NL2019817B1 - Low bend loss optical fiber with a chlorine doped core and offset trench - Google Patents

Description

Octrooicentrum

Θ 2019817

Aanvraagnummer: 2019817

Aanvraag ingediend: 27 oktober 2017

Int. CL:

G02B 6/036 (2018.01)

0 Voorrang:	0 Octrooihouder(s):
8 augustus 2017 US 62/542,518	Coming Incorporated te Coming, New York,
	Verenigde Staten van Amerika, US.
0 Aanvraag ingeschreven:
21 februari 2019	0 Uitvinder(s):
	Dana Craig Bookbinder te Coming,
0 Aanvraag gepubliceerd:	New York (US).
-	Ming-Jun Li te Coming, New York (US).
	Snigdharaj Kumar Mishra te Coming,
0 Octrooi verleend:	New York (US).
21 februari 2019	Pushkar Tandon te Coming, New York (US).
0 Octrooischrift uitgegeven:
17 mei 2019	0 Gemachtigde:
	ir. P.J. Hylarides c.s. te Den Haag.

LOW BEND LOSS OPTICAL FIBER WITH A CHLORINE DOPED CORE AND OFFSET TRENCH © The invention relates to an optical fiber, wherein the optical fiber includes:

(i) a chlorine doped silica based core having a core alpha (Core») > 4, a radius n, and a maximum refractive index delta Aimax%; and (ii) a cladding surrounding the core.

The cladding surrounding the core includes:

a) a first inner cladding region adjacent to and in contact with the core and having a refractive index delta Δ₂, a radius r₂, and a minimum refractive index delta A_2minSuch that A_2min< Ai_max;

b) a second inner cladding adjacent to and in contact with the first inner cladding having a refractive index Δ₃, a radius r₃, and a minimum refractive index delta A_3minsuch that A_3min<A₂; and

c) an outer cladding region surrounding the second inner cladding region and having a refractive index Δ₅, a radius r_max and a minimum refractive index delta A_3min such that A_3min <Δ₂.

The optical fiber has a mode field diameter MFD at 1310 of > 9 microns, a cable cutoff of > 1260 nm, a zero dispersion wavelength of 1300 nm > zero dispersion wavelength > 1324 nm, and a macrobending loss at 1550 nm for a 20 mm mandrel of less than 0.75 dB/turn.

NL B1 2019817

Dit octrooi is verleend ongeacht het bijgevoegde resultaat van het onderzoek naar de stand van de techniek en schriftelijke opinie. Het octrooischrift komt overeen met de oorspronkelijk ingediende stukken.

LOW BEND LOSS OPTICAL FIBER WITH A CHLORINE DOPED CORE AND OFFSET TRENCH

The present disclosure generally relates to optical fibers, for example single mode optical fibers, having low bend losses, and in particular relates to optical fibers having chlorine doped cores and more particularly to single mode fibers with a chlorine doped core and a cladding having an offset trench region surrounding the core.

There is a need for low bend loss optical fibers, particularly for optical fibers utilized in so-called “access” and fiber to the premises (FTTx) optical networks. Optical fiber can be deployed in such networks in a manner which induces bend losses in optical signals transmitted through the optical fiber. Some applications that can impose physical demands, such as tight bend radii, compression of optical fiber, etc., that induce bend losses include the deployment of optical fiber in optical drop cable assemblies, distribution cables with Factory Installed Termination Systems (FITS) and slack loops, small bend radius multiports located in cabinets that connect feeder and distribution cables, and jumpers in Network Access Points between distribution and drop cables. It has been difficult in some optical fiber designs to simultaneously achieve low macrobending loss, low microbending loss, low cable cutoff wavelength, a zero dispersion wavelength between 1300 nm and 1324 nm, 1310 mode field diameter of 8.2 to 9.6 microns, and ITU G.652/G.657 standards compliance.

According to the present disclosure, an optical fiber is provided. The optical fiber includes:

(i) a chlorine doped silica based core, preferably having a core alpha (Core_a) > 10, and having a radius r,, and a maximum refractive index delta A_!max%; and (ii) a cladding surrounding the core.

The cladding surrounding the core is adjacent to and in contact with the core and has a refractive index delta A₂, a radius r₂, and a minimum refractive index delta A_2min such that A_2min< Aj niax·

The optical fiber preferably comprises a second inner cladding adjacent to and in contact with the first inner cladding and having a refractive index A₃, a radius r₃

The second inner cladding preferably has a minimum refractive index delta A_3min such that A_3min< Δ₂.

The optical fiber can have an outer cladding region surrounding the second inner cladding region, which outer cladding region preferably has a refractive index A₅ and a radius r_max, such that Δ_3πώ) < A₂.

The optical fiber can have a mode field diameter MFD at 1310 of > 9 microns, a cable cutoff of < 1260 nm, a zero dispersion wavelength ranging from 1300 nm < λ₀ < 1324 nm, and a macrobending loss at 1550 nm for a 20 mm mandrel of less than 0.75 dB/turn.

An example of the optical fiber includes:

(i) a chlorine doped silica based core having a core alpha (Core,,) > 4, a radius r_i; and a maximum refractive index delta A_)max%; and (ii) a cladding surrounding the core.

The cladding surrounding the core can include:

a) a first inner cladding region adjacent to and in contact with the core and having a refractive index delta Δ₂, a radius r₂, and a minimum refractive index delta A_2mill such that Δ_2ηώ,<Δ_1ηκ(Χ;

b) a second inner cladding adjacent to and in contact with the first inner cladding and having a refractive index Δ₂„ a radius r₂„ and a maximum refractive index delta Ajniax such that Δ₂₁₁^_η < A-.niax' and

c) an outer cladding region surrounding the inner cladding region and having a refractive index Δ₅ and a radius r_max, such that Δ₅ < A_3max.

Additional features and advantages will be set forth in the detailed description which follows, and in part will be readily apparent to those skilled in the art from that description or recognized by practicing the embodiments as described herein, including the detailed description which follows, the clauses, as well as the appended drawings.

It is to be understood that both the foregoing general description and the following detailed description are merely exemplary, and are intended to provide an overview or framework to understanding the nature and character of the clauses. The accompanying drawings are included to provide a further understanding, and are incorporated in and constitute a part of this specification. The drawings illustrate one or more embodiments, and together with the description serve to explain principles and operation of the various embodiments.

- FIG. 1 is a side perspective view of an optical fiber according to the present disclosure;

- FIG. 2 is a cross-sectional view of the optical fiber taken through line II-Π of FIG. 1 according to the present disclosure;

- FIG. 3A is a plot of the relative refractive index profile Δ versus the radius of the optical fiber of FIG. 2;

- FIG. 3B is a plot of the relative refractive index profile Δ versus the radius of the optical fiber according to examples of the present disclosure;

- FIG. 4 is a plot of the relative refractive index profile Δ versus the radius of the optical fiber according to examples of the present disclosure; and

- FIGS. 5-14 are profile schematic plots of the relative refractive index profile Δ versus the radius for various optical fibers according to examples of the present disclosure.

Additional features and advantages will be set forth in the detailed description which follows and will be apparent to those skilled in the art from the description or recognized by practicing as described in the following description together with the clauses and appended drawings.

Low attenuation is a critical property in optical fibers. Optical fibers disclosed herein are valuable for use as low attenuation optical fibers such as in optical fiber cables for submarine and terrestrial long haul systems.

The “refractive index profile” is the relationship between refractive index or relative refractive index (also referred to as refractive index delta herein) and waveguide fiber radius. The radius for each segment of the refractive index profile is given by the abbreviations r_1? r₂, r₃, r₄, etc. and lower and upper case are used interchangeably herein (e.g., π is equivalent to R|).

Unless stated otherwise, the “relative refractive index percent” is defined as A% = 100 x (n² -nc²)/²nf, and as used herein nc is the average refractive index of undoped silica glass. As used herein, the relative refractive index is represented by A and its values are given in units of “%”, unless otherwise specified. The terms: relative refractive index percent, relative refractive index, refractive index delta, refractive index, relative refractive index delta, delta. A, A%, %A, delta%, %delta and percent delta may be used interchangeably herein. In cases where the refractive index of a region is less than the average refractive index of undoped silica, the relative index percent is negative and is referred to as having a depressed region or depressed index. In cases where the refractive index of a region is greater than the average refractive index of the cladding region, the relative index percent is positive. An “updopant” is herein considered to be a dopant which has a propensity to raise the refractive index relative to pure undoped SiO₂. A “downdopant” is herein considered to be a dopant which has a propensity to lower the refractive index relative to pure undoped SiO₂. Examples of updopants include GeO₂ (germania), A1₂O₃, P₂O₅, TiO₂, Cl, and/or Br. Examples of downdopants include fluorine and B₂O₃. As described herein, while the relative refractive index of the optical profiles are calculated where index of n_t. is undoped silica, the entire index profile of the optical fiber can be shifted linearly up (or down) in order to obtain equivalent optical fiber properties.

“Chromatic dispersion”, herein referred to as “dispersion” unless otherwise noted, of a waveguide fiber is the sum of the material dispersion, the waveguide dispersion, and the intermodal dispersion. In the case of single mode w'aveguide fibers, the inter-modal dispersion is zero. Zero dispersion wavelength is a wavelength at which the dispersion has a value of zero. Dispersion slope is the rate of change of dispersion with respect to wavelength.

“Effective area” is defined in equation 1 as:

A_eff = 2π (Jf² r drjVcff⁴ r dr) Eq. 1 where the integration limits are 0 to oo, and f is the transverse component of the electric field associated with light propagated in the waveguide. As used herein, “effective area” or “A_eff” refers to optical effective area at a wavelength of 1550 nm unless otherwise noted.

The term “α-core profile, refers to a relative refractive index profile of the core, expressed in terms of A(r) which is in units of where r is radius, which follows the equation (Eq. 2),

A(r) - A(r_o) (1 - [|r-r₀| / (r_rr₀)J ^ucore)Eq. 2 where r_o is the point at which A(r) is maximum and is the initial point of the α-core profile, Γ] is the outer radius of the core and corresponds to the final point of the core’s α-profile, it is defined as where a tangent line drawn through maximum slope of the refractive index of core crosses the zero delta line (i.e., the point at which A(r)% is zero), and r is in the range η < r < r_t, where Δ is defined above, r_o corresponds to the initial point ofthe core’s α-profile, η corresponds to the final point of the α-profile, Core_a, and a_core (also referred to herein as “core alpha”) is an exponent which is a real number. In some embodiments, the core alpha is 1 < ac_Ore < 100. In other embodiments, the core alpha is 4 < a_core< 30. In the discussion below, example values of a_wre are provided for at least some of the embodiments described herein.

The term “α-profile of the inner cladding”, also referred herein as the alpha_pedestal or Oped, refers to a relative refractive index profile of the inner cladding region, expressed in terms of Δ(γ) which is in units of “%”, where r is radius, which follows the equation (Eq. 3),

Δ(γ) - Δ(γ₂) + (Δ(_Γ1) - Δ(γ₂))( 1 - [Ir-rj | / (r₂-r₁)]^oped) Eq. 3 where r₍ is defined as above, and is typically the point at which Δ(γ) of hte inner cladding region is maximum, r₂ is the outer radius of the inner cladding and corresponds to a point at which a (vertical) line drawn through refractive index profile of inner cladding associated with its minimum refractive index crosses the zero delta line (i.e., the point at which Δ(γ)% is zero), and r is in the range r, < r < r_f, where Δ is defined above, η is the initial point of the α-profile of the inner cladding region, r_t is the final point of the α-profile of the inner cladding region, and a_ped is an exponent which is a real number (also referred to as an inner cladding alpha herein). In some embodiments, the pedestal alpha is 1 < a_ped < 100. In some embodiments, the pedestal alpha is 5 < ctj,_ed < 20.

The term “α-profile of the trench”, also referred herein as the alpha_uench or a_T, refers to a relative refractive index profile of the inner cladding region, expressed in terms of Δ(γ) which is in units of “%”, where r is radius, which follows the equation (Eq. 4),

Δ(γ) = Δ(γ₃) + (Δ(γ₂) - Δ(γ₃))(1 -[|r-r₂| / (r₃-r₂)]^aT) Eq. 4 where r, is defined as above, and is typically the point at which Δ(γ) of the trench region is maximum, r₃ is the outer radius of the inner cladding and corresponds to a point at which a (vertical) line drawn through refractive index profile of trench associated with its minimum refractive index crosses the zero delta line (i.e., the point at which Δ(γ)% is zero), and r is in the range η < r < r< _ where Δ is defined above, r_; is the initial point of the α-profile of the trench region, r_f is the final point of the α-profile of the trench region, and a_T is an exponent which is a real number (also referred to as a trench alpha herein). In some embodiments, the trench alpha is 1 < a_T < 100. In some embodiments, the pedestal alpha is 5 < a_T < 20.

The term “trench” as used herein, refers to a cladding region that has a variable refractive index with a minimum refractive index at A_3max that is lower than that of the adjacent cladding regions that are in contact therewith. The trench volume V_T is defined herein in equation 5 as:

V_mnch = 2|Δ₅_₃(γ)ζϊ/γ Eq. 5 ?2 wherein Δ₅.₃(γ) is Δ₅ - Δ₃(γ) for a given radial position r situated between the radial positions of r₂ and r₃, and wherein r₂ is the radial position where the refractive index in the trench cladding region, moving radially outward from centerline, is first equal to the refractive index of the outer cladding region. Trench volumes are reported in absolute value in units of % delta’microns². In some embodiments, the trench volumes are 0.4% delta’microns² < Vtrench < 15% delta*microns². In other embodiments, the trench volumes are 0.3% delta»microns² < Vtrench < 5% delta*microns².

The term “pedestal” as used herein, refers to a cladding region that has a refractive index Δ₂ that is higher than that of the refractive index Δ₅ cladding region that is in contact therewith. The ring volume V_pede5tal is defined herein in equation 6 as:

^r2

V_paies_ial -2jA₅_₂(r)rt/r Eq. 6 '1 wherein Δ₅.₂(γ) is Δ₅ - Δ₂(γ) for a given radial position r situated between the radial positions of Γ| and r₂, and wherein r₂ is the radial position where the refractive index in the pedestal cladding region, moving radially outward from centerline, is first equal to the refractive index of the outer cladding region. Pedestal volumes are reported in absolute value in units of % delta»microns². In some embodiments, the pedestal volumes are 1% delta«microns² < Vpedestaj < 15% delta»microns². In other embodiments, the pedestal volumes are 2% delta*microns² < Vpedestai < 6% delta*microns².

The mode field diameter (MFD) is measured using the Peterman II method wherein, 2w = MFD, and w² = (2Jf² r dr/J[df/dr]² r dr), the integral limits being 0 to ».

The term “ring” as used herein, refers to a cladding region that has a variable refractive index with a maximum refractive index at A_3max that is higher than that of the adjacent cladding regions that are in contact therewith.

The term “ring entry α-profile”, also referred to herein as the alphari_ug._entiy ^or «ïing-ent» refers to a relative refractive index profile of the inner cladding region, expressed in terms of Δ(γ) which is in units of “%”, where r is radius, which follows the equation (Eq. 7),

A(r) = Afe) + (Δ(γ,) - Δ(γ₂))(1 - [|r-r_t| / (r₂-r,)]⁰™*) Eq. 7 where ïq is defined as above, and is typically the point at which Δ(γ) of hte inner cladding region is maximum, r₂ is the outer radius of the inner cladding and corresponds to a point at which a (vertical) line drawn through refractive index profile of inner cladding associated with its minimum refractive index crosses the zero delta line (i.e., the point at which Δ(γ)% is zero), and r is in the range r₍ < r < r_f, where Δ is defined above, η is the initial point of the α-profile of the inner cladding region, r_t is the final point of the α-profile of hte inner cladding region, and a_ling._ent is an exponent which is a real number (also referred to as a ring entry alpha herein). In some embodiments, the ring entry alpha is 1 < a_ri_!lg._ent < 100. In some embodiments, the ring entry alpha is 5 < a_ring._ent < 30. In the other embodiments herein, (e.g., Figure 4 and Table 2), the ring alpha can also be referred to as a_3a.

The term “ring exit α-profile”, also referred to herein as the alpha_ring__exit or a_ring._ex, refers to a relative refractive index profile of the inner cladding region, expressed in terms of Δ(γ) which is in units of “%”, where r is radius, which follows the equation (Eq. 8),

Δ(Γ) = Δ(γ₂) + (Δ(γ₂) - Δ(γ₃))(1 - [|r-r₂| / (r-r₃).r^ig'^ex) Eq. 8 w'here r₂ is defined as above, and is typically the point at which Δ(γ) of the ring region is maximum, r₃ is the outer radius of the ring and corresponds to a point at which a (vertical) line drawn through refractive index profile of ring associated with its minimum refractive index crosses the zero delta line (i.e., the point at which Δ(γ)% is zero), and r is in the range r_; < r < r_f, where Δ is defined above, r, is the initial point of the α-profile of the ring region, r_f is the final point of the aprofile of the ring region, and a_nng,_ex is tin exponent which is a real number (also referred to as a ring exit alpha herein). In some embodiments, the ring exit alpha is 1 < a_rj_ng-exit < 100. In some embodiments, the ring exit alpha is 5 < a_lina._exil < 30. In the embodiments herein, (e.g., Figure 4 and Table 2), the ring exit alpha can also be referred to as a_3b.

The terms “pm” and “microns” can be used interchangeably herein.

The bend resistance of a waveguide fiber can be gauged by induced attenuation under prescribed test conditions, for example by deploying or wrapping the fiber around a mandrel of a prescribed diameter, e.g., by wrapping 1 turn around either a 6 mm, 10 mm, or 20 mm or similar diameter mandrel (e.g. “1x10 mm diameter macrobend loss” or the “1x20 mm diameter macrobend loss”) and measuring the increase in attenuation per turn.

One type of bend test is the lateral load microbend test. In this so-called “lateral load” test (LEWM), a prescribed length of waveguide fiber is placed between tw'o flat plates. A #70 wire mesh is attached to one of the plates. A known length of waveguide fiber is sandwiched between the plates and a reference attenuation is measured while the plates are pressed together with a force of 30 Newton. A 70 Newton force is then applied to the plates and the increase in attenuation in dB/m is measured. The increase in attenuation is the lateral load attenuation of the waveguide in dB/m at a specified wavelength (typically within the range of 1200 nm - 1700 nm, e.g., 1310 nm or 1550 nm or 1625 nm).

Another type of bend test is the wire mesh covered drum microbend loss lest (WMCD). In this test, a 400 mm diameter aluminum drum is wrapped with wire mesh. The mesh is wrapped tightly without stretching, and should have no holes, dips, or damage. Wire mesh material specification: McMaster-Carr Supply Company (Cleveland, OH), part number 85385T106, corrosion-resistant type 304 stainless steel woven wire cloth, mesh per linear inch: 165x165, wire diameter: 0.0483 mm (0.0019), width opening: 0.1041 mm (0.0041), open area %: 44.0. A prescribed length (750 meters) of waveguide fiber is wound at 1 m/s on the wire mesh drum at 0.050 cm take-up pitch while applying 80 (+/- 1) grams tension. The ends of the prescribed length of fiber are taped to maintain tension and there are no fiber crossovers. The attenuation of the optical fiber is measured at a specified wavelength (typically within the range of 1200-1700 nm, e.g., 1310 nm or 1550 nm or 1625 nm); a reference attenuation is measured on the optical fiber wound on a smooth drum. The increase in attenuation is the wire mesh covered drum attenuation of the waveguide in dB/km at a specified wavelength (typically within the range of 1200-1700 nm, e.g., 1310 nmor 1550 nm or 1625 nm).

The “pin array” bend test is used to compare relative resistance of waveguide fiber to bending. To perform this test, attenuation loss is measured for a waveguide fiber with essentially no induced bending loss. The waveguide fiber is then woven about the pin array and attenuation again measured. The loss induced by bending is the difference between the two measured attenuations. The pin array is a set of ten cylindrical pins arranged in a single row and held in a fixed vertical position on a flat surface. The pin spacing is 5 mm, center to center. The pin diameter is 0.67 mm. During testing, sufficient tension is applied to make the waveguide fiber conform to a portion of the pin surface. The increase in attenuation is the pin array attenuation in dB of the waveguide at a specified wavelength (typically within the range of 1200-1700 nm, e.g., 1310 nm or 1550 nm or 1625 nm).

The theoretical fiber cutoff wavelength, or “theoretical fiber cutoff', or “theoretical cutoff’, for a given mode, is the wavelength above which guided light cannot propagate in that mode. A mathematical definition can be found in Single Mode Fiber Optics, Jeunhomme, pp. 3944, Marcel Dekker, New York, 1990 wherein the theoretical fiber cutoff is described as the wavelength at which the mode propagation constant becomes equal to the plane wave propagation constant in the outer cladding. This theoretical wavelength is appropriate for an infinitely long, perfectly straight fiber that has no diameter variations.

Fiber cutoff is measured by the standard 2m fiber cutoff test, FOTP-80 (ΕΙΑ-ΊΊΑ-45580), to yield the “fiber cutoff wavelength”, also known as the “2m fiber cutoff’ or “measured cutoff”. The FOTP-80 standard test is performed to either strip out the higher order modes using a controlled amount of bending, or to normalize the spectral response of the fiber to that of a multimode fiber.

By cabled cutoff wavelength, or “cabled cutoff’ as used herein, we mean the 22 m cabled cutoff test described in the EIA-445 Fiber Optic Test Procedures, which are part of the EIATIA Fiber Optics Standards, that is, the Electronics Industry Alliance - Telecommunications Industry Association Fiber Optics Standards.

The ratio of MFD at 1310 nm to Cable Cutoff wavelength (MFD at 1310 nm/Cable Cutoff wavelength in microns) is defined herein as MACC.

Unless otherwise noted herein, optical properties (such as dispersion, dispersion slope, etc.) are reported for the LP01 mode.

Referring now to FIG. 1, a side view of a single mode optical fiber 10 is provided. The optical fiber 10 has a centerline AC and a radial coordinate r. The optical fiber 10 has a chlorine doped silica central core 14 of radius r_; surrounded by a cladding 18 having a maximum radius r₄. In some embodiments, the optical fiber 10 includes an undoped silica layer 22 that surrounds the cladding 18, and having a maximum radius r_liax.

The core 14 has a core alpha profile (Core_a) where 1 < Core_a< 100 and a maximum relative refractive index delta A_)max, where some embodiments are in the following ranges: 0.10%< A_lmax < 0.45%, 0.13% < A_lmax < 0.39%, 0.14% < A_lfflax < 0.37%, 0.10% < A_lmax < 0.40%, or 0.13% < Ajmax < 0.36%. In some embodiments, the core 14 has a radius r, in the range 3.5 microns < rj < 5.5 microns, 3.6 microns < r, < 4.5 microns, or 3.7 < is < 4.3.

The core 14 can be made from silica doped with chlorine (Cl) at a Cl concentration, [Cl], >1.5 wt%. The Cl concentration in the core may be > 2.0 wt%, may be > 2.5 wt%; may be > 3.0 wt%; may be > 3.5 wt%, > 4.0 wt%, > 4.5 wt%, or > 5.5 wt%; may be 1.5 wt% < [Cl] < 8.5 wt%; may be 1.5 wt% < [Cl] < 5.5 wt%; may be 2.0 wt% < [Cl] 5.5 wt%. The single mode optical fiber 10 can include the chlorine doped silica central core 14 region where the core alpha profile (CoreJ is 1 < Core_a< 100, 1 < Core_a< 10, 4 < Core_a < 30, or 10 < Core_a < 30.The core alpha profile (Core_ff) may be > 10, > 15, > 20, or > 25.

The optical fiber 10 may have a mode field diameter (MFD) at 1310 nm of > 9 microns and can be in the range of 9 microns < MFD < 9.5 microns. The optical fiber 10 can exhibit a mode field diameter at 1310 nm of 8.2 microns < MDF_)310nm < 9.6 microns or 9.0 < MDF_i3101uu<9.6.

The optical fiber 10 may have a 22 m cable cutoff less than or equal to 1260 nm, a macrobending loss at 1550 nm of < 0.75 dB/turn on a 20 mm diameter mandrel, may exhibit a

MACC number between 6.6 and 8.3, and a zero dispersion wavelength, λ₀ ranging 1300 nm < λ₀ < 1324 nm. The optical fiber 10 may have a 22 m cable cutoff less than or equal to 1260 nm, a macrobending loss at 1550 nm of < 0.70 dB/turn on a 20 mm diameter mandrel, may exhibit a MACC number between 7.1 and 8.1, a zero dispersion wavelength, λ₀ ranging 1300 nm < λ₀ < 1324 nm, and may exhibit a mode field diameter at 1310 nm of 8.2 microns < MDF|₃io,_un < 9.6 microns.

The optical fiber 10 may have a macrobending loss at 1550 nm of < 0.5 dB/turn on a 20 nun diameter mandrel. In other embodiments, the optical fiber 10 has a macrobending loss at 1550 nm of < 0.05 dB/turn on a 30 mm diameter mandrel. The optical fiber 10 may have a macrobending loss at 1550 nm of < 0.005 dB/turn on a 30 mm diameter mandrel.

The optical fiber 10 may have an outer radius for cladding 18 of about r_max =

62.5 microns. The optical fiber 10 may have an outer radius for cladding 18 of r_ItHX = 62.5 microns.

The optical fibers shown herein meet ITU G.652 and G.657A optical performance properties, and can demonstrate or yield very low macrobend and microbending losses in addition to a very low attenuation at 1310 and 1550 nm.

The optical fiber 10 may have a number of additional features as set forth below.

Pedestal and Trench Examples

Referring now to FIG. 2, a schematic cross-sectional diagram of the optical fiber 10 is shown according to the present disclosure. The optical fiber 10 may include:

(i) the chlorine doped silica based core 14 comprising the core alpha (Core_a) > 4, the radius r, and the maximum refractive index delta A_lmax%; and (ii) the cladding 18 surrounding the core 14.

The cladding 18 surrounding the core 14 may include:

a) a pedestal layer 26 adjacent to and in contact with the core 14 and having a refractive index delta A₂, a radius r₂, and a minimum refractive index delta A_2min such that A_2min<A,_max;

b) an inner cladding layer 30 or trench layer 30a adjacent to and in contact with the first inner cladding 26 having a refractive index Δ₃, a radius r₃, and a minimum refractive index delta A_3min such that Δ_3πώ) < A₂; and

c) an outer cladding 34 adjacent to and in contact with the first inner cladding 30 having a refractive index A₅ and a radius r₄ ( which in this case is r_max), such that A_3mj_n < A₂.

The optical fiber 10 may have a mode field diameter MFD at 1310 of > 9 microns, a cable cutoff of < 1260 nm, a zero dispersion wavelength ranging from 1300 nm < λ₀< 1324 nm, and a macrobending loss at 1550 nm for a 20 mm mandrel of less than 0.5 dB/tum.

Still referring now to FIG. 2, another aspect of the schematic cross-sectional diagram of the single mode optical fiber 10 is shown. The single mode optical fiber 10 may include:

(i) the chlorine doped silica central core region 14 having comprising a core alpha (Core„) > 4, a radius r₁ and a maximum refractive index delta A_lmax%; and (ii) the cladding 18 surrounding the core 14, the cladding 18 including:

a) the pedestal layer 26 adjacent to and in contact with the core 14 and having a refractive index delta Δ₂, a radius r₂, and a minimum refractive index delta ^2min such that A_2min < A_lmax;

b) the inner cladding 30 or trench layer 30a adjacent to and in contact with the pedestal layer 26 having a refractive index Δ₃, a radius r₃, and a maximum refractive index delta Δ_3ιϊβχ such that Δ_2ιη,_η < A_3max; and

c) an outer cladding region 34 surrounding the inner cladding region 30 or trench layer 30a and having a refractive index Δ₅ and a radius r₄ (which in this case is r_max), such that Δ₅ < A_3max; wherein the optical fiber has a mode field diameter MFD at 1310 of > 9 microns, a cable cutoff of < 1260 nm, a zero dispersion wavelength ranging from 1300 nm < λ₀< 1324 nm, and a macrobending loss at 1550 nm for a 20 mm mandrel of less than 0.75 dB/turn.

Referring now to FIG. 3 A, a plot of the relative refractive index profile (“index profile”) Δ versus radius r for the optical fiber 10 represented in FIG. 2. The cladding 18 of the pedestal and trench embodiments of optical fiber 10 may include two regions that progress outwardly from the core 14 in the following order: the pedestal layer 26 surrounding the core 14 having the radius r₂and the refractive index Δ₂; the inner cladding layer 30 or trench layer 30a having the radius r₃ and the refractive index D₃; and the outer cladding layer 34 having the radius r₄ (and in this case which is equal to r_max) and having the refractive index Δ₅. The respective refractive indexes of the core 14 and cladding 18 are Δ|_ΠΚΧ> Δ₅ > Δ₂> A_3min.

Referring now to FIG. 3B, an index profile Δ versus radius r for the optical fiber 10 is represented. The cladding 18 of the pedestal embodiments of optical fiber 10 may include two regions that progress outwardly from the core 14 having the radius r_b refractive index Δ], and the refractive index A_)max in the following order: the pedestal layer 26 surrounding the core 14 having the radius r₂, the refractive index Δ₂, and the alpha pedestal and the outer cladding layer 34 having a radius r₄ (and in this case which is equal to r_max) and having a refractive index Δ₅. The respective refractive indexes of the core 14 and cladding 18 are A_lmax> Δ₂> Δ₅.

Referring now to FIG. 4, an index profile Δ versus radius r for the optical fiber 10 is represented . The cladding 18 of the pedestal embodiments of optical fiber 10 may include two regions that progress outwardly from the core 14 having the radius r_1? refractive index Δ], and the refractive index A_]max in the following order:

- the pedestal layer 26 surrounding the core 14 having the radius r₂ and the refractive index Δ₂;

- the inner cladding layer 30 or ring layer 30b having the radius r₃, a ring entry alpha a_3a, a ring exit alpha a_3b, and the refractive index A_3jnax; and

- the outer cladding layer 34 having the radius r₄ (and in this case which is equal to r_max) and having the refractive index Δ₅.

The respective refractive indexes of the core 14 and cladding 18 tire A_iJnax > Δ_3ηΗΧ > Δ₅ > Δ₂.

The pedestal layer 26 can be made from silica doped with chlorine (Cl) at a Cl concentration, [Cl], > 0.2 wt%. The Cl concentration in the pedestal may be > 0.4 wt%; may be > 0.5 wt%; may be > 0.7 wt%; may be > 1.0 wt%; may be 0.2 wt% < [Cl] < 1.5 wt%; may be 0.5 wt% < [Cl] <1.5 wt%; The pedestal layer 26 can be made from silica doped with fluorine (F) at a F concentration, [F], > 0.2 wt%. The F concentration in the pedestal may be > 0.5 wt%, > 0.7 wt%, or > 1 wt%.

Adjacent cladding regions can be coupled with one another while the pedestal layer 26 is in contact and coupled with the core 14. Inner cladding or trench layer 30a can be positioned outside and in contact with the pedestal layer 26. The outer cladding layer 34 can be positioned outside and in contact with inner cladding or trench layer 30a. Outer cladding layer 34 can be adjacent to and in contact with the outermost layer 22 of undoped silica.

The inner cladding or trench layer 30a can be made from undoped silica or silica doped with chlorine (Cl) at a Cl concentration, [Cl], >0.1 wt%. The Cl concentration in the inner cladding or trench layer 30a may be > 0.4 wt%; may be 0 wt% < [Cl] < 1.5 wt%. The inner cladding or trench layer 30a can be made from silica doped with fluorine (F) at a F concentration, [F], > 0.2 wt%. The F concentration in the pedestal may be > 0.5 wt%, > 0.7 wt%, or > 1 wt%. The F concentration in the inner cladding or trench layer 30a may be 0 wt% < [F] < 1.5 wt%.

The outer cladding layer 34 can be made from undoped silica or silica doped with chlorine (Cl) at a chlorine concentration, [Cl], > 0.1 wt%. The Cl concentration in the outer cladding layer 34 may be > 0.4 wt%; may be 0 wt% < [Cl] < 1.5 wt%. The outer cladding layer 34 can be made from silica doped with fluorine (F) at a F concentration, [Fj, > 0.2 wt%. The F concentration in the pedestal may be > 0.5 wt%, > 0.7 wt%, or > 1 wt%. The F concentration in the outer cladding layer 34 may be 0 wt% < [F] 1.5 wt%.

The chlorine concentration in the core 14 in wt%, [Cl]_core, to the fluorine concentration in the pedestal wt%, [F]_pedestal, can be greater than or equal to 1, i.e., ([ClJ_core/[F]_ped(._stal) > 1, for example ([Clj_core/[Fj_pedestal) > 2, whereby ([Crj_core/[F]_pedest;il) can be > 10.

The chlorine concentration in the core 14 wt%, [Cl]_TOre, to the fluorine concentration in the trench in wt%, [F]_ffench, can be is greater than or equal to 1, i.e., ([Clkore/LFJtrench) > l,for example ([ClJcore/fF]^*) > 2, whereby ([Cl]_core/[FJ_trcnch) can be > 10.

Table 1 below sets forth eight examples (Ex. 1.1 through Ex. 1.8) of the Pedestal and

Trench Examples used in the optical fiber 10 where the core dopant is chlorine and the pedestal dopant is at least one of chlorine or fluorine. In some examples the outer clad dopant (referred to in Table 1 as Δ₅) is chlorine. The term “na” refers to “not applicable.” The term “Attn” refers to attenuation.

Table 1

Parameter	Ex. 1.1	Ex. 1.2	Ex. 1.3	Ex. 1.4	Ex. 1.5	Ex. 1.6	Ex. 1.7	Ex. 1.8
Core, Almax, /q	0.15	0.15	0.36	0.37	0.375	0.373	0.38	0.362
Γ(, microns	4.20	4.00	4.25	4.50	4.46	4.65	4.55	4.0
Core alpha,	20	100	10	6.7	6.0	4.5	10	100
Core dopant	Cl	Cl	Cl	Cl	Cl	Cl	Cl	Cl
δ2,%	-0.18	-0.13	0.087	0.087	0.10	0.087	0.10	0.10
r2, microns	10.0	6.5	5.85	5.79	5.73	5.85	6.20	5.70
Pedestal alpha	20	20	20	20	20	20	20	20
Pedestal dopant	F	F	Cl	Cl	Cl	Cl	Cl	Cl
Pedestal volume, % delta’microns2	2.5	1.8	1.4	1.2	1.3	1.1	1.2	1.6
	-0.23	-0.23	0.00	0.00	0.00	0.00	0.00	0.00
r3, microns	20	15	na	na	na	na	15	na
Trench alpha	20	20	na	na	na	na	20	na
Trench volume, % delta»microns2	6.0	5.5	na	na	na	na	5.6	na
δ5, %	-0.21	-0.20	0.00	0.00	0.00	0.00	0.03	0.00
Δ5dopant	F	F	na	na	na	na	Cl	na
rmM, microns	62.5	62.5	62.5	62.5	62.5	62.5	62.5	62.5
Dispersion at 1310 nm (ps/nm/km)	0.37	0.20	-0.12	0.14	0.03	-0.13	0.32	0.31
Dispersion Slope at 1310 nm, (ps/nm2/km)	0.085	0.089	0.088	0.088	0.088	0.088	0.089	0.088

Dispersion at 1550 nm, (ps/nm/km)	16.7	17.5	17.0	17.2	17.2	17.1	17.6	17.4
Dispersion at Slope 1550 nm, (ps/nm2/km)	0.059	0.060	0.059	0.059	0.060	0.060	0.060	0.059
MFD at 1310 nm, microns	9.09	9.18	9.18	9.16	9.14	9.20	9.18	9.19
MFD at 1550 nm, microns	10.4	10.4	10.4	10.4	10.4	10.5	10.3	10.4
LLWM @ 1550nm, dB/m	0.362	0.40	0.45	0.33	0.32	0.42	0.43	0.33
WMCD at 1550 nm, dB/km	<0.05	<0.05	<0.05	<0.05	<0.05	<0.05	<0.05	<0.06
Pin Array at 1550 nm, dB	3.1	6.9	6.4	4.5	4.3	5.7	7.9	4.2
Zero dispersion wavelength, λο, nm	1318	1315	1319	1316	1317	1319	1314	1314
22 m Cable Cutoff, , nm	1191	1259	1225	1254	1255	1240	1254	1256
MACC (MFD at 1310 nm/Cable Cutoff)	7.63	7.29	7.5	7.3	7.3	7.4	7.3	7.3
Macrobend loss 1x20mm mandrel, dB/turn at 1550nm	0.27	0.15	0.25	0.19	0.18	0.23	0.18	0.18
Macrobend loss 1x30mm mandrel, dB/turn at 1550nm	0.002	0.003	0.004	0.003	0.003	0.003	0.003	0.0025
Attn at 1550 nm, dB/km	<0.17	<0.17	<0.17	<0.17	<0.17	<0.17	<0.17	<0.17
Attn at 1310 nm, dB/km	<0.31	<0.31	<0.31	<0.31	<0.31	<0.31	<0.31	<0.31

The results from the modeled optical fibers in Table 1 show optical fibers that meet

ITU G.652 and G.657A optical performance properties, have very low macrobend and microbending losses and very low attenuation at 1310 and 1550 nm. In these examples, in wt% ([Cl]_core)/wt% [F]_pedestaJ, the ([Cl]_TOre/[F]_pedest_!d) > 1. In these examples in wt% ([Cl]_core/wt% [FJ^h, the ([ClJeore/EFJ^h > 1.

Referring now to FIG. 5 or Example 1.1, an index profile Δ versus radius r for the optical fiber 10 is represented. The cladding 18 of the pedestal example of optical fiber 10 may include two regions that progress outwardly from the core 14 having the radius r,, refractive index

A,, and the refractive index A_lmax in the following order:

- the pedestal layer 26 surrounding the core 14 having the radius r₂, the alpha pedestal Opedestat and the refractive index Δ₂;

- the inner cladding layer 30 or trench layer 30a having the radius r₃, an alpha trench Otrench, and the refractive index Δ₃; and

- the outer cladding layer 34 having the radius r₄ (and in this case which is equal to rmax) and having the refractive index Δ₅.

The respective refractive indexes of the core 14 and cladding 18 are A_imax> Δ₂> Δ₅> Δ₃.

Referring now to FIG. 6 or Example 1.2, an index profile Δ versus radius r for the optical fiber 10 is represented. The cladding 18 of the pedestal example of optical fiber 10 may include two regions that progress outwardly from the core 14 having the radius r,, refractive index Δ], and the refractive index A_lmax in the following order:

- the pedestal layer 26 surrounding the core 14 having the radius r₂, the alpha pedestal Opedestat and the refractive index Δ₂;

- the inner cladding layer 30 or trench layer 30a having the radius r₃, an alpha trench ÖB-ench, and the refractive index Δ₃; and

- the outer cladding layer 34 having the radius r₄ (and in this case which is equal to r_max) and having the refractive index Δ₅.

The respective refracti ve indexes of the core 14 and cladding 18 are A_imax> Δ₂> Δ₅> Δ₃.

Referring now to FIGS. 7-10 or Examples 1.3-1.6, an index profile Δ versus radius r for some the optical fiber 10 is represented. The cladding 18 of the pedestal example of optical fiber 10 may include two regions that progress outwardly from the core 14 having the radius r_b refractive index A_t, and the refractive index Δ_11ιωχ in the following order:

- the pedestal layer 26 surrounding the core 14 having the radius r₂, the alpha pedestal Opedestat and the refractive index Δ₂; and

- the inner cladding layer 30 or trench layer 30a having the radius r₃ (and in this case which is equal to r_niax) and the refractive index Δ₃.

The respective refractive indexes of the core 14 and cladding 18 are Δ_1ηκχ> Δ₂> Δ₃.

Referring now to FIG. 11 or Example 1.7, an index profile Δ versus radius r for the optical fiber 10 is represented. The cladding 18 of the pedestal example of optical fiber 10 may include two regions that progress outwardly from the core 14 having the radius r_)? refractive index Δι, and the refractive index Δ_1πΕ1χ in the following order:

- the pedestal layer 26 surrounding the core 14 having the radius r₂, the alpha pedestal a_pedestill and the refractive index Δ₂;

- the inner cladding layer 30 or trench layer 30a having the radius r₃, an alpha trench toench, and the refractive index Δ₃; and

- the outer cladding layer 34 having the radius r₄ (and in this case which is equal to r_max) and having the refractive index Δ₅.

The respective refractive indexes ofthe core 14 and cladding 18 are Δ_1ηκχ> Δ₂> Δ₅> Δ₃.

Referring now to FIG. 12 or Example 1.8, an index profile Δ versus radius r for the optical fiber 10 is represented. The cladding 18 of the pedestal example of optical fiber 10 may include two regions that progress outwardly from the core 14 having the radius r_B refractive index Δ₍, and the refractive index A_lmax in the following order:

- the pedestal layer 26 surrounding the core 14 having the radius r₂, the alpha pedestal a_pedestai and the refractive index Δ₂; and

- the inner cladding layer 30 or trench layer 30a having the radius r₃ (and in this case which is equal to r_max) and the refractive index Δ₃.

The respective refractive indexes ofthe core 14 and cladding 18 are Δ_1ΙΠί1χ> Δ₂> Δ₃.

Table 2 below sets forth two examples (Ex. 2.1 and Ex. 2.2) of Ring examples used in the optical fiber 10 where the core dopant is chlorine and the ring (Δ₂), as well as Δ₃ and Δ4 dopant is chlorine.

Table 2

Parameter	Ex. 2.1	Ex. 2.2
Core, Δ iniax, /0	0.352	0.38
Γ], microns	4.30	4.53
Core alpha, Δ core	20	20
Core dopant	Cl	Cl
Δ 2,%	0.00	0.00
r2, microns	5.33	5.48
Δ 3max, %	0.10	0.10
r3, microns	6.28	6.55
Ring entry alpha, Δ 3a	20	20
Ring exit alpha, Δ 3b	20	20
Ring dopant	Cl	Cl
δ5,%	0.00	0.03
Δ 5 dopant	none	Cl
rmax, microns	62.5	62.5
Dispersion at 1310 nm (ps/nm/km)	-0.55	-0.59

Dispersion Slope at 1310 nm, (ps/nm2/km)	0.087	0.088
Dispersion at 1550 nm, (ps/nm/km)	16.5	16.7
Dispersion at Slope 1550 nm, (ps/nm2/km)	0.06	0.06
MFD at 1310 nm, microns	9.20	9.20
MFD at 1550 nm, microns	10.5	10.5
LLWM at 1550 nm, dB/m	0.57	0.53
WMCD at 1550 nm, dB/km	< 0.05	< 0.05
Pin Array at 1550 nm, dB	8.0	7.5
Zero dispersion wavelength, , nm	1316	1317
22 m Cable Cutoff, Xc, nm	1200	1205
MACC ( MFD at 1310 nm/Cable Cutoff)	7.67	7.63
Macrobend loss 1 x20mm mandrel, dB/turn at 1550nm	0.41	0.33
Macrobend loss 1x30mm mandrel, dB/turn at 1550nm	0.005	0.004
Attn at 1550 nm, dB/km	<0.17	<0.17
Attn at 1310 nm, dB/km	<0.31	<0.31

The results from the modeled optical fibers in Table 2 show optical fibers that meet

ITU G.652 and G.657A optical performance properties, have very low macrobend and microbending losses and very low attenuation at 1310 and 1550 nm.

Referring now to FIG. 13 or Example 2.1, an index profile Δ versus radius r for the optical fiber 10 is represented. The cladding 18 of the pedestal examples of optical fiber 10 may include two regions that progress outwardly from the core 14 having the radius r_1; refractive index Δ₍, and the refractive index Δ_!ιη£ιχ in the following order:

- the pedestal layer 26 surrounding the core 14 having the radius r₂ and the refractive index Δ₂;

- the inner cladding layer 30 or ring layer 30b having the radius r₃, the ring entry alpha α^_α, the ring exit alpha a_3b, and the refractive index A_3max; and

- the outer cladding layer 34 having the radius r₄ (and in this case which is equal to r_11!ax) and having the refractive index Δ₅.

The respective refractive indexes of the core 14 and cladding 18 are A_!max> Δ_311ΒΧ and Δ₅ = Δ₂.

Referring now to FIG. 14 or Example 2.2, an index profile Δ versus radius r for the optical fiber 10 is represented. The cladding 18 of the pedestal examples of optical fiber 10 may include two regions that progress outwardly from the core 14 having the radius r₁₍ refractive index Δ₍, and the refractive index Δ_!ιη£ιχ in the following order:

- the pedestal layer 26 surrounding the core 14 having the radius r₂ and the refractive index Δ₂;

- the inner cladding layer 30 or ring layer 30b having the radius r₃, the ring entry alpha a_3a, the ring exit alpha a_3b, and the refractive index A_3max; and

- the outer cladding layer 34 having the radius r₄ (and in this case which is equal to r_11!ax) and having the refractive index Δ₅.

The respective refractive indexes of the core 14 and cladding 18 are Δ_!πκχ> Δ_311ιαχ > Δ₅> Δ₂.

The A_imax ranges can be from 0.10% < Δ_1ηκ(Χ < 0.45%, 0.13% < A_imax < 0.39%, 0.14% < A_]max < 0.37%, 0.10% < A_lmax < 0.40%, or 0.13% < A_iJnax < 0.36%. In other examples A_lmaxcan be 0.12%, 0.13%, 0.14%, 0.15%, 0.16%, 0.17%, 0.18%, 0.33%, 0.34%, 0.35%, 0.36%, 0.37%, 0.38%, or 0.39%.

The pedestal radius r₂ ranges can be from 4.5 microns < r₂ < 20.5 microns, 4.5 microns < r₂ < 7.5 microns, 5.3 microns < r₂ < 17.5 microns, 5.3 microns < r₂ < 8.0 microns, 5.5 microns < r₂ < 20.5 microns, 7.5 microns < r₂ < 17.5 microns, 6.0 microns < r₂ < 17.5 microns, or 9.0 microns < r₂ < 16.0 microns. r₂ can be about 6.0 microns, 6.3 microns, 6.5 microns, 6.8 microns, 7.0 microns, 7.3 microns, 10.0 microns, 12.5 microns, 15.0 microns, 17.5 microns, or 20.5 microns.

The refractive index Δ₂ ranges can be from 0% < Δ₂ < 1.0% or 0% < Δ₂ < 0.5%, 0% < Δ₂ < 0.1%. Δ₂ can be about 0.01%, 0.03%, 0.05%, 0.07%, or 0.09%.

Pedestal volumes are reported in absolute value in units of % delta*microns². The pedestal volumes can be 0.5% delta*microns² < Vpedestal < 15% delta»microns², preferably 0.5% delta»microns² < VpedesIal < 6% delta·microns². Trench volumes are reported in absolute value in units of % delta*microns². The trench volumes can be 1% delta’microns² < V_he,_Kh < 15% delta»microns² preferably 2% delta’microns² < Vn-ench < 6% delta»microns².

The inner cladding or trench radius r₃ ranges can be from 15.0 microns < r₃< 75.0 microns, 15.0 microns < r₃< 65.0 microns, 15.0 microns < r₃ < 30.0 microns, or 50.0 microns < r₃ < 70.0 microns. In other embodiments, r₃can be about 15.0 microns, 20.0 microns, 25.0 microns, 30.0 microns, 35.0 microns, 40.0 microns, 45.0 microns, 50.0 microns, 55.0 microns, 60.0 microns, 65.0 microns, 7.3 microns, 10.0 microns, 12.5 microns, 15.0 microns, 17.5 microns, or 20.5 microns.

The Δ₃ may include both a Δ_311ΜΧ and a A_3min. The refractive index Δ_3πκχ ranges can be from -1.5% < A_3max < 1.5%, -0.5% < Δ_3ιηί1χ < 0.5%, 0% < Δ_311ΗΧ < 1.0%, 0% < Δ_3μιχ < 0.5%, or 0% < Δ_3ιϊβχ < 0.05%. Δ_311ΏΧ can be about 0%, 0.01%, 0.03%, 0.05%, 0.07%, 0.09%, -0.01%, -0.03%, 0.05%, -0.07%, or -0.09%. The refractive index Δ_3ηώ1 ranges can be from -1.5% < A_3min < 1.5%, 0.5% < A_3min < 0.5%, 0% < Δ_3πώ1 < 1.0%, 0% < A_3min < 0.5%, or 0% < A_3min < 0.05%. A_3mill can be about 0%, 0.01%, 0.03%, 0.05%, 0.07%, 0.09%, -0.01%, -0.03%, -0.05%, -0.07%, or -0.09%.

The r_maxcan be about 62.5 microns. The refractive index Δ₅ ranges can be from -1.5% < Δ₅ < 1.5%, -0.5% < Δ₅ < 0.5%, 0% < Δ₅ < 1.0%, 0% < Δ₅ < 0.5%, or 0% < Δ₅ < 0.05%. In other embodiments, Δ₅ can be about 0%, 0.01%, 0.03%, 0.05%, 0.07%, 0.09%, 0.10%, 0.15%, 0.20%, 0.25%, -0.01%, -0.03%, -0.05%, -0.07%, -0.09%, -0.10%, -0.15%, -0.20, or -0.25%.

The optical fiber 10 can have a macrobending loss at 1550 nm of < 0.75 dB/turn on a 20 mm diameter mandrel. The optical fiber 10 can have a macrobending loss at 1550 nm of 0.5 dB/turn on a 20 mm diameter mandrel. The optical fiber 10 can have a macrobending loss at 1550 nm of < 0.05 dB/turn on a 30 mm diameter mandrel. The optical fiber 10 can have a macrobending loss al 1550 nm of < 0.005 dB/turn on a 30 mm diameter mandrel.

The optical fiber 10 may exhibit the wire mesh covered drum microbend loss, WMCD, at 1550 nm is < 0.1 dB/km. In other embodiments, the wire mesh covered drum microbend loss, WMCD, at 1550 nm is < 0.05 dB/km.

The attenuation at 1550 nm can be < 0.19 dB/km for the pedestal examples. The attenuation at 1550 nm can be < 0.18 dB/km for the pedestal examples. The attenuation at 1550 nm can be < 0.17 dB/km for the pedestal examples.

The attenuation at 1310 nm can be < 0.33 dB/km, can be < 0.32 dB/km, and can be < 0.31 dB/km for the pedestal examples.

The attenuation at 1550 nm can be < 0.19 dB/km; can be < 0.18 dB/km, and can be <0.17 dB/km for the ring examples.

The attenuation at 1310 nm can be < 0.33 dB/km, can be < 0.32 dB/km, and can be <0.31 dB/km for the ring examples.

The optical fiber 10 can have a zero dispersion wavelength, λ₀, and 1300 nm < <

1324 nm.

The optical fiber 10 may exhibit a mode field diameter at 1310 nm (MDF_J3]Onm) of 8.2 < MDF|₃₁()_nm < 9.6 microns. The optical fiber 10 may exhibit a mode field diameter at 1310 nm of 9.0 microns < MDFi_310nm < 9.5 microns.

Referring now to FIG. 4, a plot or profile schematic of the relative refractive index profile (“index profile’’) Δ versus radius r for some aspects of the optical fiber 10 represented in FIG. 2. The optical fiber 10 represented by FIG. 4 include the chlorine doped core 14 with a gradual transition in refractive index between Δ₃ and Δ₅. The respective refractive indexes of the core 14 and cladding 18 can be Δ,_Μ1Χ> Δ₅ > Δ₂ > Δ_31ιώ1.

The core and cladding of the present coated fibers may be produced in a single-step operation or multi-step operation by methods which are well known in the art. Suitable methods include:

- the double crucible method, rod-in-tube procedures; and

- doped deposited silica processes, also commonly referred to as chemical vapor deposition (“CVD”) or vapor phase oxidation.

A variety of CVD processes are known and are suitable for producing the core and cladding layer used in the coated optical fibers disclosed herein. They include external CVD processes, axial vapor deposition processes, modified CVD (MCVD), inside vapor deposition, and plasma-enhanced CVD (PECVD).

The glass portion of the coated fibers may be drawn from a specially prepared, cylindrical preform which has been locally and symmetrically heated to a temperature sufficient to soften the glass, e.g., a temperature of about 2000 °C for a silica glass. As the preform is heated, such as by feeding the preform into and through a furnace, a glass fiber is drawn from the molten material. See, for example, U.S. Patent Nos. 7,565,820; 5,410,567; 7,832,675; and 6,027,062; the disclosures of which are hereby incorporated by reference herein, for further details about fiber making processes.

The optical fibers 10 described in the pedestal and trench chlorine examples herein may include one or more coatings positioned between the chlorine doped silica central core 14 region and the one or more layers of cladding 18. There can be a primary coating in contact with the outer radius of the chlorine doped silica central core 14 region and a secondary coating in contact with the outer radius of the primary coating.

The primary coating may be formed from a curable composition that includes an oligomer and a monomer. The oligomer may be a urethane acrylate or a urethane acrylate with acrylate substitutions. The urethane acrylate with acrylate substitutions may be a urethane methacrylate. The oligomer may include urethane groups. The oligomer may be a urethane acrylate that includes one or more urethane groups. The oligomer may be a urethane acrylate with acrylate substitutions that includes one or more urethane groups. Urethane groups may be formed as a reaction product of an isocyanate group and an alcohol group.

The primary coating may have an in situ modulus of elasticity of 10 bar (1 MPa) or less, 5 bar (0.50 MPa) or less, 2.5 bar (0.25 MPa) or less, 2 bar (0.20 MPa) or less, 1.9 bar (0.19 MPa) or less, 1.8 bar (0.18 MPa) or less, 1.7 bar (0.17 MPa) or less, 1.6 bar (0.16 MPa) or less, or

1.5 bar (0.15 MPa) or less. The glass transition temperature of the primary coating may be -15 °C or less, -25 °C or less, -30 °C or less, or -40 °C or less.

The secondary coating may be formed from a curable secondary composition that includes one or more monomers. The one or more monomers may include bisphenol-A diacrylate, or a substituted bisphenol-A diacrylate, or an alkoxylated bisphenol-A diacrylate. The alkoxylated bisphenol-A diacrylate may be an ethoxylated bisphenol-A diacrylate. The curable secondary composition may further include an oligomer. The oligomer may be a urethane acrylate or a urethane acrylate with acrylate substitutions. The secondary composition may be free of urethane groups, urethane acrylate compounds, urethane oligomers or urethane acrylate oligomers.

The secondary coating may be a material with a higher modulus of elasticity and higher glass transition temperature than the primary coating. The in situ modulus of elasticity of the secondary coating may be 12,000 bar (1,200 MPa) or greater, 15,000 bar (1500 MPa) or greater, 18,000 bar (1800 MPa) or greater, 21,000 bar (2100 MPa) or greater, 24,000 bar (2,400 MPa) or greater, or 27,000 bar (2,700 MPa) or greater. The secondary coating may have an in situ modulus between about 15,000 bar (1,500 MPa) and 100,000 bar (10,000 MPa) or between 15,000 bar (1,500 MPa) and 50,000 bar (5,000 MPa). The in situ glass transition temperature of the secondary coating may be at least 50 °C, at least 55 °C, at least 60 °C or between 55 °C and 65 °C.

The radius of the coated fibers coincides with the outer diameter of the secondary coating. The radius of the coated fiber may be 125 pm or less, 110 pm or less, 105 pm or less, or 100 pm or less. In some embodiments, the coated optical fiber diameter is 150 microns < coated optical fiber diameter < 210 microns. Within the coated fiber, the glass radius (coinciding with the outer diameter of the cladding) may be at least 50 pm, at least 55 pm, at least 60 pm, or at least

62.5 pm. The chlorine doped silica central core 14 region may be surrounded by the primary coating. The outer radius of the primary coating may be 85 pm or less, 82.5 pm or less, 80 pm or less, 77.5 pm or less, or 75 pm or less. The balance of the coated fiber diameter is provided by the secondary coating.

EXAMPLES

Example A is a single mode optical fiber comprising:

(i) a chlorine doped silica based core comprising a core alpha (CoreJ > 4, a radius η and a maximum refractive index delta A_lmax; and (ii) a cladding surrounding the core, the cladding comprising:

a) a first inner cladding region adjacent to and in contact with the core and having a refractive index delta Δ₂, a radius r₂, and a minimum refractive index delta A_2min such that Δ_2πώ) < A_imax; and

b) an outer cladding region surrounding the second inner cladding region and having a refractive index Δ₅ and a radius r_niax, such that Δ_2ηιίη> Δ₅.

The optical fiber has a mode field diameter MFD at 1310 of > 9 microns, a cable cutoff of < 1260 nm, a zero dispersion wavelength ranging from 1300 nm < < 1324 nm, and a macrobending loss at 1550 nm for a 20 mm mandrel of less than 0.75 dB/turn.

The single mode optical fiber of example A comprising a second inner cladding adjacent to and in contact with the first inner cladding and having a refractive index Δ₃, a radius r₃, and a minimum refractive index delta Δ_3ιώη such that Δ_;,_Λ1ίη < Δ₂.

The single mode optical fiber of example A or example A with any of the intervening features wherein the outer cladding region surrounding the second inner cladding region has a refractive index Δ₅ and a radius r_max, such that Δ_3ηιίη < Δ₅.

The single mode optical fiber of example A or example A with any of the intervening features further comprising a chlorine concentration in the core of > 1.5 wt%.

The single mode optical fiber of example A or example A with any of the intervening features wherein the macrobending loss at 1550 nm is < 0.5 dB/turn on a 20 mm diameter mandrel.

The single mode optical fiber of example A or example A with any of the intervening features wherein the maximum refractive index Δ _lmax ranges from 0.10% < Δ_1ηΏΧ < 0.45%.

The single mode optical fiber of example A or example A with any of the intervening features wherein the minimum refractive index Δ_3ιηιη is -0.5% < A_3min < 0.25%.

The single mode optical fiber of example A or example A with any of the intervening features wherein the minimum refractive index A_3minis -0.25% < Δ_311ώ1 < 0.15%.

The single mode optical fiber of example A or example A with any of the intervening features wherein the outer radius r₃ is 12.0 microns < r₃ < 25.0 microns.

The single mode optical fiber of example A or example A with any of the intervening features wherein the macrobending loss exhibited by the optical fiber at 1550 nm is < 0.70 dB/turn on a 20 mm diameter mandrel and exhibits a MACC number between 7.1 and 8.1.

Example B is a single mode optical fiber comprising:

(i) a chlorine doped silica based core comprising a core alpha (CoreJ > 4, a radius r_b and a maximum refractive index delta Δ_1πΕ1χ; and (ii) a cladding surrounding the core, the cladding comprising:

a) a first inner cladding region adjacent to and in contact with the core and having a refractive index delta Δ₂, a radius r₂, and a minimum refractive index delta Δ_2η1ί_η such that A_2min ^< A_lmax;

b) a second inner cladding adjacent to and in contact with the first inner cladding and having a refractive index Δ₃, a radius r₃, and a maximum refractive index delta Δ_3πβχ such that A_2mi_n < A_3inax; and

c) an outer cladding region surrounding the second inner cladding region and having a refractive index Δ₅ and a radius r_niax, such that Δ₅ < Δ_3πΕ1χ.

The optical fiber has a mode field diameter MFD at 1310 of > 9 microns, a cable cutoff of < 1260 nm, a zero dispersion wavelength ranging from 1300 nm < λ₀ < 1324 nm, and a macrobending loss at 1550 nm for a 20 mm mandrel of less than 0.75 dB/turn.

The single mode optical fiber of example B further comprising a chlorine concentration in the core of > 1.5 wt%.

The single mode optical fiber of example B or example B with any of the intervening features wherein the macrobending loss at 1550 nm is < 0.5 dB/turn on a 20 mm diameter mandrel.

The single mode optical fiber of example B or example B with any of the intervening features wherein the macrobending loss at 1550 nm of < 0.005 dB/turn on a 30 mm diameter mandrel.

The single mode optical fiber of example B or example B with any of the intervening features wherein the maximum refractive index _iJnax ranges from 0.10% < A_iJnax < 0.45%.

The single mode optical fiber of example B or example B with any of the intervening features w'herein Core_a >15.

The single mode optical fiber of example B or example B with any of the intervening features wherein the maximum refractive index A_3maxis -0.5% < A_3jnin < 0.25%.

The single mode optical fiber of example B or example B with any of the intervening features wherein the outer radius r₃ is 15.0 microns < r₃< 15.0 microns.

The single mode optical fiber of example B or example B with any of the intervening features wherein the macrobending loss exhibited by the optical fiber at 1550 nm is < 0.70 dB/turn on a 20 mm diameter mandrel and exhibits a MACC number between 7.1 and 8.1.

The single mode optical fiber of example B or example B with any of the intervening features w'herein the optical fiber has a wire mesh covered drum microbend loss, (WMCD) at 1550 nm of < 0.1 dB/km.

Claims (22)

1. CLAUSES

   1. An optical fiber comprising:

   i) a chlorine doped silica based core having a radius o and a maximum refractive index delta A_lmax, ii) a cladding surrounding the core, adjacent to and in contact with the core, having a refractive index delta A₂, a radius r₂, and a minimum refractive index delta A_2min such that A_2min < A]max·
2. 2. The optical fiber according to clause 1, wherein the chlorine doped silica based core comprises a core alpha (Core_a) > 4.
3. 3. The optical fiber according to clause 1 or 2, having:

   - a mode field diameter MFD at 1310 of > 9 microns;

   - a cable cutoff of < 1260 nm;

   - a zero dispersion wavelength ranging from 1300 nm < λ₀ < 1324 nm; and

   - a macrobending loss at 1550 nm for a 20 mm mandrel of less than 0.75 dB/turn.
4. 4. The optical fiber of any of the clauses 1-3, further comprising a second inner cladding adjacent to and in contact with the first inner cladding surrounding the core, wherein the second inner cladding has a refractive index A₃, and a radius r₃.
5. 5. The optical fiber according to clause 4, wherein the second inner cladding has a minimum refractive index delta A_3min such that A_3mi„ < A₂
6. 6. The optical fiber according to clause 4 or 5, wherein the second inner cladding has a maximum refractive index delta A_3max such that A_2min< A_3111ax
7. 7. The optical fiber according to any of the preceding clauses, further comprising an outer cladding region.
8. 8. The optical fiber according to clause 7, wherein the outer cladding region has a refractive index A₅ and a radius r_max, such that A_2mm > A₅.
9. 9. The optical fiber according to clause 6, further comprising an outer cladding region having a refractive index A₅ and a radius r_max, with one or more of the following:

   - whereby Δ_21Ι1ίη > Δ₅;

   - whereby Δ₅ < Δ_3ηΐΜ; and

   - whereby Δ_31Λ1ίη < Δ₅.
10. 10. The optical fiber of any of the preceding clauses, further comprising a chlorine concentration in the core of > 1.5 wt%.
11. 11. The optical fiber of any of the preceding clauses, wherein the macrobending loss at

    1550 nm is < 0.5 dB/turn on a 20 mm diameter mandrel.
12. 12. The optical fiber of any of the preceding clauses, wherein the maximum refractive index Δ _lmax ranges from 0.10% < Δ_1π):ίχ < 0.45%.
13. 13. The optical fiber of any of the preceding clauses 5-12, when depend on clause 5, wherein the minimum refractive index A_3minis -0.5% < A_3min < 0.25%, preferably wherein the minimum refractive index A_3minis -0.25% < A_3min < 0.15%.
14. 14. The optical fiber of any of the clauses 4-13, when depended on clause 4, wherein the outer radius r₃ is 12.0 microns < r₃ < 25.0 microns.
15. 15. The optical fiber of any of the preceding clauses, wherein the macrobending loss exhibited by the optical fiber at 1550 nm is < 0.70 dB/tum on a 20 mm diameter mandrel and exhibits a MACC number between 7.1 and 8.1.
16. 16. The optical fiber according to any of the preceding clauses, being a single mode optical fiber.
17. 17. The optical fiber of any of the preceding clauses, wherein the macrobending loss at 1550 nm of < 0.005 dB/turn on a 30 mm diameter mandrel.
18. 18. The optical fiber according to any of the preceding clauses, wherein the chlorine doped silica based core comprises a core alpha (Core_a) >15.
19. 19. The optical fiber of any of the preceding clauses 6-18, when depend on clause 6, wherein the maximum refractive index A_3maxis -0.5% < A_3mi„ < 0.25%.
20. 20. The optical fiber of any of the preceding clauses 4-19, when depend on clause 4, wherein the outer radius r₃ is 15.0 microns < r₃ < 15.0 microns.
21. 21. The optical fiber according to any of the preceding clauses 3- 20, when depend on

    5 clause 3, wherein the macrobending loss exhibited by the optical fiber at 1550 nm is < 0.70 dB/turn on a 20 mm diameter mandrel and exhibits a MACC number between 7.1 and 8.1.
22. 22. The optical fiber according to any of the preceding clauses 3-21, when depend on clause 3, wherein the optical fiber has a wire mesh covered drum microbend loss, (WMCD) at

    10 1550 nm of <0.1 dB/km.

    CONCLUSIES

    1. Optische vezel omvattende:

    i) een chloor gedoteerde siliciumgebaseerde kern met een straal r₁ en een maximum brekingsindex delta A_lmax; en ii) een bekleding die de kern omgeeft, aanliggend en in contact met de kern is, en een brekingsindex delta Δ₂, een straal r₂, en een minimum brekingsindex delta A_2min zodat Δ_21Λ1ίη < A_imax heeft.

    2. De optische vezel volgens conclusie 1, waarbij de chloor gedoteerde siliciumgebaseerde kern een kern alpha (Core_a) > 4 omvat.

    3. De optische vezel volgens conclusie 1 of 2, voorzien van:

    - een veldmodusdiameter MFD van 1310 bij > 9 micron;

    - een kabeldoorsnede van < 1260 nm;

    - een nul dispersiegolflengte in het bereik van 1300 nm < λο < 1324 nm; en

    - een macrobuigingsverlies bij 1550 nm voor een 20 mm spil van minder dan 0.75 dB/rotatie.

    4. De optische vezel volgens één der conclusies 1-3, verder omvattende een tweede binnenbekleding aanliggend en in contact met de eerste binnenbekleding die de kern omgeeft, waarbij de tweede binnenbekleding een brekingsindex Δ₃ en een straal r₃ heeft.

    5. De optische vezel volgens conclusie 4, waarbij de tweede binnenbekleding een minimum brekingsindex delta Δ_3ηιίη zodat A_3mm < Δ₂ heeft.

    6. De optische vezel volgens conclusie 4 of 5, waarbij de tweede binnenbekleding een maximum brekingsindex delta A_3max zodat A_2min < Δ_3πμχ heeft.

    7. De optische vezel volgens één der voorgaande conclusies, verder omvattende een buitenbekledingsgebied.

    8. De optische vezel volgens conclusie 7, waarbij het buitenbekledingsgebied een brekingsindex Δ₅ en een straal r_Jnax heeft, zodat Δ_2η„_η > Δ₅.

    9. De optische vezel volgens conclusie 6, verder omvattende een buitenbekledingsgebied dat een brekingsindex Δ₅ en een straal r_lliax heeft, met één of meer van de volgende:

    - waarbij A_2min > Δ₅;

    - waarbij Δ₅ < Δ_3ηΐί1χ; en

    - waarbij Δ_3πΛ1 < Δ₅.

    10. De optische vezel volgens één der voorgaande conclusies, verder omvattende een chloorconcentratie in de kern van >1.5 gew%.

    11. De optische vezel volgens één der voorgaande conclusies, waarbij het macrobuigingsverlies bij 1550 nm < 0.5 dB/rotatie is op een 20 mm diameter spil.

    12. De optische vezel volgens één der voorgaande conclusies, waarbij de maximum brekingsindex Δ_1ηκϋί in het bereik is van 0.10% < A_lmax < 0.45%.

    13. De optische vezel volgens één der voorgaande conclusies 5 - 12, wanneer afhankelijk van conclusie 5, waarbij de minimum brekingsindex A_3min -0.5% < A_3min < 0.25% is, bij voorkeur waarin de minimum brekingsindex A_3min 0.25% < A_3min < 0.15% is.

    14. De optische vezel volgens één der conclusies 4-13, wanneer afhankelijk van conclusie 4, waar in de buitenste straal r₃ 12.0 micron < r₃ < 25.0 micron is.

    15. De optische vezel volgens één der voorgaande conclusies, waarbij het macrobuigingsverlies vertoond door de optische vezel bij 1550 nm < 0.70 dB/rotatie is voor een 20 mm diameter spil en een MACC getal tussen 7.1 en 8.1 vertoont.

    16. De optische vezel volgens één der voorgaande conclusies een singlemodus optische vezel is.

    17. De optische vezel volgens één der voorgaande conclusies, waarbij het macrobuigingsverlies bij 1550 nm < 0.005 dB/rotatie is voor een 30 mm diameter spil.

    18. De optische vezel volgens één der voorgaande conclusies, waarbij de chloor gedoteerde siliciumgebaseerde kern een kern alpha (CoreJ > 15 omvat.

    19. De optische vezel volgens één der conclusies 6-18, wanneer afhankelijk van conclusie

    6, waarbij de maximum brekingsindex Δ_3πβχ -0.5% < Δ_3ιη)η < 0.25% is.

    20. De optische vezel volgens één der conclusies 4-19, wanneer afhankelijk van conclusie 4, waarbij de buitenste straal r₃ 15.0 micron < r₃ < 15.0 micron is.

    21. De optische vezel volgens één der conclusies 3 - 20, wanneer afhankelijk van onclusie

    5 3, waarbij het macrobuigingsverlies vertoond door de optische vezel bij 1550 nm < 0.70 dB/rotatie is voor een 20 mm diameter spil en een MACC getal tussen 7.1 en 8.1 vertoont.

    22. De optische vezel volgens één der conclusies 3-21, wanneer afhankelijk van conclusie

    3, waarbij de optische vezel een wire mesh covered drum microbuigingsverlies, (WMCD) bij 1550 10 nm van < 0.1 dB/km heeft.

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