MX9603162A - Derivados de fenilimino-tiadiazabicicloalcano, procesos e intermediarios para su preparacion, y su uso como herbicidas. - Google Patents

Derivados de fenilimino-tiadiazabicicloalcano, procesos e intermediarios para su preparacion, y su uso como herbicidas.

Info

Publication number
MX9603162A
MX9603162A MX9603162A MX9603162A MX9603162A MX 9603162 A MX9603162 A MX 9603162A MX 9603162 A MX9603162 A MX 9603162A MX 9603162 A MX9603162 A MX 9603162A MX 9603162 A MX9603162 A MX 9603162A
Authority
MX
Mexico
Prior art keywords
c4alkyl
c4alkoxy
halogen
phenyl
c6alkyl
Prior art date
Application number
MX9603162A
Other languages
English (en)
Inventor
Georg Pissiotas
Hans Moser
Hans-Georg Brunner
Original Assignee
Novartis Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Novartis Ag filed Critical Novartis Ag
Publication of MX9603162A publication Critical patent/MX9603162A/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/08—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms
    • C07D295/084—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms with the ring nitrogen atoms and the oxygen or sulfur atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings
    • C07D295/088—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms with the ring nitrogen atoms and the oxygen or sulfur atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings to an acyclic saturated chain
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/49—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by carboxyl groups
    • C07C205/57—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by carboxyl groups having nitro groups and carboxyl groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C205/58—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by carboxyl groups having nitro groups and carboxyl groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton the carbon skeleton being further substituted by halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C229/52—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton
    • C07C229/54—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton with amino and carboxyl groups bound to carbon atoms of the same non-condensed six-membered aromatic ring
    • C07C229/60—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton with amino and carboxyl groups bound to carbon atoms of the same non-condensed six-membered aromatic ring with amino and carboxyl groups bound in meta- or para- positions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C235/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms
    • C07C235/02—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C235/04—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C235/06—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton the carbon skeleton being acyclic and saturated having the nitrogen atoms of the carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C235/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms
    • C07C235/02—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C235/04—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C235/08—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton the carbon skeleton being acyclic and saturated having the nitrogen atom of at least one of the carboxamide groups bound to an acyclic carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/32—Oximes
    • C07C251/62—Oximes having oxygen atoms of oxyimino groups esterified
    • C07C251/64—Oximes having oxygen atoms of oxyimino groups esterified by carboxylic acids
    • C07C251/66—Oximes having oxygen atoms of oxyimino groups esterified by carboxylic acids with the esterifying carboxyl groups bound to hydrogen atoms, to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C259/00—Compounds containing carboxyl groups, an oxygen atom of a carboxyl group being replaced by a nitrogen atom, this nitrogen atom being further bound to an oxygen atom and not being part of nitro or nitroso groups
    • C07C259/04—Compounds containing carboxyl groups, an oxygen atom of a carboxyl group being replaced by a nitrogen atom, this nitrogen atom being further bound to an oxygen atom and not being part of nitro or nitroso groups without replacement of the other oxygen atom of the carboxyl group, e.g. hydroxamic acids
    • C07C259/06—Compounds containing carboxyl groups, an oxygen atom of a carboxyl group being replaced by a nitrogen atom, this nitrogen atom being further bound to an oxygen atom and not being part of nitro or nitroso groups without replacement of the other oxygen atom of the carboxyl group, e.g. hydroxamic acids having carbon atoms of hydroxamic groups bound to hydrogen atoms or to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C327/00—Thiocarboxylic acids
    • C07C327/20—Esters of monothiocarboxylic acids
    • C07C327/28—Esters of monothiocarboxylic acids having sulfur atoms of esterified thiocarboxyl groups bound to carbon atoms of hydrocarbon radicals substituted by singly-bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C331/00—Derivatives of thiocyanic acid or of isothiocyanic acid
    • C07C331/16—Isothiocyanates
    • C07C331/26—Isothiocyanates having isothiocyanate groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D237/00—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings
    • C07D237/02—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings
    • C07D237/04—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having less than three double bonds between ring members or between ring members and non-ring members
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D513/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for in groups C07D463/00, C07D477/00 or C07D499/00 - C07D507/00
    • C07D513/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for in groups C07D463/00, C07D477/00 or C07D499/00 - C07D507/00 in which the condensed system contains two hetero rings
    • C07D513/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

Los compuestos de la formula (I): en donde: R es alquilo de 1 a 6 átomos de carbono, haloalquilo de 1 a 6 átomos de carbono, alquenilo de 3 a 6 átomos de carbono, alquinilo de 3 a 6 átomos de carbono, alcoxi de 1 a 4 átomos de carbono , o cicloalquilo de 3 a 6 átomos de carbono; R1 es halogeno; R2 y R3, son cada uno independientemente del otro alquilo de 1 a 4 átomos de carbono; R4 es halogeno o un grupo de la formula -X-R5-X-A-R6 o (a); R5 es hidrogeno, alquilo de 1 a 6 átomos de carbono, haloalquilo de 1 a 8 átomos de carbono, alcoxi de 1 a 4 átomos de carbono-alquilo de 1 a 4 átomos de carbono, tioalquilo de 1 a 10 átomos de carbono -alquilo de 1 a 4 átomos de carbono, alquilo de 1 a 4 átomos de carbono-aminoalquilo de 1 a 4 átomos de carbono, dialquilo de 1 a 4 átomos de carbono-aminoalquilo de 1 a 4 átomos de carbono, cianoalquilo de 1 a 8 átomos de carbono, alquenilo de 3 a 8 átomos de carbono, haloalquenilo de 3 a 8 átomos de carbono, alquinilo de 3 a 8 átomos de carbono, cicloalquilo de 3 a6 átomos de carbono, oxetanilo, halocicloalquilo de 3 a 7 átomos de carbono, cicloalquilo de 3 a 7 átomos de carbono-alquilo de 1 a 4 átomos de carbono, fenilalquilo de 1 a 3 átomos de carbono que está insustituido o sustituido en el anillo de fenilo por 1, 2, o 3 sustituyentes idénticos o diferentes seleccionados a partir de halogeno, alquilo de 1 a 4 átomos de carbono, haloalquilo de 1 a 4 átomos de carbono, alcoxi de 1 a 4 átomos de carbono, y haloalcoxi de 1 a 4 átomos de carbono, o R5 es un metal alcanilo, un metal alcalinotérreo, o un ion de amonio, o es el grupo -N=C(CH3)2,CH2-O-N=C(CH3)2 o -CH2CH2-O-N=C(CH3)2; X es oxígeno o azufre; A es alquileno de 1 a 4 átomos de carbono; R6 es un anillo heterocíclico de 5 o 6 miembros que contiene de 1 a 3 heteroátomos seleccionados a partir del grupo de oxígeno, nitrogeno, y azufre, y que está enlazado por medio del átomo de carbono o de nitrogeno con la cadena de alquileno A, siendo posible que el anillo heterocíclico también esté a su vez fundido con benceno y mono-o di-sustituido por halogeno, alquilo de 1 a 4 átomos de carbono, haloalquilo de 1 a 3 átomos de carbono, alcoxi de 1 a3 átomos de carbono, haloalcoxi de 1 a 3 átomos d carbono, dialquilo de 1 a 3 átomos de carbono-amino, o por una funcion oxi; R7 es hidrogeno, alquilo de 1 a 6 átomos de carbono, haloalquilo de 1 a 4 átomos de carbono, alcoxi de 1 a 4 átomos de carbono alquilo de 1 a 4 átomos de carbono, alquenilo de 3 a 6 átomos de carbono, alquinilo de 3 a 6 átomos de carbono, cicloalquilo de 3 a 8 átomos de carbono, hidroxialquilo de 1 a 4 átomos de carbono, o cianoalquilo de 1 a 4 átomos de carbono; R8 es hidrogeno, alquilo de 1 a 6 átomos de carbono, haloalquilo de 1 a 4 átomos de carbono, alcoxi de 1 a 4 átomos de carbono-alquilo de 1 a 4 átomos de carbono, hidroxialquilo de 1 a 4 átomos de carbono, alquenilo de 3 a 6 átomos de carbono, fenilo, o fenilalquilo de 1 a 3 átomos de carbono, estando el anillo de fenilo insustituido o mono-, di-, o tri-sustituido por halogeno, alquilo de 1 a 4 átomos de carbono, haloalquilo de 1 a 4 átomos de carbono, alcoxi de 1 a 4 átomos de carbono, o por haloalcoxi de 1 a 4 átomos de carbono; o R7 y R8, junto con elátomo de nitrogeno con el que están enlazados, forman un anillo de pirrolidino, piperidino, morfolino,tiomorfolino, o piperazino que está insustituido o mono-o di-sustituido por alquilo de 1 a 3 átomos de carbono; Z es oxígeno o azufre; n es 3, 4, o 5; y n1 es 0,1,2, o 3, y las sales de esos compuestos, son adecuados como herbicidas para controlar hierbas en cultivos de plantas utiles.
MX9603162A 1994-02-04 1995-01-25 Derivados de fenilimino-tiadiazabicicloalcano, procesos e intermediarios para su preparacion, y su uso como herbicidas. MX9603162A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH33694 1994-02-04
PCT/EP1995/000253 WO1995021174A1 (en) 1994-02-04 1995-01-25 Phenylimino-thiadiazabicycloalkane derivatives, processes and intermediates for their preparation and their use as herbicides

Publications (1)

Publication Number Publication Date
MX9603162A true MX9603162A (es) 1997-05-31

Family

ID=4184700

Family Applications (1)

Application Number Title Priority Date Filing Date
MX9603162A MX9603162A (es) 1994-02-04 1995-01-25 Derivados de fenilimino-tiadiazabicicloalcano, procesos e intermediarios para su preparacion, y su uso como herbicidas.

Country Status (8)

Country Link
EP (1) EP0741733A1 (es)
JP (1) JPH09508395A (es)
AU (1) AU1576095A (es)
CA (1) CA2181583A1 (es)
IL (1) IL112523A (es)
MX (1) MX9603162A (es)
WO (1) WO1995021174A1 (es)
ZA (1) ZA95864B (es)

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4439229A (en) * 1981-06-29 1984-03-27 Rohm And Haas Company Substituted phthalimides herbicides
DE3675931D1 (de) * 1986-03-25 1991-01-10 Kumiai Chemical Industry Co Thiadiazabicyclononanderivate, verfahren zu ihrer herstellung und herbizide zusammensetzungen.
DK0436680T3 (da) * 1989-06-29 1994-10-10 Ciba Geigy Ag Heterocycliske forbindelser
EP0457714A1 (de) * 1990-03-22 1991-11-21 Ciba-Geigy Ag Thiadiazabicyclononanderivate, Verfahren zu ihrer Herstellung, Zwischenprodukte und ihre Verwendung als Herbizide
BR9206101A (pt) * 1991-06-06 1994-08-02 Ciba Geigy Ag Novos herbicidas
JPH09500373A (ja) * 1993-06-23 1997-01-14 チバ−ガイギー アクチエンゲゼルシャフト 除草性チアジアザビシクロデカン

Also Published As

Publication number Publication date
IL112523A0 (en) 1995-05-26
AU1576095A (en) 1995-08-21
IL112523A (en) 1998-06-15
CA2181583A1 (en) 1995-08-10
EP0741733A1 (en) 1996-11-13
JPH09508395A (ja) 1997-08-26
ZA95864B (en) 1995-08-04
WO1995021174A1 (en) 1995-08-10

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