MX2016000550A - Metodo para fabricar aldehido insaturado y/o acido carboxilico insaturado. - Google Patents

Metodo para fabricar aldehido insaturado y/o acido carboxilico insaturado.

Info

Publication number
MX2016000550A
MX2016000550A MX2016000550A MX2016000550A MX2016000550A MX 2016000550 A MX2016000550 A MX 2016000550A MX 2016000550 A MX2016000550 A MX 2016000550A MX 2016000550 A MX2016000550 A MX 2016000550A MX 2016000550 A MX2016000550 A MX 2016000550A
Authority
MX
Mexico
Prior art keywords
carboxylic acid
unsaturated
manufacturing
unsaturated carboxylic
aldehyde
Prior art date
Application number
MX2016000550A
Other languages
English (en)
Inventor
Toru Kawaguchi
Tomoyuki Kawamura
Tatsuhiko Kurakami
Yuuta NAKAZAWA
Motohiko Sugiyama
Original Assignee
Nippon Kayaku Kk
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Kayaku Kk filed Critical Nippon Kayaku Kk
Publication of MX2016000550A publication Critical patent/MX2016000550A/es

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B61/00—Other general methods
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
    • C07C27/10—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons
    • C07C27/12—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons with oxygen
    • C07C27/14—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons with oxygen wholly gaseous reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
    • C07C47/21—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C47/22—Acryaldehyde; Methacryaldehyde
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente invención se refiere a un método para la oxidación parcial de un alqueno utilizando un reactor multitubular de lecho fijo para fabricar el aldehído insaturado y/o el ácido carboxílico insaturado correspondientes, en donde son provistas las capas múltiples del catalizador, las cuales son formadas dividiendo la dirección de flujo del gas del tubo de reacción entre N (N = 2), y cuando el cambio (°C) en la temperatura del punto caliente por un cambio de 1 °C de la temperatura del baño de la reacción en una capa del catalizador es (Sn), Sn = 6 en al menos una de las capas múltiples del catalizador.
MX2016000550A 2013-07-18 2014-07-17 Metodo para fabricar aldehido insaturado y/o acido carboxilico insaturado. MX2016000550A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2013149333 2013-07-18
PCT/JP2014/068992 WO2015008814A1 (ja) 2013-07-18 2014-07-17 不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法

Publications (1)

Publication Number Publication Date
MX2016000550A true MX2016000550A (es) 2016-04-20

Family

ID=52346257

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016000550A MX2016000550A (es) 2013-07-18 2014-07-17 Metodo para fabricar aldehido insaturado y/o acido carboxilico insaturado.

Country Status (12)

Country Link
US (1) US9580376B2 (es)
EP (1) EP3023405A4 (es)
JP (1) JP6199972B2 (es)
KR (1) KR101819465B1 (es)
CN (1) CN105392761A (es)
MX (1) MX2016000550A (es)
MY (1) MY182262A (es)
RU (1) RU2654063C2 (es)
SA (1) SA516370412B1 (es)
SG (1) SG11201600350RA (es)
TW (1) TWI585075B (es)
WO (1) WO2015008814A1 (es)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017010159A1 (ja) * 2015-07-10 2017-01-19 日本化薬株式会社 不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法
JP6752035B2 (ja) * 2016-03-29 2020-09-09 日本化薬株式会社 再スタートアップ方法
EP3769838B1 (en) 2018-03-23 2024-05-22 Mitsubishi Chemical Corporation Catalyst
US11254634B2 (en) 2018-04-10 2022-02-22 Nippon Kayaku Kabushiki Kaisha Method for producing at least one of unsaturated aldehyde and unsaturated carboxylic acid and catalyst for producing at least one of unsaturated aldehyde and unsaturated carboxylic acid
EP3950122A4 (en) * 2019-03-29 2022-12-21 Nippon Kayaku Kabushiki Kaisha DRIED PELLETS FOR CATALYST PRODUCTION, CATALYST, AND COMPOUND PRODUCTION METHOD
CN113573811B (zh) * 2019-03-29 2023-12-08 日本化药株式会社 不饱和醛的制造方法
CN113905818B (zh) 2020-01-10 2023-01-13 日本化药株式会社 催化剂、催化剂填充方法和使用催化剂的化合物制造方法
JP2020152727A (ja) * 2020-06-01 2020-09-24 日本化薬株式会社 再スタートアップ方法

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JP3139285B2 (ja) * 1994-06-20 2001-02-26 住友化学工業株式会社 アクロレインおよびアクリル酸の製造方法
JPH08336298A (ja) 1995-06-06 1996-12-17 Nippondenso Co Ltd 車両用交流発電機の制御装置
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CN1093417C (zh) * 1999-11-01 2002-10-30 何国顺 一种毛孔缩小的药物及其制备方法
US6620968B1 (en) 1999-11-23 2003-09-16 Rohm And Haas Company High hydrocarbon space velocity process for preparing unsaturated aldehydes and acids
JP4318367B2 (ja) 2000-02-16 2009-08-19 株式会社日本触媒 アクロレインおよびアクリル酸の製造方法
CN1170555C (zh) * 2000-04-11 2004-10-13 隋锡梅 一种治疗溃疡病的中成药
JP3943311B2 (ja) 2000-05-19 2007-07-11 株式会社日本触媒 不飽和アルデヒドおよび不飽和カルボン酸の製造方法
US6960684B2 (en) 2002-03-29 2005-11-01 Nippon Shokubai Co., Ltd. Production process for unsaturated aldehyde
JP3939187B2 (ja) 2002-03-29 2007-07-04 株式会社日本触媒 不飽和アルデヒドの製造方法
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JP2014019675A (ja) * 2012-07-20 2014-02-03 Nippon Kayaku Co Ltd 不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法

Also Published As

Publication number Publication date
CN105392761A (zh) 2016-03-09
TW201512164A (zh) 2015-04-01
EP3023405A4 (en) 2016-12-28
US20160145180A1 (en) 2016-05-26
SA516370412B1 (ar) 2017-11-21
JPWO2015008814A1 (ja) 2017-03-02
MY182262A (en) 2021-01-18
US9580376B2 (en) 2017-02-28
KR101819465B1 (ko) 2018-01-17
JP6199972B2 (ja) 2017-09-20
RU2654063C2 (ru) 2018-05-16
KR20160014666A (ko) 2016-02-11
SG11201600350RA (en) 2016-02-26
EP3023405A1 (en) 2016-05-25
TWI585075B (zh) 2017-06-01
WO2015008814A1 (ja) 2015-01-22
RU2016105244A (ru) 2017-08-23

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