NL2021723A - Special peanut fertilizer prepared from peanut stalk and preparation method thereof - Google Patents
Special peanut fertilizer prepared from peanut stalk and preparation method thereof Download PDFInfo
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- NL2021723A NL2021723A NL2021723A NL2021723A NL2021723A NL 2021723 A NL2021723 A NL 2021723A NL 2021723 A NL2021723 A NL 2021723A NL 2021723 A NL2021723 A NL 2021723A NL 2021723 A NL2021723 A NL 2021723A
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- calcium
- carbonized
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D3/00—Calcareous fertilisers
- C05D3/02—Calcareous fertilisers from limestone, calcium carbonate, calcium hydrate, slaked lime, calcium oxide, waste calcium products
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Soil Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Fertilizers (AREA)
Abstract
The disclosure pertains to the technical field of crop fertilizer, and specifically pertains to a special peanut fertilizer prepared from peanut stalk and preparation method thereof. The special fertilizer includes following parts by weight of starting materials: 40-50 parts of carbonized peanut stalk, 10-15 parts of nano-calcium carbonate, and 5-8 parts of wheat malt flour. The disclosure achieves innocently returning peanut stalk to field by carbonizing peanut stalk. The stalk itself contains a considerable amount of nutrient elements, and can provide comprehensive nutritions for crops, enhance organic contents in soil, improve physicochemical properties and bioactivities of soil, and strengthen calcium adsorption by introducing tetrabutyl titanate. The disclosure not only improves calcium fertilizer utilization by integrating nano-calcium and carbonized stalk, but also achieves good fertilizer conservation of soil on calcium fertilizer because of good adsorptivity of biochar, achieves the goal of slowing release, meets the calcium fertilizer demand in later growth stage of peanut, and improves the yield and quality of peanut.
Description
TECHNICAL FIELD [0001] The disclosure pertains to the technical field of crop fertilizer, and specifically pertains to a special peanut fertilizer prepared from peanut stalk and preparation method thereof.
BACKGROUND [0002] In recent years, crop stalks have become a new source of the non-point source pollution in rural areas, where the field incineration has caused serious air pollution. As a large agricultural country, China can generate more than 700 million tons of stalks every year. As a large peanut producing country, China had the total peanut yield of more than 16 million tons in 2016, where the yield of peanut stalk to the yield of peanut pod was about 1:1, i.e., China had the peanut stalk yield of more than 16 million tons. Since the autotoxicity of peanut stalk, directly returning stalk to field tends to cause successive cropping obstacles for peanut fields, thus resulting in stunted peanut plants and significantly reduced yield. Reasonable processing of peanut stalks will contribute to the development of the peanut planting industry.
[0003] In the seedling stage, peanut needs certain amount of calcium nutrition to improve its anti-adversity ability. In the later growth stage, peanut needs more calcium for pod growth, and insufficient soil exchangeable calcium tends to cause blighted grains, thereby seriously affecting the yield. Meeting calcium fertilizer demand of peanut by fertilizer application at a time and improving the fertilizer efficiency are problems in urgent need of solution. In terms of special calcium fertilizer of peanut, the existing special fertilizer is not targeted enough, and most calcium is applied directly into soil, which tends to cause curing or loss of calcium, and fails to better give play to the timeliness of the fertilizer.
SUMMARY [0004] In order to solve the peanut stalk pollution, and the problems of failure to achieve calcium fertilizer demands of peanut in different periods, low fertilizer efficiency, and failure to better give play to the timeliness of fertilizer by fertilizer application at a time, the disclosure provides a special peanut fertilizer prepared from peanut stalk. The fertilizer is a special nano-calcium fertilizer prepared from carbonized peanut stalk by carbonizing peanut stalk and integrating nano-calcium, achieves better use effect, and effectively improves the yield and quality of peanut, [0005] The disclosure further provides a preparation method of a special peanut fertilizer prepared from peanut stalk.
[0006] hi order to achieve the object, the disclosure is implemented using following technical solution:
The disclosure provides a special peanut fertilizer prepared from peanut stalk. The special fertilizer includes following parts by weight of starting materials: 40-50 parts of carbonized peanut stalk, 10-15 parts of nano-calcium carbonate, and 5-8 parts of wheat malt flour. [0007] The disclosure further provides a preparation method of a special peanut fertilizer, including following steps:
(1) pulverizing peanut stalk with a stalk pulverizer to powder of less than 600 mesh, immersing in a mixed solution for 40-50 min, rinsing with water, drying at 70-80 °C, heating the stalk powder, slowly heating to 300 °C, keeping carbonization for 3 hours, slowly cooling to below 150 °C, taking out a carbonized material, immersing in diluted hydrochloric acid for 2-3 hours, rinsing with water until neutral, adding tetrabutyl titanate dropwise whilst stirring, further stirring for another 1.5 hours after completing the dropwise addition, and drying at 70-80 °C to obtain carbonized peanut stalk;
(2) adding wheat to green tea water, immersing for 3-4 hours, germinating, stop germinating until 85% or more wheat malt has a length of more than 1cm, directly grinding germinating wheat, drying, grinding again, passing through a 60 mesh sieve to obtain wheat malt flour; and (3) suspending nano-calcium carbonate in water, stirring to obtain a uniform suspension (mass ratio of nano-calcium carbonate to water is 1:10), adding the carbonized peanut stalk and the wheat malt flour, stirring for 2-3 hours, fully mixing, and drying at 70-80 °C to obtain the fertilizer.
[0008] Furthermore, the mixed solution is prepared from dipotassium glycyrrhizinate, sodium polyacrylate, and water, [0009] A mass ratio of the dipotassium glycyrrhizinate to sodium polyacrylate to water is 1:2:100.
[0010] Furthermore, an addition amount of the tetrabutyl titanate is 2-3% of the carbonized material.
[0011] The green tea water used in the disclosure is prepared using following method: adding a mixed solution of glycerin and water (volume ratio of glycerol to water is 1: 0) having a weight 10 times as much as a weight of green tea to the green tea, then heating to 50-60 °C, immersing at the temperature for 1-2 hours, and then filtering.
[0012] The fertilizer ingredients mainly include peanut stalk. After stalk carbonization, nanocalcium is adsorbed into the carbonized material. In accordance with calcium demand characteristics in the growth period of peanut, by biochar adsorption, the fertilizer realizes not only prolonged maintenance of calcium nutrition, but also continuous supply of calcium nutrition, and meets the calcium fertilizer demand in later growth stage of pod. Moreover, due to the characteristics of easy uptake of nano-calcium, the calcium fertilizer utilization is improved, and the stalk carbonization helps to eliminate the autotoxicity of peanut stalk. Furthermore, the carbonized stalk has a large specific surface area, a porous structure, and a good adsorption characteristics, includes main ingredients of not only C element, but also H, 0, N, S, and small amounts of trace elements. Therefore, the carbonized stalk can provide comprehensive nutritions for crops, enhance soil organic contents, and improve the physicochemical properties and bioactivities of soil. The stalk carbonization not only realizes innocent processing of peanut stalk and returning stalk to field, but also achieves the win-win goal of reducing carbon emissions and increasing soil fertility. The disclosure has a simple formula, is practical and reasonable, has good use effects, can significantly improve the fertilizer utilization, and greatly improves the yield and quality of peanut, thus improving the economic benefits of peanut.
[0013] The nano-calcium carbonate used in the disclosure is a commercially available product.
[0014] The disclosure has following beneficial effects:
1. The disclosure achieves innocently returning peanut stalk to field by carbonizing peanut stalk. The stalk itself contains a considerable amount of nutrient elements, and can provide comprehensive nutritions for crops, enhance organic contents in soil, improve physicochemical properties and bioactivities of soil, and strengthen calcium adsorption by introducing tetrabutyl titanate.
2. The disclosure not only improves the calcium fertilizer utilization by integrating nanocalcium and carbonized stalk, but also achieves good fertilizer conservation of soil on the calcium fertilizer because of good adsorptivity of biochar, achieves the goal of slowing release, and meets the calcium fertilizer demand in later growth stage of peanut.
3. Carbonizing the starting material of peanut stalk in production is pollution-free for the environment and crops. Integrating the nano-calcium and biochar enables returning stalk to field and releasing nutrients from calcium fertilizer to be more rational with better use effects, can significantly improve the fertilizer utilization, and increase the yield and quality of peanut.
[0015] 4. Adding an appropriate amount of wheat malt flour enhances the fertilizer efficiency, and promotes the peanut growth, whilst increasing the fertilizer stability.
DETAILED DESCRIPTION OF EMBODIMENTS [0016] In order to better understand the disclosure, the disclosure is further described hereinafter in conjunction with specific examples.
[0017] Example 1
A special nano-calcium fertilizer prepared from carbonized peanut stalk: 40 parts of carbonized peanut stalk, 10 parts of nano-calcium, and 5 parts of wheat malt flour. The preparation method is as follows:
(1) pulverizing peanut stalk with a stalk pulverizer to powder of less than 600 mesh, immersing in a mixed solution for 40 min, rinsing with water, drying at 70-80 °C, heating the stalk powder, slowly heating to 300 °C, keeping carbonization for 3 hours, slowly cooling to below 150 °C, taking out a carbonized material, immersing in diluted hydrochloric acid for 2 hours, rinsing with water until neutral, adding tetrabutyl titanate (3% mass of the carbonized material) dropwise whilst stirring, further stirring for another 1.5 hours after completing the dropwise addition, and drying at 70-80 °C to obtain carbonized peanut stalk;
where the mixed solution was prepared from dipotassium glycyrrhizinate, sodium polyacrylate, and water at a mass ratio of 1:2: 100;
(2) adding wheat to green tea water (addition amount of the green tea water just immersing the wheat), immersing for 4 hours, germinating, stop germinating until 85% or more wheat malt has a length of more than 1cm, directly grinding germinating wheat, drying, grinding again, passing through a 60 mesh sieve to obtain wheat malt flour; and (3) suspending nano-calcium carbonate in water, stirring to obtain a uniform suspension, adding the carbonized peanut stalk and the wheat malt flour, stirring for 3 hours, fully mixing, and drying at 70-80 °C to obtain the fertilizer.
[0018] Example 2
A special nano-calcium fertilizer prepared from carbonized peanut stalk: 50 parts of carbonized peanut stalk, 12 parts of nano-calcium, and 8 parts of wheat malt flour. The preparation method is as follows:
(1) pulverizing peanut stalk with a stalk pulverizer to powder of less than 600 mesh, immersing in a mixed solution (ingredients identical to the ingredients in example 1) for 50 min, rinsing with water, drying at 70-80 °C, heating the stalk powder, slowly heating to 300 °C, keeping carbonization for 3 hours, slowly cooling to below 150 °C, taking out a carbonized material, immersing in diluted hydrochloric acid for 3 hours, rinsing with water until neutral, adding tetrabutyl titanate (2% mass of the carbonized material) dropwise whilst stirring, further stirring for another 1.5 hours after completing the dropwise addition, and drying at 70-80 °C to obtain carbonized peanut stalk;
where the mixed solution was prepared from dipotassium glycyrrhizinate, sodium polyacrylate, and water at a mass ratio of 1:2:100.
(2) adding wheat to green tea water (addition amount of the green tea water just immersing the wheat), immersing for 4 hours, germinating, stop germinating until 85% or more wheat malt has a length of more than lcm, directly grinding germinating wheat, drying, grinding again, passing through a 60 mesh sieve to obtain wheat malt flour; and (3) suspending nano-calcium carbonate in water, stirring to obtain a uniform suspension, adding the carbonized peanut stalk and the wheat malt flour, stirring for 2 hours, fully mixing, and drying at 70-80 °C to obtain the fertilizer.
[0019] Example 3
A special nano-calcium fertilizer prepared from carbonized peanut stalk: 45 parts of carbonized peanut stalk, 15 parts of nano-calcium, and 7 parts of wheat malt flour. The preparation method is as follows:
(1) pulverizing peanut stalk with a stalk pulverizer to powder of less than 600 mesh, immersing in a mixed solution (ingredients identical to the ingredients in example 1) for 50 min, rinsing with water, drying at 70-80 °C, heating the stalk powder, slowly heating to 300 °C, keeping carbonization for 3 hours, slowly cooling to below 150 °C, taking out a carbonized material, immersing in diluted hydrochloric acid for 3 hours, rinsing with water until neutral, adding tetrabutyl titanate (2.5% mass of the carbonized material) dropwise whilst stirring, further stirring for another 1.5 hours after completing the dropwise addition, and drying at 70-80 °C to obtain carbonized peanut stalk;
(2) adding wheat to green tea water (addition amount of the green tea water just immersing the wheat), immersing for 3 hours, germinating, stop germinating until 85% or more wheat malt has a length of more than lcm, directly grinding germinating wheat, drying, grinding again, passing through a 60 mesh sieve to obtain wheat malt flour; and (3) suspending nano-calcium carbonate in water, stirring to obtain a uniform suspension, adding the carbonized peanut stalk and the wheat malt flour, stirring for 3 hours, fully mixing, and drying at 70-80 °C to obtain the fertilizer.
[0020] Example 4
A special nano-calcium fertilizer prepared from carbonized peanut stalk: 40 parts of carbonized peanut stalk, 10 parts of nano-calcium, and 5 parts of wheat malt flour. The preparation method is as follows:
(1) pulverizing peanut stalk with a stalk pulverizer to powder of more than 1000 mesh, immersing in water for 24 hours, rinsing surface attachments, drying at 70-80 °C, heating the stalk powder, slowly heating to 600°C, keeping carbonization for 3 hours, slowly cooling to below 150 °C, taking out a carbonized material, immersing in diluted hydrochloric acid for 23 hours, rinsing with water until neutral, and drying at 70-80 °C.
[0021] (2) suspending nano-calcium carbonate in water, stirring to obtain a uniform suspension, adding the carbonized stalk in proportion, stirring for 2-3 hours, fully mixing, and drying at 70-80°C to obtain the fertilizer.
[0022] Comparison Example 1
A special nano-calcium fertilizer prepared from carbonized peanut stalk: 40 parts of carbonized peanut stalk, and 5 parts of wheat malt flour.
The preparation method is as follows:
(1) pulverizing peanut stalk with a stalk pulverizer to powder of less than 600 mesh, immersing in a mixed solution (ingredients identical to the ingredients in example 1) for 40 min, rinsing with water, drying at 70-80 °C, heating the stalk powder, slowly heating to 300 °C, keeping carbonization for 3 hours, slowly cooling to below 150 °C, taking out a carbonized material, immersing in diluted hydrochloric acid for 2 hours, rinsing with water until neutral, then adding tetrabutyl titanate (3% mass of the carbonized material) dropwise whilst stirring, further stirring for another 1.5 hours after completing the dropwise addition, and drying at 70-80 °C to obtain carbonized peanut stalk;
(2) adding the carbonized peanut stalk and the wheat malt flour in an appropriate amount of water, stirring for 3 hours, fully mixing, and drying at 70-80 °C to obtain the fertilizer. [0023] Comparison Example 2
A special nano-calcium fertilizer prepared from carbonized peanut stalk: 40 parts of carbonized peanut stalk, and 10 parts of nano-calcium.
The preparation method is as follows:
(1) pulverizing peanut stalk with a stalk pulverizer to powder of less than 600 mesh, immersing in a mixed solution (ingredients identical to the ingredients in example 1) for 40 min, rinsing with water, drying at 70-80 °C, heating the stalk powder, slowly heating to 300 °C, keeping carbonization for 3 hours, slowly cooling to below 150 °C, taking out a carbonized material, immersing in diluted hydrochloric acid for 2 hours, rinsing with water until neutral, then adding tetrabutyl titanate (3% mass of the carbonized material) clropwise whilst stirring, further stirring for another 1.5 hours after completing the dropwise addition, and drying at 70-80 °C to obtain carbonized peanut stalk;
(2) suspending nano-calcium carbonate in water, stirring to obtain a uniform suspension, adding the carbonized peanut stalk and the wheat malt flour, stirring for 3 hours, fully mixing, and drying at 70-80 °C to obtain the fertilizer.
[0024] At the same time, the inventor has found after a considerable amount of experiments that when titanium dioxide powder was directly added, its effect was worse than that in comparison example 2, and the yield per mu was reduced by 5-8% compared with that in comparison example 2.
[0025] Effect Validation Experiment (I) Spring peanut experiment: adjacent spring peanut fields of the same size having equivalent soil properties, fertility, environment, and the like were selected, equally divided into 10 pieces, and numbered S1-S10. The experimental fields were seeded with one seed in one hole at a design density of 16000 holes/mu. A compound fertilizer was pre-applied in each of the experimental fields at a rate of 50kg/mu. The fertilizer prepared in examples 1-4 was used in S1-S4 respectively, the fertilizer prepared in comparison examples 1-2 was used in S5-S6 respectively, and a control group was established: only commercially available nano-calcium was applied in S7, only carbonized peanut stalk was applied in S8, a mixture of commercially available nano-calcium and wheat malt flour (10 parts of nano-calcium and 5 parts of wheat malt flour) was applied in S9, and no substance was applied in S10; the application amount was 4 kg/mu in the each experimental field. Other field management modes were identical. At harvest, the number of fruits per plant, the full fruit rate, and the yield per mu of the each experimental field were collected, and specific results are shown in Table 1.
[0026] Table 1
Number of plants per mu | Number of fruits per plant | Full fruit rate (%) | Yield (kg/mu) | |
SI | 15400 | 15.5 | 74.2 | 425 |
S2 | 15200 | 15.2 | 74.1 | 412 |
S3 | 15500 | 16.1 | 74.6 | 448 |
S4 | 15000 | 12.5 | 65.5 | 295 |
S5 | 14800 | 11.6 | 62.8 | 259 |
S6 | 14300 | 12.8 | 59.9 | 263 |
S7 | 13900 | 10.1 | 56.1 | 189 |
S8 | 12600 | 12.3 | 52.3 | 194 |
S9 | 14200 | 11.6 | 62.9 | 248 |
S10 | 10500 | 10.2 | 53.5 | 137 |
(I) Summer peanut experiment: adjacent spring peanut fields of the same size having equivalent soil properties, fertility, environment, and the like were selected, equally divided into 10 pieces, and numbered X1-X10. The experimental fields were seeded with one seed in one hole at a design density of 16000 holes/mu. A compound fertilizer was pre-applied in each of the experimental fields at a rate of 50kg/mu. The fertilizer prepared in examples 1-4 was used in XI-X4 respectively, the fertilizer prepared in comparison examples 1-2 was used in X4-X6 respectively, and a control group was established: only commercially available nano-calcium was applied in X7, only carbonized peanut stalk was applied in X8, a mixture of commercially available nano-calcium and wheat malt flour (10 parts of nano-calcium and 5 parts of wheat malt flour) was applied in X9, and no substance was applied in X10; the application amount was 4 kg/mu in the each experimental field. Other field management modes were identical. At harvest, the number of fruits per plant, the full fruit rate, and the yield per mu of the each experimental field were collected, and specific results are shown in
Table 2.
[0027] Table 2
Number of plants per mu | Number of fruits per plant | Full fruit rate (%) | Yield (kg/mu) | |
XI | 14800 | 13.6 | 63.1 | 305 |
X2 | 14600 | 13.1 | 63.8 | 292 |
X3 | 15000 | 13.8 | 64.5 | 321 |
X4 | 13100 | 13.2 | 52.5 | 218 |
X5 | 13600 | 11.8 | 51.8 | 200 |
X6 | 13600 | 12.6 | 48.7 | 207 |
X7 | 13000 | 11.3 | 46.4 | 152 |
X8 | 13000 | 11.6 | 46.0 | 167 |
X9 | 12800 | 12.5 | 47.2 | 182 |
X10 | 12400 | 9.8 | 44.6 | 130 |
As can be seen from the above experiments, the special nano-calcium fertilizer prepared from carbonized peanut stalk according to the disclosure not only can effectively meet the nutritional demand in each growth stage of peanut, promote better growth of peanut, increase the yield of peanut, but also reduces the application amount of fertilizer, saves costs, and effectively reduces carbon emissions.
Claims (5)
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AU (1) | AU2018100547A4 (en) |
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CN116984355B (en) * | 2023-07-27 | 2024-06-07 | 昆明理工大学 | Method for preparing biochar from solid waste, product and application |
CN117796321B (en) * | 2023-12-29 | 2024-07-12 | 云南省农业科学院茶叶研究所 | Culture medium for improving survival rate of tea tree tissue culture seedlings |
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JP2001089283A (en) * | 1999-09-28 | 2001-04-03 | Mitsubishi Chemicals Corp | Coating material for coated granular fertilizer and coated granular fertilizer using the same |
JP5589440B2 (en) * | 2010-02-26 | 2014-09-17 | 住友化学株式会社 | Coated granular fertilizer |
CN103755866B (en) * | 2013-07-29 | 2016-04-20 | 湖北大学 | Modified swill-cooked dirty oil coated fertilizer and the application in coating slowly/controlled releasing fertilizer thereof |
US9890332B2 (en) * | 2015-03-08 | 2018-02-13 | Proton Power, Inc. | Biochar products and production |
CN105399580A (en) * | 2015-12-11 | 2016-03-16 | 深圳市芭田生态工程股份有限公司 | Plant nutrition conditioning fertilizer capable of reducing pesticide residue in soil |
CN105753611A (en) * | 2016-01-11 | 2016-07-13 | 湖北省农业科学院植保土肥研究所 | Unsaturated polyester coated controlled-release fertilizer prepared from PET wastes and preparation method thereof |
CN105884513B (en) * | 2016-04-11 | 2019-11-12 | 山东省农业科学院生物技术研究中心 | A kind of single grain fine sowing fertilizer specially for peanut and preparation method thereof |
CN106278723A (en) * | 2016-08-12 | 2017-01-04 | 廖晖 | Manganese modification biological charcoal is fertile and preparation method thereof |
CN106748488A (en) * | 2016-12-28 | 2017-05-31 | 新昌县奥而特农业科技有限公司 | Biological organic composite coated fertilizer of activating soil and preparation method thereof |
CN106744940A (en) * | 2017-02-22 | 2017-05-31 | 安徽帝元现代农业投资发展有限公司 | A kind of soil conditioner straw biomass charcoal of composite sodium selenite activation modification and preparation method thereof |
CN107032881A (en) * | 2017-04-21 | 2017-08-11 | 袁春华 | A kind of preparation method of plant graft consolidant |
CN107056544A (en) * | 2017-04-27 | 2017-08-18 | 河南农业大学 | One kind promotes root growth high carbon-based soil remediation fertilizer and method |
CN107021857A (en) * | 2017-05-27 | 2017-08-08 | 临沂大学 | A kind of Chinese medicine dreg biological organic fertilizer |
CN107235776A (en) * | 2017-07-21 | 2017-10-10 | 张娟 | A kind of extremely frigid zones fertilizer and preparation method thereof |
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CN107501009A (en) | 2017-12-22 |
CN107501009B (en) | 2020-11-24 |
AU2018100547A4 (en) | 2018-05-24 |
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