MX2012007272A - Procedimiento de sintesis de una resina polimerica base agua podapa con nanotubos de dioxido de titanio con aplicacion como recubrimiento anticorrosivo. - Google Patents

Procedimiento de sintesis de una resina polimerica base agua podapa con nanotubos de dioxido de titanio con aplicacion como recubrimiento anticorrosivo.

Info

Publication number
MX2012007272A
MX2012007272A MX2012007272A MX2012007272A MX2012007272A MX 2012007272 A MX2012007272 A MX 2012007272A MX 2012007272 A MX2012007272 A MX 2012007272A MX 2012007272 A MX2012007272 A MX 2012007272A MX 2012007272 A MX2012007272 A MX 2012007272A
Authority
MX
Mexico
Prior art keywords
polymeric
synthesis
titanium dioxide
water
dioxide nanotubes
Prior art date
Application number
MX2012007272A
Other languages
English (en)
Inventor
Gerardo Ferrat Torres
Jose Antonio Toledo Antonio
Flavio Salvador Vazquez Moreno
Rosa Del Carmen Montesinos Gomez
Lizbeth Pliego Vences
Nancy Romero Hernandez
Cesar Andres Flores Sandoval
Fernando Alvarez Ramirez
Original Assignee
Mexicano Inst Petrol
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mexicano Inst Petrol filed Critical Mexicano Inst Petrol
Priority to MX2012007272A priority Critical patent/MX2012007272A/es
Priority to US13/922,909 priority patent/US9371588B2/en
Priority to BRBR102013015790-2A priority patent/BR102013015790A2/pt
Publication of MX2012007272A publication Critical patent/MX2012007272A/es
Priority to US15/158,942 priority patent/US9738793B2/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
    • C09D5/084—Inorganic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/10—Homopolymers or copolymers of methacrylic acid esters
    • C09D133/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C23F11/173—Macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/08—Ingredients agglomerated by treatment with a binding agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

La presente invención está relacionada con la aplicación de resinas poliméricas y resinas poliméricas dopadas con TiO2 como recubrimientos para superficies metálicas externas de uso industrial, principalmente, seleccionando a los siguientes metales: acero inoxidable, acero al carbón y cobre. Específicamente se enfoca en la síntesis de una resina polimérica anticorrosiva base agua, consistente en partículas poliméricas nano-estructuradas formadas con 2 o más monómeros acrílico, vinilico ó estirénico con un agente funcionalizante y un agente entrecruzante de 1.0 a 20 % p. de cada uno. Además se realiza el dopaje de las mismas resinas poliméricas, en las cuales se incorporan nanotubos de dióxido de titanio en concentraciones en el intervalo de 50 a 10,000 ppm. La resina polimérica anticorrosiva base agua es sintetizada mediante técnicas de polimerización en emulsión y es durante el proceso de síntesis que se introduce la carga de nanotubos de dióxido de titanio (los cuales son sintetizados de acuerdo a la patente US 7, 645,439 B2), lo que permite su dispersión en la matriz polimérica. Las dispersiones poliméricas obtenidas de esta manera son utilizadas como recubrimientos anticorrosivos 100% base agua.
MX2012007272A 2012-06-21 2012-06-21 Procedimiento de sintesis de una resina polimerica base agua podapa con nanotubos de dioxido de titanio con aplicacion como recubrimiento anticorrosivo. MX2012007272A (es)

Priority Applications (4)

Application Number Priority Date Filing Date Title
MX2012007272A MX2012007272A (es) 2012-06-21 2012-06-21 Procedimiento de sintesis de una resina polimerica base agua podapa con nanotubos de dioxido de titanio con aplicacion como recubrimiento anticorrosivo.
US13/922,909 US9371588B2 (en) 2012-06-21 2013-06-20 Procedure summary of water-based polymer resin doped titanium dioxide nanotubes as application corrosion coating
BRBR102013015790-2A BR102013015790A2 (pt) 2012-06-21 2013-06-21 Procedimento de síntese homogênea ou estruturada para a obtenção de uma resina polimérica anticorrosiva, resina polimérica anticorrosiva e uso da mesma
US15/158,942 US9738793B2 (en) 2012-06-21 2016-05-19 Procedure summary of water-based polymer resin doped titanium dioxide nanotubes as application corrosion coating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
MX2012007272A MX2012007272A (es) 2012-06-21 2012-06-21 Procedimiento de sintesis de una resina polimerica base agua podapa con nanotubos de dioxido de titanio con aplicacion como recubrimiento anticorrosivo.

Publications (1)

Publication Number Publication Date
MX2012007272A true MX2012007272A (es) 2013-12-23

Family

ID=50026078

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2012007272A MX2012007272A (es) 2012-06-21 2012-06-21 Procedimiento de sintesis de una resina polimerica base agua podapa con nanotubos de dioxido de titanio con aplicacion como recubrimiento anticorrosivo.

Country Status (3)

Country Link
US (2) US9371588B2 (es)
BR (1) BR102013015790A2 (es)
MX (1) MX2012007272A (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX2012007272A (es) * 2012-06-21 2013-12-23 Mexicano Inst Petrol Procedimiento de sintesis de una resina polimerica base agua podapa con nanotubos de dioxido de titanio con aplicacion como recubrimiento anticorrosivo.
CN109777232B (zh) * 2019-01-07 2020-04-03 海洋化工研究院有限公司 一种水性改性丙烯酸防腐涂料及其制备方法
CN112251089A (zh) * 2020-09-07 2021-01-22 杭州圣艾侬壁布有限公司 一种环保水性珍珠壁布及其制备方法

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Also Published As

Publication number Publication date
US9371588B2 (en) 2016-06-21
BR102013015790A2 (pt) 2015-08-18
US20140039092A1 (en) 2014-02-06
US9738793B2 (en) 2017-08-22
US20160272819A1 (en) 2016-09-22

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