MX2012009238A - Procedimiento para la alilar y vinilar halogenuros de arilo, heteroarilo, alquilo y alqueno usando catalisis de metales de transicion. - Google Patents

Procedimiento para la alilar y vinilar halogenuros de arilo, heteroarilo, alquilo y alqueno usando catalisis de metales de transicion.

Info

Publication number
MX2012009238A
MX2012009238A MX2012009238A MX2012009238A MX2012009238A MX 2012009238 A MX2012009238 A MX 2012009238A MX 2012009238 A MX2012009238 A MX 2012009238A MX 2012009238 A MX2012009238 A MX 2012009238A MX 2012009238 A MX2012009238 A MX 2012009238A
Authority
MX
Mexico
Prior art keywords
general formula
compound
vinylating
allylating
halogenides
Prior art date
Application number
MX2012009238A
Other languages
English (en)
Inventor
Matthias Gotta
Bernd Wilhelm Lehnemann
Waldemar Maximilian Czaplik
Matthias Mayer
Von Wangelin Axel Jacobi
Original Assignee
Saltigo Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saltigo Gmbh filed Critical Saltigo Gmbh
Publication of MX2012009238A publication Critical patent/MX2012009238A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/04—Preparation of carboxylic acid nitriles by reaction of cyanogen halides, e.g. ClCN, with organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B37/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving either the formation of a carbon-to-carbon bond between two carbon atoms not directly linked already or the disconnection of two directly linked carbon atoms
    • C07B37/04—Substitution
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B49/00—Grignard reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/26—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms
    • C07C1/30—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms by splitting-off the elements of hydrogen halide from a single molecule
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C07C1/325—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a metal atom
    • C07C1/326—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a metal atom the hetero-atom being a magnesium atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/263—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions
    • C07C17/2632—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions involving an organo-magnesium compound, e.g. Grignard synthesis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
    • C07C209/74—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by halogenation, hydrohalogenation, dehalogenation, or dehydrohalogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
    • C07C41/24—Preparation of ethers by reactions not forming ether-oxygen bonds by elimination of halogens, e.g. elimination of HCl
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
    • C07C41/30—Preparation of ethers by reactions not forming ether-oxygen bonds by increasing the number of carbon atoms, e.g. by oligomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/128—Compounds comprising a halogen and an iron group metal or a platinum group metal
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/02—Ortho- or ortho- and peri-condensed systems
    • C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
    • C07C2603/22—Ortho- or ortho- and peri-condensed systems containing three rings containing only six-membered rings
    • C07C2603/26—Phenanthrenes; Hydrogenated phenanthrenes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pyridine Compounds (AREA)

Abstract

La invención se refiere a un método para producir compuestos orgánicos de la fórmula general (I) R-R' (I), haciendo reaccionar un compuesto correspondiente de la fórmula general (II) R-X(H), donde X representa flúor, cloro, bromo, o yodo, formando un compuesto de magnesio orgánico de la fórmula general (III) [M+]n [RmMgXkYl] (III), los compuestos de la fórmula (III) se hace reaccionar con un compuesto de la fórmula general (IV), caracterizado porque el reacción de (III) con (IV) se lleva a cabo en presencia de a) una cantidad catalítica de un compuesto de hierro, en relación con el compuesto de la fórmula general (II), y opcionalmente en presencia de b) un aditivo que comprende nitrógeno, oxígeno , y / o fósforo en una cantidad catalítica o estequiométrica con respecto al compuesto de la fórmula general (II).
MX2012009238A 2010-02-09 2011-02-01 Procedimiento para la alilar y vinilar halogenuros de arilo, heteroarilo, alquilo y alqueno usando catalisis de metales de transicion. MX2012009238A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102010007226 2010-02-09
PCT/EP2011/051390 WO2011098375A2 (de) 2010-02-09 2011-02-01 Verfahren zur allylierung und vinylierung von aryl-, heteroaryl-, alkyl- und alkenylhalogeniden unter übergangsmetallkatalyse

Publications (1)

Publication Number Publication Date
MX2012009238A true MX2012009238A (es) 2012-12-05

Family

ID=44080124

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2012009238A MX2012009238A (es) 2010-02-09 2011-02-01 Procedimiento para la alilar y vinilar halogenuros de arilo, heteroarilo, alquilo y alqueno usando catalisis de metales de transicion.

Country Status (9)

Country Link
US (1) US9309188B2 (es)
EP (1) EP2534117A2 (es)
JP (1) JP5540117B2 (es)
KR (1) KR101536041B1 (es)
AU (1) AU2011214483A1 (es)
BR (1) BR112012019976A2 (es)
CA (1) CA2789079A1 (es)
MX (1) MX2012009238A (es)
WO (1) WO2011098375A2 (es)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016043079A1 (ja) * 2014-09-19 2016-03-24 東レ・ファインケミカル株式会社 ２'－トリフルオロメチル基置換芳香族ケトンの製造方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4423691B2 (ja) * 1998-01-30 2010-03-03 東ソー株式会社 スチレン誘導体の製造方法
US7026478B2 (en) * 2002-05-10 2006-04-11 Studiengesellschaft Kohle Mbh Iron catalyzed cross coupling reactions of aromatic compounds
CA2555453C (en) 2004-02-10 2013-04-09 Japan Science And Technology Agency Cross-coupling process for production of aromatic compounds from aliphatic organic compounds and aromatic organometallic reagents
EP1582523A1 (en) * 2004-04-02 2005-10-05 Ludwig-Maximilians-Universität München Method of preparing organomagnesium compounds
JP2007119379A (ja) * 2005-10-26 2007-05-17 Tosoh Corp ジハロゲン化ビフェニル類の製造方法
EP1889849A1 (en) 2006-07-18 2008-02-20 Lonza Ag Grignard reactions in microreactors
US8030520B2 (en) * 2008-03-31 2011-10-04 Saltigo Gmbh Process for preparing organic compounds by a transition metal-catalysed cross-coupling reaction of an aryl-X, heteroaryl-X, cycloalkenyl-X or alkenyl-X compound with an alkyl, alkenyl, cycloalkyl or cycloalkenyl halide
CN101318896B (zh) * 2008-07-03 2011-02-16 浙江大学 合成顺式α-烯丙基-β,γ-不饱和羧酸酯的方法
JP5131772B2 (ja) * 2008-10-31 2013-01-30 国立大学法人九州大学 ビニル化合物の製造方法
CA2755147A1 (en) * 2011-10-14 2013-04-14 University Of Prince Edward Island Iron bisphenolate complexes and methods of use and synthesis thereof
EP2671866A1 (de) * 2012-06-04 2013-12-11 Saltigo GmbH Verfahren zur Herstellung von Styrolderivaten

Also Published As

Publication number Publication date
JP5540117B2 (ja) 2014-07-02
WO2011098375A2 (de) 2011-08-18
US9309188B2 (en) 2016-04-12
JP2013518919A (ja) 2013-05-23
WO2011098375A3 (de) 2011-10-13
CA2789079A1 (en) 2011-08-18
AU2011214483A1 (en) 2012-09-20
EP2534117A2 (de) 2012-12-19
US20130184485A1 (en) 2013-07-18
KR101536041B1 (ko) 2015-07-10
BR112012019976A2 (pt) 2016-05-03
KR20120115577A (ko) 2012-10-18

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