NL7014360A - Stereospecific catalyst for polymerisation of - alpha olefins - Google Patents

Stereospecific catalyst for polymerisation of - alpha olefins

Info

Publication number
NL7014360A
NL7014360A NL7014360A NL7014360A NL7014360A NL 7014360 A NL7014360 A NL 7014360A NL 7014360 A NL7014360 A NL 7014360A NL 7014360 A NL7014360 A NL 7014360A NL 7014360 A NL7014360 A NL 7014360A
Authority
NL
Netherlands
Prior art keywords
polymerisation
hydrocarbyl
aralkyl
aryl
alkyl
Prior art date
Application number
NL7014360A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Priority to NL7014360A priority Critical patent/NL7014360A/en
Publication of NL7014360A publication Critical patent/NL7014360A/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

The polymerisation occurs in the presence of H2 or H2 and C2H4, with a catalyst consisting of a combination of:- A. An organo aluminium halide R3Al2X3 or RAlX2 where R is a C 1-12 hydrocarbyl, (alkyl, aryl or aralkyl) and X is Cl, Br or I. B. An organic phosphorus compound R'n P(OR")3-n where R' and R" are Cl-12 hydrocarbyl (alkyl, cycloalkyl, aryl or aralkyl) and n is 1-2. C. A composition containing Al, Ti and Cl as titanium trichloride and aluminium trichloride. Known catalyst can give high proportions of atactic polymer which must be extracted as it causes deterioration in properties. The new catalyst mixture is stereo-specific and produces polymer containing acceptable amounts of atactic polymer, giving more economic processing.
NL7014360A 1970-09-30 1970-09-30 Stereospecific catalyst for polymerisation of - alpha olefins NL7014360A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
NL7014360A NL7014360A (en) 1970-09-30 1970-09-30 Stereospecific catalyst for polymerisation of - alpha olefins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL7014360A NL7014360A (en) 1970-09-30 1970-09-30 Stereospecific catalyst for polymerisation of - alpha olefins

Publications (1)

Publication Number Publication Date
NL7014360A true NL7014360A (en) 1972-04-05

Family

ID=19811191

Family Applications (1)

Application Number Title Priority Date Filing Date
NL7014360A NL7014360A (en) 1970-09-30 1970-09-30 Stereospecific catalyst for polymerisation of - alpha olefins

Country Status (1)

Country Link
NL (1) NL7014360A (en)

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