MX366406B - Composicion de polietileno que tiene una proporcion alta de dilatacion. - Google Patents

Composicion de polietileno que tiene una proporcion alta de dilatacion.

Info

Publication number
MX366406B
MX366406B MX2015004906A MX2015004906A MX366406B MX 366406 B MX366406 B MX 366406B MX 2015004906 A MX2015004906 A MX 2015004906A MX 2015004906 A MX2015004906 A MX 2015004906A MX 366406 B MX366406 B MX 366406B
Authority
MX
Mexico
Prior art keywords
polyethylene composition
expansion
high proportion
composition
ratio
Prior art date
Application number
MX2015004906A
Other languages
English (en)
Other versions
MX2015004906A (es
Inventor
Vittorias Iakovos
Wiesecke Jens
Lothar Marczinke Bernd
Meier Gerhardus
Schüller Ulf
Dolle Volker
Lilge Dieter
Gall Barbara
Enderle Johannes-Friedrich
Original Assignee
Basell Polyolefine Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from EP12189392.9A external-priority patent/EP2722347A1/en
Priority claimed from EP12194530.7A external-priority patent/EP2738213A1/en
Application filed by Basell Polyolefine Gmbh filed Critical Basell Polyolefine Gmbh
Publication of MX2015004906A publication Critical patent/MX2015004906A/es
Publication of MX366406B publication Critical patent/MX366406B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/92—Measuring, controlling or regulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/0005—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor characterised by the material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/02—Combined blow-moulding and manufacture of the preform or the parison
    • B29C49/04—Extrusion blow-moulding
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04—Polymers of ethylene
    • B29K2023/06—PE, i.e. polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/712—Containers; Packaging elements or accessories, Packages
    • B29L2031/7154—Barrels, drums, tuns, vats
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/712—Containers; Packaging elements or accessories, Packages
    • B29L2031/7172—Fuel tanks, jerry cans
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04—Homopolymers or copolymers of ethene
    • C08J2423/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04—Homopolymers or copolymers of ethene
    • C08J2423/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/07—Long chain branching
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/02—Ziegler natta catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

La composición de polietileno con una proporción de dilatación y propiedades mecánicas mejoradas, particularmente adecuada para preparar artículos moldeados por soplado, la composición tiene las siguientes características: 1) densidad de 0,945 a menos de 0,952 g/cm3 2) relación de MIF/MIP de 15 a 30; 3) índice de cristalización inducida por cizalla de 2,5 a 5,5.
MX2015004906A 2012-10-22 2013-10-22 Composicion de polietileno que tiene una proporcion alta de dilatacion. MX366406B (es)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP12189392.9A EP2722347A1 (en) 2012-10-22 2012-10-22 Multistage process for the polymerization of olefins
US201261730925P 2012-11-28 2012-11-28
EP12194530.7A EP2738213A1 (en) 2012-11-28 2012-11-28 Polyethylene composition having high swell ratio
PCT/EP2013/072000 WO2014064062A1 (en) 2012-10-22 2013-10-22 Polyethylene composition having high swell ratio

Publications (2)

Publication Number Publication Date
MX2015004906A MX2015004906A (es) 2015-12-01
MX366406B true MX366406B (es) 2019-07-08

Family

ID=50544050

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015004906A MX366406B (es) 2012-10-22 2013-10-22 Composicion de polietileno que tiene una proporcion alta de dilatacion.

Country Status (10)

Country Link
US (3) US9428623B2 (es)
EP (2) EP2909265B1 (es)
JP (2) JP6001187B2 (es)
KR (1) KR101732831B1 (es)
CN (1) CN106170512B (es)
BR (1) BR112015008932B1 (es)
CA (1) CA2887336C (es)
MX (1) MX366406B (es)
RU (1) RU2621807C2 (es)
WO (1) WO2014064062A1 (es)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20150068438A (ko) * 2012-10-22 2015-06-19 바젤 폴리올레핀 게엠베하 우수한 기계적 성질을 가진 폴리에틸렌 조성물
MX366406B (es) * 2012-10-22 2019-07-08 Basell Polyolefine Gmbh Composicion de polietileno que tiene una proporcion alta de dilatacion.
KR101747396B1 (ko) * 2014-12-15 2017-06-14 주식회사 엘지화학 가공성이 우수한 올레핀계 중합체
PT3257130T (pt) 2015-02-10 2021-01-22 Esmart Tech Sa Sistema de comutação para ativar e desativar um aparelho elétrico
EP3313932B1 (en) 2015-06-26 2021-11-17 Basell Polyolefine GmbH Polyethylene composition having high mechanical properties and processability
BR112017028028B1 (pt) * 2015-06-26 2022-04-26 Basell Polyolefine Gmbh Composição de polietileno e artigo de manufatura que compreende o mesmo
RU2688145C1 (ru) * 2015-06-26 2019-05-20 Базелл Полиолефин Гмбх Состав полиэтилена, обладающий высокими механическими свойствами и технологичностью при обработке
GB201717185D0 (en) 2016-10-19 2017-12-06 Bhargava Saumitra Compression blow formed hdpe containers and methods of making the same
EP3321295A1 (en) * 2016-11-10 2018-05-16 Basell Polyolefine GmbH Olefin polymerization process in a gas-phase reactor having three or more polymerization zones
WO2018091261A1 (en) 2016-11-17 2018-05-24 Basell Polyolefine Gmbh Polyethylene composition having high swell ratio
CA3044697C (en) * 2016-11-24 2020-12-15 Basell Polyolefine Gmbh Polyethylene composition for blow molding having high stress cracking resistance
WO2018095700A1 (en) * 2016-11-24 2018-05-31 Basell Polyolefine Gmbh Polyethylene composition for blow molding having high swell ratio and impact resistance
CN109963880B (zh) * 2016-11-24 2021-08-03 巴塞尔聚烯烃股份有限公司 具有高抗应力开裂性的用于吹塑的聚乙烯组合物
CA3085083C (en) * 2017-12-18 2022-10-04 Basell Polyolefine Gmbh Polyethylene composition having environmental stress cracking resistance
ES2907066T3 (es) * 2018-05-14 2022-04-21 Basell Polyolefine Gmbh Composición de polietileno que tiene alta relación de hinchamiento, FNCT y resistencia al impacto
CA3112357C (en) * 2018-09-20 2022-11-22 Basell Polyolefine Gmbh Polyethylene composition for films

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YU35844B (en) 1968-11-25 1981-08-31 Montedison Spa Process for obtaining catalysts for the polymerization of olefines
IT1230134B (it) 1989-04-28 1991-10-14 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine.
GB9224876D0 (en) 1992-11-27 1993-01-13 Exxon Chemical Patents Inc Improved processing polyolefin blends
BE1009308A3 (fr) 1995-04-28 1997-02-04 Solvay Polymere d'ethylene et procedes pour son obtention.
JP3752759B2 (ja) 1997-01-07 2006-03-08 東ソー株式会社 エチレン系重合体及びその製造方法
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ATE347569T1 (de) * 2003-08-20 2006-12-15 Basell Poliolefine Srl Verfahren und vorrichtung zur polymerisation von ethylen
JP4790627B2 (ja) * 2003-12-19 2011-10-12 バーゼル・ポリオレフィン・ゲーエムベーハー エチレン（コ）ポリマーの製造方法
JP4749725B2 (ja) 2005-01-17 2011-08-17 日本ポリエチレン株式会社 ポリエチレン系樹脂材料及びそれを用いた中空成形体
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KR101950622B1 (ko) * 2012-10-22 2019-02-20 바젤 폴리올레핀 게엠베하 높은 스웰비를 가진 폴리에틸렌 조성물
MX366406B (es) * 2012-10-22 2019-07-08 Basell Polyolefine Gmbh Composicion de polietileno que tiene una proporcion alta de dilatacion.
KR101624093B1 (ko) * 2013-02-27 2016-05-24 바젤 폴리올레핀 게엠베하 폴리에틸렌 공정 및 그 조성물
EP2818508A1 (en) * 2013-06-25 2014-12-31 Basell Polyolefine GmbH Polyethylene composition having high impact and stress cracking resistance
EP2818509A1 (en) * 2013-06-25 2014-12-31 Basell Polyolefine GmbH Polyethylene composition for blow molding having high stress cracking resistance

Also Published As

Publication number Publication date
US20170121512A1 (en) 2017-05-04
JP6001187B2 (ja) 2016-10-05
US9738777B2 (en) 2017-08-22
US20150267010A1 (en) 2015-09-24
MX2015004906A (es) 2015-12-01
RU2621807C2 (ru) 2017-06-07
EP3109278B1 (en) 2023-01-25
US9580583B2 (en) 2017-02-28
US9428623B2 (en) 2016-08-30
JP2016196649A (ja) 2016-11-24
EP2909265A1 (en) 2015-08-26
BR112015008932B1 (pt) 2021-03-30
CA2887336C (en) 2017-05-02
WO2014064062A1 (en) 2014-05-01
JP2015532349A (ja) 2015-11-09
CN106170512B (zh) 2021-04-09
KR20150068439A (ko) 2015-06-19
CA2887336A1 (en) 2014-05-01
US20160326354A1 (en) 2016-11-10
JP6262289B2 (ja) 2018-01-17
BR112015008932A2 (pt) 2017-07-04
KR101732831B1 (ko) 2017-05-24
RU2015117278A (ru) 2016-11-27
CN106170512A (zh) 2016-11-30
EP2909265B1 (en) 2020-11-25
EP3109278A1 (en) 2016-12-28

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