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3706943A1 (en) * 1987-03-04 1988-09-22 Medtronic Medizinisch Elektron Illuminating device for a hand-held dental instrument
US5054106A (en) * 1988-10-05 1991-10-01 Fortune William S Hot gas soldering system
DE8814574U1 (en) * 1988-11-18 1990-01-04 Effner GmbH, 1000 Berlin Device for suction of liquid media
US6582219B1 (en) * 2000-09-28 2003-06-24 Charles T. Rockwell, Jr. Torch illumination device

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3590232A (en) * 1968-03-27 1971-06-29 Radioptics Inc Annular illuminator for dental tools or the like
US4222375A (en) * 1978-03-10 1980-09-16 Miguel Martinez In vivo illumination system utilizing a cannula with a conical opening allowing a snap-fit with a conical lens and an aperture for flow of fluids and utilizing a housing with a spherical lens for focusing light onto fiber optics
JPS58196172A (en) * 1982-05-12 1983-11-15 Hitachi Ltd Welding device provided with monitor
US4491719A (en) * 1982-12-20 1985-01-01 General Electric Company Light pattern projector especially for welding
DK326383A (en) * 1983-02-16 1984-08-17 Christian Chemnitz LIGHTING FOR A WELDING GUN
DE8306482U1 (en) * 1983-03-07 1983-06-09 Rameder, Nicolai, 8300 Landshut TEXTILE COVER
GB2154930B (en) * 1984-02-28 1988-11-09 Microsurgical Administrative S Forceps

Also Published As

Publication number Publication date
SE8503838D0 (en) 1985-08-16
DK540884A (en) 1986-05-15
NO853761L (en) 1986-05-15
NO164522C (en) 1990-10-17
GB8528038D0 (en) 1985-12-18
DK154481B (en) 1988-11-21
GB8527760D0 (en) 1985-12-18
GB2167700A (en) 1986-06-04
SE8503838L (en) 1986-05-15
GB2167700B (en) 1988-07-13
FR2572975A1 (en) 1986-05-16
DK154481C (en) 1989-06-12
DE3527487A1 (en) 1986-05-15
DK540884D0 (en) 1984-11-14

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