NO147176B - STABILIZATION ELEMENT. - Google Patents

STABILIZATION ELEMENT. Download PDF

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Publication number
NO147176B
NO147176B NO802912A NO802912A NO147176B NO 147176 B NO147176 B NO 147176B NO 802912 A NO802912 A NO 802912A NO 802912 A NO802912 A NO 802912A NO 147176 B NO147176 B NO 147176B
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Norway
Prior art keywords
hydrazine hydrate
amounts
added
fuels
fuel
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Application number
NO802912A
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Norwegian (no)
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NO802912L (en
NO147176C (en
Inventor
Per Chr Sandnaes
Original Assignee
Akers Mek Verksted As
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Akers Mek Verksted As filed Critical Akers Mek Verksted As
Priority to NO802912A priority Critical patent/NO147176C/en
Priority to DK431581A priority patent/DK153750C/en
Priority to SE8105780A priority patent/SE442736B/en
Priority to NLAANVRAGE8104472,A priority patent/NL190546C/en
Priority to GB8129480A priority patent/GB2084529B/en
Publication of NO802912L publication Critical patent/NO802912L/en
Publication of NO147176B publication Critical patent/NO147176B/en
Publication of NO147176C publication Critical patent/NO147176C/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B63SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63BSHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING 
    • B63B43/00Improving safety of vessels, e.g. damage control, not otherwise provided for
    • B63B43/02Improving safety of vessels, e.g. damage control, not otherwise provided for reducing risk of capsizing or sinking
    • B63B43/10Improving safety of vessels, e.g. damage control, not otherwise provided for reducing risk of capsizing or sinking by improving buoyancy
    • B63B43/14Improving safety of vessels, e.g. damage control, not otherwise provided for reducing risk of capsizing or sinking by improving buoyancy using outboard floating members
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B63SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63BSHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING 
    • B63B1/00Hydrodynamic or hydrostatic features of hulls or of hydrofoils
    • B63B1/02Hydrodynamic or hydrostatic features of hulls or of hydrofoils deriving lift mainly from water displacement
    • B63B1/10Hydrodynamic or hydrostatic features of hulls or of hydrofoils deriving lift mainly from water displacement with multiple hulls
    • B63B1/107Semi-submersibles; Small waterline area multiple hull vessels and the like, e.g. SWATH
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B63SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63BSHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING 
    • B63B35/00Vessels or similar floating structures specially adapted for specific purposes and not otherwise provided for
    • B63B35/44Floating buildings, stores, drilling platforms, or workshops, e.g. carrying water-oil separating devices
    • B63B35/4413Floating drilling platforms, e.g. carrying water-oil separating devices

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  • Engineering & Computer Science (AREA)
  • Ocean & Marine Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Civil Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Architecture (AREA)
  • Fluid Mechanics (AREA)
  • Structural Engineering (AREA)
  • Bridges Or Land Bridges (AREA)
  • Furan Compounds (AREA)
  • Luminescent Compositions (AREA)
  • Oscillators With Electromechanical Resonators (AREA)
  • Earth Drilling (AREA)

Description

Fremgangsmåte til å hindre korrosjon av beholdere og ledninger for mineralolje og drivstoffer. Procedure to prevent corrosion of containers and lines for mineral oil and fuels.

Den sterkt økende anvendelse av mineraloljer og drivstoffer på basis av hydrokarboner i næringsliv og industri gjør det nødvendig med en lang lagring resp. opp-bevaring av disse mineraloljer som f. eks. fyringsolje og drivstoffer som f. eks. ben-sin-hydrokarbonene. Hertil anvendes mindre metallbeholdere som alt etter forbruk The strongly increasing use of mineral oils and fuels based on hydrocarbons in business and industry necessitates a long storage or storage of these mineral oils such as heating oil and fuels such as the benzine hydrocarbons. Smaller metal containers are used for this, depending on consumption

oppfylles eller større metallbeholdere som are fulfilled or larger metal containers which

f. eks. fyringsoljetanker, idet sistnevnte e.g. fuel oil tanks, the latter being

ofte lagres stedfast underjordisk eller også often stored permanently underground or also

over jorden. Også i raffineridrift består den over the earth. It also exists in refinery operations

spesielle interesse i å hindre korrosjon i special interest in preventing corrosion i

alle systemer som fører mineraloljer og all systems carrying mineral oils and

drivstoffer på basis av hydrokarboner, spesielt når disse stoffer inneholder vann. fuels based on hydrocarbons, especially when these substances contain water.

Derved foreligger det problem å be-skytte slike metallbeholdere, tanker, ledninger og innretninger mot korrosjon for at Thereby there is a problem of protecting such metal containers, tanks, lines and devices against corrosion so that

såvel metallbeholdere som ledningene ikke metal containers as well as the cables do not

skal ødelegges i løpet av kort tid, og at hel-ler ingen fremmede stoffer kommer inn i must be destroyed within a short time, and that no foreign substances enter

mineraloljen og i drivstoffene. Hertil er det the mineral oil and in the fuels. Here it is

allerede blitt foreslått å gi metallbeholde-ren en katodisk beskyttelse ved hjelp av has already been proposed to give the metal container a cathodic protection by means of

magnesium- eller aluminium-anoder (så-kalte offer-anoder) idet det i tillegg kan magnesium or aluminum anodes (so-called sacrificial anodes) as it can also

påtrykkes et tilsvarende potensial. Ytter-ligere forslag befatter seg med å utstyre a corresponding potential is impressed. Further proposals deal with equipping

metallbeholdernes og metall-ledningenes of metal containers and metal cables

indre flater med korrosjonsfaste overtrekk. inner surfaces with corrosion-resistant covers.

Slike metoder er imidlertid på den ene side However, such methods are on the one hand

kostbare og^på den annen side kompliserte. expensive and, on the other hand, complicated.

For oppberedning av matningsvann har For preparation of feed water has

man ved siden av andre kjemikalier også one next to other chemicals as well

allerede anvendt hydrazin for høytrykks-dampanlegg og varme- og koldtvannled-ninger som antioksyderende stoff. already used hydrazine for high-pressure steam plants and heating and cold water pipes as an antioxidant.

Det er nu blitt funnet en fremgangsmåte til å hindre korrosjon av metallbehol-der og metall-ledninger som opptar mineralolje og drivstoffer på basis av hydrokarboner idet det på enkel måte ved tilsetningen av små mengder av hydrazinhydrat til disse mineraloljer og drivstoffer oppnås en utmerket korrosjonsbeskyttelse. Fordelaktig anvendes mest mulig vannfritt hydrazinhydrat for ikke å bringe noen ekstra vannmengder inn i mineraloljene, resp. for helt å unngå en forurensning med vann. Ved 100 %-ig hydrazinhydrat ligger den mengde som skal anvendes under 0,1 volumprosent referert til den samlede mengde mineralolje eller drivstoff og fortrinnsvis tilsettes 0,01 til 0,001 volumprosent 100 %-ig hydrazinhydrat. Hydrazinhydratet som settes til mineraloljen og drivstoffene er opp-løselig i disse hydrokarboner i de nevnte mengder. Kommer det til en vannutskil-lelse i beholderen eller i lagringstankene så vil det i dette vann også alltid medutskilles en bestemt mengde hydrazinhydrat som da overtar korrosjonsbeskyttelsen i den van-dige fase. A method has now been found to prevent corrosion of metal containers and metal lines that absorb mineral oil and fuels based on hydrocarbons, as excellent corrosion protection is achieved in a simple way by the addition of small amounts of hydrazine hydrate to these mineral oils and fuels. It is advantageous to use as much anhydrous hydrazine hydrate as possible so as not to introduce any additional amounts of water into the mineral oils, resp. to completely avoid a contamination with water. In the case of 100% hydrazine hydrate, the amount to be used is below 0.1 volume percent referred to the total amount of mineral oil or fuel and preferably 0.01 to 0.001 volume percent 100% hydrazine hydrate is added. The hydrazine hydrate that is added to the mineral oil and fuels is soluble in these hydrocarbons in the quantities mentioned. If water is separated in the container or in the storage tanks, a certain amount of hydrazine hydrate will also always be secreted in this water, which then takes over the corrosion protection in the aqueous phase.

For å øke alkaliteten kan det fortrinnsvis anvendes mindre mengder av et organisk amin. Det kan anvendes slike aminer som er fremstillbare økonomisk og har en tilstrekkelig basisitet. Ved substitusjon av In order to increase the alkalinity, smaller amounts of an organic amine can preferably be used. Such amines can be used which can be produced economically and have a sufficient basicity. By substitution of

aminene med kortere eller lengre alkylen- the amines with shorter or longer alkylene-

grupper kan man variere oppløsningsegen- groups, you can vary the resolution properties

skapene med hensyn til deres hydrofobe, the cabinets with respect to their hydrophobicity,

resp. hydrofile egenskaper, og kan således tilpasse korrosjonsbeskyttelsen til det gjeldende anvendelsesområdet. Størrelses- respectively hydrophilic properties, and can thus adapt the corrosion protection to the applicable area of application. Size-

orden av tilsetningen av disse aminer av- order of addition of these amines of

henger av det eventuelle amins basisitet og tilsvarer omtrent hydrazinhydratets til- depends on the basicity of the possible amine and roughly corresponds to the hydrazine hydrate's

setning. sentence.

Som aminer kan det f. eks. anvendes: As amines, it can e.g. used:

1. Alkylaminer, som etylendiamin, dietylamin, dibutylamin, tetrametylendiamin osv., 2. Alkanolaminer, som trietanolamin, butoksamin osv. 3. cykloalifatiske aminer, som cykloheksylamin, cykloheksyldiamin osv. 4. aromatiske aminer, som N,N'-di-metylfenylendiamin osv. og 5. heterocykliske aminer som morfolin osv. 1. Alkylamines, such as ethylenediamine, diethylamine, dibutylamine, tetramethylenediamine, etc., 2. Alkanolamines, such as triethanolamine, butoxamine, etc. 3. Cycloaliphatic amines, such as cyclohexylamine, cyclohexyldiamine, etc. 4. Aromatic amines, such as N,N'-dimethylphenylenediamine etc. and 5. heterocyclic amines like morpholine etc.

Spesielt fordelaktig er tilsetningen av Particularly advantageous is the addition of

slike aminer som i og for seg uten hydrazin-tilsetning har korrosjonshindrende egen- such amines which in and of themselves without the addition of hydrazine have corrosion-inhibiting properties

skaper, f. eks. fenylendiaminer. creator, e.g. phenylenediamines.

Korrosjonsbeskyttelsesmidlet, som selv- The corrosion protection agent, which self-

sagt ved sin virkning er underkastet et forbruk blir ved tilsetningen ifølge frem-gangsmåten, og ved etterfylling av behol- said by its effect is subjected to a consumption becomes by the addition according to the procedure, and by refilling the container

der og ledninger med mineraler og drivstof- there and lines with minerals and fuel

fer på hydrokarbonbasis virksomt kontinu- on a hydrocarbon basis effectively continuously

erlig således at det er gitt en varende korrosjonsbeskyttelse. En slik fremgangsmåte har den store fordel at korrosjonsbeskyttel- honest so that lasting corrosion protection is provided. Such a method has the great advantage that corrosion protection

sen alltid igjen medleveres og beholder- then always again delivered and keep-

resp. tankeierne behøver selv ikke å sørge for korrosjonsbeskyttelsen. Samtidig er det her av viktighet at det 100 %-ige hydraziri- respectively the tank owners themselves do not have to provide the corrosion protection. At the same time, it is important here that the 100% hydraziri-

hydrat som korrosjonsbeskyttelsesmiddel hverken selv eller dets reaksjonsprodukter er stoffer som utøver en hemmende inn-virkning med hensyn til anvendelsen som f. eks. ved fyringsolje og bensinhydrokar- hydrate as a corrosion protection agent neither itself nor its reaction products are substances that exert an inhibitory effect with regard to the application such as e.g. in the case of fuel oil and petrol hydrocar-

boner for Otto-motorer, da det ved den nor- bonuses for Otto engines, as at the nor-

male spaltningsreaksjon av hydrazinet som reaksjonsprodukter oppstår vann og nitro- mal cleavage reaction of the hydrazine as reaction products arise water and nitro-

gen. Eksemplene viser fremstillingen av mineraloljer og drivstoffer som er tilsatt med korrosjonsbeskyttelsesmiddel. gen. The examples show the production of mineral oils and fuels which have been added with a corrosion protection agent.

Eksempel 1: Example 1:

Til 1000 liter av en lett fyringsolje eller For 1000 liters of a light heating oil or

et dieseldrivstoff setter man 100 ml 100 %- a diesel fuel, you put 100 ml of 100%-

ig hydrazinhydrat. Tildoseringen foregår ved hjelp av en doseringspumpe i en trans-portledning for oljen. ig hydrazine hydrate. Dosing takes place using a dosing pump in a transport line for the oil.

Eksempel 2: Example 2:

Til 1000 liter motorbensin settes 20 ml Add 20 ml to 1000 liters of motor petrol

100 %-ig hydrazinhydrat og blandingen gjennomrøres godt inntil det oppstår en klar oppløsning. 100% hydrazine hydrate and the mixture is thoroughly stirred until a clear solution is formed.

Eksempel 3: Example 3:

I en tung fyringsolje tildoseres det i transportledningen til tanken og i den opp-varmede olje en blanding av 1 del hydrazinhydrat og 1 del cykloheksylamin i en mengde av 30 ml/t. In a heavy fuel oil, a mixture of 1 part hydrazine hydrate and 1 part cyclohexylamine is dosed in the transport line to the tank and in the heated oil in a quantity of 30 ml/h.

Eksempel 4: Example 4:

For å unngå korrosjon i kraftstof f tan- To avoid corrosion in fuel f tan-

ker og -ledninger blir det til kraftstoffet best med en gang i raffineriet satt en mengde på 250 g N,H,. H20 + 250 g mor- kers and lines, it is best to add a quantity of 250 g of N,H, to the fuel immediately in the refinery. H20 + 250 g mother-

folin pr. tonn. Tilsetningsmengden er her å foil per ton. The amount of addition is here to

velge noe høyere når kraftstoffet inntil endelig avfylling luftes meget sterkt. For anvendelse av kraftstoffet har en slik til- choose something higher when the fuel is heavily aerated until final filling. For the use of the fuel, such an

setning ingen innflydelse, og det er da bare for lagringen det kommer en økning av oksydasjonsbestandigheten. sentence no influence, and it is then only for storage that there is an increase in oxidation resistance.

Eksempel 5: Example 5:

Ved ifyIling av fyringsolje i en lag-ringstank tilsettes det pr. m<3> fyringsolje 100 g N2H4 . H,0 + 150 g cykloheksyldiamin. When filling fuel oil in a storage tank, it is added per m<3> fuel oil 100 g N2H4 . H,0 + 150 g of cyclohexyldiamine.

Dermed sikres en jevn gjennomblanding This ensures even mixing

med fyringsoljen og følgelig en korrosj ons-beskyttelse for tanken. with the fuel oil and consequently a corrosion protection for the tank.

Eksempel 6: Example 6:

Ved destillasjonen av råolje settes det During the distillation of crude oil, it is set

for å unngå korrosjon i anlegget til den tilrennende råolje best ved hjelp av en doseringspumpe kontinuerlig en tilsvarende blanding av hydrazin og trietanolamin. Herunder må det påsees at den siste tilset- in order to avoid corrosion in the plant to the incoming crude oil best by means of a dosing pump continuously a corresponding mixture of hydrazine and triethanolamine. Below, it must be ensured that the last addi-

ning sikkert nøytraliserer råoljens sure be-standdeler og et slikt overskudd dessuten kommer til anvendelse at også dampene i forbindelse med vann reagerer alkalisk og heri også er påvisbart et overskudd av N2H|. På denne måte er det mulig å holde rørledninger, varmeutvekslere og kjølere ytterliggående korrosj onsf rie. Trietanol- ning certainly neutralizes the acid components of the crude oil and such an excess also comes into use that the vapors in connection with water also react alkaline and here too an excess of N2H| is demonstrable. In this way, it is possible to keep pipelines, heat exchangers and coolers extremely corrosion-free. triethanol

aminet lar seg erstatte med fenylendiami- the amine can be replaced by phenylenediami-

ner f. eks. N,N'-dimetyl-fenylendiamin. down e.g. N,N'-dimethyl-phenylenediamine.

Claims (6)

1. Fremgangsmåte til å hindre korro-1. Procedure to prevent corrosion sjon av beholdere og ledninger for mineralolje og drivstoffer på basis av hydrokarboner, resp. av innretninger til raffineridrift ved tilsetning av et korrosj onsbeskyttelses-middel, karakterisert ved at man til mineraloljene og drivstoffene setter mindre mengder av høyprosentig hydrazinhydrat. tion of containers and lines for mineral oil and fuels based on hydrocarbons, resp. of facilities for refinery operation by adding a corrosion protection agent, characterized by adding smaller amounts of high-percentage hydrazine hydrate to the mineral oils and fuels. 2. Fremgangsmåte ifølge påstand 1, karakterisert ved at man tilsetter 100 %-ig hydrazinhydrat i mengder på mindre enn 0,1 volumprosent, fortrinnsvis i mengder fra 0,001 til 0,01 volumprosent, referert til den samlede mengde mineralolje resp. drivstoff. 2. Method according to claim 1, characterized in that 100% hydrazine hydrate is added in amounts of less than 0.1 volume percent, preferably in amounts from 0.001 to 0.01 volume percent, referred to the total amount of mineral oil resp. fuel. 3. Fremgangsmåte ifølge påstand 1 og 2, karakterisert ved at det tilsettes en blanding av høyprosentig hydrazinhydrat og et organisk amin. 3. Process according to claims 1 and 2, characterized in that a mixture of high percentage hydrazine hydrate and an organic amine is added. 4. Fremgangsmåte ifølge påstand 3, karakterisert ved at det anvendes omtrent like mengder hydrazinhydrat og amin. 4. Process according to claim 3, characterized in that approximately equal amounts of hydrazine hydrate and amine are used. 5. Fremgangsmåte ifølge påstand 3 og 4, karakterisert ved at det tilsettes en blanding av høyprosentig hydrazinhydrat og dietylamin, dibutylamin, tetrametylendiamin, trietanolamin, butoksamin, cykloheksylamin, fenylendiaminer eller morfolin. 5. Process according to claims 3 and 4, characterized in that a mixture of high percentage hydrazine hydrate and diethylamine, dibutylamine, tetramethylenediamine, triethanolamine, butoxamine, cyclohexylamine, phenylenediamines or morpholine is added. 6. Fremgangsmåte ifølge påstand 2, karakterisert ved at man i mineraloljer og drivstoffer på basis av hydrokarboner setter en blanding av 100 %-ig hydrazinhydrat og et organisk amin i mengder på mindre enn 0,1 volumprosent, referert til den samlede mengde mineralolje resp. drivstoff.6. Method according to claim 2, characterized in that a mixture of 100% hydrazine hydrate and an organic amine is added to mineral oils and hydrocarbon-based fuels in amounts of less than 0.1 percent by volume, referred to the total amount of mineral oil or fuel.
NO802912A 1980-10-01 1980-10-01 STABILIZATION ELEMENT. NO147176C (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
NO802912A NO147176C (en) 1980-10-01 1980-10-01 STABILIZATION ELEMENT.
DK431581A DK153750C (en) 1980-10-01 1981-09-29 STABILIZATION ELEMENT
SE8105780A SE442736B (en) 1980-10-01 1981-09-30 stabilizing members
NLAANVRAGE8104472,A NL190546C (en) 1980-10-01 1981-09-30 Stabilizing element for a floating platform construction of the semi-submersible type.
GB8129480A GB2084529B (en) 1980-10-01 1981-09-30 Stabilizing element

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NO802912A NO147176C (en) 1980-10-01 1980-10-01 STABILIZATION ELEMENT.

Publications (3)

Publication Number Publication Date
NO802912L NO802912L (en) 1982-04-02
NO147176B true NO147176B (en) 1982-11-08
NO147176C NO147176C (en) 1983-02-16

Family

ID=19885682

Family Applications (1)

Application Number Title Priority Date Filing Date
NO802912A NO147176C (en) 1980-10-01 1980-10-01 STABILIZATION ELEMENT.

Country Status (5)

Country Link
DK (1) DK153750C (en)
GB (1) GB2084529B (en)
NL (1) NL190546C (en)
NO (1) NO147176C (en)
SE (1) SE442736B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE438300B (en) * 1983-09-07 1985-04-15 Goetaverken Arendal Ab DEVICE AT SEMISUBMERSIBLE OFFSHORE DRIVING DEVICE DEVICE AT SEMISUBMERSIBLE OFFSHORE DRIVING COST

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3610193A (en) * 1969-07-29 1971-10-05 Bethelehem Steel Corp Offshore drilling structure
USRE29478E (en) * 1971-05-03 1977-11-22 Santa Fe International Corporation Single column semisubmersible drilling vessel
US3837309A (en) * 1971-06-17 1974-09-24 Offshore Technology Corp Stably buoyed floating offshore device
US3880102A (en) * 1974-02-19 1975-04-29 Offshore Technology Corp Method and apparatus for offshore submersible oil storage and drilling

Also Published As

Publication number Publication date
NL190546C (en) 1994-04-18
NL190546B (en) 1993-11-16
GB2084529B (en) 1984-06-27
DK153750C (en) 1989-01-30
DK153750B (en) 1988-08-29
GB2084529A (en) 1982-04-15
SE8105780L (en) 1982-04-02
NO802912L (en) 1982-04-02
SE442736B (en) 1986-01-27
NL8104472A (en) 1982-05-03
NO147176C (en) 1983-02-16
DK431581A (en) 1982-04-02

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