MX2020006347A - Una composicion con emision reducida de aldehidos. - Google Patents

Una composicion con emision reducida de aldehidos.

Info

Publication number
MX2020006347A
MX2020006347A MX2020006347A MX2020006347A MX2020006347A MX 2020006347 A MX2020006347 A MX 2020006347A MX 2020006347 A MX2020006347 A MX 2020006347A MX 2020006347 A MX2020006347 A MX 2020006347A MX 2020006347 A MX2020006347 A MX 2020006347A
Authority
MX
Mexico
Prior art keywords
composition
emission
foam
aldehyde emission
compound
Prior art date
Application number
MX2020006347A
Other languages
English (en)
Inventor
Joris Karel Peter Bosman
Ingrid Welvaert
Lies Bonami
Pengfei Wu
Yuefan Zhang
Xuerong Zhu
Original Assignee
Huntsman Int Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huntsman Int Llc filed Critical Huntsman Int Llc
Publication of MX2020006347A publication Critical patent/MX2020006347A/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/14—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1833—Catalysts containing secondary or tertiary amines or salts thereof having ether, acetal, or orthoester groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3271—Hydroxyamines
    • C08G18/3275—Hydroxyamines containing two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C08G18/4816—Two or more polyethers of different physical or chemical nature mixtures of two or more polyetherpolyols having at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
    • C08G18/6688—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3271
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014—Use of organic additives
    • C08J9/0033—Use of organic additives containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/125—Water, e.g. hydrated salts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41—Compounds containing sulfur bound to oxygen
    • C08K5/42—Sulfonic acids; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C08L75/08—Polyurethanes from polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0058—≥50 and <150kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/022—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments premixing or pre-blending a part of the components of a foamable composition, e.g. premixing the polyol with the blowing agent, surfactant and catalyst and only adding the isocyanate at the time of foaming
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/10—Water or water-releasing compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Esta invención proporciona por lo general una composición para elaborar una espuma de poliuretano con una emisión reducida de aldehído y más especialmente una composición útil en medios de transporte, tales como las partes interiores de automóviles, en donde la composición comprende: (a) un isocianato polifuncional; (b) una composición reactiva al isocianato; y (c) 5 un compuesto de fórmula (I) o (II), en donde el compuesto (c) está presente en porcentaje en peso en la composición en una cantidad que varía de aproximadamente 0.001 a aproximadamente 10, preferiblemente de aproximadamente 0.01 a aproximadamente 5, y más preferiblemente de aproximadamente 0.05 a aproximadamente 2 con base en el peso total de la composición. Las composiciones pueden reducir la emisión de aldehído, especialmente 10 la emisión de acetaldehído en la espuma de PU y no tiene una influencia obvia en las propiedades mecánicas de la espuma.
MX2020006347A 2017-12-18 2018-12-13 Una composicion con emision reducida de aldehidos. MX2020006347A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
PCT/CN2017/116892 WO2019119196A1 (en) 2017-12-18 2017-12-18 A composition with reduced aldehyde emission
PCT/EP2018/084656 WO2019121273A1 (en) 2017-12-18 2018-12-13 A composition with reduced aldehyde emission

Publications (1)

Publication Number Publication Date
MX2020006347A true MX2020006347A (es) 2020-09-03

Family

ID=64755528

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2020006347A MX2020006347A (es) 2017-12-18 2018-12-13 Una composicion con emision reducida de aldehidos.

Country Status (9)

Country Link
US (1) US11555091B2 (es)
EP (1) EP3728373B1 (es)
JP (1) JP7195321B2 (es)
KR (1) KR20200091929A (es)
CN (1) CN111801365B (es)
CA (1) CA3086084A1 (es)
MX (1) MX2020006347A (es)
PL (1) PL3728373T3 (es)
WO (2) WO2019119196A1 (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20220363856A1 (en) * 2019-08-30 2022-11-17 Dow Global Technologies Llc Methods for Reducing Aldehyde Emissions in Polyether Polyols and Polyurethane Foams
CN110964173B (zh) * 2019-12-13 2022-07-12 万华化学（北京）有限公司 用于蜂窝复合材料的聚氨酯组合物及其制备方法、聚氨酯泡沫及其应用
KR102517508B1 (ko) * 2021-04-23 2023-04-04 현대트랜시스 주식회사 휘발성 유기화합물 방출량을 저감시킨 폴리우레탄 수지 조성물, 이를 이용하여 폴리우레탄 폼 성형체를 제조하는 방법 및 상기 방법에 의해 제조된 폴리우레탄 폼 성형체
WO2023110560A1 (en) * 2021-12-14 2023-06-22 Covestro Deutschland Ag Polyol composition
EP4227339A1 (en) * 2022-02-15 2023-08-16 Covestro Deutschland AG Polyol composition

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002098944A1 (fr) * 2001-05-31 2002-12-12 Kaneka Corporation Polymere de polyurethane
DE10258046A1 (de) 2002-12-11 2004-06-24 Basf Ag Verfahren zur Erniedrigung von Emissionen aus Polyurethanschaumstoffen
JP2004339496A (ja) * 2003-04-21 2004-12-02 Hiroshi Takimoto 生分解性組成物及びそれを用いた基材
JP2005124743A (ja) 2003-10-22 2005-05-19 Toyo Tire & Rubber Co Ltd シート用パッド
JP2005137601A (ja) * 2003-11-06 2005-06-02 Polyplastics Co 消臭剤及び消臭性樹脂組成物
JP2005154599A (ja) 2003-11-26 2005-06-16 Mitsui Takeda Chemicals Inc 揮発アルデヒドが低減されたポリウレタンフォームの製造方法
JP2005194159A (ja) * 2004-01-09 2005-07-21 Dainippon Ink & Chem Inc 合わせガラス中間層用樹脂組成物
JP3959092B2 (ja) 2004-12-27 2007-08-15 住化バイエルウレタン株式会社 ポリウレタン成形品およびその製造方法
US20070191256A1 (en) * 2006-02-10 2007-08-16 Fossum Renae D Fabric care compositions comprising formaldehyde scavengers
EP2738192B1 (en) * 2010-07-09 2015-06-10 Air Products And Chemicals, Inc. Process for producing flexible polyurethane foam
US10066047B2 (en) 2012-02-02 2018-09-04 Covestro Llc Polyurethane foams with decreased aldehyde emissions, a process for preparing these foams and a method for decreasing aldehyde in polyurethane foams
WO2015082316A1 (de) * 2013-12-02 2015-06-11 Basf Se Polyurethane mit reduzierter aldehydemission
KR102308495B1 (ko) * 2013-12-02 2021-10-06 바스프 에스이 감소된 알데히드 방출을 지닌 폴리우레탄
RU2016134023A (ru) * 2014-01-21 2018-02-26 Басф Се Композиции для покрытия для удаления свободного формальдегида из окружающей среды
CN107531867A (zh) * 2015-04-17 2018-01-02 巴斯夫欧洲公司 具有降低的醛释放的聚氨酯
KR20170090763A (ko) * 2016-01-29 2017-08-08 현대자동차주식회사 포름알데하이드 및 아크롤레인의 방출이 저감된 폴리우레탄 폼
MX2018009401A (es) * 2016-02-05 2018-12-19 Huntsman Int Llc Metodo para la reduccion de emision de aldehidos en espuma de poliuretano.
WO2017207687A1 (de) * 2016-06-03 2017-12-07 Basf Se Polyurethane mit reduzierter aldehydemission

Also Published As

Publication number Publication date
RU2020122701A3 (es) 2022-01-20
EP3728373B1 (en) 2024-02-07
JP7195321B2 (ja) 2022-12-23
KR20200091929A (ko) 2020-07-31
WO2019119196A1 (en) 2019-06-27
BR112020010407A2 (pt) 2020-10-20
WO2019121273A1 (en) 2019-06-27
US20210221942A1 (en) 2021-07-22
CA3086084A1 (en) 2019-06-27
CN111801365B (zh) 2022-03-29
RU2020122701A (ru) 2022-01-20
US11555091B2 (en) 2023-01-17
PL3728373T3 (pl) 2024-06-03
JP2021507009A (ja) 2021-02-22
CN111801365A (zh) 2020-10-20
EP3728373A1 (en) 2020-10-28

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