NL143277B - METHOD OF TANNING SKIN AND LEATHER. - Google Patents
METHOD OF TANNING SKIN AND LEATHER.Info
- Publication number
- NL143277B NL143277B NL666603974A NL6603974A NL143277B NL 143277 B NL143277 B NL 143277B NL 666603974 A NL666603974 A NL 666603974A NL 6603974 A NL6603974 A NL 6603974A NL 143277 B NL143277 B NL 143277B
- Authority
- NL
- Netherlands
- Prior art keywords
- leather
- salts
- tanning agent
- zirconium
- tanning
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
- C14C3/04—Mineral tanning
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
In a process for tanning and re-tanning hides, pelts, e.g pickled pelts having a pH between 2.0 and 3.5, wool-skins, fur-skins and leathers, they are treated with a tanning agent comprising zirconium, aluminium and chromium salts, the proportion of these salts, computed as the proportion of the oxides ZrO2:Al2O3:Cr2O3, bein 100: 5-50: 2-30, preferably 100: 10-20: 3-8, by weight. The tanning agent may be a mixed complex of Zr, Al and Cr salts obtained by heating and/or dehydrating, e.g. evaporating, spray-drying or roller-drying, an aqueous solution containing them. According to Example 1, a powdered Al-Cr mixed complex is prepared and mixed with aqueous, technical zirconium sulphate, the mixture is heated to 80 DEG C., then cooled and spray-dried to yield a powdered tanning agent, in which the proportion of the oxides ZrO2:Al2O3: Cr2O3 is 100: 14: 7. Tanning may be effected first with a zirconium salt, and then with aluminium and chromium salts, e.g. in the form of a mixed Al-Cr complex described in French Specification 1,244,477. The tanning agent may be in the form of an aqueous paste, a highly concentrated aqueous solution, or a powder. Specified zirconium salts are: zirconium sulphate, e.g. containing finely divided silica gel, and zirconium oxychloride containing sodium sulphate. Specified aluminium salts are the sulphate, chloride and acetate. Specified chromium salts are the sulphate, nitrate, chloride, acetate and formate, and chrome alum. The tanning agent may also comprise one or more of the following acids and their sodium salts: sulphuric, phthalic, sulphophthalic, sulphosuccinic, tartaric, formic, acetic, lactic, glycollic and citric. Resulting leathers may be re-tanned or after-treated with a mineral, vegetable, synthetic or resinous tanning agent, then dyed, fatliquored, filled and dried. A suitable synthetic re-tanning agent is described in U.K. Specification 443,967. The following types of leather may be prepared using the process according to the invention: full grain leather, suede leather, nubuk, white or dyed glove leather, white splits, white belt leather, sole leather, aniline dyed kid leather and shrunk leather.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEF45647A DE1257353B (en) | 1965-03-26 | 1965-03-26 | Method of tanning |
Publications (2)
Publication Number | Publication Date |
---|---|
NL6603974A NL6603974A (en) | 1966-09-27 |
NL143277B true NL143277B (en) | 1974-09-16 |
Family
ID=7100586
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NL666603974A NL143277B (en) | 1965-03-26 | 1966-03-25 | METHOD OF TANNING SKIN AND LEATHER. |
Country Status (8)
Country | Link |
---|---|
US (1) | US3423162A (en) |
BE (1) | BE671639A (en) |
CH (1) | CH473896A (en) |
DE (1) | DE1257353B (en) |
ES (1) | ES324715A1 (en) |
FR (1) | FR1451814A (en) |
GB (1) | GB1081648A (en) |
NL (1) | NL143277B (en) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2508195A1 (en) * | 1974-03-08 | 1975-09-11 | Sandoz Ag | LEATHER PREPARATIONS, IN PARTICULAR CHROME AND ZIRCON TANKS |
US3917446A (en) * | 1974-03-22 | 1975-11-04 | Us Agriculture | Single bath fungicidal chrome-zirconyl acetate mineral dyeing process for cellulosics |
US4049379A (en) * | 1974-05-30 | 1977-09-20 | Basf Aktiengesellschaft | Complex basic zirconium salts and aluminum salts |
DE3175255D1 (en) * | 1981-05-19 | 1986-10-09 | Inst Chimii Tech Redkik | Tanning agent for skins and method of obtaining it |
TNSN89128A1 (en) * | 1988-12-02 | 1991-02-04 | Rohn And Haas Company Independance Mall West | LEATHER TREATMENT WITH SELECTED AMPHIPHITE COPOLYMERS |
US5330537A (en) * | 1990-06-07 | 1994-07-19 | Rohm And Haas Company | Leather treatment selected amphiphilic copolymer |
JPH06506456A (en) * | 1991-04-09 | 1994-07-21 | コモンウェルス・サイエンティフィック・アンド・インダストリアル・リサーチ・オーガナイゼーション | Method of tanning animal skin and compounds used therein |
CN102206717A (en) * | 2011-05-04 | 2011-10-05 | 四川大学 | Method for preparing zirconium-aluminum multi-metal tanning liquor |
CN104762422B (en) * | 2015-03-17 | 2016-10-05 | 峰安皮业股份有限公司 | A kind of manufacture method of vegetable tanning contracting stricture of vagina first layer lether |
DK3216916T3 (en) | 2016-03-10 | 2019-01-21 | Holupelli Consult Gmbh | PROCEDURE FOR REFINING LEATHER |
CN114164308B (en) * | 2021-11-18 | 2023-12-22 | 陕西科技大学 | Multi-carboxyl metal complex tanning agent with self-masking effect and preparation method thereof |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1940610A (en) * | 1933-01-20 | 1933-12-19 | Rohm & Haas Company Inc | Method of mineral tanning |
US2395472A (en) * | 1942-02-25 | 1946-02-26 | Du Pont | Tanning compositions and their manufacture |
US2826477A (en) * | 1954-05-18 | 1958-03-11 | Rohm & Haas | Process of tanning skins with acidic solutions of alkali metal zirconium silicates |
US2997363A (en) * | 1955-04-01 | 1961-08-22 | Basf Ag | Production of complex-metal tanning agents |
DE1303521C2 (en) * | 1958-09-25 | 1973-02-08 | Farbenfabriken Bayer Ag, 5090 Leverkusen | TANNING PROCESS USING BASIC ALUMINUM-CHROME (III) COMPLEX COMPLEXES |
-
1965
- 1965-03-26 DE DEF45647A patent/DE1257353B/en active Pending
- 1965-10-28 FR FR36449A patent/FR1451814A/en not_active Expired
- 1965-10-29 BE BE671639D patent/BE671639A/xx unknown
-
1966
- 1966-02-22 CH CH251866A patent/CH473896A/en not_active IP Right Cessation
- 1966-03-21 US US535721A patent/US3423162A/en not_active Expired - Lifetime
- 1966-03-25 GB GB13314/66A patent/GB1081648A/en not_active Expired
- 1966-03-25 NL NL666603974A patent/NL143277B/en unknown
- 1966-03-25 ES ES0324715A patent/ES324715A1/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
FR1451814A (en) | 1966-01-07 |
GB1081648A (en) | 1967-08-31 |
US3423162A (en) | 1969-01-21 |
DE1257353B (en) | 1967-12-28 |
NL6603974A (en) | 1966-09-27 |
CH473896A (en) | 1969-06-15 |
ES324715A1 (en) | 1967-03-01 |
BE671639A (en) | 1966-04-29 |
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