NL8202725A - Werkwijze voor het terugwinnen van condenseerbare koolwaterstoffen uit gassen. - Google Patents

Werkwijze voor het terugwinnen van condenseerbare koolwaterstoffen uit gassen. Download PDF

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Publication number
NL8202725A
NL8202725A NL8202725A NL8202725A NL8202725A NL 8202725 A NL8202725 A NL 8202725A NL 8202725 A NL8202725 A NL 8202725A NL 8202725 A NL8202725 A NL 8202725A NL 8202725 A NL8202725 A NL 8202725A
Authority
NL
Netherlands
Prior art keywords
gas
pressure
condensates
stage
cooling
Prior art date
Application number
NL8202725A
Other languages
English (en)
Dutch (nl)
Original Assignee
Snam Progetti
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Snam Progetti filed Critical Snam Progetti
Publication of NL8202725A publication Critical patent/NL8202725A/nl

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0233—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 1 carbon atom or more
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0204—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
    • F25J3/0209—Natural gas or substitute natural gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0238—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 2 carbon atoms or more
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/02—Processes or apparatus using separation by rectification in a single pressure main column system
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/70—Refluxing the column with a condensed part of the feed stream, i.e. fractionator top is stripped or self-rectified
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/74—Refluxing the column with at least a part of the partially condensed overhead gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/78—Refluxing the column with a liquid stream originating from an upstream or downstream fractionator column
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00—Processes or apparatus using other separation and/or other processing means
    • F25J2205/02—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum
    • F25J2205/04—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum in the feed line, i.e. upstream of the fractionation step
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00—Processes or apparatus using other separation and/or other processing means
    • F25J2205/60—Processes or apparatus using other separation and/or other processing means using adsorption on solid adsorbents, e.g. by temperature-swing adsorption [TSA] at the hot or cold end
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
    • F25J2230/20—Integrated compressor and process expander; Gear box arrangement; Multiple compressors on a common shaft
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
    • F25J2230/60—Processes or apparatus involving steps for increasing the pressure of gaseous process streams the fluid being hydrocarbons or a mixture of hydrocarbons
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2235/00—Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams
    • F25J2235/60—Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams the fluid being (a mixture of) hydrocarbons
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2240/00—Processes or apparatus involving steps for expanding of process streams
    • F25J2240/02—Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00—Refrigeration techniques used
    • F25J2270/04—Internal refrigeration with work-producing gas expansion loop

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Extraction Or Liquid Replacement (AREA)
NL8202725A 1981-07-07 1982-07-07 Werkwijze voor het terugwinnen van condenseerbare koolwaterstoffen uit gassen. NL8202725A (nl)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT8122781A IT1136894B (it) 1981-07-07 1981-07-07 Metodo per il recupero di condensati da una miscela gassosa di idrocarburi
IT2278181 1981-07-07

Publications (1)

Publication Number Publication Date
NL8202725A true NL8202725A (nl) 1983-02-01

Family

ID=11200397

Family Applications (1)

Application Number Title Priority Date Filing Date
NL8202725A NL8202725A (nl) 1981-07-07 1982-07-07 Werkwijze voor het terugwinnen van condenseerbare koolwaterstoffen uit gassen.

Country Status (17)

Country Link
US (1) US4486209A (el)
JP (1) JPS5817192A (el)
AU (1) AU8511382A (el)
BR (1) BR8203667A (el)
DK (1) DK301482A (el)
EG (1) EG15920A (el)
ES (1) ES514542A0 (el)
GB (1) GB2102931B (el)
GR (1) GR76195B (el)
IE (1) IE53080B1 (el)
IT (1) IT1136894B (el)
MY (1) MY8600366A (el)
NL (1) NL8202725A (el)
NO (1) NO822107L (el)
OA (1) OA07144A (el)
PL (1) PL237301A1 (el)
YU (1) YU146182A (el)

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2557586B1 (fr) * 1983-12-30 1986-05-02 Air Liquide Procede et installation de recuperation des hydrocarbures les plus lourds d'un melange gazeux
US4657571A (en) * 1984-06-29 1987-04-14 Snamprogetti S.P.A. Process for the recovery of heavy constituents from hydrocarbon gaseous mixtures
DE3445995A1 (de) * 1984-12-17 1986-06-19 Linde Ag Verfahren zur gewinnung von c(pfeil abwaerts)2(pfeil abwaerts)(pfeil abwaerts)+(pfeil abwaerts)- oder von c(pfeil abwaerts)3(pfeil abwaerts)(pfeil abwaerts)+(pfeil abwaerts)-kohlenwasserstoffen
DE3445961A1 (de) * 1984-12-17 1986-06-26 Linde Ag, 6200 Wiesbaden Verfahren zur abtrennung von c(pfeil abwaerts)3(pfeil abwaerts)(pfeil abwaerts)+(pfeil abwaerts)-kohlenwasserstoffen aus einem gasstrom
DE3445994A1 (de) * 1984-12-17 1986-06-19 Linde Ag Verfahren zur gewinnung von c(pfeil abwaerts)2(pfeil abwaerts)(pfeil abwaerts)+(pfeil abwaerts)- oder von c(pfeil abwaerts)3(pfeil abwaerts)(pfeil abwaerts)+(pfeil abwaerts)-kohlenwasserstoffen
DE3511636A1 (de) * 1984-12-17 1986-07-10 Linde Ag, 6200 Wiesbaden Verfahren zur gewinnung von c(pfeil abwaerts)2(pfeil abwaerts)(pfeil abwaerts)+(pfeil abwaerts)- oder von c(pfeil abwaerts)3(pfeil abwaerts)(pfeil abwaerts)+(pfeil abwaerts)-kohlenwasserstoffen
DE3531307A1 (de) * 1985-09-02 1987-03-05 Linde Ag Verfahren zur abtrennung von c(pfeil abwaerts)2(pfeil abwaerts)(pfeil abwaerts)+(pfeil abwaerts)-kohlenwasserstoffen aus erdgas
US4746342A (en) * 1985-11-27 1988-05-24 Phillips Petroleum Company Recovery of NGL's and rejection of N2 from natural gas
US4734115A (en) * 1986-03-24 1988-03-29 Air Products And Chemicals, Inc. Low pressure process for C3+ liquids recovery from process product gas
US4695303A (en) * 1986-07-08 1987-09-22 Mcdermott International, Inc. Method for recovery of natural gas liquids
US4711651A (en) * 1986-12-19 1987-12-08 The M. W. Kellogg Company Process for separation of hydrocarbon gases
US4710214A (en) * 1986-12-19 1987-12-01 The M. W. Kellogg Company Process for separation of hydrocarbon gases
DE3802553C2 (de) * 1988-01-28 1996-06-20 Linde Ag Verfahren zur Abtrennung von Kohlenwasserstoffen
DE3814294A1 (de) * 1988-04-28 1989-11-09 Linde Ag Verfahren zur abtrennung von kohlenwasserstoffen
GB2224036B (en) * 1988-10-21 1992-06-24 Costain Eng Ltd Separation of gas & oil mixtures
JP2637611B2 (ja) * 1990-07-04 1997-08-06 三菱重工業株式会社 Ｎｇｌまたはｌｐｇの回収方法
US5275005A (en) * 1992-12-01 1994-01-04 Elcor Corporation Gas processing
US5459994A (en) * 1993-05-28 1995-10-24 Praxair Technology, Inc. Gas turbine-air separation plant combination
US5881569A (en) * 1997-05-07 1999-03-16 Elcor Corporation Hydrocarbon gas processing
US7484385B2 (en) * 2003-01-16 2009-02-03 Lummus Technology Inc. Multiple reflux stream hydrocarbon recovery process
US20090229275A1 (en) * 2005-08-06 2009-09-17 Madison Joel V Compact configuration for cryogenic pumps and turbines
US9869510B2 (en) 2007-05-17 2018-01-16 Ortloff Engineers, Ltd. Liquefied natural gas processing
CN101348729B (zh) * 2007-07-18 2013-01-16 王建基 压缩冷凝式油气回收工艺技术
EP2250454B1 (en) * 2008-01-21 2019-03-20 Ebara International Corporation Parallel flow cryogenic liquefied gas expanders
US20090282865A1 (en) 2008-05-16 2009-11-19 Ortloff Engineers, Ltd. Liquefied Natural Gas and Hydrocarbon Gas Processing
US20100287982A1 (en) 2009-05-15 2010-11-18 Ortloff Engineers, Ltd. Liquefied Natural Gas and Hydrocarbon Gas Processing
US9021832B2 (en) 2010-01-14 2015-05-05 Ortloff Engineers, Ltd. Hydrocarbon gas processing
CN101793456B (zh) * 2010-03-03 2011-11-30 清华大学 一种用于油气回收的冷凝方法
BR112017005575B1 (pt) 2014-09-30 2022-11-08 Dow Global Technologies Llc Processo para a recuperação de componentes c2 e c3 através de um sistema de produção de propileno por encomenda
US10551119B2 (en) 2016-08-26 2020-02-04 Ortloff Engineers, Ltd. Hydrocarbon gas processing
US10533794B2 (en) 2016-08-26 2020-01-14 Ortloff Engineers, Ltd. Hydrocarbon gas processing
US10551118B2 (en) 2016-08-26 2020-02-04 Ortloff Engineers, Ltd. Hydrocarbon gas processing
US11428465B2 (en) 2017-06-01 2022-08-30 Uop Llc Hydrocarbon gas processing
US11543180B2 (en) 2017-06-01 2023-01-03 Uop Llc Hydrocarbon gas processing
AU2019259751A1 (en) * 2018-04-24 2020-10-22 Shell Internationale Research Maatschappij B.V. Method of cooling a natural gas feed stream and recovering a natural gas liquid stream from the natural gas feed stream
FR3141997B1 (fr) * 2022-11-16 2024-09-27 Air Liquide Procédé et appareil de distillation cryogénique pour production de CO2 liquide

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3702541A (en) * 1968-12-06 1972-11-14 Fish Eng & Construction Inc Low temperature method for removing condensable components from hydrocarbon gas
IT1058546B (it) * 1976-03-26 1982-05-10 Snam Progetti Processo per il frazoonamento mediante refrigerazione dei gas di cracking negli impianti per la produzione di etilene
US4203741A (en) * 1978-06-14 1980-05-20 Phillips Petroleum Company Separate feed entry to separator-contactor in gas separation

Also Published As

Publication number Publication date
BR8203667A (pt) 1983-06-21
ES8400248A1 (es) 1983-11-01
EG15920A (en) 1986-12-30
OA07144A (fr) 1984-03-31
GB2102931B (en) 1985-07-31
AU8511382A (en) 1983-01-13
US4486209A (en) 1984-12-04
IE821628L (en) 1983-01-07
DK301482A (da) 1983-01-08
NO822107L (no) 1983-01-10
YU146182A (en) 1985-10-31
GB2102931A (en) 1983-02-09
JPS5817192A (ja) 1983-02-01
PL237301A1 (en) 1983-02-28
MY8600366A (en) 1986-12-31
IT8122781A0 (it) 1981-07-07
IE53080B1 (en) 1988-06-08
IT1136894B (it) 1986-09-03
GR76195B (el) 1984-08-03
ES514542A0 (es) 1983-11-01

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BA A request for search or an international-type search has been filed
A85 Still pending on 85-01-01
BV The patent application has lapsed