MX9702304A - Procedimiento para la preparacion de filamentos y fibras de polibenzazol. - Google Patents

Procedimiento para la preparacion de filamentos y fibras de polibenzazol.

Info

Publication number
MX9702304A
MX9702304A MX9702304A MX9702304A MX9702304A MX 9702304 A MX9702304 A MX 9702304A MX 9702304 A MX9702304 A MX 9702304A MX 9702304 A MX9702304 A MX 9702304A MX 9702304 A MX9702304 A MX 9702304A
Authority
MX
Mexico
Prior art keywords
filament
contacting
dope
polyphosphoric acid
base
Prior art date
Application number
MX9702304A
Other languages
English (en)
Other versions
MXPA97002304A (es
Inventor
Sen Ashish
Yoshihiko Teramoto
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/500,651 external-priority patent/US5525638A/en
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of MXPA97002304A publication Critical patent/MXPA97002304A/es
Publication of MX9702304A publication Critical patent/MX9702304A/es

Links

Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/74—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polycondensates of cyclic compounds, e.g. polyimides, polybenzimidazoles

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Artificial Filaments (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)

Abstract

Se describe un procedimiento continuo para remover ácido polifosforico de un filamento de material absorbente de polibenzazol, el cual comprende: a) poner en contacto el filamento de material absorbente con agua o una mezcla de agua y ácido polifosforico, bajo condiciones suficientes para reducir el contenido de fosforo del filamento a menos de 10,000 ppm en peso; y después, b) poner en contacto el filamento de material absorbente con una solucion acuosa de una base inorgánica, bajo condiciones suficientes para convertir por lo menos 50% de los grupos de ácido polifosforico presentes en el filamento a una sal de la base y el ácido. Se ha descubierto que poniendo en contacto el filamento de material absorbente con una solucion de una base, después de lavar el filamento para remover la mayor parte del fosforo residual, después de lavar el filamento para remover la mayor parte del fosforo residual, ventajosamente conduce a una mejora en la resistencia inicial a la tension del filamento, así como una retencion mejorada de la resistencia a la tension y/o el peso molecular (del polímero de polibenzazol) después de exponerse a la luz y/o a altas temperaturas.
MX9702304A 1994-09-30 1995-09-08 Procedimiento para la preparacion de filamentos y fibras de polibenzazol. MX9702304A (es)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US31626694A 1994-09-30 1994-09-30
US316266 1994-09-30
US08500651 1995-07-12
US08/500,651 US5525638A (en) 1994-09-30 1995-07-12 Process for the preparation of polybenzazole filaments and fibers
PCT/US1995/011229 WO1996010661A1 (en) 1994-09-30 1995-09-08 Process for the preparation of polybenzazole filaments and fibres

Publications (2)

Publication Number Publication Date
MXPA97002304A MXPA97002304A (es) 1997-06-01
MX9702304A true MX9702304A (es) 1997-06-28

Family

ID=26980332

Family Applications (1)

Application Number Title Priority Date Filing Date
MX9702304A MX9702304A (es) 1994-09-30 1995-09-08 Procedimiento para la preparacion de filamentos y fibras de polibenzazol.

Country Status (6)

Country Link
EP (1) EP0783603B1 (es)
CN (1) CN1159836A (es)
CA (1) CA2199514A1 (es)
DE (1) DE69513844T2 (es)
MX (1) MX9702304A (es)
WO (1) WO1996010661A1 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE364743T1 (de) * 2000-04-28 2007-07-15 Toyo Boseki Polybenzazolfaser und ihre verwendung
DE50215006D1 (de) * 2001-11-23 2011-05-26 Inventio Ag Aufzug mit riemenartigem Übertragungsmittel, insbesondere mit Keilrippen-Riemen, als Tragmittel und/oder Treibmittel
CA2490025A1 (en) * 2002-06-26 2004-01-08 Toyo Boseki Kabushiki Kaisha Polybenzazole fiber and use thereof
US7189346B2 (en) 2004-07-22 2007-03-13 E. I. Du Pont De Nemours And Company Polybenzazole fibers and processes for their preparation
DE602006019572D1 (de) * 2005-03-28 2011-02-24 Du Pont Heisse oberflächen-hydrolyse von polyphosphorsäure in spun-garnen
DE602006019573D1 (en) * 2005-03-28 2011-02-24 Du Pont Fusionsfreie hydrolyse von polyphosphorsäure in multifilament-spun-garnen
KR20080034830A (ko) * 2005-03-28 2008-04-22 이 아이 듀폰 디 네모아 앤드 캄파니 측쇄 히드록실 기 및 양이온을 가진 폴리아렌아졸 중합체섬유
WO2006105226A1 (en) 2005-03-28 2006-10-05 E. I. Du Pont De Nemours And Company Process for hydrolyzing polyphosphoric acid in a spun yarn
JP4769290B2 (ja) * 2005-03-28 2011-09-07 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 繊維またはヤーンから燐を除去する方法
US7888457B2 (en) * 2005-04-01 2011-02-15 E. I. Du Pont De Nemours And Company Process for removing phosphorous from a fiber or yarn

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5273703A (en) * 1992-08-13 1993-12-28 The Dow Chemical Company Process for post-spin finishing of polybenzoxazole fibers
US5292469A (en) * 1993-01-05 1994-03-08 The Dow Chemical Company Process for coagulation, washing and leaching of shaped polybenzazole articles
US5393478A (en) * 1993-08-20 1995-02-28 The Dow Chemical Company Process for coagulation and washing of polybenzazole fibers

Also Published As

Publication number Publication date
CA2199514A1 (en) 1996-04-11
CN1159836A (zh) 1997-09-17
DE69513844T2 (de) 2000-07-27
DE69513844D1 (de) 2000-01-13
WO1996010661A1 (en) 1996-04-11
EP0783603A1 (en) 1997-07-16
EP0783603B1 (en) 1999-12-08

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Legal Events

Date Code Title Description
FA Abandonment or withdrawal