MX2016004836A - Formulaciones solventes hibridas para la remocion selectiva de sulfuro de hidrogeno (h2s). - Google Patents

Formulaciones solventes hibridas para la remocion selectiva de sulfuro de hidrogeno (h2s).

Info

Publication number
MX2016004836A
MX2016004836A MX2016004836A MX2016004836A MX2016004836A MX 2016004836 A MX2016004836 A MX 2016004836A MX 2016004836 A MX2016004836 A MX 2016004836A MX 2016004836 A MX2016004836 A MX 2016004836A MX 2016004836 A MX2016004836 A MX 2016004836A
Authority
MX
Mexico
Prior art keywords
amine
selective
removal
solvent formulations
hybrid solvent
Prior art date
Application number
MX2016004836A
Other languages
English (en)
Spanish (es)
Inventor
Gerardo Padilla
John R Dowdle
Christophe R Laroche
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of MX2016004836A publication Critical patent/MX2016004836A/es

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493Selection of liquid materials for use as absorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456Removing acid components
    • B01D53/1468Removing hydrogen sulfide
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G21/00Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
    • C10G21/06Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents characterised by the solvent used
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • C10L3/101Removal of contaminants
    • C10L3/102Removal of contaminants of acid contaminants
    • C10L3/103Sulfur containing contaminants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/10Inorganic absorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/202Alcohols or their derivatives
    • B01D2252/2023Glycols, diols or their derivatives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/202Alcohols or their derivatives
    • B01D2252/2023Glycols, diols or their derivatives
    • B01D2252/2025Ethers or esters of alkylene glycols, e.g. ethylene or propylene carbonate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/204Amines
    • B01D2252/20426Secondary amines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/204Amines
    • B01D2252/20431Tertiary amines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/204Amines
    • B01D2252/20478Alkanolamines
    • B01D2252/20489Alkanolamines with two or more hydroxyl groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/205Other organic compounds not covered by B01D2252/00 - B01D2252/20494
    • B01D2252/2056Sulfur compounds, e.g. Sulfolane, thiols
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/50Combinations of absorbents
    • B01D2252/504Mixtures of two or more absorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/60Additives
    • B01D2252/606Anticorrosion agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/60Additives
    • B01D2252/608Antifoaming agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/24Hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/24Hydrocarbons
    • B01D2256/245Methane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/302Sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/304Hydrogen sulfide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/306Organic sulfur compounds, e.g. mercaptans
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/308Carbonoxysulfide COS
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/54Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
    • C10L2290/541Absorption of impurities during preparation or upgrading of a fuel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Gas Separation By Absorption (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Treating Waste Gases (AREA)
  • Industrial Gases (AREA)
MX2016004836A 2013-10-30 2014-10-24 Formulaciones solventes hibridas para la remocion selectiva de sulfuro de hidrogeno (h2s). MX2016004836A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201361897678P 2013-10-30 2013-10-30
PCT/US2014/062153 WO2015065839A1 (en) 2013-10-30 2014-10-24 Hybrid solvent formulations for selective h2s removal

Publications (1)

Publication Number Publication Date
MX2016004836A true MX2016004836A (es) 2016-07-26

Family

ID=51869047

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016004836A MX2016004836A (es) 2013-10-30 2014-10-24 Formulaciones solventes hibridas para la remocion selectiva de sulfuro de hidrogeno (h2s).

Country Status (8)

Country Link
US (1) US10226734B2 (enExample)
EP (1) EP3074488A1 (enExample)
JP (1) JP2016536389A (enExample)
CN (1) CN105637070A (enExample)
CA (1) CA2927934A1 (enExample)
EA (1) EA201690896A1 (enExample)
MX (1) MX2016004836A (enExample)
WO (1) WO2015065839A1 (enExample)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX2016004836A (es) 2013-10-30 2016-07-26 Dow Global Technologies Llc Formulaciones solventes hibridas para la remocion selectiva de sulfuro de hidrogeno (h2s).
EA201690897A1 (ru) 2013-10-30 2016-12-30 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи Композиции гибридных растворителей для полного удаления органической серы и полного удаления кислого газа
MX389571B (es) * 2014-10-10 2025-03-20 Dow Global Technologies Llc Proceso para la remocion de gases acidos de mezclas gaseosas usando una solucion acuosa de 2-dimetilamino-2-hidroximetil-1,3-propanodiol.
EP3204142A1 (en) * 2014-10-10 2017-08-16 Dow Global Technologies LLC Aqueous solution of 2-dimethylamino-2-hydroxymethyl-1, 3-propanediol useful for acid gas removal from gaseous mixtures
CA2986035C (en) * 2015-05-20 2023-08-22 Dow Global Technologies Llc An aqueous alkanolamine composition and process for the selective removal of hydrogen sulfide from gaseous mixtures
KR20180059782A (ko) * 2015-09-29 2018-06-05 바스프 에스이 황화수소를 선택적으로 제거하기 위한 흡수제 및 방법
US9962644B2 (en) 2015-12-28 2018-05-08 Exxonmobil Research And Engineering Company Process for increased selectivity and capacity for hydrogen sulfide capture from acid gases
CN107099340B (zh) * 2017-06-22 2020-07-28 山东京博石油化工有限公司 一种去除干气中丙烯的装置以及去除干气中丙烯的方法
US10633601B2 (en) * 2017-11-16 2020-04-28 Baker Hughes, A Ge Company, Llc Nitrogen-free hydrogen sulfide scavengers
CN110596318A (zh) * 2019-09-20 2019-12-20 中国石油化工股份有限公司 一种油井硫化氢总产量的确定方法
WO2022010874A1 (en) 2020-07-07 2022-01-13 Exxonmobil Research And Engineering Company Acid gas scrubbing methods featuring amine phase separation for hydrogen sulfide capture
WO2023073389A1 (en) * 2021-10-26 2023-05-04 Totalenergies Onetech Method for the purification of a gas mixture comprising carbon dioxide and optionally hydrogen sulfide
US12172125B1 (en) * 2023-07-28 2024-12-24 Susteon Inc. High performance CO2 capture solvent compositions, and CO2 capture systems and processes utilizing same

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JP6290878B2 (ja) * 2012-06-29 2018-03-07 ダウ グローバル テクノロジーズ エルエルシー ガス混合物からh2sを除去する、水性アルカノールアミン溶液及び工程
EA201690897A1 (ru) 2013-10-30 2016-12-30 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи Композиции гибридных растворителей для полного удаления органической серы и полного удаления кислого газа
MX2016004836A (es) 2013-10-30 2016-07-26 Dow Global Technologies Llc Formulaciones solventes hibridas para la remocion selectiva de sulfuro de hidrogeno (h2s).

Also Published As

Publication number Publication date
WO2015065839A8 (en) 2016-05-06
JP2016536389A (ja) 2016-11-24
CN105637070A (zh) 2016-06-01
CA2927934A1 (en) 2015-05-07
US20160271558A1 (en) 2016-09-22
EA201690896A1 (ru) 2016-12-30
US10226734B2 (en) 2019-03-12
EP3074488A1 (en) 2016-10-05
WO2015065839A1 (en) 2015-05-07

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