MX9304293A - Metodo para curar cauchos sin la formacion de nitrosaminas. - Google Patents
Metodo para curar cauchos sin la formacion de nitrosaminas.Info
- Publication number
- MX9304293A MX9304293A MX9304293A MX9304293A MX9304293A MX 9304293 A MX9304293 A MX 9304293A MX 9304293 A MX9304293 A MX 9304293A MX 9304293 A MX9304293 A MX 9304293A MX 9304293 A MX9304293 A MX 9304293A
- Authority
- MX
- Mexico
- Prior art keywords
- group
- accelerators
- branched
- cyclic
- nitrosamines
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/39—Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Se ha descubierto que los aceleradores de N, N-dialquilditilocarbamilo cíclico para la vulcanización con azufre de caucho, generalmente funcionan tan bien como los aceleradores de N, N-dialquilditiocarbamilo de cadena recta correspondientes, pero de manera sorprendente, no producen cantidades detectables de N-nitrosaminas medio-ambientales indeseables. Los aceleradores de N, N-alquilditiocarbamilo ramificados están representados generalmente por la fórmula (I); donde R es un grupo alquilo que puede o no estar ramificado, o un grupo alquilo cíclico o un grupo alcarilo o arilo, X es otro grupo tiocarbamilo de la misma estructura general, un grupo alquilamina primario, un grupo alquiltio, un grupo 2-benzotiazilo, o un ion de metal, y n es un entero de 1 a 6. Los aceleradores de ditocarbamilo de la presente invención están representados por la fórmula (II); donde X es otro grupo tiocarbamilo de la misma estructura general, un grupo alquilamino primario, un grupo alquiltio, un grupo 2-benzotiazilo, o un ion de metal, y n es un entero de 1 a 6.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US95839592A | 1992-10-08 | 1992-10-08 |
Publications (1)
Publication Number | Publication Date |
---|---|
MX9304293A true MX9304293A (es) | 1994-04-29 |
Family
ID=25500917
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX9304293A MX9304293A (es) | 1992-10-08 | 1993-07-15 | Metodo para curar cauchos sin la formacion de nitrosaminas. |
Country Status (8)
Country | Link |
---|---|
US (1) | US5554699A (es) |
EP (1) | EP0591632B1 (es) |
JP (1) | JPH06293843A (es) |
KR (1) | KR940009258A (es) |
AT (1) | ATE165384T1 (es) |
CA (1) | CA2100627C (es) |
DE (1) | DE69318091T2 (es) |
MX (1) | MX9304293A (es) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5753290A (en) * | 1995-08-24 | 1998-05-19 | Globe Manufacturing Co. | Processed meat and poultry encased in natural rubber thread with low nitrosamine |
US7182863B2 (en) * | 2000-05-08 | 2007-02-27 | Honeywell International, Inc. | Additive dispersing filter and method of making |
KR20030033682A (ko) * | 2001-10-24 | 2003-05-01 | 금호산업 주식회사 | 니트로소아민이 발생하지 않는 림 프랜지 고무조성물 |
FR2861082B1 (fr) * | 2003-10-15 | 2005-12-30 | Arkema | Agent de vulcanisation utilisable pour les caoutchous de type epdm |
US8800974B2 (en) * | 2006-11-14 | 2014-08-12 | Firestone Industrial Products Company, Llc | Air spring sleeve |
MX2010007325A (es) | 2008-01-04 | 2012-12-06 | Bard Inc C R | Cateter de foley de poliisopreno sintetico. |
US7931817B2 (en) * | 2008-02-15 | 2011-04-26 | Honeywell International Inc. | Additive dispensing device and a thermally activated additive dispensing filter having the additive dispensing device |
DE102008010111A1 (de) * | 2008-02-20 | 2009-09-03 | Continental Aktiengesellschaft | Verfahren zur Herstellung einer Kautschukmischung |
JP2011526814A (ja) | 2008-06-30 | 2011-10-20 | シー.アール.バード,インコーポレイテッド | ポリウレタン/ポリイソプレンブレンドカテーテル |
US9623350B2 (en) | 2013-03-01 | 2017-04-18 | Fram Group Ip Llc | Extended-life oil management system and method of using same |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB711586A (en) * | 1949-07-07 | 1954-07-07 | Ind Tape Corp | Improvements in and relating to stabilised unvulcanised rubber |
US3417086A (en) * | 1964-09-21 | 1968-12-17 | Firestone Tire & Rubber Co | 2,6-dialkyl morpholinothio carbonylamino sulfides and amino thiocarbonyl - 2,6-dialkylamino morpholinosulfides |
US3426003A (en) * | 1966-08-22 | 1969-02-04 | Monsanto Co | Method of vulcanizing butyl rubber |
US3686214A (en) * | 1970-06-08 | 1972-08-22 | Monsanto Co | Thiocarbamoyl pyrrolidinyl sulfides |
US3678135A (en) * | 1970-09-09 | 1972-07-18 | Uniroyal Inc | Co-cure of blend of rubber of low unsaturation and highly unsaturated rubber using long chain hydrocarbon dithiocarbamate accelerators |
US3855192A (en) * | 1971-06-07 | 1974-12-17 | Monsanto Chemicals | Inhibiting premature vulcanization of w-type polychloroprene rubber with n-hydrocarbyl-thioimides |
US3781285A (en) * | 1971-10-04 | 1973-12-25 | Monsanto Co | Cyanoisothiazolyl bis(dithiocarbamates) |
US3852251A (en) * | 1972-04-18 | 1974-12-03 | Goodyear Tire & Rubber | Two-component accelerator system for vulcanizable rubbers |
CA1019093A (en) * | 1972-05-18 | 1977-10-11 | B.F. Goodrich Company (The) | Dienic polymer vulcanizable compositions |
US3910864A (en) * | 1973-06-06 | 1975-10-07 | Goodrich Co B F | Vulcanizable rubber compositions |
US4017439A (en) * | 1975-07-31 | 1977-04-12 | R. T. Vanderbilt Company, Inc. | Vulcanization of neoprene |
US4165416A (en) * | 1976-08-02 | 1979-08-21 | Osaka Soda Co. Ltd. | Cured or uncured chlorinated polyethylene composition and process for curing uncured chlorinated polyethylene |
US4119588A (en) * | 1976-09-14 | 1978-10-10 | The B. F. Goodrich Company | Reversion resistant rubber compositions with thio carbamyl sulfenamides |
US4496683A (en) * | 1982-08-11 | 1985-01-29 | Monsanto Company | Rubber compositions containing a vulcanization system alterative |
EP0242432A1 (en) * | 1986-04-22 | 1987-10-28 | The B.F. GOODRICH Company | Tire tread rubber composition |
US5070130A (en) * | 1990-09-19 | 1991-12-03 | The B. F. Goodrich Company | Alkaline earth oxides and hydroxides to reduce nitrosamine formation from vulcanization accelerators |
JPH0689181B2 (ja) * | 1990-10-05 | 1994-11-09 | 株式会社ブリヂストン | ゴム組成物 |
JP3133815B2 (ja) * | 1992-03-23 | 2001-02-13 | 株式会社ブリヂストン | ゴム組成物及びこれを使用したタイヤ |
-
1993
- 1993-07-14 DE DE69318091T patent/DE69318091T2/de not_active Revoked
- 1993-07-14 AT AT93111252T patent/ATE165384T1/de not_active IP Right Cessation
- 1993-07-14 EP EP93111252A patent/EP0591632B1/en not_active Revoked
- 1993-07-15 MX MX9304293A patent/MX9304293A/es unknown
- 1993-07-15 CA CA002100627A patent/CA2100627C/en not_active Expired - Fee Related
- 1993-10-08 JP JP5252921A patent/JPH06293843A/ja active Pending
- 1993-10-08 KR KR1019930020778A patent/KR940009258A/ko not_active Application Discontinuation
-
1994
- 1994-06-28 US US08/268,143 patent/US5554699A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US5554699A (en) | 1996-09-10 |
JPH06293843A (ja) | 1994-10-21 |
DE69318091D1 (de) | 1998-05-28 |
KR940009258A (ko) | 1994-05-20 |
CA2100627C (en) | 2005-11-29 |
ATE165384T1 (de) | 1998-05-15 |
EP0591632B1 (en) | 1998-04-22 |
EP0591632A3 (en) | 1994-06-15 |
EP0591632A2 (en) | 1994-04-13 |
DE69318091T2 (de) | 1998-10-29 |
CA2100627A1 (en) | 1994-04-09 |
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