NO124877B - - Google Patents
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- Publication number
- NO124877B NO124877B NO164215A NO16421566A NO124877B NO 124877 B NO124877 B NO 124877B NO 164215 A NO164215 A NO 164215A NO 16421566 A NO16421566 A NO 16421566A NO 124877 B NO124877 B NO 124877B
- Authority
- NO
- Norway
- Prior art keywords
- styrene
- weight
- methyl methacrylate
- parts
- butadiene
- Prior art date
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 37
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 25
- 239000000203 mixture Substances 0.000 claims description 21
- 239000004800 polyvinyl chloride Substances 0.000 claims description 21
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 18
- 229920001971 elastomer Polymers 0.000 claims description 17
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 16
- 229920001577 copolymer Polymers 0.000 claims description 12
- 239000003431 cross linking reagent Substances 0.000 claims description 11
- 229920000126 latex Polymers 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 238000006116 polymerization reaction Methods 0.000 claims description 9
- 229920000578 graft copolymer Polymers 0.000 claims description 8
- 239000004816 latex Substances 0.000 claims description 8
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims description 7
- 229920007962 Styrene Methyl Methacrylate Polymers 0.000 claims description 5
- 239000000806 elastomer Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 229920001328 Polyvinylidene chloride Polymers 0.000 claims description 3
- 238000005452 bending Methods 0.000 claims description 3
- 239000005033 polyvinylidene chloride Substances 0.000 claims description 3
- 239000004971 Cross linker Substances 0.000 claims 1
- -1 dimethyl acrylate Chemical compound 0.000 claims 1
- 229920005989 resin Polymers 0.000 description 28
- 239000011347 resin Substances 0.000 description 28
- 239000005060 rubber Substances 0.000 description 13
- 239000000178 monomer Substances 0.000 description 12
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 239000002245 particle Substances 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 6
- 229920003023 plastic Polymers 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000004132 cross linking Methods 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 239000011342 resin composition Substances 0.000 description 3
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 description 2
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
- ADFPJHOAARPYLP-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;styrene Chemical compound COC(=O)C(C)=C.C=CC1=CC=CC=C1 ADFPJHOAARPYLP-UHFFFAOYSA-N 0.000 description 2
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 2
- 238000005185 salting out Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- VDYWHVQKENANGY-UHFFFAOYSA-N 1,3-Butyleneglycol dimethacrylate Chemical compound CC(=C)C(=O)OC(C)CCOC(=O)C(C)=C VDYWHVQKENANGY-UHFFFAOYSA-N 0.000 description 1
- LTHJXDSHSVNJKG-UHFFFAOYSA-N 2-[2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOCCOC(=O)C(C)=C LTHJXDSHSVNJKG-UHFFFAOYSA-N 0.000 description 1
- LXAHHHIGZXPRKQ-UHFFFAOYSA-N 5-fluoro-2-methylpyridine Chemical compound CC1=CC=C(F)C=N1 LXAHHHIGZXPRKQ-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- HTEAGOMAXMOFFS-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C HTEAGOMAXMOFFS-UHFFFAOYSA-N 0.000 description 1
- 150000005673 monoalkenes Chemical class 0.000 description 1
- 229910000096 monohydride Inorganic materials 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000012254 powdered material Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
- C08F279/06—Vinyl aromatic monomers and methacrylates as the only monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4803665 | 1965-08-09 | ||
JP665266 | 1966-02-05 | ||
JP665366 | 1966-02-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
NO124877B true NO124877B (en, 2012) | 1972-06-19 |
Family
ID=27277265
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO164215A NO124877B (en, 2012) | 1965-08-09 | 1966-08-08 |
Country Status (10)
Country | Link |
---|---|
US (1) | US3671610A (en, 2012) |
BE (1) | BE685172A (en, 2012) |
CH (1) | CH472445A (en, 2012) |
DE (1) | DE1620956C3 (en, 2012) |
DK (1) | DK134860B (en, 2012) |
GB (1) | GB1159689A (en, 2012) |
NL (1) | NL6611179A (en, 2012) |
NO (1) | NO124877B (en, 2012) |
SE (1) | SE336462B (en, 2012) |
SU (1) | SU489344A3 (en, 2012) |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1404211A (en) * | 1971-10-07 | 1975-08-28 | Kureha Chemical Ind Co Ltd | Process for producing vinyl chloride resin composition |
JPS5029874B2 (en, 2012) * | 1971-12-29 | 1975-09-26 | ||
US3922320A (en) * | 1973-05-21 | 1975-11-25 | Tenneco Chem | Impact-resistant vinyl halide resin compositions containing a styrene-butadiene-alkyl methacrylate polymer and a styrene-acrylonitrile copolymer |
JPS5427383B2 (en, 2012) * | 1973-06-16 | 1979-09-10 | ||
US4115478A (en) * | 1974-11-04 | 1978-09-19 | Richardson Corporation | High impact polymer and process for its production |
CA1062390A (en) * | 1975-08-11 | 1979-09-11 | William Steffancin | Amorphous polyester graft polymer alloys |
US4133788A (en) * | 1978-01-23 | 1979-01-09 | Borg-Warner Corporation | Polymer latex which is cross-linked with a dialkyl tin diacrylate in the preparation of grafted copolymers |
JPS5817528B2 (ja) * | 1978-04-13 | 1983-04-07 | 呉羽化学工業株式会社 | グラフト共重合体の製造法 |
US4659766A (en) * | 1983-12-19 | 1987-04-21 | Borg-Warner Chemicals, Inc. | Graft copolymer - plasticized PVC blends as thermoplastic elastomers |
US4721757A (en) * | 1984-11-08 | 1988-01-26 | Rohm And Haas Company | Vinyl monomer compositions with accelerated surface cure |
US5177128A (en) * | 1985-07-10 | 1993-01-05 | Sequa Chemicals, Inc. | Paper coating composition |
US5169884A (en) * | 1985-07-10 | 1992-12-08 | Sequa Chemicals, Inc. | Coating compositions |
US5190997A (en) * | 1985-07-10 | 1993-03-02 | Sequa Chemicals, Inc. | Adhesive composition |
US4616057A (en) * | 1985-07-10 | 1986-10-07 | Sun Chemical Corporation | Polymer emulsion containing an interpenetrating polymer network |
US4686260A (en) * | 1985-07-10 | 1987-08-11 | Sun Chemical Corporation | Printing ink composition |
US5237004A (en) * | 1986-11-18 | 1993-08-17 | Rohm And Haas Company | Thermoplastic and thermoset polymer compositions |
US4942086A (en) * | 1988-09-09 | 1990-07-17 | National Starch And Chemical Investment Holding Corporation | Two-stage heat resistant binders for nonwovens |
US5391608A (en) * | 1989-04-26 | 1995-02-21 | National Starch And Chemical Investment Holding Corporation | Woodworking adhesives based on multistage emulsion polymer |
US5294676A (en) * | 1989-05-09 | 1994-03-15 | Kuraray Co., Ltd. | Methacrylic resin compositions with improved tacky adhesion and method for preparation thereof |
US5118562A (en) * | 1990-09-24 | 1992-06-02 | Minnesota Mining And Manufacturing Co. | Vibration damper having extended temperature range and low temperature shock resistance |
US5268430A (en) * | 1991-09-16 | 1993-12-07 | General Electric Company | Methacrylate-butadiene-styrene graft polymer and its PVC blends having low yellowness, good clarity, and improved impact strength |
US5534594A (en) | 1994-12-05 | 1996-07-09 | Rohm And Haas Company | Preparation of butadiene-based impact modifiers |
US6730734B1 (en) | 1998-12-08 | 2004-05-04 | Rohm And Haas Company | Impact modifier compositions which enhance the impact strength properties and lower the viscosity of melt processed plastics resins and methods of making said compositions |
EP1033390B1 (en) * | 1999-03-04 | 2006-05-03 | Rohm And Haas Company | Aqueous additive systems for polymeric matrices |
US7309729B1 (en) | 2000-03-07 | 2007-12-18 | Rohm And Haas Company | Aqueous additive systems for polymeric matrices |
US8119231B2 (en) | 2005-04-12 | 2012-02-21 | Arkema France | Transparent bullet-resistant acrylic sheet |
US8513355B2 (en) * | 2010-03-30 | 2013-08-20 | Lg Chem, Ltd. | Graft copolymer improving adhesion resistance and impact strength, method of preparing the same, and PVC composition comprising the same |
EP2718001B1 (en) | 2011-06-08 | 2019-07-03 | Arkema Inc. | Foaming of thermoplastic materials with organic peroxides |
FR3056218B1 (fr) | 2016-09-20 | 2020-10-02 | Arkema France | Composition de polymere, son procede de preparation, son utilisation et objet comprenant celle-ci |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA629066A (en) * | 1961-10-17 | Oliver W. Burke, Jr. | Graft vinylic fillers and their uses | |
US3041310A (en) * | 1959-07-14 | 1962-06-26 | Shell Oil Co | Polystyrene-styrene copolymer molding compositions |
US3328488A (en) * | 1963-04-02 | 1967-06-27 | Monsanto Co | Grafting vinyl monomers onto a diene polymer backbone with a divinylbenzene cross-linking agent present |
-
1966
- 1966-08-05 BE BE685172D patent/BE685172A/xx not_active IP Right Cessation
- 1966-08-08 DK DK408666AA patent/DK134860B/da unknown
- 1966-08-08 NO NO164215A patent/NO124877B/no unknown
- 1966-08-08 GB GB35410/66A patent/GB1159689A/en not_active Expired
- 1966-08-08 SE SE10690/66A patent/SE336462B/xx unknown
- 1966-08-08 CH CH1154166A patent/CH472445A/fr not_active IP Right Cessation
- 1966-08-09 SU SU1095932A patent/SU489344A3/ru active
- 1966-08-09 DE DE1620956A patent/DE1620956C3/de not_active Expired
- 1966-08-09 NL NL6611179A patent/NL6611179A/xx unknown
-
1969
- 1969-11-14 US US876920A patent/US3671610A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE1620956A1 (de) | 1970-07-09 |
DK134860B (da) | 1977-01-31 |
CH472445A (fr) | 1969-05-15 |
NL6611179A (en, 2012) | 1967-02-10 |
GB1159689A (en) | 1969-07-30 |
US3671610A (en) | 1972-06-20 |
SE336462B (en, 2012) | 1971-07-05 |
DE1620956B2 (de) | 1975-03-13 |
DK134860C (en, 2012) | 1977-08-15 |
DE1620956C3 (de) | 1975-10-30 |
BE685172A (en, 2012) | 1967-01-16 |
SU489344A3 (ru) | 1975-10-25 |
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