NO120248B - - Google Patents
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- Publication number
- NO120248B NO120248B NO2638/69A NO263869A NO120248B NO 120248 B NO120248 B NO 120248B NO 2638/69 A NO2638/69 A NO 2638/69A NO 263869 A NO263869 A NO 263869A NO 120248 B NO120248 B NO 120248B
- Authority
- NO
- Norway
- Prior art keywords
- aluminum
- tin
- alternating current
- electrolyte
- salt
- Prior art date
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- 229910052782 aluminium Inorganic materials 0.000 claims description 27
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 16
- 150000003839 salts Chemical class 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 12
- 238000004040 coloring Methods 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 230000002378 acidificating effect Effects 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 229910021626 Tin(II) chloride Inorganic materials 0.000 claims description 2
- 239000003792 electrolyte Substances 0.000 description 15
- 238000000576 coating method Methods 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 229910000838 Al alloy Inorganic materials 0.000 description 3
- 229910000906 Bronze Inorganic materials 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 239000010974 bronze Substances 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 229910052711 selenium Inorganic materials 0.000 description 2
- 239000011669 selenium Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 229910052714 tellurium Inorganic materials 0.000 description 2
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 2
- 229910001432 tin ion Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 238000002048 anodisation reaction Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- -1 tin Chemical class 0.000 description 1
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
- C25D11/18—After-treatment, e.g. pore-sealing
- C25D11/20—Electrolytic after-treatment
- C25D11/22—Electrolytic after-treatment for colouring layers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Printing Plates And Materials Therefor (AREA)
- Electroplating Methods And Accessories (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Description
Fremgangsmåte ved elektrolytisk farving av aluminium som på forhånd er blitt anodisk oxydert. Process for electrolytic coloring of aluminum that has been anodically oxidized beforehand.
Oppfinnelsen angår en fremgangsmåte ved elektrolytisk farving The invention relates to a method of electrolytic dyeing
av aluminium eller aluminiumlegeringar som på forhånd er blitt anodisk oxydert. De ved fremgangsmåten oppnådde belegg har en- .jevn farve med god holdbarhet» of aluminum or aluminum alloys that have been anodically oxidized in advance. The coatings obtained by the method have a uniform color with good durability"
Det er for aluminium og aluminiumlegeringer, som for enkelhets skyld nedenfor også vil bli betegnet som aluminium, blitt utviklet en rekke farvemetoder. Den mest anvendte består i en neddypping av anodisk oxydert aluminium i en farveopplosning av anilinfarver. Ved denne neddyppingsmetode kan det også anvendes noen få uorganiske og halvorganiske farveopplosninger„ En neddypping i to på hverandre foigende uorganiske bad for å utfelle et farvet, uopploselig salt A number of coloring methods have been developed for aluminum and aluminum alloys, which for the sake of simplicity will below also be referred to as aluminium. The most widely used consists of dipping anodic oxidized aluminum into a color solution of aniline dyes. With this immersion method, a few inorganic and semi-organic dye solutions can also be used„ An immersion in two adjacent inorganic baths to precipitate a colored, insoluble salt
i oxydskiktet er også brukt. in the oxide layer is also used.
Det er også blitt utviklet fremgangsmåter basert på en såkalt integrert farveanodisering hvor farven utvikles av legeringselementer i aluminiumet samtidig med dannelsen av aluminiumoxydbelegget. Methods have also been developed based on a so-called integrated color anodization where the color is developed by alloying elements in the aluminum simultaneously with the formation of the aluminum oxide coating.
Det tas ved disse fremgangsmåter hele tiden sikte på å tilveie-bringe vakre og holdbare farver på aluminiumet for utendors bruk. With these methods, the aim is always to provide beautiful and durable colors on the aluminum for outdoor use.
De ovennevnte fremgangsmåter gir imidlertid enten for lite holdbare belegg eller belegg som er dyre å fremstille. However, the above-mentioned methods either provide coatings that are not very durable or coatings that are expensive to produce.
De seneste fremskritt er basert på elektrolytisk utfelling av farvede metallforbindelser i et på forhånd dannet aluminiumoxydskikt ved å lede vekselstrom mellom en aluminiumgjenstand og en annen elektrode i en sur elektrolytt inneholdende opploselige metallforbindelser. Således angår norsk patent nr. 69930 bruk av en sur elektrolytt inneholdende metallsalter av gruppen jern-, kobolt-, nikkel-, mangan- og/eller kromsalter sammen med små mengder av inntil 10 g/liter av en annen gruppe omfattende opploselige forbindelser av arsen, antimon, vismut, selen, tellur og/eller tinn. Det oppnåes med disse sammensatte elektrolytter forskjellige bronsetoner på aluminiumgjenstanden ved at farvede forbindelser av metallene jern, kobolt, nikkel og mangan derved lar seg innfore elektrolytisk i oxydskiktene. Det angis i patentet at innholdet av arsen, antimon, vismut, selen, tellur og/eller tinn ikke må overstige en bestemt grense for at det skal kunne opprettholdes en i praksis brukbar stromtetthet. The latest advances are based on electrolytic precipitation of colored metal compounds in a previously formed aluminum oxide layer by passing alternating current between an aluminum object and another electrode in an acidic electrolyte containing soluble metal compounds. Thus, Norwegian patent no. 69930 relates to the use of an acidic electrolyte containing metal salts from the group of iron, cobalt, nickel, manganese and/or chromium salts together with small amounts of up to 10 g/liter of another group comprising soluble compounds of arsenic , antimony, bismuth, selenium, tellurium and/or tin. With these compound electrolytes, different bronze tones are achieved on the aluminum object by the fact that colored compounds of the metals iron, cobalt, nickel and manganese can thereby be introduced electrolytically into the oxide layers. It is stated in the patent that the content of arsenic, antimony, bismuth, selenium, tellurium and/or tin must not exceed a certain limit in order to maintain a practically usable current density.
Britisk patent nr. 1022927 angår en fremgangsmåte hvor det for farving av en anodisk oxydertaluminiumgjenstand ledes en vekselstrom mellom denne og en motelektrode av carbon, carborundum eller aluminium i et vandig bad inneholdende et salt som gir et farvet metalloxyd eller -hydroxyd. Som metallsalter i elektrolytten er det foreslått å anvende små mengder av et salt av nikkel, kobolt, krom, kadmium? vanadium, gull, solv, jern eller bly. British patent no. 1022927 relates to a method where, for coloring an anodic oxidized aluminum object, an alternating current is passed between it and a counter electrode of carbon, carborundum or aluminum in an aqueous bath containing a salt which gives a colored metal oxide or hydroxide. As metal salts in the electrolyte, it is proposed to use small amounts of a salt of nickel, cobalt, chromium, cadmium? vanadium, gold, silver, iron or lead.
Fra tysk patent nr. 7<1>+1753 er det kjent elektrolytisk å farve gjenstander av på forhånd oxydert aluminium ved å lede vekselstrom gjennom et bad inneholdende opploste salter av metaller som er mer elektropositive enn aluminium, under anvendelse av en motelektrode bestående av det samme metall som metallet av det salt som er opplost i badet. De eneste metallsalter som er spesielt anfort som anvende-lige ved fremgangsmåten ifolge det tyske patent nr. 7^1.753» er From German Patent No. 7<1>+1753 it is known electrolytically to dye articles of previously oxidized aluminum by passing alternating current through a bath containing dissolved salts of metals more electropositive than aluminum, using a counter electrode consisting of the the same metal as the metal of the salt dissolved in the bath. The only metal salts which are specifically stated to be applicable in the process according to German Patent No. 71,753" are
kobber salter, nikkelsalter og solvsalter. copper salts, nickel salts and solar salts.
Det er en rekke metaller, deriblant tinn, som er mer elektropositive enn aluminium, men det er typisk for teknikkens stand at det ikke er blitt foreslått å anvende en elektrolytt inneholdende et opplost salt av tinn som det metall som skal gi farving av oxydskiktet til på forhånd anodisk oxyderte gjenstander av aluminium eller aluminiumlegeringer. There are a number of metals, including tin, which are more electropositive than aluminium, but it is typical of the state of the art that it has not been proposed to use an electrolyte containing a dissolved salt of tin as the metal which will give the color of the oxide layer to pre-anodically oxidized articles of aluminum or aluminum alloys.
Det har nu overraskende vist seg at det ved anvendelse av en elektrolytt inneholdende i det vesentlige bare tinnioner som metall-ioner kan oppnåes jevne, meget pene, farvede belegg på en på forhånd anodisk oxydert aluminiumgjenstand ved mellom denne og en motelektrode neddykket i elektrolytten å lede en vekselstrom. It has now surprisingly been shown that by using an electrolyte containing essentially only tin ions as metal ions, even, very attractive, colored coatings can be obtained on a previously anodically oxidized aluminum object by conducting between this and a counter electrode immersed in the electrolyte an alternating current.
Oppfinnelsen angår således en fremgangsmåte ved elektrolytisk farving av aluminium ved i en sur, vandig opplosning av et metallsalt å lede en vekselstrom mellom en på forhånd anodisk oxydert aluminiumgjenstand og en motelektrode fortrinnsvis bestående av tinn eller titan, og fremgangsmåten er særpreget ved at det som metallsalt anvendes et tinnsalt. The invention thus relates to a method for electrolytic coloring of aluminum by passing an alternating current in an acidic, aqueous solution of a metal salt between a previously anodically oxidized aluminum object and a counter electrode preferably consisting of tin or titanium, and the method is characterized by the fact that the metal salt a stannous salt is used.
Den ved foreliggende fremgangsmåte anvendte motelektrode er ikke av avgjorende betydning, men den bor fortrinnsvis være av tinn dersom det er onskelig kontinuerlig å erstatte de tinnioner i elektrolytten som forbrukes under farvingen, eller av et materiale som ikke an-gripes av elektrolytten, f.eks. rustfritt stål og titan, for å få The counter electrode used in the present method is not of decisive importance, but it should preferably be made of tin if it is desirable to continuously replace the tin ions in the electrolyte that are consumed during the dyeing, or of a material that is not attacked by the electrolyte, e.g. . stainless steel and titanium, to get
en elektrode med lang brukstid, og for å hindre forurensninger fra å tilfores elektrolytten. Den ved foreliggende fremgangsmåte anvendte motelektrode består fortrinnsvis av tinn eller titan. an electrode with a long service life, and to prevent impurities from being added to the electrolyte. The counter electrode used in the present method preferably consists of tin or titanium.
Foreliggende' fremgangsmåte kan utfores ved anvendelse av tinn-salter i en konsentrasjon av 0,5 - 20 %, fortrinnsvis ca. 2,0 %, basert på elektrolytten. Denne kan fortrinnsvis ha en pH av ca. 1,5. Vekselstrømmen kan være sinusformet eller ha annen kurveform og ha et periodetall av 10-500 perioder pr. sekund, fortrinnsvis 50 perioder pr. sekund, og en spenning av 2-50 V, fortrinnsvis 6 V, og det kan anvendes en stromtetthet av 0,2 - 0,8 A/dm^, basert på aluminiumg jenstanden. The present method can be carried out using tin salts in a concentration of 0.5 - 20%, preferably approx. 2.0%, based on the electrolyte. This can preferably have a pH of approx. 1.5. The alternating current can be sinusoidal or have a different curve shape and have a period number of 10-500 periods per second, preferably 50 periods per second, and a voltage of 2-50 V, preferably 6 V, and a current density of 0.2 - 0.8 A/dm^ can be used, based on the aluminum thickness.
EKSEMPEL 1 EXAMPLE 1
En aluminiumgjenstand som på forhånd var blitt anodisk oxydert An aluminum object that had previously been anodically oxidized
i en 15^ vandig opplosning av svovelsyre, ble forbundet med en motr elektrode av tinn i en vandig elektrolytt inneholdende 2 % tinn- in a 15% aqueous solution of sulfuric acid, was connected to a counter electrode of tin in an aqueous electrolyte containing 2% tin-
klorid og 50 ml konsentrert saltsyre pr. liter. En vekselspenning av 5-8 V ble ved værelsetemperatur tilfort elektrodene i en tid vari-erende fra 5-15 min, og den anvendte strømtetthet ble variert fra 0,2-0,8 A/dm 2 . Det ble oppnåodd meget pene bronsenyanser på aluminiumgjenstandene avhengig av varigheten av vekselstromtilforselen. Bronsenyansene ble dypere med tiltagende varighet av vekselstromtilforselen. chloride and 50 ml concentrated hydrochloric acid per litres. An alternating voltage of 5-8 V was applied to the electrodes at room temperature for a time varying from 5-15 min, and the applied current density was varied from 0.2-0.8 A/dm 2 . Very nice bronze shades were obtained on the aluminum objects depending on the duration of the alternating current supply. The bronze hues deepened with increasing duration of the alternating current supply.
EKSEMPEL 2 EXAMPLE 2
En aluminiumstrimmel som på forhånd var blitt anodisk oxydert i ^5 min i en 15 % vandig opplosning av svovelsyre, ble farvet elektrolytisk under anvendelse av vekselstrom, en motelektrode av rustfritt stål og en vandig elektrolytt inneholdende ^0 ml konsentrert HC1 og 2,7 % SnCl2 pr. liter. Den anvendte vekselspenning var 3 vqlt med et periodetall av 50, og dette ga en stromtetthet av 0,^ - 0,5 An aluminum strip which had previously been anodically oxidized for ^5 min in a 15% aqueous solution of sulfuric acid was dyed electrolytically using alternating current, a stainless steel counter electrode and an aqueous electrolyte containing ^0 ml of concentrated HCl and 2.7% SnCl2 per litres. The alternating voltage used was 3 vqlt with a period number of 50, and this gave a current density of 0.^ - 0.5
A/dm . Farvingen varte i 10 min, -og det ble oppnådd en meget til^ talende brunsort farve på aluminiumstrimmelen. A/dm. The coloring lasted for 10 minutes, and a very attractive brown-black color was achieved on the aluminum strip.
De oppnådde belegg hadde en meget jevn farve, og dette viser The coatings obtained had a very uniform colour, and this shows
at elektrolytten hadde en god spredningsevne. that the electrolyte had good dispersibility.
I motsetning til hva det var rimelig å vente seg, tok aluminiumgjenstandene ved de anvendte tider for vekselstromtilforselen ingen skade av den kiorholdige elektrolytt, og de farved beleggs holdbarhet overfor korrosjon var meget god efter at aluminiumgjenstandene var blitt skylt med vann og "forseglet" på kjent måte. Contrary to what was reasonable to expect, the aluminum objects at the times used for the alternating current supply were not damaged by the chlorine-containing electrolyte, and the durability of the colored coatings against corrosion was very good after the aluminum objects had been rinsed with water and "sealed" in known manner.
Claims (1)
Priority Applications (13)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NO2638/69A NO120248B (en) | 1969-06-25 | 1969-06-25 | |
DE2025284A DE2025284B2 (en) | 1969-06-25 | 1970-05-23 | Process for making colored aluminum articles |
NL707008252A NL141580B (en) | 1969-06-25 | 1970-06-05 | PROCEDURE FOR THE ELECTROLYTIC COLORING OF PRE-ANODIC OXIDIZED ALUMINUM, AND COLORED OBJECTS THEREOF. |
ES380638A ES380638A1 (en) | 1969-06-25 | 1970-06-11 | Process for electrolytically colouring of aluminium which has previously been anodically oxidized |
AT547470A AT298924B (en) | 1969-06-25 | 1970-06-18 | Process for the electrolytic coloring of objects made of aluminum or an aluminum alloy |
FR7022404A FR2047917B1 (en) | 1969-06-25 | 1970-06-18 | |
SE08588/70A SE357392B (en) | 1969-06-25 | 1970-06-22 | |
BE752359D BE752359A (en) | 1969-06-25 | 1970-06-22 | PROCESS FOR ELECTROLYTICALLY COLORING ALUMINUM OBJECTS THAT HAVE BEEN SUBJECT TO ANODIC OXIDATION |
DK326970AA DK131243B (en) | 1969-06-25 | 1970-06-24 | Electrolytic dyeing process aluminum that has been previously anodic oxidized. |
FI701764A FI46987C (en) | 1969-06-25 | 1970-06-24 | Procedure for electrolytic dyeing of aluminum, which has been oxidized in advance |
CH953570A CH554945A (en) | 1969-06-25 | 1970-06-24 | PROCESS FOR ELECTROLYTIC STAINING OF ANODIC OXIDIZED OBJECTS MADE OF ALUMINUM OR AN ALUMINUM ALLOY. |
GB3089070A GB1311716A (en) | 1969-06-25 | 1970-06-25 | Process for electrolytically colouring an anodically oxidized aluminium or aluminium alloy article |
US00049951A US3849263A (en) | 1969-06-25 | 1970-06-25 | Process for electrolytically colouring of aluminium which has previously been anodically oxidized |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NO2638/69A NO120248B (en) | 1969-06-25 | 1969-06-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
NO120248B true NO120248B (en) | 1970-09-21 |
Family
ID=19878994
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO2638/69A NO120248B (en) | 1969-06-25 | 1969-06-25 |
Country Status (13)
Country | Link |
---|---|
US (1) | US3849263A (en) |
AT (1) | AT298924B (en) |
BE (1) | BE752359A (en) |
CH (1) | CH554945A (en) |
DE (1) | DE2025284B2 (en) |
DK (1) | DK131243B (en) |
ES (1) | ES380638A1 (en) |
FI (1) | FI46987C (en) |
FR (1) | FR2047917B1 (en) |
GB (1) | GB1311716A (en) |
NL (1) | NL141580B (en) |
NO (1) | NO120248B (en) |
SE (1) | SE357392B (en) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT324795B (en) * | 1973-07-02 | 1975-09-25 | Piesslinger Ind Baubedarf | PROCESS AND COLORING ELECTROLYTE FOR COLORING GRAY OF ANODIC OXIDIZED OBJECTS MADE OF ALUMINUM OR ITS ALLOYS |
CH581706A5 (en) * | 1973-11-09 | 1976-11-15 | Alusuisse | |
JPS5334107B2 (en) * | 1974-04-23 | 1978-09-19 | ||
US4128460A (en) * | 1976-09-13 | 1978-12-05 | Daiwa Kasei Kenkyujo Kabushiki Kaisha | Coloring by electrolysis of aluminum or aluminum alloys |
DE2732668C2 (en) * | 1977-07-20 | 1979-08-23 | Langbein-Pfanhauser Werke Ag, 4040 Neuss | Aluminum sheet baking pan and process for its manufacture |
DE2965186D1 (en) * | 1978-06-28 | 1983-05-19 | Reynolds Metals Co | Coating system |
US4179342A (en) * | 1978-06-28 | 1979-12-18 | Reynolds Metals Company | Coating system method for coloring aluminum |
US4180443A (en) * | 1978-06-28 | 1979-12-25 | Reynolds Metals Company | Method for coloring aluminum |
IT1142650B (en) * | 1981-12-31 | 1986-10-08 | Grace Italiana Spa | ALUMINUM ELECTRO-COLORING PLANT AND PROCESS |
US4526671A (en) * | 1982-09-24 | 1985-07-02 | Pilot Man-Nen-Hitsu Kabushiki Kaisha | Surface treatment of aluminum or aluminum alloys |
DE3824403A1 (en) * | 1988-07-19 | 1990-01-25 | Henkel KGaA, 4000 Düsseldorf | METHOD FOR ELECTROLYTIC METAL SALT COLORING OF ANODISED ALUMINUM SURFACES |
US4931151A (en) * | 1989-04-11 | 1990-06-05 | Novamax Technologies Holdings Inc. | Method for two step electrolytic coloring of anodized aluminum |
DE4120415A1 (en) * | 1991-06-20 | 1992-12-24 | Henkel Kgaa | MADE-UP TIN (II) SULFATE GRANULES FOR ELECTROLYTIC METAL SALT COLORING |
US5538617A (en) * | 1995-03-08 | 1996-07-23 | Bethlehem Steel Corporation | Ferrocyanide-free halogen tin plating process and bath |
US5658529A (en) * | 1996-03-13 | 1997-08-19 | Johnson & Johnson Medical, Inc. | Method of protecting and sterilizing aluminum surfaces on medical instruments |
EP3421646A1 (en) | 2017-06-29 | 2019-01-02 | EMPA Eidgenössische Materialprüfungs- und Forschungsanstalt | Colouring method of aluminium alloy member |
EP4257659A3 (en) * | 2022-04-04 | 2024-02-28 | Samsung Electronics Co., Ltd. | Etching composition, method of etching metal-containing film by using the same, and method of manufacturing semiconductor device by using the same |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE741753C (en) * | 1940-04-13 | 1943-11-17 | Langbein Pfanhauser Werke Ag | Process for the electrolytic coloring of objects made of aluminum with an oxidic surface layer |
US3382160A (en) * | 1960-03-31 | 1968-05-07 | Asada Tahei | Process for inorganically coloring aluminum |
US3227639A (en) * | 1961-10-24 | 1966-01-04 | Aluminum Co Of America | Method of anodizing aluminum with electrolyte containing sulfophthalic acid |
GB1173597A (en) * | 1965-12-09 | 1969-12-10 | Acorn Anodising Company Ltd | Improvements in or relating to the Anodising of Aluminium and its Alloys. |
GB1127160A (en) * | 1965-12-27 | 1968-09-11 | Sumitomo Chemical Co | A method of producing a coloured anodic oxide film on aluminium |
-
1969
- 1969-06-25 NO NO2638/69A patent/NO120248B/no unknown
-
1970
- 1970-05-23 DE DE2025284A patent/DE2025284B2/en active Pending
- 1970-06-05 NL NL707008252A patent/NL141580B/en unknown
- 1970-06-11 ES ES380638A patent/ES380638A1/en not_active Expired
- 1970-06-18 FR FR7022404A patent/FR2047917B1/fr not_active Expired
- 1970-06-18 AT AT547470A patent/AT298924B/en not_active IP Right Cessation
- 1970-06-22 SE SE08588/70A patent/SE357392B/xx unknown
- 1970-06-22 BE BE752359D patent/BE752359A/en unknown
- 1970-06-24 CH CH953570A patent/CH554945A/en not_active IP Right Cessation
- 1970-06-24 FI FI701764A patent/FI46987C/en active
- 1970-06-24 DK DK326970AA patent/DK131243B/en unknown
- 1970-06-25 GB GB3089070A patent/GB1311716A/en not_active Expired
- 1970-06-25 US US00049951A patent/US3849263A/en not_active Expired - Lifetime
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SE357392B (en) | 1973-06-25 |
NL141580B (en) | 1974-03-15 |
US3849263A (en) | 1974-11-19 |
DK131243B (en) | 1975-06-16 |
FR2047917A1 (en) | 1971-03-19 |
BE752359A (en) | 1970-12-01 |
FR2047917B1 (en) | 1975-11-07 |
DE2025284A1 (en) | 1971-01-14 |
FI46987B (en) | 1973-05-02 |
FI46987C (en) | 1973-08-10 |
AT298924B (en) | 1972-05-25 |
NL7008252A (en) | 1970-12-29 |
DK131243C (en) | 1975-11-17 |
DE2025284B2 (en) | 1975-08-07 |
CH554945A (en) | 1974-10-15 |
ES380638A1 (en) | 1972-10-01 |
GB1311716A (en) | 1973-03-28 |
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