MX2015014766A - Oligomerizacion de etileno para mezclas de 1-hexeno y 1-octeno. - Google Patents

Oligomerizacion de etileno para mezclas de 1-hexeno y 1-octeno.

Info

Publication number
MX2015014766A
MX2015014766A MX2015014766A MX2015014766A MX2015014766A MX 2015014766 A MX2015014766 A MX 2015014766A MX 2015014766 A MX2015014766 A MX 2015014766A MX 2015014766 A MX2015014766 A MX 2015014766A MX 2015014766 A MX2015014766 A MX 2015014766A
Authority
MX
Mexico
Prior art keywords
ethylene
octene
hexene
oligomerisation
mixtures
Prior art date
Application number
MX2015014766A
Other languages
English (en)
Other versions
MX364019B (es
Inventor
Matthew James Overett
Munaka Christopher Maumela
Moses Mokgolela Mogorosi
Original Assignee
Sasol Tech Pty Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sasol Tech Pty Ltd filed Critical Sasol Tech Pty Ltd
Publication of MX2015014766A publication Critical patent/MX2015014766A/es
Publication of MX364019B publication Critical patent/MX364019B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/107—Alkenes with six carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24
    • C07C2531/34—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24 of chromium, molybdenum or tungsten
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

Un proceso para la oligomerización, de preferencia la tetramerización, de etileno para predominantemente 1-hexeno o 1-octeno o mezclas de 1-hexeno y 1-octeno, incluye poner en contacto el etileno con un catalizador bajo condiciones de oligomerización de etileno. El catalizador comprende una fuente de cromo, un compuesto ligante de difosfina, y opcionalmente un activador. El compuesto ligante de difosfina incluye al menos un anillo aromático sustituido enlazado a un átomo de fósforo. El anillo aromático sustituido se sustituye en un átomo de anillo adyacente al átomo de anillo enlazado al átomo de fósforo respectivo con un grupo Y, donde Y es de la forma -AREWG, A es O, S o NR5, donde R5 es un grupo hidrocarbilo, heterohidrocarbilo u organoheterilo, y REWG es un grupo aceptor de electrones.
MX2015014766A 2013-05-09 2014-05-06 Oligomerizacion de etileno para mezclas de 1-hexeno y 1-octeno. MX364019B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ZA201303374 2013-05-09
PCT/IB2014/061233 WO2014181248A1 (en) 2013-05-09 2014-05-06 Oligomerisation of ethylene to mixtures of 1-hexene and 1-octene

Publications (2)

Publication Number Publication Date
MX2015014766A true MX2015014766A (es) 2016-03-11
MX364019B MX364019B (es) 2019-04-11

Family

ID=50842292

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015014766A MX364019B (es) 2013-05-09 2014-05-06 Oligomerizacion de etileno para mezclas de 1-hexeno y 1-octeno.

Country Status (11)

Country Link
US (1) US9533923B2 (es)
EP (1) EP2994445B1 (es)
KR (3) KR20220151023A (es)
CN (1) CN105228974B (es)
BR (1) BR112015027178A2 (es)
CA (1) CA2908588C (es)
MX (1) MX364019B (es)
MY (1) MY174705A (es)
SG (1) SG11201508464XA (es)
WO (1) WO2014181248A1 (es)
ZA (1) ZA201507329B (es)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016129901A1 (ko) * 2015-02-12 2016-08-18 주식회사 엘지화학 올레핀 올리고머화 방법
KR101679515B1 (ko) 2015-02-12 2016-11-24 주식회사 엘지화학 올리고머화 촉매계의 제조방법 및 이에 의해 제조된 올리고머화 촉매계
JP6871358B2 (ja) * 2016-07-15 2021-05-12 パブリック・ジョイント・ストック・カンパニー・“シブール・ホールディング” オレフィンのオリゴマー化法
KR102450815B1 (ko) 2017-06-16 2022-10-05 에스케이이노베이션 주식회사 헤테로원자 리간드, 이를 포함하는 올리고머화 촉매 및 올리고머 제조방법
KR102605188B1 (ko) 2018-02-27 2023-11-24 에스케이이노베이션 주식회사 리간드, 이를 포함하는 올리고머화 촉매 및 이를 이용한 에틸렌 올리고머의 제조방법
US10947324B2 (en) 2019-03-13 2021-03-16 Tpc Group Llc Flexible manufacturing system for selectively producing different linear alpha olefins
US11946000B2 (en) 2019-05-24 2024-04-02 Eastman Chemical Company Blend small amounts of pyoil into a liquid stream processed into a gas cracker
US11945998B2 (en) 2019-10-31 2024-04-02 Eastman Chemical Company Processes and systems for making recycle content hydrocarbons
EP4054997A4 (en) * 2019-11-07 2024-02-21 Eastman Chem Co ALPHA-OLEFINS AND FAT ALCOHOLS WITH RECYCLING CONTENT
CN116328837A (zh) * 2021-12-24 2023-06-27 中国石油化工股份有限公司 一种乙烯齐聚催化剂组合物及应用
CN116328836A (zh) * 2021-12-24 2023-06-27 中国石油化工股份有限公司 多孔有机聚合物负载型乙烯聚合主催化剂及乙烯聚合催化剂组合物及应用

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG112883A1 (en) 1992-09-17 2005-07-28 Mitsubishi Chem Corp Method for oligomerizing an alpha-olefin
TW354300B (en) 1993-02-17 1999-03-11 Mitsubishi Chem Corp Process for producing <alpha>-olefin oligomers
US5910619A (en) 1994-06-21 1999-06-08 Mitsubishi Chemical Corporation Process for producing α-olefin oligomers
US5856257A (en) 1997-05-16 1999-01-05 Phillips Petroleum Company Olefin production
DE10032395A1 (de) 2000-07-06 2002-01-17 Zeiss Carl Jena Gmbh Erkennung des Maximalposition eines Revolvers oder Schiebers in Mikroskopen
GB0016895D0 (en) 2000-07-11 2000-08-30 Bp Chem Int Ltd Olefin oligomerisation
JP2006516265A (ja) 2002-12-20 2006-06-29 サソル テクノロジー （ピーティーワイ） リミテッド オレフィンの三量体化
US7323524B2 (en) 2002-12-20 2008-01-29 Sasol Technology (Pty) Limited Tandem tetramerisation-polymerisation of olefins
US7414006B2 (en) 2005-03-09 2008-08-19 Exxonmobil Chemical Patents Inc. Methods for oligomerizing olefins
CN101248029B (zh) 2005-07-12 2012-06-27 Sasol技术股份有限公司 在稀释的含金属的活化剂存在下烯属化合物的低聚反应
GB0520085D0 (en) 2005-10-03 2005-11-09 Sasol Tech Pty Ltd Oligomerisation of olefinic compounds in the presence of an oligomerisation catalyst, and a catalyst activator including a halogenated -AR group
WO2007088329A1 (en) 2006-02-03 2007-08-09 Ineos Europe Limited Transition metal catalysts
US7378537B2 (en) 2006-07-25 2008-05-27 Chevron Phillips Chemical Company Lp Olefin oligomerization catalysts and methods of using same
KR101074202B1 (ko) 2007-01-18 2011-10-14 에스케이종합화학 주식회사 에틸렌 사량체화 촉매계 및 이를 이용한 1-옥텐의 제조방법
CA2583007C (en) 2007-03-29 2015-03-31 Nova Chemicals Corporation Amino phosphine
CN101687189A (zh) 2007-05-28 2010-03-31 Sasol技术股份有限公司 低聚催化剂的两段活化和在如此活化的低聚催化剂的存在下烯属化合物的低聚
WO2009006979A2 (en) * 2007-07-11 2009-01-15 Linde Ag Catalyst composition and process for di-, tri- and/or tetramerization of ethylene
KR101057576B1 (ko) 2007-08-16 2011-08-17 에스케이종합화학 주식회사 선택적 에틸렌 올리머고화 촉매계
KR100942978B1 (ko) 2008-07-10 2010-02-17 주식회사 하이닉스반도체 반도체 메모리 소자
MY156607A (en) 2009-02-16 2016-03-15 Sasol Tech Pty Ltd Oligomerisation of olefinic compounds in the presence of an activated oligomerisation catalyst
US8859696B2 (en) 2009-10-19 2014-10-14 Sasol Technology (Pty) Limited Oligomerisation of olefinic compounds with reduced polymer formation
CA2703435C (en) 2010-05-12 2017-05-02 Nova Chemicals Corporation Oligomerization process using a chromium p-n-p catalyst with added alkyl zinc
WO2012034101A2 (en) 2010-09-09 2012-03-15 The Regents Of The University Of California Expandable cell source of neuronal stem cell populations and methods for obtaining and using them
CA2723515C (en) 2010-12-01 2018-05-15 Nova Chemicals Corporation Heat management in ethylene oligomerization
SG11201508461RA (en) * 2013-05-09 2015-11-27 Sasol Tech Pty Ltd Oligomerisation of ethylene to mixtures of 1-hexene and 1-octene

Also Published As

Publication number Publication date
SG11201508464XA (en) 2015-11-27
MX364019B (es) 2019-04-11
EP2994445A1 (en) 2016-03-16
US20160083312A1 (en) 2016-03-24
KR20220151023A (ko) 2022-11-11
MY174705A (en) 2020-05-08
BR112015027178A2 (pt) 2017-07-25
CA2908588C (en) 2021-08-17
KR20210043726A (ko) 2021-04-21
CN105228974B (zh) 2021-01-19
CA2908588A1 (en) 2014-11-13
WO2014181248A1 (en) 2014-11-13
KR20160006192A (ko) 2016-01-18
US9533923B2 (en) 2017-01-03
ZA201507329B (en) 2017-01-25
EP2994445B1 (en) 2023-05-24
CN105228974A (zh) 2016-01-06

Similar Documents

Publication Publication Date Title
MX2015014766A (es) Oligomerizacion de etileno para mezclas de 1-hexeno y 1-octeno.
WO2016149024A3 (en) Chromium complex with a phosphacycle-containing ligand and olefin oligomerisation catalyst therefrom
MY173996A (en) Oligomerisation of ethylene to mixtures of 1-hexene and 1-octene
SA519401701B1 (ar) مركب كروم، ونظام محفز باستخدامه، وطريقة لتحضير أوليجومر إيثيلين
MX2016002748A (es) Regeneracion de un catalizador heterogeneo utilizado en la oligomerizacion del eteno.
IN2014DN05988A (es)
MX2016008029A (es) Procatalizador para polimerizacion de olefinas.
CL2012001681A1 (es) Compuestos n2-fosfinil amidina; complejos metalicos; sistemas catalizadores; metodos de preparacion; y su uso para oligomerizar o polimerizar olefinas.
BR112016018423A2 (pt) Polímero
EA201590400A1 (ru) Превращение природного газа в органические соединения
MX2016000507A (es) Preparacion combinada de al menos buteno y octeno a partir de eteno.
MY179457A (en) Tetramerisation of ethylene
EA201691268A1 (ru) Каталитическая система для полимеризации олефинов
MX2019003030A (es) Catalizador que contiene ni para la oligomerizacion de olefinas.
EP2918340A4 (en) LIGAND COMPOUND, OLEFIN OLIGOMERIZATION CATALYTIC SYSTEM, AND OLEFIN OLIGOMERIZATION METHOD USING THE SAME
WO2019168249A8 (ko) 리간드, 이를 포함하는 올리고머화 촉매 및 이를 이용한 에틸렌 올리고머의 제조방법
EA034784B9 (ru) Прокатализатор для полимеризации олефинов
AR110555A1 (es) Procedimiento de neutralización de un sistema catalítico de dimerización de olefinas que contienen al menos un derivado halogenado
EP3345913A4 (en) Ligand compound, organic chromium compound, catalyst system for oligomerizing olefin, and method for oligomerizing olefin using same
MY171855A (en) Metalated ligand, catalyst composition, and use thereof in the oligomerization of ethylene
MX2022006139A (es) Reactor de oligomerizacion gas/liquido que tiene zonas sucesivas de diametro variable.
MY190667A (en) Process for oligomerization with stage-customized exchange of the oligomerization catalyst
WO2011085951A8 (en) Oligomerization of olefins
MX2017004615A (es) Catalizador para produccion en fase gaseosa de acidos carboxilicos.
WO2017013062A3 (en) Catalytic ethenolysis of optionally-functionalized internal unsaturated olefins

Legal Events

Date Code Title Description
FG Grant or registration