MX359467B - Proceso de epoxidacion. - Google Patents
Proceso de epoxidacion.Info
- Publication number
- MX359467B MX359467B MX2015014574A MX2015014574A MX359467B MX 359467 B MX359467 B MX 359467B MX 2015014574 A MX2015014574 A MX 2015014574A MX 2015014574 A MX2015014574 A MX 2015014574A MX 359467 B MX359467 B MX 359467B
- Authority
- MX
- Mexico
- Prior art keywords
- guard bed
- aqueous stream
- ethylene
- resin
- epoxidation process
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 238000006735 epoxidation reaction Methods 0.000 title 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- 125000000524 functional group Chemical group 0.000 abstract 1
- 238000005342 ion exchange Methods 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 229920005990 polystyrene resin Polymers 0.000 abstract 1
- 125000001453 quaternary ammonium group Chemical group 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/06—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the liquid phase
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/32—Separation; Purification
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Epoxy Compounds (AREA)
Abstract
Se proporciona un método de oxidación de etileno para formar óxido de etileno, el cual incluye pasar una corriente acuosa a través de un lecho de protección y uno o más lechos de tratamiento de intercambio iónico. El lenco de protección y la corriente acuosa contiene desde aproximadamente 0.2 a 20% en peso de etilenglicol. El lecho de protección contiene una resina de poliestireno reticulado, parcialmente funcionalizada con grupos funcionales de amonio cuaternario y la resina tiene un área de superficie mayor a 400 m2/g.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201361812037P | 2013-04-15 | 2013-04-15 | |
PCT/US2014/033928 WO2014172240A1 (en) | 2013-04-15 | 2014-04-14 | Epoxidation process |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2015014574A MX2015014574A (es) | 2016-07-05 |
MX359467B true MX359467B (es) | 2018-09-28 |
Family
ID=51687225
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2015014574A MX359467B (es) | 2013-04-15 | 2014-04-14 | Proceso de epoxidacion. |
Country Status (9)
Country | Link |
---|---|
US (1) | US9096561B2 (es) |
EP (1) | EP2986595B1 (es) |
KR (1) | KR102187622B1 (es) |
CN (1) | CN105228990B (es) |
BR (1) | BR112015026194A2 (es) |
MX (1) | MX359467B (es) |
RU (1) | RU2653534C2 (es) |
TW (1) | TWI632137B (es) |
WO (1) | WO2014172240A1 (es) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102438316B1 (ko) * | 2016-08-09 | 2022-08-31 | 사이언티픽 디자인 컴파니 인코포레이티드 | 에폭시화 공정 |
US20220289702A1 (en) * | 2021-03-11 | 2022-09-15 | Scientific Design Company, Inc. | Epoxidation process with increased cycle water absorption |
Family Cites Families (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1170663A (en) | 1967-03-22 | 1969-11-12 | Shell Int Research | Process for preparing Silver Catalysts |
US3702259A (en) | 1970-12-02 | 1972-11-07 | Shell Oil Co | Chemical production of metallic silver deposits |
US3745092A (en) * | 1971-01-11 | 1973-07-10 | Shell Oil Co | Recovery and purification of ethylene oxide by distillation and absorption |
US3904656A (en) * | 1973-02-13 | 1975-09-09 | Ppg Industries Inc | Process for preparing monoethylene glycol and ethylene oxide |
CA1330350C (en) * | 1986-10-07 | 1994-06-21 | Thomas Martin Schmitt | Method for purification of ethylene glycol |
US4766105A (en) | 1986-10-31 | 1988-08-23 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
US4761394A (en) | 1986-10-31 | 1988-08-02 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
US5057481A (en) | 1987-02-20 | 1991-10-15 | Union Carbide Chemicals And Plastics Technology Corporation | Catalyst composition for oxidation of ethylene to ethylene oxide |
US4908343A (en) | 1987-02-20 | 1990-03-13 | Union Carbide Chemicals And Plastics Company Inc. | Catalyst composition for oxidation of ethylene to ethylene oxide |
US4822926A (en) * | 1988-02-29 | 1989-04-18 | Shell Oil Company | Ethylene oxide/glycols recovery process |
EP0357292A1 (en) | 1988-08-30 | 1990-03-07 | Imperial Chemical Industries Plc | Production of ethylene oxide and catalysts therefor |
US5187140A (en) | 1989-10-18 | 1993-02-16 | Union Carbide Chemicals & Plastics Technology Corporation | Alkylene oxide catalysts containing high silver content |
US5102848A (en) | 1990-09-28 | 1992-04-07 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition for oxidation of ethylene to ethylene oxide |
US5171868A (en) * | 1992-04-15 | 1992-12-15 | Arco Chemical Technology, L.P. | Epoxidate treatment |
US5407888A (en) | 1992-05-12 | 1995-04-18 | Basf Aktiengesellschaft | Silver catalyst |
US5440058A (en) * | 1994-06-07 | 1995-08-08 | Union Carbide Chemicals & Plastics Technology Corporation | Method for separating compounds in process streams |
US5529667A (en) * | 1994-12-01 | 1996-06-25 | Hoechst Celanese Corporation | Process for recovering ethylene oxide |
US5503813A (en) * | 1995-05-12 | 1996-04-02 | Arco Chemical Technology, L.P. | Molybdenum recovery from epoxidate |
US6187973B1 (en) * | 2000-04-06 | 2001-02-13 | Scientific Design Company, Inc. | Glycol purification |
FR2851564A1 (fr) * | 2003-02-24 | 2004-08-27 | Bp Lavera Snc | Procede de fabrication combinee d'oxyde d'ethylene et d'ethanolamine(s) |
MY153179A (en) * | 2003-02-28 | 2015-01-29 | Shell Int Research | A method of manufacturing ethylene oxide |
US8791280B2 (en) | 2005-08-10 | 2014-07-29 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Process for preparation of catalyst carrier and its use in catalyst preparation |
US7615654B2 (en) * | 2005-10-20 | 2009-11-10 | Lyondell Chemical Technology, L.P. | Direct epoxidation process |
US8187561B2 (en) * | 2007-12-05 | 2012-05-29 | Ames Goldsmith Corporation | Processes and systems for recovering catalyst promoter from catalyst substrates |
JP2013514975A (ja) * | 2009-12-17 | 2013-05-02 | サイエンティフィック・デザイン・カンパニー・インコーポレーテッド | 酸化オレフィン製造工程 |
US8440846B2 (en) * | 2010-09-30 | 2013-05-14 | Lyondell Chemical Technology, L.P. | Direct epoxidation process |
US8742146B2 (en) * | 2010-12-08 | 2014-06-03 | Shell Oil Company | Process for improving the selectivity of an EO catalyst |
-
2014
- 2014-04-14 EP EP14785671.0A patent/EP2986595B1/en active Active
- 2014-04-14 MX MX2015014574A patent/MX359467B/es active IP Right Grant
- 2014-04-14 BR BR112015026194A patent/BR112015026194A2/pt not_active IP Right Cessation
- 2014-04-14 WO PCT/US2014/033928 patent/WO2014172240A1/en active Application Filing
- 2014-04-14 CN CN201480021209.4A patent/CN105228990B/zh active Active
- 2014-04-14 TW TW103113539A patent/TWI632137B/zh active
- 2014-04-14 RU RU2015148768A patent/RU2653534C2/ru active
- 2014-04-14 KR KR1020157032586A patent/KR102187622B1/ko active IP Right Grant
- 2014-04-15 US US14/253,366 patent/US9096561B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
EP2986595A1 (en) | 2016-02-24 |
US20140309442A1 (en) | 2014-10-16 |
EP2986595B1 (en) | 2021-06-02 |
WO2014172240A1 (en) | 2014-10-23 |
MX2015014574A (es) | 2016-07-05 |
KR102187622B1 (ko) | 2020-12-07 |
BR112015026194A2 (pt) | 2017-07-25 |
EP2986595A4 (en) | 2016-12-21 |
CN105228990B (zh) | 2018-01-30 |
KR20150143736A (ko) | 2015-12-23 |
TW201509923A (zh) | 2015-03-16 |
CN105228990A (zh) | 2016-01-06 |
US9096561B2 (en) | 2015-08-04 |
RU2015148768A (ru) | 2017-05-17 |
TWI632137B (zh) | 2018-08-11 |
RU2653534C2 (ru) | 2018-05-11 |
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Legal Events
Date | Code | Title | Description |
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FG | Grant or registration |