MX370915B - Método para producir un producto de hidrocarburo líquido a partir de un proceso de fischer-tropsch mediante la utilización de un gas de síntesis producido a partir de un reactor de reformado con base en una membrana transportadora de oxígeno. - Google Patents
Método para producir un producto de hidrocarburo líquido a partir de un proceso de fischer-tropsch mediante la utilización de un gas de síntesis producido a partir de un reactor de reformado con base en una membrana transportadora de oxígeno.Info
- Publication number
- MX370915B MX370915B MX2016011379A MX2016011379A MX370915B MX 370915 B MX370915 B MX 370915B MX 2016011379 A MX2016011379 A MX 2016011379A MX 2016011379 A MX2016011379 A MX 2016011379A MX 370915 B MX370915 B MX 370915B
- Authority
- MX
- Mexico
- Prior art keywords
- fischer
- synthesis gas
- transport membrane
- oxygen transport
- reforming reactor
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/382—Multi-step processes
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/02—Preparation of oxygen
- C01B13/0229—Purification or separation processes
- C01B13/0248—Physical processing only
- C01B13/0251—Physical processing only by making use of membranes
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
- C01B2203/0255—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a non-catalytic partial oxidation step
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
- C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Un sistema y un método para producir un producto de hidrocarburo líquido a partir de un proceso de Fischer-Tropsch que utiliza una alimentación de gas de síntesis producido en un reactor de reformado con base en membrana transportadora de oxígeno. El sistema y el método involucran reformar una corriente de alimentación mezclada que comprende gas natural, hidrógeno y el gas de cola de Fischer-Tropsch, en un reactor de reformado en la presencia de vapor, calor radiante a partir de elementos de membranas transportadoras de oxígeno y un catalizador de reformado para producir una corriente de gas de síntesis reformado que comprende hidrógeno, monóxido de carbono y gas de hidrocarburo sin reformar. La corriente de gas de síntesis reformado es reformada adicionalmente en un reactor de reformado con base en membrana transportadora de oxígeno y acondicionada para producir una corriente de producto de gas de síntesis que tiene de preferencia una proporción de H2/CO desde aproximadamente 1.7 hasta aproximadamente 2.2. La corriente de producto de gas de síntesis se sintetiza entonces con el uso de un proceso de Fischer Tropsch para producir el producto de hidrocarburo líquido y un gas de cola de Fischer-Tropsch.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201461948249P | 2014-03-05 | 2014-03-05 | |
| US14/638,344 US9365466B2 (en) | 2014-03-05 | 2015-03-04 | Method and system for producing a liquid hydrocarbon product from a Fischer-Tropsch process using a synthesis gas produced from an oxygen transport membrane based reforming reactor |
| PCT/US2015/018719 WO2015134598A1 (en) | 2014-03-05 | 2015-03-04 | Method for producing a liquid hydrocarbon product from a fischer-tropsch process using a synthesis gas produced from an oxygen transport membrane based reforming reactor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2016011379A MX2016011379A (es) | 2016-11-16 |
| MX370915B true MX370915B (es) | 2020-01-09 |
Family
ID=54016702
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2016011379A MX370915B (es) | 2014-03-05 | 2015-03-04 | Método para producir un producto de hidrocarburo líquido a partir de un proceso de fischer-tropsch mediante la utilización de un gas de síntesis producido a partir de un reactor de reformado con base en una membrana transportadora de oxígeno. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9365466B2 (es) |
| EP (1) | EP3114079B1 (es) |
| CN (1) | CN106103339B (es) |
| CA (1) | CA2938146C (es) |
| MX (1) | MX370915B (es) |
| RU (1) | RU2676062C2 (es) |
| WO (1) | WO2015134598A1 (es) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2935155B1 (en) | 2012-12-19 | 2019-02-13 | Praxair Technology Inc. | Method for sealing an oxygen transport membrane assembly |
| US9611144B2 (en) | 2013-04-26 | 2017-04-04 | Praxair Technology, Inc. | Method and system for producing a synthesis gas in an oxygen transport membrane based reforming system that is free of metal dusting corrosion |
| US9212113B2 (en) | 2013-04-26 | 2015-12-15 | Praxair Technology, Inc. | Method and system for producing a synthesis gas using an oxygen transport membrane based reforming system with secondary reforming and auxiliary heat source |
| US9938145B2 (en) | 2013-04-26 | 2018-04-10 | Praxair Technology, Inc. | Method and system for adjusting synthesis gas module in an oxygen transport membrane based reforming system |
| US9296671B2 (en) | 2013-04-26 | 2016-03-29 | Praxair Technology, Inc. | Method and system for producing methanol using an integrated oxygen transport membrane based reforming system |
| EP3055052A2 (en) | 2013-10-07 | 2016-08-17 | Praxair Technology Inc. | Ceramic oxygen transport membrane array reactor and reforming method |
| WO2015160609A1 (en) | 2014-04-16 | 2015-10-22 | Praxair Technology, Inc. | Method and system for oxygen transport membrane enhanced integrated gasifier combined cycle (igcc) |
| US9789445B2 (en) | 2014-10-07 | 2017-10-17 | Praxair Technology, Inc. | Composite oxygen ion transport membrane |
| US10441922B2 (en) | 2015-06-29 | 2019-10-15 | Praxair Technology, Inc. | Dual function composite oxygen transport membrane |
| US10118823B2 (en) | 2015-12-15 | 2018-11-06 | Praxair Technology, Inc. | Method of thermally-stabilizing an oxygen transport membrane-based reforming system |
| US9938146B2 (en) | 2015-12-28 | 2018-04-10 | Praxair Technology, Inc. | High aspect ratio catalytic reactor and catalyst inserts therefor |
| US11052353B2 (en) | 2016-04-01 | 2021-07-06 | Praxair Technology, Inc. | Catalyst-containing oxygen transport membrane |
| EP3797085A1 (en) | 2018-05-21 | 2021-03-31 | Praxair Technology, Inc. | Otm syngas panel with gas heated reformer |
| CN108745262B (zh) * | 2018-07-05 | 2020-02-11 | 山东理工大学 | 透氧-透氢-甲烷部分氧化脱氢三效平板式膜反应器的制备方法及其测试系统 |
| CN108745263B (zh) * | 2018-07-05 | 2020-02-07 | 山东理工大学 | 甲烷部分氧化制氢的透氧-透氢-反应三效管状膜反应器的制备方法 |
| US11879099B1 (en) | 2022-08-04 | 2024-01-23 | Uop Llc | Method for making liquid hydrocarbons |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5980840A (en) * | 1997-04-25 | 1999-11-09 | Bp Amoco Corporation | Autothermic reactor and process using oxygen ion--conducting dense ceramic membrane |
| US6048472A (en) | 1997-12-23 | 2000-04-11 | Air Products And Chemicals, Inc. | Production of synthesis gas by mixed conducting membranes |
| US6296686B1 (en) | 1998-06-03 | 2001-10-02 | Praxair Technology, Inc. | Ceramic membrane for endothermic reactions |
| US6114400A (en) | 1998-09-21 | 2000-09-05 | Air Products And Chemicals, Inc. | Synthesis gas production by mixed conducting membranes with integrated conversion into liquid products |
| US7261751B2 (en) | 2004-08-06 | 2007-08-28 | Conocophillips Company | Synthesis gas process comprising partial oxidation using controlled and optimized temperature profile |
| RU2417158C2 (ru) * | 2009-05-25 | 2011-04-27 | Институт химии твердого тела Уральского отделения Российской Академии наук | Способ получения синтез-газа |
| US8349214B1 (en) * | 2011-07-08 | 2013-01-08 | Praxair Technology, Inc. | Synthesis gas method and apparatus |
-
2015
- 2015-03-04 RU RU2016139016A patent/RU2676062C2/ru active
- 2015-03-04 EP EP15710064.5A patent/EP3114079B1/en active Active
- 2015-03-04 MX MX2016011379A patent/MX370915B/es active IP Right Grant
- 2015-03-04 WO PCT/US2015/018719 patent/WO2015134598A1/en active Application Filing
- 2015-03-04 CA CA2938146A patent/CA2938146C/en active Active
- 2015-03-04 US US14/638,344 patent/US9365466B2/en active Active
- 2015-03-04 CN CN201580011880.5A patent/CN106103339B/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US9365466B2 (en) | 2016-06-14 |
| RU2016139016A (ru) | 2018-04-05 |
| CA2938146A1 (en) | 2015-09-11 |
| RU2676062C2 (ru) | 2018-12-25 |
| EP3114079B1 (en) | 2019-05-22 |
| US20150251967A1 (en) | 2015-09-10 |
| CN106103339B (zh) | 2018-09-04 |
| CA2938146C (en) | 2022-06-21 |
| MX2016011379A (es) | 2016-11-16 |
| WO2015134598A1 (en) | 2015-09-11 |
| RU2016139016A3 (es) | 2018-07-24 |
| EP3114079A1 (en) | 2017-01-11 |
| CN106103339A (zh) | 2016-11-09 |
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