NO143072B - INPUT CASE DEVICE FOR ADDING MASS TO A FORM - Google Patents
INPUT CASE DEVICE FOR ADDING MASS TO A FORM Download PDFInfo
- Publication number
- NO143072B NO143072B NO4120/73A NO412073A NO143072B NO 143072 B NO143072 B NO 143072B NO 4120/73 A NO4120/73 A NO 4120/73A NO 412073 A NO412073 A NO 412073A NO 143072 B NO143072 B NO 143072B
- Authority
- NO
- Norway
- Prior art keywords
- methylcoumarin
- polyamide
- adding mass
- case device
- input case
- Prior art date
Links
- 239000004952 Polyamide Substances 0.000 claims description 11
- 229920002647 polyamide Polymers 0.000 claims description 11
- -1 8-methylamino-4-methylcoumarin Chemical compound 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 8
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N benzo-alpha-pyrone Natural products C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 claims description 7
- 235000001671 coumarin Nutrition 0.000 claims description 7
- 150000004775 coumarins Chemical class 0.000 claims description 7
- 229960000956 coumarin Drugs 0.000 claims description 5
- 230000000694 effects Effects 0.000 claims description 4
- 239000003381 stabilizer Substances 0.000 claims description 4
- 230000000087 stabilizing effect Effects 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- AFYCEAFSNDLKSX-UHFFFAOYSA-N coumarin 460 Chemical compound CC1=CC(=O)OC2=CC(N(CC)CC)=CC=C21 AFYCEAFSNDLKSX-UHFFFAOYSA-N 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 239000011541 reaction mixture Substances 0.000 claims description 2
- 239000007858 starting material Substances 0.000 claims description 2
- NDLFZLPQECAGEP-UHFFFAOYSA-N 7-(butylamino)-4-methylchromen-2-one Chemical compound CC1=CC(=O)OC2=CC(NCCCC)=CC=C21 NDLFZLPQECAGEP-UHFFFAOYSA-N 0.000 claims 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- LKJDPYZBJFUZNS-UHFFFAOYSA-N 4-methyl-7-(methylamino)chromen-2-one Chemical compound CC1=CC(=O)OC2=CC(NC)=CC=C21 LKJDPYZBJFUZNS-UHFFFAOYSA-N 0.000 description 1
- CXYPXORWEBRUHN-UHFFFAOYSA-N 6-(diethylamino)chromen-2-one Chemical compound O1C(=O)C=CC2=CC(N(CC)CC)=CC=C21 CXYPXORWEBRUHN-UHFFFAOYSA-N 0.000 description 1
- GLPFKLSDVORDDT-UHFFFAOYSA-N 6-(methylamino)chromen-2-one Chemical compound O1C(=O)C=CC2=CC(NC)=CC=C21 GLPFKLSDVORDDT-UHFFFAOYSA-N 0.000 description 1
- QXAMGWKESXGGNV-UHFFFAOYSA-N 7-(diethylamino)-1-benzopyran-2-one Chemical compound C1=CC(=O)OC2=CC(N(CC)CC)=CC=C21 QXAMGWKESXGGNV-UHFFFAOYSA-N 0.000 description 1
- JTFIEIKSYKBZHT-UHFFFAOYSA-N 7-(dimethylamino)chromen-2-one Chemical compound C1=CC(=O)OC2=CC(N(C)C)=CC=C21 JTFIEIKSYKBZHT-UHFFFAOYSA-N 0.000 description 1
- XSZAYPUIRCPEPI-UHFFFAOYSA-N 7-(ethylamino)-3-methylchromen-2-one Chemical compound CC=1C(OC2=CC(=CC=C2C1)NCC)=O XSZAYPUIRCPEPI-UHFFFAOYSA-N 0.000 description 1
- LQDAIRJFZNQMNK-UHFFFAOYSA-N 7-(ethylamino)chromen-2-one Chemical compound C1=CC(=O)OC2=CC(NCC)=CC=C21 LQDAIRJFZNQMNK-UHFFFAOYSA-N 0.000 description 1
- BZCQGAVADFKHAF-UHFFFAOYSA-N 7-(methylamino)chromen-2-one Chemical compound C1=CC(=O)OC2=CC(NC)=CC=C21 BZCQGAVADFKHAF-UHFFFAOYSA-N 0.000 description 1
- WGWXUTNUPOLTAD-UHFFFAOYSA-N 8-(methylamino)chromen-2-one Chemical compound CNC=1C=CC=C2C=CC(OC12)=O WGWXUTNUPOLTAD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F1/00—Wet end of machines for making continuous webs of paper
- D21F1/02—Head boxes of Fourdrinier machines
- D21F1/028—Details of the nozzle section
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F1/00—Wet end of machines for making continuous webs of paper
- D21F1/02—Head boxes of Fourdrinier machines
Landscapes
- Paper (AREA)
- Perforating, Stamping-Out Or Severing By Means Other Than Cutting (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Developing Agents For Electrophotography (AREA)
- Graft Or Block Polymers (AREA)
- Discharge Heating (AREA)
Description
Fremgangsmåte til stabilisering av syntetiske polyamider. Process for stabilizing synthetic polyamides.
Ved fremstilling av tekstilmaterialer og In the manufacture of textile materials and
andre formede gjenstander fra polyamider på-virker utsettelse for varme og lys i mange tilfelle i en alvorlig grad fibrenes bruddfast-het og forlengelse, samt også farven av mange ferdige gjenstander. For å forbedre polyami-ders motstandsdyktighet mot denne avbyg-ning ved innvirkning av lys og varme, er der tidligere anvendt forskjellige midler for å other shaped objects from polyamides exposure to heat and light in many cases affects the breaking strength and elongation of the fibers to a serious extent, as well as the color of many finished objects. In order to improve the resistance of polyamides to this degradation when exposed to light and heat, various means have previously been used to
stabilisere polyamidene, slik at de forblir ufor-andret etter at de er utsatt for varme og lys eller andre innvirkninger som kan frembringe uønskede forandringer i deres egenskaper. stabilize the polyamides, so that they remain unchanged after they are exposed to heat and light or other influences that can produce unwanted changes in their properties.
Ved hjelp av foreliggende oppfinnelse By means of the present invention
skaffes der en fremgangsmåte til stabilisering av syntetiske lineære polyamider mot innvirkning av varme, lys, fuktighet og oxygen, ved tilsetning av stabiliseringsmidler til de polya-mid-dannende utgangsmaterialer, den polya-mid-dannende reaksjonsblanding eller den varme polyamidsmelte. a method for stabilizing synthetic linear polyamides against the effects of heat, light, moisture and oxygen is obtained there, by adding stabilizers to the polyamide-forming starting materials, the polyamide-forming reaction mixture or the hot polyamide melt.
Det karakteristiske hovedtrekk ved fremgangsmåten ifølge oppfinnelsen er at der som stabiliseringsmiddel anvendes et alkylaminsubstituert cumarin i en mengde fra 0,05 til 2 vektprosent av reaksjonskomponentene. The characteristic main feature of the method according to the invention is that an alkylamine-substituted coumarin is used as stabilizer in an amount of from 0.05 to 2% by weight of the reaction components.
Polyamider som med fordel kan stabili-seres ved fremgangsmåten ifølge foreliggende oppfinnelse, er beskrevet f.eks. i U.S. patent-skrifter nr. 2 071 250, 2 071 253 og 2 130 948. Spesielt kommer to typer polyamider i be-traktning, nemlig de som kan fåes fra poly-meriserbare monoaminomonocarboxylsyrer og deres amiddannede derivater, såsom f.eks. Polyamides which can advantageously be stabilized by the method according to the present invention are described, e.g. in the U.S. patent documents Nos. 2,071,250, 2,071,253 and 2,130,948. In particular, two types of polyamides come into consideration, namely those which can be obtained from polymerizable monoaminomonocarboxylic acids and their amide-formed derivatives, such as e.g.
caprolactam, og de som kan fåes ved omset-ning av egnede diaminer og egnede dicar- caprolactam, and those which can be obtained by the reaction of suitable diamines and suitable dicar-
boxylsyrer eller amid-dannende derivater av tobasiske dicarboxylsyrer. carboxylic acids or amide-forming derivatives of dibasic dicarboxylic acids.
Eksempler på alkylaminsubstituerte cu-mariner som kan anvendes ved fremgangsmåten ifølge oppfinnelsen, er 7-methylaminocumarin, 7-dimethylaminocumarin, 7-ethylaminocumarin, 7-diethylaminocumarin, 8-methylaminocumarin, 8-dimethylaminocumarin, 8-ethylaminocumarin, 8-diethylaminocumarin, 7-propylaminocumarin, 8-propylaminocumarin, 7-butylaminocumarin, 8-butylaminocumarin, 7-diisopropylaminocumarin, 6-methylaminocumarin og 6-diethylaminocumarin. Anvendbare er likeledes 7-methylamino-4-methylcumarin, 7-ethylamino-3-methylcumarin, 8-ethylamino-4-methyl-cumarin og 7-diethylamino-4-methylcumarin. Examples of alkylamine-substituted coumarins that can be used in the method according to the invention are 7-methylaminocoumarin, 7-dimethylaminocoumarin, 7-ethylaminocoumarin, 7-diethylaminocoumarin, 8-methylaminocoumarin, 8-dimethylaminocoumarin, 8-ethylaminocoumarin, 8-diethylaminocoumarin, 7-propylaminocoumarin , 8-propylaminocoumarin, 7-butylaminocoumarin, 8-butylaminocoumarin, 7-diisopropylaminocoumarin, 6-methylaminocoumarin and 6-diethylaminocoumarin. Also usable are 7-methylamino-4-methylcoumarin, 7-ethylamino-3-methylcoumarin, 8-ethylamino-4-methylcoumarin and 7-diethylamino-4-methylcoumarin.
Den mengde alkylamino-substituert cumarin som kan tilsettes ifølge oppfinnelsen er fra 0,05 til 2 vektprosent. Den nøyaktige mengde alkylaminosubstituert cumarin som er nødvendig for å oppnå den ønskede stabilisering i et gitt tilfelle, kan en fagmann bestem-me ved å utføre et enkelt forsøk. The amount of alkylamino-substituted coumarin that can be added according to the invention is from 0.05 to 2% by weight. The exact amount of alkylamino-substituted coumarin necessary to achieve the desired stabilization in a given case can be determined by a person skilled in the art by performing a simple experiment.
De alkylaminosubstituerte cumåriner som anvendes, tilsettes til polyamidene på et hvil-ket som helst passende trinn før fullførelsen av polymeriseringsreaksjonen. Herved inn-blandes stabiliseringsmidlet i polymerisatet og forblir således ikke bare på dets overflate. Herved oppnår man en meget langvarigere stabiliserende virkning enn hva der er mulig bare ved et ovetrekk på overflaten. The alkylamino substituted coumarins used are added to the polyamides at any convenient stage prior to completion of the polymerization reaction. In this way, the stabilizer is mixed into the polymer and thus does not just remain on its surface. In this way, a much longer-lasting stabilizing effect is achieved than is possible simply by overcoating the surface.
I det følgende beskrives som eksempel en utførelsesform for oppfinnelsen. In the following, an embodiment of the invention is described as an example.
Eksempel. Example.
En nylpnsaltoppløsning av omtrentlig ekvimolekylære mengder hexamethylen-diamin og adipinsyre ble fremstillet. Oppløsningen ble tilsatt 0,1 vektprosent 7-diethylamino-4-methylcumarin, hvorpå der ble fremstillet fibre av oppløsningen. Resultatene er oppført i nedenstående tabell. A sodium salt solution of approximately equimolar amounts of hexamethylenediamine and adipic acid was prepared. 0.1% by weight of 7-diethylamino-4-methylcoumarin was added to the solution, after which fibers were produced from the solution. The results are listed in the table below.
De resultater som ble funnet ved utset- The results found at exposure
telse for lysets innvirkning, er basert på 100 SFH (Standard Fade-O-meter-timer) i et Atlas Fade-O-Meter under anvendelse av de metoder som anbefales av «Technical Manual of the American Association of Textile Che-mists and Colorists», Howes Publishing Co., 44 E. 23rd Street, New York City (1957). calculation for the effect of light is based on 100 SFH (Standard Fade-O-meter-hours) in an Atlas Fade-O-Meter using the methods recommended by the "Technical Manual of the American Association of Textile Chemists and Colorists », Howes Publishing Co., 44 E. 23rd Street, New York City (1957).
Målinger angående innvirkning av varme er basert på 8 timer ved 200 °C i et varmeskap med varm luft. Measurements regarding the effect of heat are based on 8 hours at 200 °C in a hot air oven.
Claims (2)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US303972A US3888729A (en) | 1972-11-06 | 1972-11-06 | Papermaking machine headbox slice chamber containing pivotable thin rigid plates with flexible elements attached thereto |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| NO143072B true NO143072B (en) | 1980-09-01 |
| NO143072C NO143072C (en) | 1980-12-10 |
Family
ID=23174492
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO734120A NO143072C (en) | 1972-11-06 | 1973-10-25 | INPUT CASE DEVICE FOR ADDING MASS TO A FORM |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US3888729A (en) |
| AR (1) | AR199318A1 (en) |
| BE (1) | BE806590R (en) |
| BR (1) | BR7308640D0 (en) |
| CA (1) | CA980156A (en) |
| CH (1) | CH576554A5 (en) |
| DE (1) | DE2354426C3 (en) |
| ES (1) | ES420267A1 (en) |
| FR (1) | FR2205603B2 (en) |
| GB (1) | GB1443540A (en) |
| IT (1) | IT1054147B (en) |
| NL (1) | NL157067B (en) |
| NO (1) | NO143072C (en) |
| SE (1) | SE403917B (en) |
| ZA (1) | ZA738504B (en) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4133715A (en) * | 1977-03-29 | 1979-01-09 | Beloit Corporation | Headbox and holders for floating slice chamber dividers |
| FI771209A (en) * | 1977-04-15 | 1978-10-16 | Valmet Oy | PAPER MUSHROOMS FOR THE PULP OF THE PULP MUSCLE |
| US4128455A (en) * | 1977-05-20 | 1978-12-05 | Beloit Corporation | Headbox trailing element mounting and method |
| FI58364C (en) * | 1977-07-13 | 1981-01-12 | Tampella Oy Ab | PROCEDURE FOR BANFORMING MACHINES FOR FRAMSTAELLNING AV EN TVAO- ELLER FLERSKIKTIG FIBERBANA |
| US4184913A (en) * | 1978-03-31 | 1980-01-22 | Western Electric Company, Incorporated | Methods of simultaneously covering each of a plurality of elongated materials with uniformly weighted pulp insulation |
| US4224105A (en) * | 1979-03-02 | 1980-09-23 | Western Electric Company, Inc. | Apparatus for simultaneously covering each of a plurality of elongated materials with uniformly weighted pulp insulation |
| US4340623A (en) * | 1980-12-08 | 1982-07-20 | Beloit Corporation | High speed size press |
| US4517056A (en) * | 1983-12-01 | 1985-05-14 | Beloit Corporation | Slice lip adjustment |
| GB8711330D0 (en) * | 1987-05-14 | 1987-06-17 | Beloit Corp | Headbox |
| US4885060A (en) * | 1988-02-01 | 1989-12-05 | Westvaco Corporation | Papermachine headbox profiling bar with fluid discharge orifices along its length |
| US5000227A (en) * | 1988-02-01 | 1991-03-19 | Westvaco Corporation | Pressurized fluid carrier conduit connection |
| US4981587A (en) * | 1988-09-13 | 1991-01-01 | Electric Power Research Institute, Inc. | Sieve with adjustable throat mechanism discharge |
| DE4136530A1 (en) * | 1991-11-06 | 1993-05-13 | Escher Wyss Gmbh | FABRIC DRAIN |
| FI112808B (en) * | 1993-10-29 | 2004-01-15 | Metso Paper Inc | Multilayer headbox |
| CN1151196A (en) * | 1994-05-02 | 1997-06-04 | 墨西哥斯姆尔菲特纸板纸张有限公司 | Inclined planar former for producing paper sheet under the felt for the production of multilayer or single-layer paper |
| DE4435860C2 (en) * | 1994-10-07 | 1998-03-19 | Voith Gmbh J M | Headbox for creating a multilayer paper web |
| WO1998050625A1 (en) * | 1997-05-09 | 1998-11-12 | Beloit Technologies, Inc. | A holder device for holding a trailing element |
| WO1998051856A1 (en) * | 1997-05-12 | 1998-11-19 | Beloit Technologies, Inc. | A trailing element device |
| US6146500A (en) * | 1998-06-19 | 2000-11-14 | Kimberly-Clark Worldwide, Inc. | Suction breast roll former and method, with flexible headbox roof |
| DE19930592A1 (en) | 1999-07-02 | 2001-01-11 | Voith Paper Patent Gmbh | Headbox |
| DE19946756A1 (en) * | 1999-09-29 | 2001-04-12 | Voith Paper Patent Gmbh | Stock inlet for a papermaking or cardboard prodn machine has a blade inserted between the rows of turbulence tubes with a lateral zone of a reduced cross section to reduce force peaks on starting/stopping the stock inlet |
| DE19962709A1 (en) * | 1999-12-23 | 2001-06-28 | Voith Paper Patent Gmbh | Head box of papermaking machine, comprises improved hinge joints between lamellae and turbulence-generating sections |
| JP2003532809A (en) | 2000-05-10 | 2003-11-05 | メッツォ ペーパー カルルスタッド アクチボラグ | Head box, vane mounting device and vane mounting method |
| US6521095B1 (en) | 2002-02-05 | 2003-02-18 | Metso Paper, Inc. | Composite vane hinge in a headbox |
| DE10211178A1 (en) * | 2002-03-14 | 2003-09-25 | Voith Paper Patent Gmbh | Laminated outlet for production of sandwich plaster board or corrugated cardboard has bends in channel sidewalls to jet outlet |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3092540A (en) * | 1960-11-09 | 1963-06-04 | Beloit Iron Works | Method and apparatus for distributing particle suspensions |
| US3607625A (en) * | 1968-01-17 | 1971-09-21 | Beloit Corp | Headbox |
| US3619362A (en) * | 1969-02-03 | 1971-11-09 | Beloit Corp | Papermaking headbox stock nozzle with liquid jacket means for elimination of stock exposure to air |
| CA936722A (en) * | 1970-08-31 | 1973-11-13 | A. Betley Raymond | Headbox slice chamber |
-
1972
- 1972-11-06 US US303972A patent/US3888729A/en not_active Expired - Lifetime
-
1973
- 1973-10-16 GB GB4819773A patent/GB1443540A/en not_active Expired
- 1973-10-24 FR FR7338998A patent/FR2205603B2/fr not_active Expired
- 1973-10-25 NO NO734120A patent/NO143072C/en unknown
- 1973-10-26 BE BE137130A patent/BE806590R/en not_active IP Right Cessation
- 1973-10-26 CA CA184,359A patent/CA980156A/en not_active Expired
- 1973-10-26 CH CH1514373A patent/CH576554A5/xx not_active IP Right Cessation
- 1973-10-30 NL NL7314912.A patent/NL157067B/en not_active IP Right Cessation
- 1973-10-31 DE DE2354426A patent/DE2354426C3/en not_active Expired
- 1973-10-31 AR AR250792A patent/AR199318A1/en active
- 1973-10-31 IT IT30799/73A patent/IT1054147B/en active
- 1973-10-31 SE SE7314782A patent/SE403917B/en unknown
- 1973-11-05 ES ES420267A patent/ES420267A1/en not_active Expired
- 1973-11-05 ZA ZA738504A patent/ZA738504B/en unknown
- 1973-11-06 BR BR8640/73A patent/BR7308640D0/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA980156A (en) | 1975-12-23 |
| BE806590R (en) | 1974-02-15 |
| BR7308640D0 (en) | 1974-09-05 |
| IT1054147B (en) | 1981-11-10 |
| DE2354426C3 (en) | 1982-03-11 |
| NL157067B (en) | 1978-06-15 |
| NO143072C (en) | 1980-12-10 |
| US3888729A (en) | 1975-06-10 |
| GB1443540A (en) | 1976-07-21 |
| ZA738504B (en) | 1974-09-25 |
| ES420267A1 (en) | 1976-03-01 |
| AR199318A1 (en) | 1974-08-23 |
| NL7314912A (en) | 1974-05-08 |
| DE2354426A1 (en) | 1974-05-30 |
| FR2205603A2 (en) | 1974-05-31 |
| CH576554A5 (en) | 1976-06-15 |
| SE403917B (en) | 1978-09-11 |
| FR2205603B2 (en) | 1979-10-05 |
| DE2354426B2 (en) | 1981-07-30 |
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