MX360353B - Hidrogenacion selectiva de aldehidos con complejos de ligandos ru/bidentados. - Google Patents

Hidrogenacion selectiva de aldehidos con complejos de ligandos ru/bidentados.

Info

Publication number
MX360353B
MX360353B MX2015010916A MX2015010916A MX360353B MX 360353 B MX360353 B MX 360353B MX 2015010916 A MX2015010916 A MX 2015010916A MX 2015010916 A MX2015010916 A MX 2015010916A MX 360353 B MX360353 B MX 360353B
Authority
MX
Mexico
Prior art keywords
aldehydes
selective hydrogenation
bidentate ligands
coordinating
catalyst
Prior art date
Application number
MX2015010916A
Other languages
English (en)
Other versions
MX2015010916A (es
Inventor
Dupau Philippe
Bonomo Lucia
Kermorvan Laurent
Original Assignee
Firmenich & Cie
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Firmenich & Cie filed Critical Firmenich & Cie
Publication of MX2015010916A publication Critical patent/MX2015010916A/es
Publication of MX360353B publication Critical patent/MX360353B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C07C29/157—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente invención se relaciona a procesos para la reducción por hidrogenación, usando H2 molecular, de un substrato de C5-C20 que contiene uno o dos grupos funcionales aldehídos en los alcoholes o dioles correspondientes, caracterizado porque el proceso se realiza en la presencia de por lo menos un catalizador o pre-catalizar en la forma de un complejo de rutenio que tiene una esfera de coordinación del NIP3O2, en donde el átomo de coordinación N y un átomo de coordinación P son proporcionados por un primer ligando bidentando, y los otros dos átomos de coordinación P2 son proporcionados por un segundo ligando bidentado y los átomos de coordinación O2 son proporcionados por dos ligandos carboxilados no lineales; y opcionalmente un aditivo ácido.
MX2015010916A 2013-03-15 2014-03-06 Hidrogenacion selectiva de aldehidos con complejos de ligandos ru/bidentados. MX360353B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP13159479 2013-03-15
PCT/EP2014/054337 WO2014139854A1 (en) 2013-03-15 2014-03-06 Selective hydrogenation of aldehydes with ru/bidentate ligands complexes

Publications (2)

Publication Number Publication Date
MX2015010916A MX2015010916A (es) 2016-01-12
MX360353B true MX360353B (es) 2018-10-30

Family

ID=47900854

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015010916A MX360353B (es) 2013-03-15 2014-03-06 Hidrogenacion selectiva de aldehidos con complejos de ligandos ru/bidentados.

Country Status (9)

Country Link
US (1) US9714263B2 (es)
EP (1) EP2970067B1 (es)
JP (1) JP6419096B2 (es)
CN (1) CN105073696B (es)
BR (1) BR112015022807A2 (es)
ES (1) ES2647159T3 (es)
IL (1) IL241408B (es)
MX (1) MX360353B (es)
WO (1) WO2014139854A1 (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2018260727B2 (en) 2017-04-27 2022-07-21 Deuteria Beverages, Llc Process for the preparation of deuterated ethanol from D2O
US10343955B2 (en) 2017-04-27 2019-07-09 Deuteria Beverages, Llc Process for the preparation of deuterated ethanol from D2

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4144814B2 (ja) 1997-09-05 2008-09-03 長谷川香料株式会社 光学活性アルコール化合物の製造方法
AU2001239442A1 (en) * 2000-03-30 2001-10-15 Chirotech Technology Limited Ruthenium-diphosphine complexes and their use as catalysts
JP5345270B2 (ja) 2000-09-13 2013-11-20 フイルメニツヒ ソシエテ アノニム 接触水素化法
US6878852B2 (en) 2000-11-17 2005-04-12 Firmenich Sa Process for hydrogenation of carbonyl and iminocarbonyl compounds using ruthenium catalysts comprising tetradentate diimino-diphosphine ligands
JP4919562B2 (ja) 2001-09-28 2012-04-18 日本曹達株式会社 ルテニウムヒドリド錯体、アルコール化合物の製造方法およびラセミ体カルボニル化合物の分割方法
WO2005092825A1 (ja) * 2004-03-29 2005-10-06 Nagoya Industrial Science Research Institute 光学活性アルコールの製法
EP1813621B1 (en) 2004-10-25 2011-06-08 Nagoya Industrial Science Research Institute Ruthenium complex and process for producing tert-alkyl alcohol therewith
WO2006106483A1 (en) * 2005-04-05 2006-10-12 Firmenich Sa Hydrogenation of esters with ru/bidentate ligands complexes
CN100475338C (zh) * 2005-12-16 2009-04-08 中国石油天然气集团公司 一种钌-氢配合物制备方法及其催化制备直链十八烯内烯烃的方法
AU2008318239B2 (en) 2007-10-30 2014-06-05 Kanata Chemical Technologies Inc. Cationic transition metal catalysts
EP2344276A1 (en) 2008-10-02 2011-07-20 Firmenich S.A. Hydrogenation of esters or carbonyl groups with phosphino-oxide based ruthenium complexes

Also Published As

Publication number Publication date
BR112015022807A2 (pt) 2017-07-18
IL241408A0 (en) 2015-11-30
JP2016513628A (ja) 2016-05-16
EP2970067B1 (en) 2017-08-16
WO2014139854A1 (en) 2014-09-18
CN105073696B (zh) 2018-06-05
EP2970067A1 (en) 2016-01-20
US9714263B2 (en) 2017-07-25
ES2647159T3 (es) 2017-12-19
IL241408B (en) 2018-03-29
JP6419096B2 (ja) 2018-11-07
MX2015010916A (es) 2016-01-12
CN105073696A (zh) 2015-11-18
US20160039853A1 (en) 2016-02-11

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