NO120857B - - Google Patents
Download PDFInfo
- Publication number
- NO120857B NO120857B NO162627A NO16262766A NO120857B NO 120857 B NO120857 B NO 120857B NO 162627 A NO162627 A NO 162627A NO 16262766 A NO16262766 A NO 16262766A NO 120857 B NO120857 B NO 120857B
- Authority
- NO
- Norway
- Prior art keywords
- alkali metal
- latex
- polymerization
- ethylene
- approx
- Prior art date
Links
- 239000007858 starting material Substances 0.000 claims description 30
- -1 polyethylene Polymers 0.000 claims description 29
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 25
- 239000005977 Ethylene Substances 0.000 claims description 25
- 238000006116 polymerization reaction Methods 0.000 claims description 19
- 239000000839 emulsion Substances 0.000 claims description 18
- 229920000573 polyethylene Polymers 0.000 claims description 16
- 239000004698 Polyethylene Substances 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 13
- 229910052783 alkali metal Inorganic materials 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 claims description 7
- 239000012736 aqueous medium Substances 0.000 claims description 6
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical group CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 4
- 150000001340 alkali metals Chemical class 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 159000000000 sodium salts Chemical class 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 239000003995 emulsifying agent Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 150000004968 peroxymonosulfuric acids Chemical class 0.000 claims description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Natural products C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims 1
- 229920000126 latex Polymers 0.000 description 40
- 239000004816 latex Substances 0.000 description 40
- 150000001875 compounds Chemical class 0.000 description 28
- 230000001804 emulsifying effect Effects 0.000 description 21
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- 239000002245 particle Substances 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 239000004615 ingredient Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 230000005540 biological transmission Effects 0.000 description 7
- 239000012141 concentrate Substances 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 230000001105 regulatory effect Effects 0.000 description 6
- 239000002609 medium Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000012431 aqueous reaction media Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000005498 polishing Methods 0.000 description 3
- 230000000379 polymerizing effect Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 210000000988 bone and bone Anatomy 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000002596 correlated effect Effects 0.000 description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- FVCFWDZMRBCZSD-UHFFFAOYSA-N 1-(2,3,3,4,4-pentamethylheptan-2-yl)cyclohexa-2,4-diene-1-sulfonic acid Chemical compound CCCC(C)(C)C(C)(C)C(C)(C)C1(C=CC=CC1)S(O)(=O)=O FVCFWDZMRBCZSD-UHFFFAOYSA-N 0.000 description 1
- DAALWPVFARNJHT-UHFFFAOYSA-N 2-(2,4,4-trimethylpentan-2-yl)benzenesulfonic acid Chemical compound CC(C)(C)CC(C)(C)C1=CC=CC=C1S(O)(=O)=O DAALWPVFARNJHT-UHFFFAOYSA-N 0.000 description 1
- PUAFSHSONAIXPG-UHFFFAOYSA-N 2-(2-methylheptan-2-yl)benzenesulfonic acid Chemical compound CCCCCC(C)(C)C1=CC=CC=C1S(O)(=O)=O PUAFSHSONAIXPG-UHFFFAOYSA-N 0.000 description 1
- BGMULSCUKIIJFT-UHFFFAOYSA-N 2-(2-methylundecan-2-yl)benzenesulfonic acid Chemical compound CCCCCCCCCC(C)(C)C1=CC=CC=C1S(O)(=O)=O BGMULSCUKIIJFT-UHFFFAOYSA-N 0.000 description 1
- VKRBVQFAAIHDFV-UHFFFAOYSA-N 2-(4,6,8,10,12-pentamethyltridecan-2-yl)benzenesulfonic acid Chemical compound CC(C)CC(C)CC(C)CC(C)CC(C)CC(C)C(C=CC=C1)=C1S(O)(=O)=O VKRBVQFAAIHDFV-UHFFFAOYSA-N 0.000 description 1
- RGAKRGIRMXFGMG-UHFFFAOYSA-N 2-(4,6,8-trimethylnonan-2-yl)benzenesulfonic acid Chemical compound CC(C)CC(C)CC(C)CC(C)C1=CC=CC=C1S(O)(=O)=O RGAKRGIRMXFGMG-UHFFFAOYSA-N 0.000 description 1
- ZBFIAZCKLNHUOG-UHFFFAOYSA-N 2-dodecan-2-ylbenzenesulfonic acid Chemical compound CCCCCCCCCCC(C)C1=CC=CC=C1S(O)(=O)=O ZBFIAZCKLNHUOG-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- OHLSGVWDNXTRKA-UHFFFAOYSA-N dodecan-2-yl benzenesulfonate Chemical compound CCCCCCCCCCC(C)OS(=O)(=O)C1=CC=CC=C1 OHLSGVWDNXTRKA-UHFFFAOYSA-N 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000011552 falling film Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229920003008 liquid latex Polymers 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- BRGBXEYUKCDBJN-UHFFFAOYSA-N octan-2-yl benzenesulfonate Chemical compound CCCCCCC(C)OS(=O)(=O)C1=CC=CC=C1 BRGBXEYUKCDBJN-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US449265A US3352807A (en) | 1965-04-19 | 1965-04-19 | Process of preparing stable unoxidized polyethylene emulsions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO120857B true NO120857B (de) | 1970-12-14 |
Family
ID=23783522
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO162627A NO120857B (de) | 1965-04-19 | 1966-04-19 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3352807A (de) |
| DE (1) | DE1595740B2 (de) |
| DK (1) | DK120780B (de) |
| FR (1) | FR1560213A (de) |
| GB (1) | GB1098669A (de) |
| NL (1) | NL148066B (de) |
| NO (1) | NO120857B (de) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL286467A (de) * | 1961-12-09 | |||
| NL129663C (de) * | 1964-05-16 | |||
| US4018737A (en) * | 1975-01-06 | 1977-04-19 | Cosden Technology, Inc. | Emulsions of ethylene polymers and copolymers with controlled molecular weight and particle size |
| US3978017A (en) * | 1975-02-07 | 1976-08-31 | Cosden Technology, Inc. | Production of high solids containing polyethylene emulsions |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2449489A (en) * | 1947-07-03 | 1948-09-14 | Du Pont | Preparation of polymeric ethylene emulsions |
| NL68862C (de) * | 1947-11-19 | |||
| NL267515A (de) * | 1960-07-25 | |||
| US3244652A (en) * | 1961-04-21 | 1966-04-05 | Gulf Oil Corp | Stable polyethylene latices |
-
1965
- 1965-04-19 US US449265A patent/US3352807A/en not_active Expired - Lifetime
-
1966
- 1966-04-18 DK DK197866AA patent/DK120780B/da unknown
- 1966-04-19 DE DE1966G0046632 patent/DE1595740B2/de active Granted
- 1966-04-19 NO NO162627A patent/NO120857B/no unknown
- 1966-04-19 FR FR1560213D patent/FR1560213A/fr not_active Expired
- 1966-04-19 NL NL666605218A patent/NL148066B/xx unknown
- 1966-04-19 GB GB17036/66A patent/GB1098669A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE1595740B2 (de) | 1971-09-02 |
| US3352807A (en) | 1967-11-14 |
| DK120780B (da) | 1971-07-12 |
| NL6605218A (de) | 1966-10-20 |
| NL148066B (nl) | 1975-12-15 |
| FR1560213A (de) | 1969-03-21 |
| GB1098669A (en) | 1968-01-10 |
| DE1595740A1 (de) | 1970-03-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2072465A (en) | Production of polymeric nu-vinyl compounds | |
| US2188778A (en) | Production of polymerization products of vinyl ethers | |
| NO136984B (no) | Vandig suspensjon for liming av papir og fremgangsm}te for fremstilling av suspensjonen. | |
| NO120857B (de) | ||
| NO143749B (no) | Fremgangsmaate ved klorering av etylenpolymerer | |
| NO855170L (no) | Fremgangsmaate til adskillelse av olje-i-vann-emulsjon. | |
| US3963687A (en) | Two step continuous polymerization method to form acrylonitrile copolymers | |
| NO121808B (de) | ||
| US3640981A (en) | Vinyl toluene-alpha methyl styrene co-polymers and method of preparing the same | |
| US3084186A (en) | Preparation of alkyl sulfonates | |
| US3707519A (en) | Process for the manufacture of stabilized polytetrafluoroethylene dispersions | |
| US2635086A (en) | Emulsion polymerization process | |
| USRE20968E (en) | Treatment of hydrocarbons with sulphur dioxide and chlorine | |
| US2703788A (en) | Preparation of sulfonated alkyl aryl detergent slurries | |
| CN102585250A (zh) | 一种蜡乳液的制备方法 | |
| US2470629A (en) | Process of emulsion polymerizing butadienes | |
| US4009140A (en) | Clear ethylene polymer emulsions having light transmission of at least 95% and polishes containing the same | |
| CH626641A5 (de) | ||
| US4052431A (en) | Process for the production of commercial alpha olefin sulfonates | |
| NO155151B (no) | Lavlegert hvitt stoepejern. | |
| US4145502A (en) | Spheroidal particulate polytetrafluoroethylene dispersion resin | |
| US2908668A (en) | Emulsion polymerization with trisubstituted hydroperoxy methanes | |
| US3978017A (en) | Production of high solids containing polyethylene emulsions | |
| US3743673A (en) | Single step sulfoxidation process | |
| US2857352A (en) | Process for the production of polyethylene-wax blends |