MX360320B - Proceso para la obtencion de mezclas de imidazolinas e inhibidores de corrosion a partir de los desechos del café. - Google Patents

Proceso para la obtencion de mezclas de imidazolinas e inhibidores de corrosion a partir de los desechos del café.

Info

Publication number
MX360320B
MX360320B MX2014002086A MX2014002086A MX360320B MX 360320 B MX360320 B MX 360320B MX 2014002086 A MX2014002086 A MX 2014002086A MX 2014002086 A MX2014002086 A MX 2014002086A MX 360320 B MX360320 B MX 360320B
Authority
MX
Mexico
Prior art keywords
imidazolines
coffee oil
coffee
aeea
aminoethylethanolamine
Prior art date
Application number
MX2014002086A
Other languages
English (en)
Other versions
MX2014002086A (es
Inventor
Martínez Gomez Lorenzo
Martinez Martinez De La Escalera Lorenzo
Joaquín Cantó Ibáñez Jorge
Antonio Ascencio Gutierrez Jorge
Ignacio Regla Contreras José
Patricia Shirley Demare Negrete María
Carrillo Salgado Irene
Original Assignee
Corrosion Y Proteccion S A De C V
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Corrosion Y Proteccion S A De C V filed Critical Corrosion Y Proteccion S A De C V
Priority to MX2014002086A priority Critical patent/MX360320B/es
Priority to US14/220,596 priority patent/US9573905B2/en
Publication of MX2014002086A publication Critical patent/MX2014002086A/es
Publication of MX360320B publication Critical patent/MX360320B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D233/06—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F5/00—Fertilisers from distillery wastes, molasses, vinasses, sugar plant or similar wastes or residues, e.g. from waste originating from industrial processing of raw material of agricultural origin or derived products thereof
    • C05F5/006—Waste from chemical processing of material, e.g. diestillation, roasting, cooking
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D233/06—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
    • C07D233/08—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms with alkyl radicals, containing more than four carbon atoms, directly attached to ring carbon atoms
    • C07D233/12—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms with alkyl radicals, containing more than four carbon atoms, directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D233/14—Radicals substituted by oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C23F11/14—Nitrogen-containing compounds
    • C23F11/149—Heterocyclic compounds containing nitrogen as hetero atom
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Botany (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Fats And Perfumes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La presente invención consiste en la extracción bifásica del café de desecho sin secado previo para obtener, después de concentración de la fase hidrocarbonada, el aceite de café, el cual es transferido con metanol catalizado con KOH para producir mezclas de ésteres metílicos libres de glicerol, también llamado biodiesel de aceite de café, el cual se somete a una reacción de aminólisis con la aminoetiletanolamina (AEEA) entre 140-160 °C a presión atmosférica con posterior deshidratación por calentamiento a la misma temperatura pero con presión reducida a 200-300 mmHg, para realizar la ciclación de las amidas intermediarias a las correspondientes imidazolinas. En un proceso alternativo, el aceite de café puede ser sometido al mismo proceso de aminólisis con la aminoetiletanolamina (AEEA) entre 140-160 °C a presión atmosférico con posterior deshidratación por calentamiento a la misma temperatura pero con presión reducida a 200-300 mmHg, para producir mezclas de imidazolinas que contienen el glicerol residual de los triglicéridos originales. Las mezclas de imidazolinas obtenidas por cualquiera de los dos procesos alternativos, presenta un alto desempeño como inhibidores de corrosión. Las mezclas de imidazolinas obtenidas de conformidad con la presente invención se caracterizan por contener un alto grado de insaturación en las cadenas alquílicas, lo que les confiere mayor adherencia a las superficies metálicas que las imidazolinas saturadas. Esta mezcla de imidazolinas constituye un inhibidor de corrosión de alto desempeño, baja toxicidad y buena biodegradabilidad.
MX2014002086A 2014-02-13 2014-02-13 Proceso para la obtencion de mezclas de imidazolinas e inhibidores de corrosion a partir de los desechos del café. MX360320B (es)

Priority Applications (2)

Application Number Priority Date Filing Date Title
MX2014002086A MX360320B (es) 2014-02-13 2014-02-13 Proceso para la obtencion de mezclas de imidazolinas e inhibidores de corrosion a partir de los desechos del café.
US14/220,596 US9573905B2 (en) 2014-02-13 2014-03-20 Process to obtain mixtures of imidazolines and corrosion inhibitors from coffee waste

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
MX2014002086A MX360320B (es) 2014-02-13 2014-02-13 Proceso para la obtencion de mezclas de imidazolinas e inhibidores de corrosion a partir de los desechos del café.

Publications (2)

Publication Number Publication Date
MX2014002086A MX2014002086A (es) 2015-08-13
MX360320B true MX360320B (es) 2018-10-05

Family

ID=53774355

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014002086A MX360320B (es) 2014-02-13 2014-02-13 Proceso para la obtencion de mezclas de imidazolinas e inhibidores de corrosion a partir de los desechos del café.

Country Status (2)

Country Link
US (1) US9573905B2 (es)
MX (1) MX360320B (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX366074B (es) * 2014-04-30 2019-06-17 Univ Mexico Nac Autonoma Proceso para la obtencion de mezclas de imidazolinas de aceites vegetales.
CN113234428A (zh) * 2015-11-20 2021-08-10 瀚森公司 用于表面保护的化学产品
CA3005231C (en) 2015-11-20 2021-02-09 Hexion Inc. Chemical products for surface protection

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2200815A (en) 1940-05-14 Imidazoline derivatives and process
US2161938A (en) 1934-07-31 1939-06-13 Soc Of Chemical Ind Imidazolines
US5154841A (en) 1988-12-21 1992-10-13 The Procter & Gamble Company Process for preparing substituted imidazoline fabric conditioning compounds
DE3919863A1 (de) 1989-06-19 1990-12-20 Schaefer Chem Inst Polycarbonsaeureimidazoline, verfahren zu ihrer herstellung und ihre verwendung in reinigungsmitteln
US6448411B1 (en) 1999-03-15 2002-09-10 Ondeo Nalco Energy Services, L.P. Corrosion inhibitor compositions
US6488732B2 (en) 2000-05-09 2002-12-03 Joseph Scanlan Plant growth medium
US20070259084A1 (en) 2006-05-04 2007-11-08 Gaonkar Anilkumar G Coffee-Derived Surfactants
WO2009015358A2 (en) 2007-07-26 2009-01-29 The Board Of Regents Of The Nevada System Of Higher Education, On Behalf Of The University Of Nevada, Reno Methods, systems, and apparatus for obtaining biofuel from coffee and fuels produced therefrom
AR075138A1 (es) 2010-01-15 2011-03-09 Mongelli Elena Rita Utilizacion de la borra del cafe para la produccion de biodiesel
JP5814658B2 (ja) 2011-06-30 2015-11-17 サントリー食品インターナショナル株式会社 コーヒーオイルの製造方法
CN102875160B (zh) 2012-10-16 2013-10-30 福州大学 一种微波辐射诱导生产的复合型陶瓷添加剂及其方法
US8540881B1 (en) 2012-11-27 2013-09-24 Menlo Energy Management, LLC Pretreatment, esterification, and transesterification of biodiesel feedstock
US8545702B1 (en) 2012-11-27 2013-10-01 Menlo Energy Management, LLC Production of biodiesel from feedstock

Also Published As

Publication number Publication date
US20150225351A1 (en) 2015-08-13
MX2014002086A (es) 2015-08-13
US9573905B2 (en) 2017-02-21

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